FR3081349B1 - Synthese directe d'un catalyseur comprenant une zeolithe de type structural afx et au moins un metal de transition pour la reduction selective de nox - Google Patents
Synthese directe d'un catalyseur comprenant une zeolithe de type structural afx et au moins un metal de transition pour la reduction selective de nox Download PDFInfo
- Publication number
- FR3081349B1 FR3081349B1 FR1854390A FR1854390A FR3081349B1 FR 3081349 B1 FR3081349 B1 FR 3081349B1 FR 1854390 A FR1854390 A FR 1854390A FR 1854390 A FR1854390 A FR 1854390A FR 3081349 B1 FR3081349 B1 FR 3081349B1
- Authority
- FR
- France
- Prior art keywords
- transition metal
- nox
- catalyst
- selective reduction
- structural type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 229910052723 transition metal Inorganic materials 0.000 title abstract 3
- 150000003624 transition metals Chemical class 0.000 title abstract 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- 239000002243 precursor Substances 0.000 abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000010335 hydrothermal treatment Methods 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000007790 solid phase Substances 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/74—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B01J35/56—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
Abstract
L'invention concerne un procédé de préparation d'un catalyseur à base de zéolithe de type structural AFX et d'au moins un métal de transition comprenant au moins les étapes suivantes : i) mélange en milieu aqueux, d'au moins une source d'au moins d'un élément tétravalent X sous forme oxyde XO2, au moins une source d'au moins un élément tétravalent sous forme oxyde Y2O3 d'un composé organique azoté R, d'au moins une source d'au moins un métal alcalin et/ou alcalino-terreux M jusqu'à l'obtention d'un gel précurseur homogène; ii) traitement hydrothermal dudit gel précurseur pour obtenir une phase solide cristallisée, dite « solide » ;iii) au moins un échange ionique avec un métal de transition, iv) traitement thermique. L'invention concerne également le catalyseur susceptible d'être obtenu ou directement obtenu par le procédé et son utilisation pour la réduction sélective de NOx.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1854390A FR3081349B1 (fr) | 2018-05-24 | 2018-05-24 | Synthese directe d'un catalyseur comprenant une zeolithe de type structural afx et au moins un metal de transition pour la reduction selective de nox |
PCT/EP2019/062553 WO2019224081A1 (fr) | 2018-05-24 | 2019-05-16 | Synthese directe d'un catalyseur comprenant une zeolithe de type structural afx et au moins un metal de transition pour la reduction selective de nox |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1854390A FR3081349B1 (fr) | 2018-05-24 | 2018-05-24 | Synthese directe d'un catalyseur comprenant une zeolithe de type structural afx et au moins un metal de transition pour la reduction selective de nox |
FR1854390 | 2018-05-24 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3081349A1 FR3081349A1 (fr) | 2019-11-29 |
FR3081349B1 true FR3081349B1 (fr) | 2023-11-10 |
Family
ID=63834106
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1854390A Active FR3081349B1 (fr) | 2018-05-24 | 2018-05-24 | Synthese directe d'un catalyseur comprenant une zeolithe de type structural afx et au moins un metal de transition pour la reduction selective de nox |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR3081349B1 (fr) |
WO (1) | WO2019224081A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3095130B1 (fr) * | 2019-04-19 | 2022-03-11 | Ifp Energies Now | Synthese rapide d’un catalyseur comprenant une zeolithe de type structural afx et au moins un metal de transition pour la reduction selective de nox |
FR3101259B1 (fr) * | 2019-09-30 | 2022-07-29 | Ifp Energies Now | Synthese a basse temperature de catalyseur a base de zeolithe afx et son application en nh3-scr |
CN111905709A (zh) * | 2020-07-31 | 2020-11-10 | 江南大学 | 一种介孔铈钛基低温脱硝催化剂及其制备方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5194235A (en) | 1992-08-27 | 1993-03-16 | Chevron Research And Technology Company | Synthesis of SSZ-16 zeolite catalyst |
JP6070230B2 (ja) | 2013-02-01 | 2017-02-01 | 東ソー株式会社 | Afx型シリコアルミノリン酸塩及びその製造方法、並びにこれを用いた窒素酸化物還元方法 |
BR112017007017B1 (pt) * | 2014-10-07 | 2021-05-18 | Johnson Matthey Public Limited Company | catalisador para tratamento de gás de escape, catalisador de composição de revestimento, sistema de tratamento de gás de escape, e, método para tratar um gás de escape |
US20160137518A1 (en) | 2014-11-14 | 2016-05-19 | Johnson Matthey Public Limited Company | Afx zeolite |
EP3362173B1 (fr) | 2015-10-12 | 2019-08-28 | Umicore AG & Co. KG | Synthèse directe de zéolites à petite pores contenant du cuivre |
US10744449B2 (en) * | 2015-11-16 | 2020-08-18 | Exxonmobil Upstream Research Company | Adsorbent materials and methods of adsorbing carbon dioxide |
BR112018070992A2 (pt) * | 2016-05-24 | 2019-01-29 | Exxonmobil Chemical Patents Inc | zeólita sintética compreendendo um metal catalítico |
US10500573B2 (en) | 2016-09-30 | 2019-12-10 | Johnson Matthey Public Limited Company | Zeolite synthesis with alkaline earth metal |
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2018
- 2018-05-24 FR FR1854390A patent/FR3081349B1/fr active Active
-
2019
- 2019-05-16 WO PCT/EP2019/062553 patent/WO2019224081A1/fr active Application Filing
Also Published As
Publication number | Publication date |
---|---|
WO2019224081A1 (fr) | 2019-11-28 |
FR3081349A1 (fr) | 2019-11-29 |
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