CN1074913A - 氯乙烯聚合物 - Google Patents
氯乙烯聚合物 Download PDFInfo
- Publication number
- CN1074913A CN1074913A CN92113843A CN92113843A CN1074913A CN 1074913 A CN1074913 A CN 1074913A CN 92113843 A CN92113843 A CN 92113843A CN 92113843 A CN92113843 A CN 92113843A CN 1074913 A CN1074913 A CN 1074913A
- Authority
- CN
- China
- Prior art keywords
- oligopolymer
- polymkeric substance
- polymerization
- olefin
- alpha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005601 base polymer Polymers 0.000 title description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title description 4
- 229920002554 vinyl polymer Polymers 0.000 title description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000126 substance Substances 0.000 claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 239000004711 α-olefin Substances 0.000 claims abstract description 13
- 150000001336 alkenes Chemical class 0.000 claims abstract description 6
- 229920001519 homopolymer Polymers 0.000 claims abstract description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 37
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 9
- 239000013638 trimer Substances 0.000 claims description 5
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 4
- 230000036571 hydration Effects 0.000 claims description 2
- 238000006703 hydration reaction Methods 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 14
- 229920000915 polyvinyl chloride Polymers 0.000 description 13
- 239000003999 initiator Substances 0.000 description 10
- -1 as stablizer Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 230000009466 transformation Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical compound OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- IQFVPQOLBLOTPF-HKXUKFGYSA-L congo red Chemical compound [Na+].[Na+].C1=CC=CC2=C(N)C(/N=N/C3=CC=C(C=C3)C3=CC=C(C=C3)/N=N/C3=C(C4=CC=CC=C4C(=C3)S([O-])(=O)=O)N)=CC(S([O-])(=O)=O)=C21 IQFVPQOLBLOTPF-HKXUKFGYSA-L 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N n-alpha-hexadecene Natural products CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- 238000006384 oligomerization reaction Methods 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- GGQQNYXPYWCUHG-RMTFUQJTSA-N (3e,6e)-deca-3,6-diene Chemical compound CCC\C=C\C\C=C\CC GGQQNYXPYWCUHG-RMTFUQJTSA-N 0.000 description 1
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004610 Internal Lubricant Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229940071676 hydroxypropylcellulose Drugs 0.000 description 1
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 229940095068 tetradecene Drugs 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI916190 | 1991-12-31 | ||
| FI916190A FI95474C (fi) | 1991-12-31 | 1991-12-31 | Vinyylikloridipolymeeri |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1074913A true CN1074913A (zh) | 1993-08-04 |
Family
ID=8533759
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN92113843A Pending CN1074913A (zh) | 1991-12-31 | 1992-12-31 | 氯乙烯聚合物 |
Country Status (20)
| Country | Link |
|---|---|
| EP (1) | EP0619828A1 (enExample) |
| JP (1) | JPH07506847A (enExample) |
| KR (1) | KR940703867A (enExample) |
| CN (1) | CN1074913A (enExample) |
| AU (1) | AU3161093A (enExample) |
| BR (1) | BR9207003A (enExample) |
| CA (1) | CA2127104A1 (enExample) |
| CZ (1) | CZ154294A3 (enExample) |
| EE (1) | EE9400235A (enExample) |
| FI (1) | FI95474C (enExample) |
| HU (1) | HUT68309A (enExample) |
| LT (1) | LT3070B (enExample) |
| LV (1) | LV10115B (enExample) |
| NO (1) | NO942384L (enExample) |
| RU (1) | RU94031216A (enExample) |
| SI (1) | SI9200419A (enExample) |
| SK (1) | SK78294A3 (enExample) |
| TW (1) | TW254960B (enExample) |
| WO (1) | WO1993013144A1 (enExample) |
| YU (1) | YU112492A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747459B (zh) * | 2008-12-02 | 2011-09-07 | 卢金永 | 化学改性聚乙烯醇分散剂的制备方法 |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5780549A (en) * | 1996-07-29 | 1998-07-14 | General Electric Company | Polybutene polymers as modifiers for PVC |
| US20200149520A1 (en) * | 2017-04-28 | 2020-05-14 | Panasonic Appliances Refrigeration Devices Singapore | Sealed refrigerant compressor and refrigeration device including same |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3560462A (en) * | 1967-09-15 | 1971-02-02 | Tenneco Chem | Vinyl chloride copolymers and process for preparing same |
| JPS5812286B2 (ja) | 1974-11-22 | 1983-03-07 | リヨウニチ カブシキガイシヤ | エンカビニルジユシノ セイゾウホウホウ |
| US4031299A (en) * | 1975-04-11 | 1977-06-21 | Stauffer Chemical Company | Process for forming a polyvinyl chloride extender resin by incorporating in the suspension polymerization medium a prehomogenized solution of a polyallyl compound and a low molecular polymer of propylene |
| US4508863A (en) * | 1983-07-06 | 1985-04-02 | Argus Chemical Corporation | Stabilization of polyvinyl chloride |
| JPS61155401A (ja) | 1984-12-27 | 1986-07-15 | Mitsubishi Chem Ind Ltd | 塩化ビニル重合体の製造法 |
-
1991
- 1991-12-31 FI FI916190A patent/FI95474C/fi not_active IP Right Cessation
-
1992
- 1992-12-23 LT LTIP254A patent/LT3070B/lt not_active IP Right Cessation
- 1992-12-23 WO PCT/FI1992/000360 patent/WO1993013144A1/en not_active Ceased
- 1992-12-23 BR BR9207003A patent/BR9207003A/pt not_active Application Discontinuation
- 1992-12-23 SK SK782-94A patent/SK78294A3/sk unknown
- 1992-12-23 CA CA002127104A patent/CA2127104A1/en not_active Abandoned
- 1992-12-23 RU RU94031216/04A patent/RU94031216A/ru unknown
- 1992-12-23 EP EP93900211A patent/EP0619828A1/en not_active Ceased
- 1992-12-23 HU HU9401946A patent/HUT68309A/hu unknown
- 1992-12-23 CZ CZ941542A patent/CZ154294A3/cs unknown
- 1992-12-23 JP JP5511464A patent/JPH07506847A/ja active Pending
- 1992-12-23 AU AU31610/93A patent/AU3161093A/en not_active Abandoned
- 1992-12-23 KR KR1019940702278A patent/KR940703867A/ko not_active Withdrawn
- 1992-12-29 SI SI19929200419A patent/SI9200419A/sl unknown
- 1992-12-30 LV LVP-92-565A patent/LV10115B/lv unknown
- 1992-12-31 CN CN92113843A patent/CN1074913A/zh active Pending
- 1992-12-31 YU YU112492A patent/YU112492A/sh unknown
-
1993
- 1993-01-07 TW TW082100066A patent/TW254960B/zh active
-
1994
- 1994-06-22 NO NO942384A patent/NO942384L/no unknown
- 1994-11-22 EE EE9400235A patent/EE9400235A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747459B (zh) * | 2008-12-02 | 2011-09-07 | 卢金永 | 化学改性聚乙烯醇分散剂的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| FI95474C (fi) | 1996-02-12 |
| SK78294A3 (en) | 1995-02-08 |
| WO1993013144A1 (en) | 1993-07-08 |
| FI95474B (fi) | 1995-10-31 |
| HU9401946D0 (en) | 1994-09-28 |
| YU112492A (sh) | 1995-10-03 |
| KR940703867A (ko) | 1994-12-12 |
| FI916190A0 (fi) | 1991-12-31 |
| CZ154294A3 (en) | 1994-11-16 |
| NO942384D0 (enExample) | 1994-06-22 |
| HUT68309A (en) | 1995-06-28 |
| JPH07506847A (ja) | 1995-07-27 |
| LT3070B (en) | 1994-10-25 |
| LV10115B (en) | 1995-02-20 |
| CA2127104A1 (en) | 1993-07-08 |
| SI9200419A (en) | 1993-06-30 |
| RU94031216A (ru) | 1996-04-20 |
| BR9207003A (pt) | 1995-12-05 |
| LV10115A (lv) | 1994-05-10 |
| EE9400235A (et) | 1996-02-15 |
| EP0619828A1 (en) | 1994-10-19 |
| LTIP254A (lt) | 1994-03-25 |
| FI916190L (fi) | 1993-07-01 |
| TW254960B (enExample) | 1995-08-21 |
| AU3161093A (en) | 1993-07-28 |
| NO942384L (no) | 1994-06-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |