CN108367930A - 具有bea框架结构的含锡沸石材料 - Google Patents

具有bea框架结构的含锡沸石材料 Download PDF

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Publication number
CN108367930A
CN108367930A CN201680072205.8A CN201680072205A CN108367930A CN 108367930 A CN108367930 A CN 108367930A CN 201680072205 A CN201680072205 A CN 201680072205A CN 108367930 A CN108367930 A CN 108367930A
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China
Prior art keywords
tin
bea framework
zeolitic material
weight
boron
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CN201680072205.8A
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Chinese (zh)
Inventor
A-N·帕伏列斯库
J·H·特莱斯
N·沃特拉韦尔
U·穆勒
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7057—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/86—Borosilicates; Aluminoborosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D313/00—Heterocyclic compounds containing rings of more than six members having one oxygen atom as the only ring hetero atom
    • C07D313/02—Seven-membered rings
    • C07D313/04—Seven-membered rings not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
CN201680072205.8A 2015-12-08 2016-12-07 具有bea框架结构的含锡沸石材料 Pending CN108367930A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP15198362.4 2015-12-08
EP15198362.4A EP3178788A1 (en) 2015-12-08 2015-12-08 A tin-containing zeolitic material having a bea framework structure
PCT/EP2016/080076 WO2017097835A1 (en) 2015-12-08 2016-12-07 A tin-containing zeolitic material having a bea framework structure

Publications (1)

Publication Number Publication Date
CN108367930A true CN108367930A (zh) 2018-08-03

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CN201680072205.8A Pending CN108367930A (zh) 2015-12-08 2016-12-07 具有bea框架结构的含锡沸石材料

Country Status (9)

Country Link
US (1) US10766781B2 (https=)
EP (2) EP3178788A1 (https=)
JP (1) JP6959234B2 (https=)
CN (1) CN108367930A (https=)
BR (1) BR112018011447A2 (https=)
ES (1) ES2916089T3 (https=)
MX (1) MX2018007058A (https=)
PL (1) PL3386917T3 (https=)
WO (1) WO2017097835A1 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111253364A (zh) * 2018-11-30 2020-06-09 中国石油化工股份有限公司 一种催化甘油制备酮缩甘油和/或醛缩甘油的方法
CN114604878A (zh) * 2022-03-18 2022-06-10 大连理工大学 一种多级孔结构的双功能Sn-B-BEA分子筛的制备方法与应用
CN115121279A (zh) * 2021-03-25 2022-09-30 河南省高新技术实业有限公司 一种固体催化剂及其制备方法和应用

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017133995A1 (de) 2016-02-01 2017-08-10 Basf Se Verfahren zur herstellung von c4-c15-lactamen
JP7039498B2 (ja) 2016-06-29 2022-03-22 ビーエーエスエフ ソシエタス・ヨーロピア 液相の存在下でのアルコールの酸化によるアルファ，ベータ不飽和アルデヒドの製造方法
EP3481800B1 (en) 2016-07-08 2020-08-05 Basf Se Process for preparing an organic sulfone
EP3544730A1 (en) 2016-11-28 2019-10-02 Basf Se Catalyst composite comprising an alkaline earth metal containing cha zeolite and use thereof in a process for the conversion of oxygenates to olefins
CN109996783A (zh) 2016-11-30 2019-07-09 巴斯夫欧洲公司 使用mor骨架结构的铜改性沸石将单乙醇胺转化成乙二胺的方法
US11091425B2 (en) 2016-11-30 2021-08-17 Basf Se Process for the conversion of ethylene glycol to ethylenediamine employing a zeolite catalyst
BR112019017044B1 (pt) 2017-02-28 2023-03-28 Basf Se Processo para preparar um composto, e, uso de um material zeolítico
EP3601206B1 (de) 2017-03-21 2021-07-21 Basf Se Verfahren zur herstellung einer korrosionsschutzkomponente für ein gefrierschutzmittel
JP2020518558A (ja) 2017-05-03 2020-06-25 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ゼオライトを用いた、エチレンオキシドのモノエタノールアミンおよびエチレンジアミンへの変換方法
CN107244678B (zh) * 2017-07-04 2019-03-12 江西师范大学 Sn-β分子筛及其水热合成方法和苯酚羟基化的方法
CN110152648B (zh) * 2018-02-12 2022-01-04 中国石油化工股份有限公司 锡催化剂的制备方法、锡催化剂及其应用
US11655158B2 (en) 2019-10-14 2023-05-23 Totalenergies Onetech Isomorphous substitution of metals during the synthesis of a zeolite framework
CN112645347B (zh) * 2020-12-23 2022-10-25 中触媒新材料股份有限公司 一种纳米级Sn-Beta分子筛及其制备方法
JP7789610B2 (ja) * 2022-03-29 2025-12-22 旭化成株式会社 ゼオライト成形体、吸着装置、及び精製ガスの製造方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1430616A (zh) * 2000-04-25 2003-07-16 环球油品公司 用锡取代的β沸石将酮氧化成酯
WO2015067654A1 (en) * 2013-11-05 2015-05-14 Basf Se A tin-containing zeolitic material having a bea framework structure
CN104709920A (zh) * 2013-12-16 2015-06-17 中国科学院大连化学物理研究所 一种含锡杂原子功能性分子筛及其合成和应用

Family Cites Families (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5324702A (en) * 1991-11-22 1994-06-28 Amoco Corporation Catalytic oxidation and oxidative dehydrogenation using metal-compound-loaded, deboronated hams-1b crystalline borosilicate molecular sieve compositions
WO1996001239A1 (en) * 1994-07-05 1996-01-18 Amoco Corporation Dehydrogenation catalyst and process
US6331500B1 (en) * 1997-08-25 2001-12-18 California Institute Of Technology Functionalized molecular sieves
US9108190B1 (en) 2012-09-12 2015-08-18 University Of Massachusetts Rapid synthesis of beta zeolites
WO2014060259A1 (en) * 2012-10-18 2014-04-24 Basf Se Post-treatment of deboronated zeolite beta
MX361540B (es) * 2012-11-05 2018-12-10 Basf Se Un material zeolítico que contiene estaño que tiene una estructura de marco de tipo mww.
BR112015031174B8 (pt) * 2013-06-13 2020-12-22 Basf Se processo em fase gasosa para a preparação de butadieno
KR20160097257A (ko) 2013-12-11 2016-08-17 바스프 에스이 2-메르캅토에탄올의 산화
EP3110931B1 (en) 2013-12-20 2018-04-18 Basf Se Novel aroma chemicals
US10596518B2 (en) 2014-01-03 2020-03-24 Basf Se Bimetal-exchanged zeolite beta from organotemplate-free synthesis and use thereof in the selective catalytic reduction of NOx
WO2015123531A1 (en) 2014-02-14 2015-08-20 Basf Corporation Methods and systems for heating adsorbed gas systems
WO2015123530A1 (en) 2014-02-14 2015-08-20 Basf Corporation Methods and systems for improving capacity of adsorbed gas systems
ES2823823T3 (es) 2014-03-27 2021-05-10 Basf Se Películas porosas que comprenden materiales de estructura organometálica
WO2015162082A1 (en) 2014-04-22 2015-10-29 Wintershall Holding GmbH Solid-stabilized emulsion
CN106164212A (zh) 2014-04-22 2016-11-23 温特沙尔控股有限公司 采油方法
US9765003B2 (en) 2014-05-05 2017-09-19 Basf Se Process for producing 2,6-dimethyl-5-hepten-1-al
WO2015169939A1 (en) 2014-05-09 2015-11-12 Basf Se Method and device for filling a storage tank by recirculation of gas
WO2015177141A1 (en) 2014-05-20 2015-11-26 Basf Se Process for the dimerization of activated olefins
DE102014008081A1 (de) 2014-05-30 2015-11-19 Basf Se Verfahren zur Herstellung von Acrylsäure unter Verwendung eines alkali- und erdalkalifreien zeolithischen Materials
DE102014008080A1 (de) 2014-05-30 2015-11-12 Basf Se Verfahren zur Herstellung von Acrylsäure unter Verwendung eines aluminiumfreien zeolithischen Materials
CN106660918B (zh) 2014-05-30 2019-10-11 巴斯夫欧洲公司 2,6-和2,7-二取代的蒽醌衍生物的制备
EP3148927B1 (en) 2014-05-30 2018-02-28 Basf Se Preparation of 2,6- and 2,7-disubstituted anthraquinone derivates
MX379278B (es) 2014-06-05 2025-03-11 Basf Mobile Emissions Catalysts Llc Materiales zeoliticos de tipo cha y metodos para su preparacion usando combinaciones de compuestos de cicloalquil- y tetraalquilamonio.
US10196276B2 (en) 2014-06-06 2019-02-05 Basf Se Synthesis of a boron-containing zeolite with an MWW framework structure
WO2015197699A1 (en) 2014-06-25 2015-12-30 Basf Se Process for preparing furan-2,5-dicarboxylic acid
EP2985075A1 (en) 2014-08-15 2016-02-17 Basf Se Shaped body made of a porous material
CN107074429B (zh) 2014-09-05 2019-08-09 巴斯夫公司 用于延长农产品(produce)贮存寿命的吸附剂材料
US9687830B2 (en) * 2014-09-08 2017-06-27 Chevron U.S.A., Inc. Highly active, selective, accessible, and robust zeolitic Sn-baeyer-villiger oxidation catalyst
US20170275225A1 (en) 2014-09-09 2017-09-28 Basf Se Method for the preparation of 2-alkoxy cyclohexanol
JP6775491B2 (ja) 2014-09-09 2020-10-28 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ホウ素およびチタンを含むｍｗｗゼオライト系材料の製造のための方法
WO2016059042A1 (de) 2014-10-14 2016-04-21 Basf Se Verwendung von hexadeca-8,15-dienal als aromachemikalie
WO2016058541A1 (en) 2014-10-15 2016-04-21 Basf Se Solidothermal synthesis of zeolitic materials and zeolites obtained therefrom
CN107148415B (zh) 2014-10-23 2020-11-13 建筑研究和技术有限公司 制备甘油酸碳酸酯的方法
WO2016075100A1 (en) 2014-11-11 2016-05-19 Basf Se Storage vessel comprising layers of a shaped body of a porous solid separated by a seal
WO2016074918A1 (en) 2014-11-11 2016-05-19 Basf Se Thermoelectric device
WO2016075129A1 (en) 2014-11-11 2016-05-19 Basf Se Storage vessel comprising at least one shaped body of a porous solid with spacers
CN106922168B (zh) 2014-11-11 2019-09-03 巴斯夫欧洲公司 包括多孔固体的一体式成形体的储存容器
DE102014017804A1 (de) 2014-12-02 2016-04-21 Basf Se Verfahren zur Herstellung von Acrylsäure
KR102558113B1 (ko) 2015-02-12 2023-07-24 바스프 에스이 Bea 골격 구조를 갖는 탈알루미늄화된 제올라이트 물질의 제조 방법
JP6685315B2 (ja) 2015-02-13 2020-04-22 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ プロピレンのエポキシ化のためのチタンゼオライト触媒の再生方法
WO2016135133A1 (en) 2015-02-27 2016-09-01 Basf Se A vehicle comprising a storage system and a combustion engine, the storage system comprising a container and at least one storage vessel
JP6741687B2 (ja) 2015-05-04 2020-08-19 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ メロナールの調製方法
EP3093550A1 (en) 2015-05-11 2016-11-16 Basf Se Storage vessel comprising at least one shaped body of a porous solid
CN107848929A (zh) 2015-07-15 2018-03-27 巴斯夫欧洲公司 制备芳基丙烯的方法
US10202323B2 (en) 2015-07-15 2019-02-12 Basf Se Process for preparing an arylpropene
WO2017012937A1 (en) 2015-07-22 2017-01-26 Basf Se Mixture of n-(1,3-benzothiazol-2-ylsulfanyl)-2-methylcyclohexanamine and n-(1,3-benzothiazol-2-ylsulfanyl)-4-methylcyclohexanamine
BR112018000606B1 (pt) 2015-07-22 2022-01-18 Basf Se Processo para preparação de ácido furan-2,5- dicarboxílico e uso de um catalisador
EP3359516A1 (de) 2015-10-08 2018-08-15 Basf Se Verwendung neuartiger gemische von (e/z)-cyclopentadecenon-isomeren, deren herstellung und deren verwendung als aromastoff
DE102015222198A1 (de) 2015-11-11 2017-05-11 Basf Se Oxidische Zusammensetzung
WO2017085049A1 (en) 2015-11-18 2017-05-26 Basf Se Heat recovery adsorber as ventilation system in buildings
EP3380227B1 (en) 2015-11-27 2019-10-16 Basf Se Process for preparation of a molding composition and production of shaped bodies containing mof
JP7058602B2 (ja) * 2016-03-04 2022-04-22 カリフォルニア インスティチュート オブ テクノロジー 新規ゲルマノシリケート組成物及びその製造方法
US20190168197A1 (en) * 2016-05-24 2019-06-06 ExxonMobil Chemical Company - Law Technology Synthetic Zeolite Comprising A Catalytic Metal

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1430616A (zh) * 2000-04-25 2003-07-16 环球油品公司 用锡取代的β沸石将酮氧化成酯
WO2015067654A1 (en) * 2013-11-05 2015-05-14 Basf Se A tin-containing zeolitic material having a bea framework structure
CN104709920A (zh) * 2013-12-16 2015-06-17 中国科学院大连化学物理研究所 一种含锡杂原子功能性分子筛及其合成和应用

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111253364A (zh) * 2018-11-30 2020-06-09 中国石油化工股份有限公司 一种催化甘油制备酮缩甘油和/或醛缩甘油的方法
CN115121279A (zh) * 2021-03-25 2022-09-30 河南省高新技术实业有限公司 一种固体催化剂及其制备方法和应用
CN114604878A (zh) * 2022-03-18 2022-06-10 大连理工大学 一种多级孔结构的双功能Sn-B-BEA分子筛的制备方法与应用

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