CN107889472B - 制备改性粘土负载的茂金属聚合催化剂的方法、所制备的催化剂及其用途 - Google Patents

制备改性粘土负载的茂金属聚合催化剂的方法、所制备的催化剂及其用途 Download PDF

Info

Publication number
CN107889472B
CN107889472B CN201680041028.7A CN201680041028A CN107889472B CN 107889472 B CN107889472 B CN 107889472B CN 201680041028 A CN201680041028 A CN 201680041028A CN 107889472 B CN107889472 B CN 107889472B
Authority
CN
China
Prior art keywords
group
groups
substituted
clay
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201680041028.7A
Other languages
English (en)
Chinese (zh)
Other versions
CN107889472A (zh
Inventor
M.D.詹森
J.R.麦考利
A.G.辛格尔顿
D.米乔斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co Conn
Original Assignee
WR Grace and Co Conn
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WR Grace and Co Conn filed Critical WR Grace and Co Conn
Publication of CN107889472A publication Critical patent/CN107889472A/zh
Application granted granted Critical
Publication of CN107889472B publication Critical patent/CN107889472B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN201680041028.7A 2015-05-11 2016-05-09 制备改性粘土负载的茂金属聚合催化剂的方法、所制备的催化剂及其用途 Expired - Fee Related CN107889472B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562159555P 2015-05-11 2015-05-11
US62/159555 2015-05-11
PCT/US2016/031464 WO2016183006A1 (en) 2015-05-11 2016-05-09 Process to produce modified clay, supported metallocene polymerization catalyst, catalyst produced and use thereof

Publications (2)

Publication Number Publication Date
CN107889472A CN107889472A (zh) 2018-04-06
CN107889472B true CN107889472B (zh) 2021-09-07

Family

ID=57249519

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201680041028.7A Expired - Fee Related CN107889472B (zh) 2015-05-11 2016-05-09 制备改性粘土负载的茂金属聚合催化剂的方法、所制备的催化剂及其用途

Country Status (11)

Country Link
US (1) US10982023B2 (enExample)
EP (1) EP3294454A4 (enExample)
JP (1) JP6963350B2 (enExample)
KR (1) KR102578006B1 (enExample)
CN (1) CN107889472B (enExample)
BR (1) BR112017024302A2 (enExample)
CA (1) CA2985611C (enExample)
RU (1) RU2736492C2 (enExample)
SA (1) SA517390319B1 (enExample)
SG (1) SG10201912335XA (enExample)
WO (1) WO2016183006A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10940460B2 (en) 2015-05-11 2021-03-09 W. R. Grace & Co.-Conn. Process to produce modified clay, modified clay produced and use thereof
KR102578006B1 (ko) 2015-05-11 2023-09-12 더블유.알. 그레이스 앤드 캄파니-콘. 개질된 점토, 지지된 메탈로센 중합 촉매의 제조 방법, 제조된 촉매, 및 이의 용도
KR102284949B1 (ko) 2017-06-16 2021-08-03 에스케이이노베이션 주식회사 파울링 방지방법 및 올레핀의 올리고머화 방법
CN111057170B (zh) * 2019-12-06 2022-06-03 中玺新材料（安徽）有限公司 一种负载铬钕钴三金属催化剂及其制备方法和应用
US11339229B2 (en) 2020-01-27 2022-05-24 Formosa Plastics Corporation, U.S.A. Process for preparing catalysts and catalyst compositions
CN115023446B (zh) * 2020-01-27 2024-08-30 台塑工业美国公司 制备催化剂的工艺和催化剂组合物
WO2023239560A1 (en) * 2022-06-09 2023-12-14 Formosa Plastics Corporaton, U.S.A. Clay composite support-activators and catalyst compositions

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5362825A (en) * 1992-07-13 1994-11-08 Phillips Petroleum Company Catalysts for polymerizing olefins and methods
CN1683419A (zh) * 1999-12-27 2005-10-19 住友化学株式会社 改性颗粒及用该颗粒的烯烃聚合催化剂和烯烃聚合物制法
CN101238154A (zh) * 2005-08-03 2008-08-06 伊奎斯塔化学有限公司 烯烃聚合方法
CN101258173A (zh) * 2005-08-17 2008-09-03 沙特基础工业公司 用于聚合烯烃的催化剂组合物，使用它的聚合方法以及它的制备方法
CN101747462A (zh) * 2008-12-18 2010-06-23 切弗朗菲利浦化学公司 产生具有反共聚单体分布和低水平长链分支的较宽分子量分布聚合物的方法
CN103221439A (zh) * 2010-11-26 2013-07-24 巴塞尔聚烯烃股份有限公司 气相反应器中的聚乙烯聚合

Family Cites Families (127)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB489769A (en) 1937-01-25 1938-08-03 Ig Farbenindustrie Ag Improvements in the manufacture and production of water-soluble basic aluminium compounds
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US3242099A (en) 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
US4176090A (en) 1975-11-18 1979-11-27 W. R. Grace & Co. Pillared interlayered clay materials useful as catalysts and sorbents
US4248739A (en) 1979-09-04 1981-02-03 W. R. Grace & Co. Stabilized pillared interlayered clays
US4737280A (en) 1980-09-17 1988-04-12 Phillips Petroleum Company Separation of solid polymers and liquid diluent
NL8102495A (nl) 1981-05-21 1982-12-16 Philips Nv Modulaire gegevensopslaginrichting.
US4424341A (en) 1981-09-21 1984-01-03 Phillips Petroleum Company Separation of solid polymers and liquid diluent
US4501885A (en) 1981-10-14 1985-02-26 Phillips Petroleum Company Diluent and inert gas recovery from a polymerization process
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
GB8317328D0 (en) * 1983-06-25 1983-07-27 British Petroleum Co Plc Stabilised pillared layered clay
US4542118A (en) 1984-02-02 1985-09-17 W. R. Grace & Co. Catalyst manufacture
US4613484A (en) 1984-11-30 1986-09-23 Phillips Petroleum Company Loop reactor settling leg system for separation of solid polymers and liquid diluent
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5084209A (en) 1990-11-06 1992-01-28 The Dow Chemical Company Layered mixed metal hydroxides made in non-aqueous media
GB8614909D0 (en) 1986-06-19 1986-07-23 British Petroleum Co Plc Production of glycol ethers
US4761391A (en) 1986-06-30 1988-08-02 Union Oil Company Of California Delaminated clays and their use in hydrocarbon conversion processes
US4742033A (en) * 1987-01-29 1988-05-03 Phillips Petroleum Company Cracking catalysts comprising pillared clays
US4775461A (en) 1987-01-29 1988-10-04 Phillips Petroleum Company Cracking process employing catalysts comprising pillared clays
US4952544A (en) 1987-03-05 1990-08-28 Uop Stable intercalated clays and preparation method
US5202295A (en) 1987-03-05 1993-04-13 Uop Intercalated clay having large interlayer spacing
US4957889A (en) * 1987-03-05 1990-09-18 Uop Stable intercalated clays and preparation method
US5059568A (en) * 1987-03-05 1991-10-22 Uop Intercalated clay having large interlayer spacing
US4995964A (en) 1987-03-05 1991-02-26 Uop Midbarrel hydrocracking process employing rare earth pillared clays
US4939217A (en) 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
US4794096A (en) 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US5705478A (en) 1989-02-21 1998-01-06 Washington University Covalently linked β subunits of the glycoprotein hormones as antagonists
US5079203A (en) 1990-05-25 1992-01-07 Board Of Trustees Operating Michigan State University Polyoxometalate intercalated layered double hydroxides
US5575979A (en) 1991-03-04 1996-11-19 Phillips Petroleum Company Process and apparatus for separating diluents from solid polymers utilizing a two-stage flash and a cyclone separator
GB9108771D0 (en) 1991-04-24 1991-06-12 Laporte Industries Ltd Pillared clays
JP3414769B2 (ja) * 1991-05-01 2003-06-09 日本ポリケム株式会社 オレフィン重合用触媒およびこれを用いたオレフィン重合体の製造方法
TW218884B (enExample) 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
US5466766A (en) 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5401817A (en) 1991-05-09 1995-03-28 Phillips Petroleum Company Olefin polymerization using silyl-bridged metallocenes
US5210352A (en) 1991-05-09 1993-05-11 Phillips Petroleum Company Fluorene compounds
US5451649A (en) 1991-05-09 1995-09-19 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
US5191132A (en) 1991-05-09 1993-03-02 Phillips Petroleum Company Cyclopentadiene type compounds and method for making
US5347026A (en) 1993-06-11 1994-09-13 Phillips Petroleum Company Fluorene compounds and methods for making
US5399636A (en) 1993-06-11 1995-03-21 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5436305A (en) 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
US5571880A (en) 1991-05-09 1996-11-05 Phillips Petroleum Company Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process
US5631335A (en) 1991-05-09 1997-05-20 Phillips Petroleum Company Process of polymerizing olefins using diphenylsilyl or dimethyl tin bridged 1-methyl fluorenyl metallocenes
US5594078A (en) 1991-07-23 1997-01-14 Phillips Petroleum Company Process for producing broad molecular weight polyolefin
US5668230A (en) 1991-07-23 1997-09-16 Phillips Petroleum Company Olefin polymerization
US5214211A (en) 1991-12-12 1993-05-25 Uop Alkylation of diarylamines with olefins using rare earth modified pillared clays
US5354721A (en) 1993-06-22 1994-10-11 Phillips Petroleum Company Organo-aluminoxy product and use
JPH0733814A (ja) 1993-07-21 1995-02-03 Showa Denko Kk オレフィンの重合触媒及びポリオレフィンの製造方法
US5389593A (en) 1993-10-12 1995-02-14 Uop Pillared clay containing fluorided pillars
US5576259A (en) 1993-10-14 1996-11-19 Tosoh Corporation Process for producing α-olefin polymer
EP0658576B1 (en) 1993-12-17 1998-07-29 Tosoh Corporation Olefin polymerization catalyst and olefin polymerization process
US5496781A (en) 1994-05-16 1996-03-05 Phillips Petroleum Company Metallocene catalyst systems, preparation, and use
DE69525679T2 (de) 1994-05-18 2002-11-07 Mitsubishi Chemical Corp., Tokio/Tokyo Katalysator zur Polymerisation eines Olefins und Verfahren zum Polymerisieren des Olefins
US5498581A (en) 1994-06-01 1996-03-12 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
US5541272A (en) 1994-06-03 1996-07-30 Phillips Petroleum Company High activity ethylene selective metallocenes
US5420320A (en) 1994-06-08 1995-05-30 Phillips Petroleum Company Method for preparing cyclopentadienyl-type ligands and metallocene compounds
NL9401433A (nl) 1994-09-02 1996-04-01 Univ Utrecht Synthetische zwelbare kleimineralen.
US5563284A (en) 1994-09-09 1996-10-08 Phillips Petroleum Company Cyclopentadienyl-type ligands, metallocenes, catalyst systems, preparation, and use
IT1276866B1 (it) 1994-11-10 1997-11-03 Enichem Augusta Ind Catalizzatore e processo per la preparazione di composti alchilaromatici a catena lunga
NZ303800A (en) 1995-01-24 2000-05-26 Univ North Carolina Olefin polymers and block polymers, preparation, use, catalysts and catalyst intermediates
DE69611554T2 (de) 1995-02-20 2001-07-05 Tosoh Corp., Shinnanyo Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten
EP0728773B1 (en) 1995-02-21 1998-11-04 Mitsubishi Chemical Corporation Catalysts for olefin polymerization and a process for preparing olefin polymers therewith
US5631203A (en) 1995-05-04 1997-05-20 Phillips Petroleum Company Metallocene compounds and preparation thereof containing terminal alkynes
US5654454A (en) 1995-05-30 1997-08-05 Phillips Petroleum Company Metallocene preparation and use
JPH09132613A (ja) 1995-11-09 1997-05-20 Mitsubishi Chem Corp エチレン重合用触媒及びエチレン重合体の製造法
EP0791608B1 (en) 1996-02-23 2000-05-10 Tosoh Corporation Olefin polymerization catalyst based on organometallic complexes and processes for production of polyolefins using the catalyst
EP0889912B1 (en) 1996-03-27 2000-07-12 The Dow Chemical Company Highly soluble olefin polymerization catalyst activator
JP3383155B2 (ja) 1996-06-26 2003-03-04 三菱化学株式会社 エチレン系重合体
US5705579A (en) 1996-07-17 1998-01-06 Phillips Petroleum Company Olefin polymerization
JP3635822B2 (ja) 1996-11-06 2005-04-06 東ソー株式会社 オレフィン重合用触媒およびオレフィンの重合方法
JP3772472B2 (ja) 1996-11-06 2006-05-10 東ソー株式会社 オレフィン重合用触媒およびオレフィンの重合方法
US5906955A (en) 1996-12-20 1999-05-25 Tosoh Corporation Catalyst for polymerization of an olefin, and method for producing an olefin polymer
ID24325A (id) 1997-08-29 2000-07-13 Dow Chemical Co Komposit polimer pengisi yang homogen
TW381097B (en) 1997-09-18 2000-02-01 Idemitsu Petrochemical Co Catalyst for use in alkene monomer polymerization, manufacturing method for alkene polymers, and manufacturing method for styrine polymers
BR9908859A (pt) 1998-03-16 2000-10-31 Dow Chemical Co Nanocompostos de poliolefina e método para sua preparação
JP2002507533A (ja) 1998-03-26 2002-03-12 ザ ダウ ケミカル カンパニー イオン交換されているアルミニウム−マグネシウム又はフッ素化マグネシウムシリケートエーロゲル及びそれからの触媒支持体
EP1018520A4 (en) 1998-07-24 2007-07-25 Japan Polypropylene Corp PROCESS RELATING TO THE PRODUCTION OF OLEFIN POLYMER
US6395846B1 (en) 1998-08-20 2002-05-28 Idemitsu Petrochemical Co., Ltd. Catalysts for olefin polymer production
JP4173242B2 (ja) 1999-03-17 2008-10-29 出光興産株式会社 オレフィン重合用触媒及びオレフィン重合体の製造法
US6521559B1 (en) 1999-09-27 2003-02-18 The Regents Of The University Of Michigan Superior pillared clay catalysts for selective catalytic reduction of nitrogen oxides for power plant emission control
US6355594B1 (en) 1999-09-27 2002-03-12 Phillips Petroleum Company Organometal catalyst compositions
US6288182B1 (en) * 1999-10-12 2001-09-11 Saudi Basic Industries Corporation Supported metallocene catalyst system for olefin polymerization
US6559090B1 (en) 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6399535B1 (en) 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
WO2001032723A1 (en) 1999-11-01 2001-05-10 W. R. Grace & Co.-Conn. Active, heterogeneous supported bi- or tri-dentate olefin polymerisation catalyst
US6613712B1 (en) 1999-11-24 2003-09-02 Phillips Petroleum Company Organometal catalyst compositions with solid oxide supports treated with fluorine and boron
AU1362801A (en) 1999-12-10 2001-06-18 Dow Chemical Company, The Treated clay compositions and olefin polymerization catalysts comprising the same
US6632894B1 (en) 1999-12-30 2003-10-14 Phillips Petroleum Company Organometal catalyst compositions
JP2001299204A (ja) 2000-04-26 2001-10-30 Toyo Shinyaku:Kk 緑色植物粉末の製造方法
US6846943B2 (en) 2000-05-23 2005-01-25 Chisso Corporation Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
EP1160261B1 (en) 2000-05-29 2007-06-27 Japan Polychem Corporation Olefin polymerization catalyst and method for polymerizing olefin using the same
EP1241188B1 (en) 2000-09-13 2009-01-21 Japan Polychem Corporation Component of catalyst for olefin polymerization
JP2002208785A (ja) 2001-01-09 2002-07-26 Nabco Ltd 電気ボックス
US7005400B2 (en) 2001-04-05 2006-02-28 Japan Polychem Corporation Component of catalyst for polymerizing olefin, catalyst for polymerizing olefin and process for polymerizing olefin
EP1416001A4 (en) 2001-06-29 2005-03-09 Japan Polypropylene Corp CATALYST FOR OLEFINE POLYMERIZATION AND METHOD FOR OLEFIN POLYMERIZATION
EP1414746A1 (en) 2001-07-06 2004-05-06 The University Of Queensland Metal oxide nanoparticles in an exfoliated silicate framework
JP2003113209A (ja) 2001-08-01 2003-04-18 Japan Polychem Corp オレフィン重合用触媒
JP2003113210A (ja) 2001-08-03 2003-04-18 Japan Polychem Corp オレフィン重合用触媒
JP2003105015A (ja) 2001-09-28 2003-04-09 Japan Polychem Corp オレフィン重合用触媒成分
JP2003128719A (ja) 2001-10-30 2003-05-08 Tosoh Corp オレフィン系重合体の製造方法
JP2004059828A (ja) 2002-07-31 2004-02-26 Japan Polychem Corp オレフィン重合用触媒及びそれを用いるオレフィン重合体の製造方法
US6995279B2 (en) 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
WO2004026923A2 (en) 2002-09-20 2004-04-01 Exxonmobil Chemical Patents Inc. Supercritical polymerization process and polymers produced therefrom
DE10245963A1 (de) 2002-09-30 2004-04-22 Iko Minerals Gmbh Verfahren zur Herstellung von katalytisch wirkenden Schichtsilikaten
US6767975B1 (en) 2003-07-14 2004-07-27 Equistar Chemicals, Lp Olefin polymerization with pyridine moiety-containing singe-site catalysts
JP4517695B2 (ja) 2003-12-25 2010-08-04 東ソー株式会社 エチレン系重合体およびその製造方法
US7220695B2 (en) 2004-01-07 2007-05-22 Exxonmobil Chemical Patents Inc. Supported activator
US7119153B2 (en) 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
US20050288461A1 (en) 2004-06-25 2005-12-29 Jensen Michael D Polymerization catalysts for producing polymers with low levels of long chain branching
US7148298B2 (en) 2004-06-25 2006-12-12 Chevron Phillips Chemical Company, L.P. Polymerization catalysts for producing polymers with low levels of long chain branching
US20060040822A1 (en) 2004-08-23 2006-02-23 Shveima Joseph S Catalyst compositions, processes, and products utilizing pillared clays
US7226886B2 (en) 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7846318B2 (en) 2006-01-06 2010-12-07 Nextchem, Llc Polyaluminum chloride and aluminum chlorohydrate, processes and compositions: high-basicity and ultra high-basicity products
US7517939B2 (en) 2006-02-02 2009-04-14 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching
US8501655B2 (en) 2006-09-20 2013-08-06 Albemarle Corporation Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
EP2222723B1 (en) 2007-12-18 2013-02-27 Univation Technologies, LLC Method for controlling bimodal catalyst activity during polymerization
US8138269B2 (en) 2007-12-20 2012-03-20 Exxonmobil Research And Engineering Company Polypropylene ethylene-propylene copolymer blends and in-line process to produce them
US8309485B2 (en) 2009-03-09 2012-11-13 Chevron Phillips Chemical Company Lp Methods for producing metal-containing sulfated activator-supports
RU2404921C1 (ru) * 2009-05-27 2010-11-27 Государственное образовательное учреждение высшего профессионального образования "Белгородский государственный университет" Способ модифицирования глины
KR101741855B1 (ko) 2009-06-29 2017-05-30 셰브론 필립스 케미컬 컴퍼니 엘피 용융지수 감소 및 중합체 생성률 증가를 위한 이중 메탈로센 촉매시스템
CN102039181B (zh) 2009-10-16 2013-08-28 中国科学院化学研究所 粘土负载过渡金属催化剂及其制备方法与应用
US8501651B2 (en) 2010-09-24 2013-08-06 Chevron Phillips Chemical Company Lp Catalyst systems and polymer resins having improved barrier properties
US8637616B2 (en) 2010-10-07 2014-01-28 Chevron Philips Chemical Company Lp Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects
US8309748B2 (en) 2011-01-25 2012-11-13 Chevron Phillips Chemical Company Lp Half-metallocene compounds and catalyst compositions
US20130059140A1 (en) 2011-09-02 2013-03-07 Chevron Phillips Chemical Company Lp Multilayer Polymer Films Having Improved Barrier Properties
IN2014MN02035A (enExample) 2012-04-23 2015-10-09 Unilever Plc
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
KR102578006B1 (ko) 2015-05-11 2023-09-12 더블유.알. 그레이스 앤드 캄파니-콘. 개질된 점토, 지지된 메탈로센 중합 촉매의 제조 방법, 제조된 촉매, 및 이의 용도

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5362825A (en) * 1992-07-13 1994-11-08 Phillips Petroleum Company Catalysts for polymerizing olefins and methods
CN1683419A (zh) * 1999-12-27 2005-10-19 住友化学株式会社 改性颗粒及用该颗粒的烯烃聚合催化剂和烯烃聚合物制法
CN101238154A (zh) * 2005-08-03 2008-08-06 伊奎斯塔化学有限公司 烯烃聚合方法
CN101258173A (zh) * 2005-08-17 2008-09-03 沙特基础工业公司 用于聚合烯烃的催化剂组合物，使用它的聚合方法以及它的制备方法
CN101747462A (zh) * 2008-12-18 2010-06-23 切弗朗菲利浦化学公司 产生具有反共聚单体分布和低水平长链分支的较宽分子量分布聚合物的方法
CN103221439A (zh) * 2010-11-26 2013-07-24 巴塞尔聚烯烃股份有限公司 气相反应器中的聚乙烯聚合

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Ernst Booij et al..Preparation, structural characteristics and catalytic properties of large-pore rare earth element (Ce, La)/A1-pillared smectites.《Clays and Clay Minerals》.1996, *
Preparation, structural characteristics and catalytic properties of large-pore rare earth element (Ce, La)/A1-pillared smectites;Ernst Booij et al.;《Clays and Clay Minerals》;19961231;第774页摘要、第775-776页的材料及方法，第781页的结论 *

Also Published As

Publication number Publication date
JP6963350B2 (ja) 2021-11-05
KR102578006B1 (ko) 2023-09-12
EP3294454A1 (en) 2018-03-21
CN107889472A (zh) 2018-04-06
RU2736492C2 (ru) 2020-11-17
RU2017142712A (ru) 2019-06-11
KR20180006408A (ko) 2018-01-17
RU2017142712A3 (enExample) 2019-12-31
US20180142047A1 (en) 2018-05-24
BR112017024302A2 (pt) 2018-07-24
CA2985611A1 (en) 2016-11-17
SG10201912335XA (en) 2020-02-27
SA517390319B1 (ar) 2022-04-07
CA2985611C (en) 2021-06-01
WO2016183006A1 (en) 2016-11-17
JP2018520225A (ja) 2018-07-26
EP3294454A4 (en) 2019-02-27
US10982023B2 (en) 2021-04-20

Similar Documents

Publication Publication Date Title
CN107864635B (zh) 制备改性粘土的方法、所制备的改性粘土及其用途
US10982023B2 (en) Process to produce modified clay, supported metallocene polymerization catalyst
CN104661744B (zh) 催化剂体系
US20030203808A1 (en) Method of making supported transition metal polymerization catalysts and compositions formed therefrom
WO2013155982A1 (zh) 一种负载型金属氧化物双活性中心乙烯聚合催化剂及其制备方法与应用
US11814461B2 (en) Process for preparing catalysts and catalyst compositions
JP2003511524A (ja) オレフィン重合用の支持されたメタロセン触媒系
JP7578702B2 (ja) 触媒および触媒組成物の調製プロセス
CN119343380A (zh) 二氧化硅负载的聚烯烃催化剂体系

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20210907