CN108136380B - 含铜小孔沸石的一锅合成 - Google Patents
含铜小孔沸石的一锅合成 Download PDFInfo
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- CN108136380B CN108136380B CN201680057573.5A CN201680057573A CN108136380B CN 108136380 B CN108136380 B CN 108136380B CN 201680057573 A CN201680057573 A CN 201680057573A CN 108136380 B CN108136380 B CN 108136380B
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- zeolite
- copper
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- tepa
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/763—CHA-type, e.g. Chabazite, LZ-218
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/072—Iron group metals or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
- B01J29/52—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952 containing iron group metals, noble metals or copper
- B01J29/56—Iron group metals or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/7607—A-type
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/026—After-treatment
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/404—Nitrogen oxides other than dinitrogen oxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/01—Engine exhaust gases
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/34—Reaction with organic or organometallic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/40—Special temperature treatment, i.e. other than just for template removal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15189310 | 2015-10-12 | ||
EP15189310.4 | 2015-10-12 | ||
PCT/EP2016/073853 WO2017080722A1 (en) | 2015-10-12 | 2016-10-06 | One-pot synthesis of copper containing small-pore zeolites |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108136380A CN108136380A (zh) | 2018-06-08 |
CN108136380B true CN108136380B (zh) | 2021-07-30 |
Family
ID=54359727
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201680057573.5A Active CN108136380B (zh) | 2015-10-12 | 2016-10-06 | 含铜小孔沸石的一锅合成 |
Country Status (4)
Country | Link |
---|---|
US (1) | US10486145B2 (de) |
EP (1) | EP3362173B1 (de) |
CN (1) | CN108136380B (de) |
WO (1) | WO2017080722A1 (de) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101598723B1 (ko) * | 2014-12-30 | 2016-03-03 | 포항공과대학교 산학협력단 | 제올라이트 pst-20 및 그 제조방법, 이를 이용한 이산화탄소의 선택적 분리방법 |
FR3067020B1 (fr) | 2017-05-31 | 2022-03-18 | Ifp Energies Now | Synthese directe d'un materiau sapo de structure afx comprenant du cuivre et utilisation de ce materiau |
FR3069238B1 (fr) | 2017-07-18 | 2019-07-12 | IFP Energies Nouvelles | Synthese directe d'un materiau aluminosilicate microporeux de structure afx comprenant du cuivre et utilisation de ce materiau |
CN110997137B (zh) * | 2017-08-04 | 2022-02-25 | 巴斯夫欧洲公司 | 具有骨架类型cha且包含过渡金属以及钾和铯中的一种或多种的沸石材料 |
DE102018100833A1 (de) | 2018-01-16 | 2019-07-18 | Umicore Ag & Co. Kg | Verfahren zur Herstellung eines SCR-Katalysators |
DE102018100834A1 (de) | 2018-01-16 | 2019-07-18 | Umicore Ag & Co. Kg | Verfahren zur Herstellung eines SCR-Katalysators |
WO2019180663A1 (en) | 2018-03-21 | 2019-09-26 | Basf Corporation | Cha zeolite material and related method of synthesis |
WO2019219629A1 (en) | 2018-05-14 | 2019-11-21 | Umicore Ag & Co. Kg | Stable small-pore zeolites |
US20210138441A1 (en) | 2018-05-14 | 2021-05-13 | Umicore Ag & Co. Kg | Stable CHA Zeolites |
FR3081349B1 (fr) | 2018-05-24 | 2023-11-10 | Ifp Energies Now | Synthese directe d'un catalyseur comprenant une zeolithe de type structural afx et au moins un metal de transition pour la reduction selective de nox |
FR3081339B1 (fr) | 2018-05-24 | 2023-11-10 | Ifp Energies Now | Catalyseur comprenant une zeolithe de type structural afx de haute purete et au moins un metal de transition pour la reduction selective de nox |
FR3081348B1 (fr) | 2018-05-24 | 2023-11-10 | Ifp Energies Now | Catalyseur comprenant une zeolithe de type structural afx de tres haute purete et au moins un metal de transition pour la reduction selective de nox |
FR3081338B1 (fr) * | 2018-05-24 | 2020-06-26 | IFP Energies Nouvelles | Catalyseur a base d'un materiau aluminosilicate composite comprenant du cuivre et un melange de zeolithes de type structural afx et de type structural bea, pour la reduction selective de nox |
FR3081340B1 (fr) | 2018-05-24 | 2020-06-26 | IFP Energies Nouvelles | Catalyseur comprenant un melange d'une zeolithe de type structural afx et d'une zeolithe de type structural bea et au moins un metal de transition pour la reduction selective de nox |
FR3081351B1 (fr) | 2018-05-24 | 2021-02-26 | Ifp Energies Now | Catalyseur comprenant une zeolithe de type structural afx preparee a partir d'un melange de fau et au moins un metal de transition pour la reduction selective de nox |
FR3081346B1 (fr) * | 2018-05-24 | 2020-06-26 | IFP Energies Nouvelles | Procede de preparation d'un materiau composite zeolithique contenant du cuivre et un melange de zeolithes de type structural afx et de type structural bea |
EP3841064A1 (de) * | 2018-08-24 | 2021-06-30 | UMICORE AG & Co. KG | Verfahren zur herstellung eines molekularsiebs vom cha-typ |
CN109364989B (zh) * | 2018-11-20 | 2020-09-11 | 中国科学院生态环境研究中心 | 一种改性Cu-SSZ-13催化剂及其制备方法和用途 |
FR3095130B1 (fr) | 2019-04-19 | 2022-03-11 | Ifp Energies Now | Synthese rapide d’un catalyseur comprenant une zeolithe de type structural afx et au moins un metal de transition pour la reduction selective de nox |
JP2024513444A (ja) | 2021-04-09 | 2024-03-25 | ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト | 遷移金属促進チャバザイトのワンポット合成 |
CN113247942B (zh) * | 2021-05-13 | 2022-04-26 | 贵州理工学院 | 一种纳米氧化铜的制备方法及应用 |
WO2023180461A1 (en) | 2022-03-23 | 2023-09-28 | Umicore Ag & Co. Kg | Scr zeolite catalysts for improved nox reduction |
WO2023180462A1 (en) | 2022-03-23 | 2023-09-28 | Umicore Ag & Co. Kg | Scr zeolite catalysts for reduced n2o formation |
WO2023180460A1 (en) | 2022-03-23 | 2023-09-28 | Umicore Ag & Co. Kg | Copper and manganese containing chabazite scr catalyst for n2o reduction |
FR3142917A1 (fr) | 2022-12-09 | 2024-06-14 | IFP Energies Nouvelles | Catalyseur comprenant une zéolithe IZM-9 de type structural AFX de très haute pureté et au moins un métal de transition pour la réduction sélective de NOx |
Citations (3)
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CN101973562A (zh) * | 2010-09-07 | 2011-02-16 | 浙江大学 | 以铜胺络合物作为模板剂合成硅基分子筛的方法 |
CN104105663A (zh) * | 2012-07-03 | 2014-10-15 | 雪佛龙美国公司 | 制备高氧化硅lev-型沸石的方法 |
CN104801338A (zh) * | 2013-12-02 | 2015-07-29 | 庄信万丰股份有限公司 | Aei沸石的合成 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IN2015DN02842A (de) | 2012-12-12 | 2015-09-11 | Haldor Topsoe As | |
WO2015084817A1 (en) * | 2013-12-02 | 2015-06-11 | Johnson Matthey Public Limited Company | Mixed template synthesis of high silica cu-cha |
US11266981B2 (en) * | 2013-12-02 | 2022-03-08 | Johnson Matthey Public Limited Company | Mixed template synthesis of low silica CHA zeolite |
GB2522530B (en) * | 2013-12-03 | 2017-02-08 | Johnson Matthey Plc | Copper CHA framework Zeolite catalyst and use thereof |
US9938157B2 (en) * | 2014-07-23 | 2018-04-10 | Chevron U.S.A. Inc. | Interzeolite transformation and metal encapsulation in the absence of an SDA |
US10173211B2 (en) * | 2014-10-14 | 2019-01-08 | California Institute Of Technology | Organic-free synthesis of small pore zeolite catalysts |
US9643853B2 (en) * | 2015-01-26 | 2017-05-09 | Chevron U.S.A. Inc | Synthesis of GME framework type zeolites |
KR102413862B1 (ko) * | 2016-09-01 | 2022-06-29 | 셰브런 유.에스.에이.인크. | 제올라이트 간 변형을 통한 알루미노실리케이트 제올라이트 ssz-26의 합성 |
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2016
- 2016-10-06 WO PCT/EP2016/073853 patent/WO2017080722A1/en active Application Filing
- 2016-10-06 EP EP16778001.4A patent/EP3362173B1/de active Active
- 2016-10-06 CN CN201680057573.5A patent/CN108136380B/zh active Active
- 2016-10-06 US US15/765,873 patent/US10486145B2/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101973562A (zh) * | 2010-09-07 | 2011-02-16 | 浙江大学 | 以铜胺络合物作为模板剂合成硅基分子筛的方法 |
CN104105663A (zh) * | 2012-07-03 | 2014-10-15 | 雪佛龙美国公司 | 制备高氧化硅lev-型沸石的方法 |
CN104801338A (zh) * | 2013-12-02 | 2015-07-29 | 庄信万丰股份有限公司 | Aei沸石的合成 |
Non-Patent Citations (2)
Title |
---|
"Efficient synthesis of the Cu-SSZ-39 catalyst for DeNOx applications";Nuria Martín et al.;《Chemical Communications》;20150602;第51卷;摘要和Electronic Supplementary Information * |
"High yield synthesis of high-silica chabazite by combining the role of zeolite precursors and tetraethylammonium: SCR of NOx";Nuria Martín et al.;《Chemical Communications》;20150511;第51卷;第9965-9968页 * |
Also Published As
Publication number | Publication date |
---|---|
EP3362173A1 (de) | 2018-08-22 |
WO2017080722A1 (en) | 2017-05-18 |
CN108136380A (zh) | 2018-06-08 |
EP3362173B1 (de) | 2019-08-28 |
US10486145B2 (en) | 2019-11-26 |
US20180304242A1 (en) | 2018-10-25 |
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