CN108349738B - 制备Na3V2(PO4)2F3颗粒材料的方法 - Google Patents

制备Na3V2(PO4)2F3颗粒材料的方法 Download PDF

Info

Publication number
CN108349738B
CN108349738B CN201680060268.1A CN201680060268A CN108349738B CN 108349738 B CN108349738 B CN 108349738B CN 201680060268 A CN201680060268 A CN 201680060268A CN 108349738 B CN108349738 B CN 108349738B
Authority
CN
China
Prior art keywords
electrode
carbon
sodium
vpo
reducing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201680060268.1A
Other languages
English (en)
Chinese (zh)
Other versions
CN108349738A (zh
Inventor
N·霍尔
S·布利诺
L·克罗盖内克
S·劳诺伊斯
C·马斯克利耶
L·塞莫南
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University De Picardie Jules Vernes
Centre National de la Recherche Scientifique CNRS
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
University De Picardie Jules Vernes
Centre National de la Recherche Scientifique CNRS
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University De Picardie Jules Vernes, Centre National de la Recherche Scientifique CNRS, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical University De Picardie Jules Vernes
Publication of CN108349738A publication Critical patent/CN108349738A/zh
Application granted granted Critical
Publication of CN108349738B publication Critical patent/CN108349738B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00Phosphorus; Compounds thereof
    • C01B25/16Oxyacids of phosphorus; Salts thereof
    • C01B25/26Phosphates
    • C01B25/455Phosphates containing halogen
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/20Two-dimensional structures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/62Submicrometer sized, i.e. from 0.1-1 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/12Surface area
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/054Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
CN201680060268.1A 2015-10-13 2016-10-13 制备Na3V2(PO4)2F3颗粒材料的方法 Active CN108349738B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1559709A FR3042313B1 (fr) 2015-10-13 2015-10-13 Procede de preparation d'un materiau particulaire na3v2(po4)2f3
FR1559709 2015-10-13
PCT/EP2016/074597 WO2017064189A1 (fr) 2015-10-13 2016-10-13 Procede de preparation d'un materiau particulaire na3v2(po4)2f3

Publications (2)

Publication Number Publication Date
CN108349738A CN108349738A (zh) 2018-07-31
CN108349738B true CN108349738B (zh) 2023-02-21

Family

ID=55589932

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201680060268.1A Active CN108349738B (zh) 2015-10-13 2016-10-13 制备Na3V2(PO4)2F3颗粒材料的方法

Country Status (9)

Country Link
US (1) US11040881B2 (enExample)
EP (1) EP3484814B1 (enExample)
JP (2) JP7004646B2 (enExample)
KR (1) KR102743837B1 (enExample)
CN (1) CN108349738B (enExample)
FR (1) FR3042313B1 (enExample)
HU (1) HUE047790T2 (enExample)
PL (1) PL3484814T3 (enExample)
WO (1) WO2017064189A1 (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3062384B1 (fr) * 2017-02-01 2021-02-12 Centre Nat Rech Scient Procede de preparation d'un materiau composite phosphate de vanadium-carbone par voie liquide
FR3067709B1 (fr) * 2017-06-16 2020-06-19 Rhodia Operations Procede de preparation d'un phosphate de vanadium
CN116598479A (zh) * 2018-06-27 2023-08-15 宁德时代新能源科技股份有限公司 正极活性材料、正极极片及钠离子二次电池
CN112512966B (zh) * 2018-07-30 2024-02-20 罗地亚经营管理公司 正极组合物
CN110092366B (zh) * 2019-04-25 2023-03-31 西北工业大学 一种复相磷酸钒钠电极材料及其制备方法
CN112216823B (zh) * 2019-07-10 2022-03-08 上海交通大学 氟磷酸钒钠包覆正极材料、钠离子电池及其制备方法和应用
CN112864358B (zh) * 2019-11-27 2023-11-07 中国科学院大连化学物理研究所 一种一步法制备的钒基聚阴离子型化合物及应用
CN111606314B (zh) * 2020-06-04 2023-05-26 哈尔滨工业大学 一种钠离子电池正极材料三氟磷酸钒钠的制备方法
CN111943161B (zh) * 2020-08-24 2022-05-17 西北大学 一种氟磷酸钒钠和碳复合的二次电池正极材料的制备方法及其应用
CN114538400A (zh) * 2020-11-24 2022-05-27 天津理工大学 多元阳离子取代磷酸盐电极材料及其制备方法
CN113293459A (zh) * 2021-05-24 2021-08-24 中南大学 一种介孔纳米纤维氟磷酸钒钠正极材料及其制备方法
CN113764662A (zh) * 2021-07-29 2021-12-07 武汉理工大学 一种碳包覆磷酸钒钛锰钠微米球及其制备方法与应用
CN114572957B (zh) * 2022-02-22 2023-03-28 鞍钢集团北京研究院有限公司 一种磷酸钒钠材料的制备方法
CN114572958B (zh) * 2022-03-04 2023-03-21 湖南大学 一种含氟聚阴离子型正极材料的制备方法及含氟聚阴离子型正极材料
CN114933293B (zh) * 2022-04-29 2024-06-14 广州鹏辉能源科技股份有限公司 氟磷酸钒钠的制备和在钠离子电池中的应用
CN118281179B (zh) * 2022-12-29 2025-11-11 比亚迪股份有限公司 钠电池用正极材料及其制备方法、正极极片、钠电池
WO2025003375A1 (en) 2023-06-30 2025-01-02 Specialty Operations France Positive electrode composition
CN119008903A (zh) * 2024-08-19 2024-11-22 湖北万润新能源科技股份有限公司 一种碳包覆氟磷酸钒钠正极材料及其制备方法、正极极片和二次电池

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100814540B1 (ko) * 2001-04-06 2008-03-17 발렌스 테크놀로지, 인코포레이티드 나트륨 이온 배터리
US20070160519A1 (en) * 2005-03-28 2007-07-12 Jeremy Barker Method Of Making Active Materials For Use In Secondary Electrochemical Cells
CN101369661A (zh) * 2008-10-17 2009-02-18 吉林大学 一种钠基锂离子二次电池正极材料及其制备方法
WO2010080519A1 (en) * 2008-12-19 2010-07-15 Conocophillips Company Process for making fluorinated lithium vanadium polyanion powders for batteries
CN102306771A (zh) * 2011-08-17 2012-01-04 中南大学 一种混合离子电池氟磷酸钒钠正极材料的制备方法
JP2013089391A (ja) * 2011-10-14 2013-05-13 Kyushu Univ ナトリウムイオン二次電池用の電極活物質
CN102509789A (zh) * 2011-10-17 2012-06-20 中南大学 一种制备含钠锂离子电池正极材料掺氟磷酸钒钠的方法
CN103022490A (zh) * 2012-12-31 2013-04-03 广西地博矿业集团股份有限公司 钠离子电池正极材料氟磷酸钒钠的制备方法
US9673454B2 (en) 2013-02-18 2017-06-06 Semiconductor Energy Laboratory Co., Ltd. Sodium-ion secondary battery
WO2015067316A1 (en) * 2013-11-08 2015-05-14 MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. Method of manufacturing an electrode material, electrode material and vehicle comprising a battery including such an electrode material
US9564656B1 (en) * 2015-09-14 2017-02-07 Nanotek Instruments, Inc. Process for producing alkali metal or alkali-ion batteries having high volumetric and gravimetric energy densities

Also Published As

Publication number Publication date
FR3042313A1 (fr) 2017-04-14
HUE047790T2 (hu) 2020-05-28
CN108349738A (zh) 2018-07-31
JP7301101B2 (ja) 2023-06-30
WO2017064189A1 (fr) 2017-04-20
EP3484814A1 (fr) 2019-05-22
US11040881B2 (en) 2021-06-22
KR102743837B1 (ko) 2024-12-17
JP7004646B2 (ja) 2022-02-04
FR3042313B1 (fr) 2020-04-03
JP2021185125A (ja) 2021-12-09
JP2018531871A (ja) 2018-11-01
PL3484814T3 (pl) 2020-06-01
US20180297847A1 (en) 2018-10-18
EP3484814B1 (fr) 2019-11-20
KR20180072708A (ko) 2018-06-29

Similar Documents

Publication Publication Date Title
CN108349738B (zh) 制备Na3V2(PO4)2F3颗粒材料的方法
US7390472B1 (en) Method of making nanostructured lithium iron phosphate—based powders with an olivine type structure
Qin et al. A porous C/LiFePO4/multiwalled carbon nanotubes cathode material for Lithium ion batteries
US11165056B2 (en) Method of producing an electrode material for a battery electrode
US8911904B2 (en) Mesoporous metal oxide microsphere electrode compositions and their methods of making
JP6288257B2 (ja) ナノシリコン材料とその製造方法及び二次電池の負極
EP3371104B1 (en) Direct synthesis of carbon doped tio2-bronze nanostructures as anode materials for high performance lithium batteries
KR20110005854A (ko) 2차 리튬 배터리용 캐쏘드 활물질로서의 리튬 망간 포스페이트/탄소 나노복합체
WO2010089931A1 (ja) リチウムシリケート系化合物の製造方法
CN103715449B (zh) 钠离子电池系统
JP6176510B2 (ja) シリコン材料及び二次電池の負極
CN117062774A (zh) 磷酸钛钠盐及其用途
CN106061892B (zh) 高功率电极材料
Xu et al. Enhanced electrochemical performance of LiFePO4 cathode with carbon-TiO2 hybrid coating
CN103974905B (zh) 氧化硅-碳复合物及其制备方法
CN103715453B (zh) 钠离子电池系统、钠离子电池的使用方法、钠离子电池的制造方法
Camacho et al. Strategies to increase the stability and energy density of NVPF–A comprehensive review
Shin et al. Restacked nanohybrid graphene layers with expanded interlayer distance enabled by inorganic spacer for highly efficient, flexible Na-ion battery anodes
Lokeswararao et al. Enabling high-rate capability by combining sol-gel synthesis and solid-state reaction with PTFE of 4.2 V cathode material LiVPO4F/C
KR20190137367A (ko) 리튬 이차전지용 TiO2 기반 산화물 복합체 및 이의 제조방법
JP6176511B2 (ja) シリコン材料及び二次電池の負極
Xiong et al. A 3D interconnected NH 4 Fe 0.6 V 2.4 O 7.4@ C nanocomposite with superior sodium storage properties
KR102198624B1 (ko) 리튬이차전지용 음극활물질 및 그 제조방법

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant