CN108504380B - 塑料转化为烯烃和芳族产物 - Google Patents
塑料转化为烯烃和芳族产物 Download PDFInfo
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- CN108504380B CN108504380B CN201810273452.5A CN201810273452A CN108504380B CN 108504380 B CN108504380 B CN 108504380B CN 201810273452 A CN201810273452 A CN 201810273452A CN 108504380 B CN108504380 B CN 108504380B
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- Prior art keywords
- catalyst
- zeolite
- catalytic cracking
- zsm
- fluidized catalytic
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- 150000001336 alkenes Chemical class 0.000 title claims abstract description 46
- 125000003118 aryl group Chemical group 0.000 title abstract description 8
- 239000003054 catalyst Substances 0.000 claims abstract description 359
- 239000010457 zeolite Substances 0.000 claims abstract description 183
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 176
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 175
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 53
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- 239000010452 phosphate Substances 0.000 claims description 7
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 6
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- 239000004575 stone Substances 0.000 claims description 6
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- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 claims description 5
- 239000002808 molecular sieve Substances 0.000 claims description 4
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 4
- 238000004523 catalytic cracking Methods 0.000 claims 29
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 13
- 238000000197 pyrolysis Methods 0.000 description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 11
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- 238000004230 steam cracking Methods 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
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- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000003483 aging Methods 0.000 description 1
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- 239000001273 butane Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
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- 150000002148 esters Chemical class 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
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- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
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- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
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- 229920000620 organic polymer Polymers 0.000 description 1
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- 229910052698 phosphorus Inorganic materials 0.000 description 1
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052649 zeolite group Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/80—Mixtures of different zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J2029/062—Mixtures of different aluminosilicates
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/764,886 | 2013-02-12 | ||
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Families Citing this family (109)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9428695B2 (en) * | 2013-02-12 | 2016-08-30 | Saudi Basic Industries Corporation | Conversion of plastics to olefin and aromatic products with product recycle |
| WO2016142806A1 (en) | 2015-03-10 | 2016-09-15 | Sabic Global Technologies, B.V. | Process for hydrocracking of hydrocarbon streams and pyrolysis oils |
| WO2016142807A1 (en) | 2015-03-10 | 2016-09-15 | Sabic Global Technologies, B.V. | Process for preparation of hydrocracking catalyst for use in hydrocracking of hydrocarbon streams |
| WO2016142805A1 (en) | 2015-03-10 | 2016-09-15 | Sabic Global Technologies, B.V. | Process for dechlorination of hydrocarbon streams and pyrolysis oils |
| US10703977B2 (en) | 2015-10-05 | 2020-07-07 | Uop Llc | Processes for reducing the energy consumption of a catalytic cracking process |
| US10647922B2 (en) * | 2015-12-18 | 2020-05-12 | Solvay Sa | Use of a catalyst composition for the catalytic depolymerization of plastics waste |
| EP3390575A1 (en) | 2015-12-18 | 2018-10-24 | Solvay Sa | Process for continuously converting mixed waste plastic into waxes and liquid fuels by cracking |
| WO2017103012A1 (en) * | 2015-12-18 | 2017-06-22 | Solvay Sa | Use of a catalyst composition for the catalytic depolymerization of plastics waste |
| CA3017821A1 (en) * | 2016-03-23 | 2017-09-28 | Inaeris Technologies, Llc | Catalyst containing phosphated kaolin and alumina from ach and method of using the same |
| US9981888B2 (en) | 2016-06-23 | 2018-05-29 | Saudi Arabian Oil Company | Processes for high severity fluid catalytic cracking systems |
| US10442997B2 (en) * | 2016-06-29 | 2019-10-15 | Sabic Global Technologies B.V. | Plastic pyrolysis |
| US10865348B2 (en) | 2016-07-13 | 2020-12-15 | Sabic Global Technologies B.V. | Process which does simultaneous dehydrochlorination and hydrocracking of pyrolysis oils from mixed plastic pyrolysis while achieving selective hydrodealkylation of C9+ aromatics |
| CN106216357B (zh) * | 2016-07-29 | 2018-11-23 | 陈佳男 | 一种聚苯乙烯塑料垃圾处理方法 |
| CN109563414B (zh) | 2016-08-01 | 2021-07-27 | 沙特基础全球技术有限公司 | 使用脱挥挤出和氯化物清除剂对混合塑料热解油的脱氯 |
| WO2018055555A1 (en) | 2016-09-22 | 2018-03-29 | Sabic Global Technologies, B.V. | An integrated process configuration involving the steps of pyrolysis, hydrocracking, hydrodealkylation and steam cracking |
| CN107032367B (zh) * | 2016-12-08 | 2019-01-15 | 安顺学院 | 一种利用原位碳化模板合成有序介孔zsm-5的方法 |
| JP7065372B2 (ja) | 2017-01-05 | 2022-05-12 | サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ | 廃棄プラスチックの熱分解によるベンゼンおよびキシレン類のような高価値産物への変換 |
| JP7051873B2 (ja) | 2017-01-05 | 2022-04-11 | サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ | 廃棄プラスチックのプロピレンおよびクメンへの変換 |
| CN110139846B (zh) | 2017-01-05 | 2022-07-01 | 沙特基础全球技术有限公司 | 废塑料向丙烯和枯烯的转化 |
| US10870802B2 (en) | 2017-05-31 | 2020-12-22 | Saudi Arabian Oil Company | High-severity fluidized catalytic cracking systems and processes having partial catalyst recycle |
| US10889768B2 (en) | 2018-01-25 | 2021-01-12 | Saudi Arabian Oil Company | High severity fluidized catalytic cracking systems and processes for producing olefins from petroleum feeds |
| JP7085923B2 (ja) * | 2018-07-05 | 2022-06-17 | 三菱電機株式会社 | 再生スチレン系樹脂組成物 |
| WO2020152329A1 (en) * | 2019-01-24 | 2020-07-30 | Sabic Global Technologies B.V. | Process for the preparation of polymers from waste plastic feedstocks |
| US12234412B2 (en) | 2019-05-14 | 2025-02-25 | Anellotech, Inc. | Olefin and aromatics production by the catalytic pyrolysis of polymers |
| US11365357B2 (en) | 2019-05-24 | 2022-06-21 | Eastman Chemical Company | Cracking C8+ fraction of pyoil |
| US11946000B2 (en) | 2019-05-24 | 2024-04-02 | Eastman Chemical Company | Blend small amounts of pyoil into a liquid stream processed into a gas cracker |
| CN113891928B (zh) | 2019-05-24 | 2024-10-29 | 伊士曼化工公司 | 裂化热解油的c4-c7馏分 |
| US12497467B2 (en) | 2019-05-24 | 2025-12-16 | Exxon Mobil Product Solutions Company | Recycle content cellulose ester |
| WO2020242920A1 (en) | 2019-05-24 | 2020-12-03 | Eastman Chemical Company | Thermal pyoil to a gas fed cracker furnace |
| US12031091B2 (en) | 2019-05-24 | 2024-07-09 | Eastman Chemical Company | Recycle content cracked effluent |
| SG11202112958PA (en) | 2019-06-13 | 2021-12-30 | Exxonmobil Chemical Patents Inc | Light olefin recovery from plastic waste pyrolysis |
| EP3996841A4 (en) * | 2019-07-10 | 2023-08-09 | W. R. Grace & Co.-Conn | Fluidized cracking process for increasing olefin yield and catalyst composition for same |
| CN119912669A (zh) | 2019-07-29 | 2025-05-02 | 伊士曼化工公司 | 回收成分环丁二醇聚酯 |
| US20220281796A1 (en) * | 2019-07-29 | 2022-09-08 | Eastman Chemical Company | Recycle content (c4)alkanoic acid |
| US12338211B2 (en) | 2019-07-29 | 2025-06-24 | Eastman Chemical Company | Recycle content (C4)alkanal |
| US11466218B2 (en) | 2019-09-05 | 2022-10-11 | Molecule Works Inc. | Catalytic reactor apparatus for conversion of plastics |
| WO2021048351A2 (en) | 2019-09-11 | 2021-03-18 | Michiel Cramwinckel | Process to convert a waste polymer product to a gaseous product |
| EP4051762A4 (en) | 2019-10-31 | 2023-12-27 | Eastman Chemical Company | PYROLYSIS PROCESS AND SYSTEM FOR RECYCLED WASTE |
| US11945998B2 (en) | 2019-10-31 | 2024-04-02 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
| US12528995B2 (en) | 2019-10-31 | 2026-01-20 | ExxonMobil Product Solutions Company | Pyrolysis method and system for recycled waste |
| US11319262B2 (en) | 2019-10-31 | 2022-05-03 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
| US12173237B2 (en) | 2019-10-31 | 2024-12-24 | Eastman Chemical Company | Processes and systems for formation of recycle-content hydrocarbon compositions |
| KR20220091569A (ko) | 2019-10-31 | 2022-06-30 | 이스트만 케미칼 컴파니 | 재활용물 탄화수소 조성물의 생성을 위한 방법 및 시스템 |
| EP4055001A4 (en) | 2019-11-07 | 2024-02-14 | Eastman Chemical Company | MIXED ESTERS AND SOLVENTS WITH RECYCLED CONTENTS |
| CN118851872A (zh) | 2019-11-07 | 2024-10-29 | 伊士曼化工公司 | 回收成分丙醇 |
| CN114728868B (zh) | 2019-11-07 | 2024-09-03 | 伊士曼化工公司 | 回收成分羰基合成醇和羰基合成增塑剂 |
| KR20220097485A (ko) | 2019-11-07 | 2022-07-07 | 이스트만 케미칼 컴파니 | 재활용물 옥소 글리콜 |
| US11939534B2 (en) | 2019-11-07 | 2024-03-26 | Eastman Chemical Company | Recycle content alpha olefins and fatty alcohols |
| US11066605B2 (en) | 2019-11-12 | 2021-07-20 | Saudi Arabian Oil Company | Systems and methods for catalytic upgrading of vacuum residue to distillate fractions and olefins |
| US11066606B2 (en) | 2019-11-12 | 2021-07-20 | Saudi Arabian Oil Company | Systems and methods for catalytic upgrading of vacuum residue to distillate fractions and olefins with steam |
| FR3104604B1 (fr) * | 2019-12-16 | 2022-04-22 | Ifp Energies Now | Dispositif et procédé de production d’oléfines légères et d’aromatiques par craquage catalytique. |
| EP4081618A4 (en) * | 2019-12-23 | 2024-01-03 | Chevron U.S.A. Inc. | CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYPROPYLENE VIA FCC REFINERY UNIT |
| JP7623380B2 (ja) | 2019-12-23 | 2025-01-28 | シェブロン ユー．エス．エー． インコーポレイテッド | 精製ｆｃｃ及び異性化脱ろうユニットを介したポリプロピレン及び潤滑油への廃プラスチックのサーキュラーエコノミー |
| US11104851B2 (en) | 2020-01-29 | 2021-08-31 | Saudi Arabian Oil Company | Method and process for depolymerization of a plastic polymer |
| NL2027029B1 (en) | 2020-12-03 | 2022-07-06 | Cramwinckel Michiel | Suspension of a waste plastic and a vacuum gas oil |
| EP3878926A1 (en) | 2020-03-09 | 2021-09-15 | Michiel Cramwinckel | Suspension of a waste plastic and a vacuum gas oil, its preparation and use in fcc |
| FI4133028T3 (fi) | 2020-04-07 | 2024-09-17 | Totalenergies Onetech Belgium | Jätemuovipohjaisen öljyn jalostaminen arvokkaiksi kemikaaleiksi suoralla katalyyttisellä krakkauksella |
| KR20230004715A (ko) * | 2020-04-22 | 2023-01-06 | 셰브런 유.에스.에이.인크. | 열분해 오일의 여과 및 금속 산화물 처리가 있는 오일 정제를 통한 플라스틱 폐기물의 폴리프로필렌으로의 순환 경제 |
| MX2022012745A (es) * | 2020-04-22 | 2022-11-08 | Chevron Usa Inc | Economia circular de residuos plasticos a polietileno mediante una refineria de aceite con filtracion y tratamiento con oxido metalico del aceite de pirolisis. |
| WO2021216281A1 (en) | 2020-04-23 | 2021-10-28 | Exxonmobil Chemical Patents Inc. | Fluidized bed plastic waste pyrolysis with screw feeder |
| WO2021216285A1 (en) | 2020-04-23 | 2021-10-28 | Exxonmobil Chemical Patents Inc. | Fluidized bed plastic waste pyrolysis with pneumatic feeder |
| EP4139421A1 (en) | 2020-04-23 | 2023-03-01 | ExxonMobil Chemical Patents Inc. | Fluidized bed plastic waste pyrolysis with melt extruder |
| US12305126B2 (en) | 2020-06-18 | 2025-05-20 | University Of Delaware | Hydrocracking catalysts and uses thereof |
| US11446645B2 (en) * | 2020-07-02 | 2022-09-20 | Saudi Arabian Oil Company | FCC catalyst compositions for fluid catalytic cracking and methods of using the FCC catalyst compositions |
| EP4185662A1 (en) | 2020-07-23 | 2023-05-31 | ExxonMobil Chemical Patents Inc. | Plastic waste pyrolysis with liquid recycle |
| FI130263B (en) * | 2020-08-20 | 2023-05-19 | Teknologian Tutkimuskeskus Vtt Oy | Method and process arrangement for producing hydrocarbons and use |
| KR20230054399A (ko) | 2020-08-20 | 2023-04-24 | 스미또모 가가꾸 가부시끼가이샤 | 올레핀의 제조 방법 |
| US11230672B1 (en) | 2020-09-01 | 2022-01-25 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking |
| US11230673B1 (en) | 2020-09-01 | 2022-01-25 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking of a lesser boiling point fraction with steam |
| US11505754B2 (en) | 2020-09-01 | 2022-11-22 | Saudi Arabian Oil Company | Processes for producing petrochemical products from atmospheric residues |
| US11352575B2 (en) | 2020-09-01 | 2022-06-07 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize hydrotreating of cycle oil |
| US11332680B2 (en) | 2020-09-01 | 2022-05-17 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking of lesser and greater boiling point fractions with steam |
| US11242493B1 (en) | 2020-09-01 | 2022-02-08 | Saudi Arabian Oil Company | Methods for processing crude oils to form light olefins |
| US11434432B2 (en) | 2020-09-01 | 2022-09-06 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking of a greater boiling point fraction with steam |
| US11518942B2 (en) | 2020-09-28 | 2022-12-06 | Chevron Phillips Chemical Company Lp | Circular chemicals or polymers from pyrolyzed plastic waste and the use of mass balance accounting to allow for crediting the resultant products as circular |
| CN114507113B (zh) * | 2020-10-28 | 2024-03-12 | 中国石油化工股份有限公司 | 一种废塑料制备乙烯、丙烯的方法和系统 |
| US12404464B2 (en) | 2020-12-10 | 2025-09-02 | Totalenergies One Tech Belgium | Method for improving feedstock flexibility of steam cracking |
| US20240010918A1 (en) * | 2020-12-10 | 2024-01-11 | Sabic Global Technologies B.V. | A process for steam cracking chlorine-containing feedstock |
| CN114713268B (zh) * | 2021-01-06 | 2024-06-25 | 中国石油天然气股份有限公司 | 一种废塑料裂解用分子筛催化剂及其制备方法与废塑料裂解方法 |
| US11584888B2 (en) | 2021-03-15 | 2023-02-21 | Anellotech, Inc. | Two step process for chemically recycling plastic waste |
| EP4323474A1 (en) | 2021-04-16 | 2024-02-21 | Chevron Phillips Chemical Company LP | Pyrolysis of plastic waste to produce light gaseous hydrocarbons and integration with an ethylene cracker |
| EP4124638A1 (fr) | 2021-07-26 | 2023-02-01 | TotalEnergies OneTech | Composition de bases bitume pour la fabrication de bitume comprenant une huile de pyrolyse de plastique |
| US12195674B2 (en) | 2021-09-21 | 2025-01-14 | Eastman Chemical Company | Using spent caustic solution from pygas treatment to neutralize halogens from liquified waste plastic |
| CN117999330A (zh) | 2021-09-21 | 2024-05-07 | 伊士曼化工公司 | 用于回收成分烯烃生产商的低碳足迹集成方法 |
| KR20240111748A (ko) * | 2021-10-06 | 2024-07-17 | 더블유.알. 그레이스 앤드 캄파니-콘. | 석유화학 공급원료를 생성하기 위한 플라스틱의 촉매 열분해 |
| US20240417625A1 (en) * | 2021-12-15 | 2024-12-19 | Sabic Global Technologies B.V. | Systems and methods for catalytic cracking of naphtha with co-feed of mixed waste plastic oil to produce light olefins |
| NO348031B1 (en) | 2021-12-31 | 2024-06-24 | Inrigo As | Method and device for pyrolysis-based production of hydrocarbon oils based on plastic containing raw material |
| WO2023139363A1 (en) * | 2022-01-19 | 2023-07-27 | Oxford University Innovation Limited | Decomposition of polyolefins |
| US20250296900A1 (en) * | 2022-01-19 | 2025-09-25 | Oxford University Innovation Limited | Decomposition of polyolefins |
| CN118632915A (zh) | 2022-01-20 | 2024-09-10 | 埃克森美孚化学专利公司 | 集成的塑料再循环过程中的污染物去除 |
| JP2023136646A (ja) * | 2022-03-17 | 2023-09-29 | 出光興産株式会社 | 軽質オレフィン含有ガスの製造方法 |
| CN116851030B (zh) * | 2022-03-28 | 2025-12-02 | 中国石油化工股份有限公司 | 新型催化剂及其制备方法以及在废塑料直接转化制低碳烯烃反应中的应用 |
| EP4499743A1 (en) * | 2022-03-30 | 2025-02-05 | Basell Poliolefine Italia S.r.l. | Thermal process for conversion of plastic waste into olefins |
| WO2023192449A1 (en) | 2022-04-01 | 2023-10-05 | Chevron U.S.A. Inc. | Circular economy for plastic waste to polypropylene and base oil via refinery hydrocracking unit |
| MX2024011623A (es) * | 2022-04-01 | 2024-09-30 | Chevron Usa Inc | Economia circular de plasticos residuales a polietileno mediante una unidad de craqueo catalitico fluido (fcc) de refineria. |
| CA3260886A1 (en) * | 2022-07-08 | 2024-01-11 | Chevron U.S.A. Inc. | USE OF A MIXTURE OF PLASTIC WASTE AND BIOLOGICAL RAW MATERIALS FOR THE PRODUCTION OF CIRCULAR-ECONOMICAL POLYPROPYLENE |
| JP2025521934A (ja) * | 2022-07-08 | 2025-07-10 | シェブロン ユー．エス．エー． インコーポレイテッド | サーキュラーエコノミーポリエチレン生産のための廃プラスチックとバイオ原料のブレンドの使用 |
| WO2024013333A1 (en) | 2022-07-14 | 2024-01-18 | Totalenergies Onetech | Process for the recycling of waste plastics based oil |
| CN117443441B (zh) * | 2022-07-19 | 2025-10-14 | 中国石油化工股份有限公司 | 废塑料制低碳烯烃催化剂及其制备方法和应用 |
| WO2024155608A2 (en) * | 2023-01-20 | 2024-07-25 | The Regents Of The University Of California | Hydrocarbon pyrolysis for hydrogen production using a ternary liquid metal alloy |
| CN116493039B (zh) * | 2023-03-11 | 2025-02-11 | 中国石油化工股份有限公司 | 一种废塑料催化裂解生产烯烃的催化剂及其制备方法和应用 |
| US12453993B2 (en) | 2023-03-31 | 2025-10-28 | Nexus Circular LLC | Hydrocarbon compositions derived from pyrolysis of post-consumer and/or post-industrial plastics and methods of making and use thereof |
| US12435278B2 (en) | 2023-03-31 | 2025-10-07 | Nexus Circular LLC | Hydrocarbon compositions derived from pyrolysis of post-consumer and/or post-industrial plastics and methods of making and use thereof |
| US12453994B2 (en) | 2023-03-31 | 2025-10-28 | Nexus Circular LLC | Hydrocarbon compositions derived from pyrolysis of post-consumer and/or post-industrial plastics and methods of making and use thereof |
| US12595424B2 (en) | 2023-03-31 | 2026-04-07 | Nexus Circular LLC | Hydrocarbon compositions derived from pyrolysis of post-consumer and/or post-industrial plastics and methods of making and use thereof |
| US12473506B2 (en) | 2023-03-31 | 2025-11-18 | Nexus Circular LLC | Hydrocarbon compositions derived from pyrolysis of post-consumer and/or post-industrial plastics and methods of making and use thereof |
| US20250320409A1 (en) | 2024-01-29 | 2025-10-16 | Nexus Circular LLC | Systems and methods for making hydrocarbon compositions derived from pyrolysis of post-consumer and/or post-industrial plastics |
| JP7803503B1 (ja) * | 2024-10-29 | 2026-01-21 | 住友化学株式会社 | オレフィンの製造方法 |
| CN119425750B (zh) * | 2024-11-15 | 2025-07-18 | 中国石油大学(华东) | 一种废塑料催化裂解用碱性催化剂及其应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5079385A (en) * | 1989-08-17 | 1992-01-07 | Mobil Oil Corp. | Conversion of plastics |
| CN101213269A (zh) * | 2005-06-29 | 2008-07-02 | 格雷斯公司 | 在流化催化装置中用于轻质烯烃的五元环高硅沸石催化剂 |
| CN102019200A (zh) * | 2010-04-13 | 2011-04-20 | 卓润生 | 一种高活性的催化热裂解催化剂及其制备方法 |
Family Cites Families (72)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3702886A (en) | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
| CA1050956A (en) * | 1977-01-10 | 1979-03-20 | Engelhard Minerals And Chemicals Corporation | Catalytic cracking |
| JPS57121093A (en) | 1981-01-21 | 1982-07-28 | Mitsui Petrochem Ind Ltd | Pyrolysis |
| JPS57209988A (en) | 1981-06-19 | 1982-12-23 | Mitsubishi Heavy Ind Ltd | Pyrolysis of solid waste-containing plastics |
| US4480047A (en) | 1983-04-07 | 1984-10-30 | Ashland Oil, Inc. | High performance catalysts for carbometallic oil conversion and their manufacturing and use |
| AU581439B2 (en) * | 1984-07-05 | 1989-02-23 | Mobil Oil Corporation | Method of adding zsm-5 containing catalyst to moving bed catalytic cracking units |
| DE3523653A1 (de) | 1985-07-02 | 1987-02-12 | Bbc Brown Boveri & Cie | Wirbelschichtreaktor |
| DE3545954A1 (de) | 1985-12-23 | 1987-07-02 | Bbc Brown Boveri & Cie | Verfahren zum pyrolytischen aufarbeiten von ausgangsmaterial |
| BR8606515A (pt) * | 1986-01-16 | 1987-10-20 | Grace W R & Co | Composicao catalitica em particulas;composicao para catalisador de fcc e processo para a conversao de hidrocarbonetos para obter fracoes de gasolina de octanas acentuadas |
| DE3721341C1 (de) | 1987-06-27 | 1988-11-17 | Bbc Brown Boveri & Cie | Verfahren zum thermischen Zersetzen von Abfallmaterial sowie Wirbelschicht-Pyrolysereaktor zur Durchfuehrung des Verfahrens |
| DE3743752A1 (de) | 1987-12-23 | 1989-07-13 | Asea Brown Boveri | Verfahren zum aufarbeiten von abfallmaterial |
| US4851601A (en) | 1988-01-19 | 1989-07-25 | Mobil Oil Corporation | Processing for producing hydrocarbon oils from plastic waste |
| DE3817437A1 (de) | 1988-05-21 | 1989-11-30 | Asea Brown Boveri | Verfahren zum aufarbeiten von abfallmaterial |
| JPH0421681A (ja) | 1990-05-14 | 1992-01-24 | Fujisawa Pharmaceut Co Ltd | ピロロピリジン誘導体 |
| US5136117A (en) | 1990-08-23 | 1992-08-04 | Battelle Memorial Institute | Monomeric recovery from polymeric materials |
| EP0502618B1 (en) | 1991-03-05 | 1996-08-14 | BP Chemicals Limited | Polymer cracking |
| US5481052A (en) * | 1992-04-22 | 1996-01-02 | Bp Chemicals Limited | Polymer cracking |
| DE69323125T2 (de) | 1992-06-29 | 1999-08-19 | Mortimer Technology Holdings Ltd. | Verfahren zur Umwandlung von Polymeren |
| FI931785A7 (fi) | 1993-04-20 | 1994-10-21 | Valtion Teknillinen | Menetelmä ja laitteisto nestemäisen polttoaineen valmistamiseksi pyrolysoimalla raakapolttoainetta |
| DE4329434C2 (de) | 1993-09-01 | 1996-01-11 | Leuna Werke Gmbh | Verfahren zur Aufbereitung von Altkunststoffen oder Altkunststoffgemischen für das rohstoffliche Recycling |
| US5447622A (en) * | 1993-11-19 | 1995-09-05 | Exxon Research & Engineering Co. | Integrated catalytic cracking and olefin producing process using staged backflow regeneration |
| DE4344311A1 (de) | 1993-12-23 | 1995-06-29 | Linde Ag | Verfahren und Vorrichtung zur thermischen Depolymerisation von Kunststoffen |
| DE4413093A1 (de) | 1994-04-15 | 1995-10-19 | Leuna Werke Gmbh | Verfahren zur Herstellung von fuktionalisierten, niedermolekularen Polymeren aus Altkunststoffen |
| DE4417386A1 (de) | 1994-05-18 | 1995-11-23 | Leuna Werke Gmbh | Verfahren zur Herstellung destillierbarer Kohlenwasserstoffe |
| GB9412028D0 (en) | 1994-06-16 | 1994-08-03 | Bp Chem Int Ltd | Waste processing |
| DE69602741D1 (de) * | 1995-04-27 | 1999-07-08 | Abb Lummus Global Inc | Verfahren für die umsetzung von olefinischen kohlenwasserstoffen mittels verbrauchtes fcc katalysator |
| CN1145395A (zh) * | 1995-08-08 | 1997-03-19 | 周鼎力 | 利用废橡胶制造汽油、柴油和炭黑的方法及设备 |
| WO1997018892A1 (en) | 1995-11-17 | 1997-05-29 | Hydrocarbon Technologies, Inc. | Supported solid superacid catalysts and method for making them |
| JP4103198B2 (ja) | 1998-09-21 | 2008-06-18 | 株式会社Ｉｈｉ | 廃プラスチック処理装置 |
| ES2168033B1 (es) | 1999-04-29 | 2003-05-01 | Univ Valencia Politecnica | Proceso para el craqueo catalitico de residuos plasticos. |
| CN1074447C (zh) | 1999-06-08 | 2001-11-07 | 周鼎力 | 用废塑料和或重油生产汽油柴油的方法和设备 |
| CN2408118Y (zh) | 1999-07-16 | 2000-11-29 | 周继福 | 一种用废塑料和或重油生产汽油柴油的设备 |
| US6797155B1 (en) * | 1999-12-21 | 2004-09-28 | Exxonmobil Research & Engineering Co. | Catalytic cracking process using a modified mesoporous aluminophosphate material |
| KR100322663B1 (ko) | 2000-03-20 | 2002-02-07 | 곽호준 | 폐플라스틱을 이용한 휘발유, 등유 및 경유의 연속식제조방법 및 그 시스템 |
| JP4314546B2 (ja) | 2000-05-02 | 2009-08-19 | 株式会社Ｉｈｉ | 廃プラスチック処理方法および装置 |
| JP4341162B2 (ja) | 2000-09-18 | 2009-10-07 | 株式会社Ｉｈｉ | 廃プラスチック処理方法および装置 |
| JP4465851B2 (ja) | 2000-10-17 | 2010-05-26 | 株式会社Ｉｈｉ | 廃プラスチックのケミカルリサイクル方法及び装置 |
| EP1270848B1 (de) | 2001-06-24 | 2006-09-13 | Joachim Falkenhagen | Nachgiebige Seilabspannung für Wasserbauwerke |
| CN1397627A (zh) | 2001-07-23 | 2003-02-19 | 北京国硕科技开发有限责任公司 | 一种用废塑料和/或重油生产汽油柴油的方法和设备 |
| KR100517898B1 (ko) | 2001-07-31 | 2005-09-30 | 김범진 | 폐합성수지를 원료로 하는 촉매 하행식 크래킹반응기 및 이를 이용한 휘발유·경유의 제조방법 |
| JP2003105125A (ja) | 2001-09-28 | 2003-04-09 | Ebara Corp | 混合廃プラスチックの油化等用の熱分解方法及び装置 |
| JP3654858B2 (ja) | 2001-10-11 | 2005-06-02 | 株式会社荏原製作所 | 混合廃プラスチックの油化等用の熱分解装置 |
| US6858556B2 (en) * | 2002-02-25 | 2005-02-22 | Indian Oil Corporation Limited | Stabilized dual zeolite single particle catalyst composition and a process thereof |
| US7122493B2 (en) * | 2003-02-05 | 2006-10-17 | Exxonmobil Chemical Patents Inc. | Combined cracking and selective hydrogen combustion for catalytic cracking |
| CN1190269C (zh) | 2003-05-26 | 2005-02-23 | 四川大学 | 用于裂解废塑料以生产燃油的催化剂 |
| JP4337517B2 (ja) | 2003-11-21 | 2009-09-30 | 株式会社Ｉｈｉ | 廃プラスチックのケミカルリサイクル方法及びその装置 |
| JP2005154510A (ja) | 2003-11-21 | 2005-06-16 | Ishikawajima Harima Heavy Ind Co Ltd | 廃プラスチックのケミカルリサイクル装置 |
| GB0329708D0 (en) | 2003-12-22 | 2004-01-28 | Bp Chem Int Ltd | Process |
| WO2005094990A1 (en) | 2004-03-30 | 2005-10-13 | Indian Oil Corporation Limited | A catalyst composition for catalytic cracking of waste plastic |
| US7589041B2 (en) | 2004-04-23 | 2009-09-15 | Massachusetts Institute Of Technology | Mesostructured zeolitic materials, and methods of making and using the same |
| US7868214B2 (en) | 2005-05-19 | 2011-01-11 | Uop Llc | Production of olefins from biorenewable feedstocks |
| US9480975B2 (en) | 2005-08-15 | 2016-11-01 | China Petroleum & Chemical Corporation | Catalyst for catalytic cracking in a fluidized bed |
| KR100632571B1 (ko) | 2005-10-07 | 2006-10-09 | 에스케이 주식회사 | 탄화수소 원료 혼합물로부터 접촉분해공정을 통해서 경질올레핀계 탄화수소 화합물을 증산하는 방법 |
| TWI265174B (en) | 2005-11-16 | 2006-11-01 | Chinese Petroleum Corp | Method of catalytically recycles plastics for producing fuel and petrochemicals |
| US7932424B2 (en) | 2006-01-26 | 2011-04-26 | Kitakyushu Foundation For The Advancement Of Industry, Science And Technology | Method for catalytically cracking waste plastics and apparatus for catalytically cracking waste plastics |
| ES2334293B1 (es) | 2007-04-12 | 2011-05-13 | ENERGY & ENVIRONMENT CONSULTING, S.L. | Procedimiento para el tratamiento de plasticos, en especial de residuos plasticos, y utilizacion de hidrocarburos procedentes de la pirolisis catalitica de dichos residuos plasticos. |
| EP2027918A1 (en) | 2007-07-31 | 2009-02-25 | Total Petrochemicals Research Feluy | Mixtures of molecular sieves comprising MeAPO, their use in conversion of organics to olefins |
| US8545581B2 (en) | 2007-08-01 | 2013-10-01 | Virginia Tech Intellectual Properties, Inc. | Production of stable biomass pyrolysis oils using fractional catalytic pyrolysis |
| AR068838A1 (es) | 2007-10-09 | 2009-12-09 | Cbp Carbon Ind Inc | Composicion de elastomero con materiales de relleno reciclados |
| EP2257612B1 (en) * | 2008-03-04 | 2021-05-05 | University of Massachusetts | Method for the catalytic pyrolysis of solid biomass for the production of hydrocarbons |
| FR2932495B1 (fr) | 2008-06-17 | 2011-03-25 | Inst Francais Du Petrole | Dispositif de controle des conditions operatoires dans une unite de craquage catalytique a deux risers. |
| BRPI0803718A2 (pt) | 2008-08-29 | 2010-06-15 | Petroleo Brasileiro Sa | método para produção de olefinas leves em unidades de craqueamento catalìtico com deficiência energética |
| KR20110059879A (ko) * | 2008-09-15 | 2011-06-07 | 유오피 엘엘씨 | 프로필렌 수율을 향상시키고 벤젠 나프타 유분을 감소시키기 위한 접촉 분해 |
| BRPI0803617A2 (pt) | 2008-09-19 | 2010-06-15 | Petroleo Brasileiro Sa | Aditivo com sistema múltiplo de zeólitas e método de preparo |
| KR101503069B1 (ko) | 2008-10-17 | 2015-03-17 | 에스케이이노베이션 주식회사 | 유동층 접촉 분해 공정의 경질 사이클 오일로부터 고부가 방향족 및 올레핀을 제조하는 방법 |
| BRPI0805207B1 (pt) | 2008-11-25 | 2019-11-12 | Petróleo Brasileiro S.A. - Petrobras | processo de craqueamento catalítico de uma corrente de hidrocarbonetos para maximização de olefinas leves |
| CN102438969A (zh) | 2009-05-22 | 2012-05-02 | 科伊奥股份有限公司 | 利用氢源处理生物质 |
| US7981273B2 (en) | 2009-06-22 | 2011-07-19 | Uop Llc | Process for catalytic cracking of hydrocarbons using UZM-35 |
| ES2864545T3 (es) | 2009-09-09 | 2021-10-14 | Univ Massachusetts | Proceso con reciclado de olefinas para la pirólisis catalítica de biomasa y materiales hidrocarbonados en un lecho fluidizado para la producción de compuestos aromáticos |
| WO2011103026A1 (en) | 2010-02-16 | 2011-08-25 | Kior Inc. | Co-processing of biomass and synthetic polymer based materials in a pyrolysis conversion process |
| CN102166529A (zh) | 2010-02-25 | 2011-08-31 | 中国石油天然气股份有限公司 | 一种碳四烯烃催化裂解制乙烯丙烯的催化剂及应用方法 |
| BR112012023536B1 (pt) | 2010-03-18 | 2018-06-12 | W.R. Grace & Co. -Conn. | Composição catalisadora para craqueamento catalítico de hidrocarbonetos para maximizar a produção de olefinas leves e processo de craqueamento catalítico de hidrocarbonetos |
-
2013
- 2013-02-12 US US13/764,886 patent/US8895790B2/en active Active
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5079385A (en) * | 1989-08-17 | 1992-01-07 | Mobil Oil Corp. | Conversion of plastics |
| CN101213269A (zh) * | 2005-06-29 | 2008-07-02 | 格雷斯公司 | 在流化催化装置中用于轻质烯烃的五元环高硅沸石催化剂 |
| CN102019200A (zh) * | 2010-04-13 | 2011-04-20 | 卓润生 | 一种高活性的催化热裂解催化剂及其制备方法 |
Non-Patent Citations (3)
| Title |
|---|
| atalytic degradation of high-density polyethylene over different zeolitic structures;Manos et al.;《Ind. Eng. Chem. Res.》;20000531;第39卷;1198-1202 |
| Zeolites and catalysis;Jens Weitkamp;《Solid State Ionics》;20000630;第131卷;175-188 |
| 废塑料油化技术及其裂解催化剂的研究进展;石葆莹，等;《塑料科技》;20060630;第34卷;61-62 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105102587B (zh) | 2018-03-27 |
| JP2016513147A (ja) | 2016-05-12 |
| CN105102587A (zh) | 2015-11-25 |
| WO2014125344A1 (en) | 2014-08-21 |
| JP2017137347A (ja) | 2017-08-10 |
| EP3865557B1 (en) | 2023-12-20 |
| US8895790B2 (en) | 2014-11-25 |
| US20140228204A1 (en) | 2014-08-14 |
| EP2956525B1 (en) | 2021-04-07 |
| EP2956525A1 (en) | 2015-12-23 |
| EP3865557A1 (en) | 2021-08-18 |
| US20140228205A1 (en) | 2014-08-14 |
| JP6173637B1 (ja) | 2017-08-02 |
| US9212318B2 (en) | 2015-12-15 |
| CN108504380A (zh) | 2018-09-07 |
| JP6139707B2 (ja) | 2017-05-31 |
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