CN107069092A - 电解液、电化学装置、电池组、电子装置、电动车辆、电力系统以及蓄电电源 - Google Patents
电解液、电化学装置、电池组、电子装置、电动车辆、电力系统以及蓄电电源 Download PDFInfo
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- CN107069092A CN107069092A CN201710010333.6A CN201710010333A CN107069092A CN 107069092 A CN107069092 A CN 107069092A CN 201710010333 A CN201710010333 A CN 201710010333A CN 107069092 A CN107069092 A CN 107069092A
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- Prior art keywords
- electrolyte
- sulfone
- solvent
- magnesium
- magnesium salts
- Prior art date
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- 239000003792 electrolyte Substances 0.000 title claims abstract description 240
- 238000003860 storage Methods 0.000 title claims abstract description 14
- 238000009434 installation Methods 0.000 title claims abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 101
- 150000003457 sulfones Chemical class 0.000 claims abstract description 95
- 159000000003 magnesium salts Chemical class 0.000 claims abstract description 92
- 239000011777 magnesium Substances 0.000 claims description 112
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 84
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 66
- 229910052749 magnesium Inorganic materials 0.000 claims description 55
- URDYJNJREUFXGD-UHFFFAOYSA-N 1-ethylsulfonylpropane Chemical compound CCCS(=O)(=O)CC URDYJNJREUFXGD-UHFFFAOYSA-N 0.000 claims description 46
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 42
- -1 alkyl sulfone Chemical class 0.000 claims description 40
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 30
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 30
- CMXPERZAMAQXSF-UHFFFAOYSA-M sodium;1,4-bis(2-ethylhexoxy)-1,4-dioxobutane-2-sulfonate;1,8-dihydroxyanthracene-9,10-dione Chemical compound [Na+].O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=CC=C2O.CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC CMXPERZAMAQXSF-UHFFFAOYSA-M 0.000 claims description 30
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 27
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 19
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 18
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 230000005611 electricity Effects 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical compound CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 claims description 8
- YBJCDTIWNDBNTM-UHFFFAOYSA-N 1-methylsulfonylethane Chemical compound CCS(C)(=O)=O YBJCDTIWNDBNTM-UHFFFAOYSA-N 0.000 claims description 7
- 125000004429 atom Chemical group 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 7
- MBDUIEKYVPVZJH-UHFFFAOYSA-N 1-ethylsulfonylethane Chemical compound CCS(=O)(=O)CC MBDUIEKYVPVZJH-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 claims description 6
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 150000002576 ketones Chemical class 0.000 claims description 6
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 claims description 6
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 239000000446 fuel Substances 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 5
- AIDFJGKWTOULTC-UHFFFAOYSA-N 1-butylsulfonylbutane Chemical compound CCCCS(=O)(=O)CCCC AIDFJGKWTOULTC-UHFFFAOYSA-N 0.000 claims description 4
- QAPSIUMUNHNUPW-UHFFFAOYSA-N 1-methylsulfonylpropane Chemical compound CCCS(C)(=O)=O QAPSIUMUNHNUPW-UHFFFAOYSA-N 0.000 claims description 4
- ZDULHUHNYHJYKA-UHFFFAOYSA-N 2-propan-2-ylsulfonylpropane Chemical compound CC(C)S(=O)(=O)C(C)C ZDULHUHNYHJYKA-UHFFFAOYSA-N 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- VBQUDDWATQWCPP-UHFFFAOYSA-N ethylsulfonylbenzene Chemical group CCS(=O)(=O)C1=CC=CC=C1 VBQUDDWATQWCPP-UHFFFAOYSA-N 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000000962 organic group Chemical group 0.000 claims description 4
- 239000011135 tin Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical class C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 claims description 3
- QNLFYPNWULMHEA-UHFFFAOYSA-N 2-ethylsulfonylbutane Chemical compound CCC(C)S(=O)(=O)CC QNLFYPNWULMHEA-UHFFFAOYSA-N 0.000 claims description 3
- HLEIMSOLPXIGIS-UHFFFAOYSA-N 2-methyl-2-methylsulfonylpropane Chemical compound CC(C)(C)S(C)(=O)=O HLEIMSOLPXIGIS-UHFFFAOYSA-N 0.000 claims description 3
- QTKFGJSWCIAGNC-UHFFFAOYSA-N 2-methylsulfonylbutane Chemical compound CCC(C)S(C)(=O)=O QTKFGJSWCIAGNC-UHFFFAOYSA-N 0.000 claims description 3
- VTWYQAQIXXAXOR-UHFFFAOYSA-N 2-methylsulfonylpropane Chemical compound CC(C)S(C)(=O)=O VTWYQAQIXXAXOR-UHFFFAOYSA-N 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
- 241000370738 Chlorion Species 0.000 claims description 3
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 3
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical group CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 3
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 3
- 229910052790 beryllium Inorganic materials 0.000 claims description 3
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims description 3
- HQMFNPIXATUHGM-UHFFFAOYSA-N boric acid;magnesium Chemical compound [Mg].OB(O)O HQMFNPIXATUHGM-UHFFFAOYSA-N 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 229940006460 bromide ion Drugs 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 3
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 3
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- 229910052738 indium Inorganic materials 0.000 claims description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 claims description 3
- 229940006461 iodide ion Drugs 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 3
- BLQJIBCZHWBKSL-UHFFFAOYSA-L magnesium iodide Chemical compound [Mg+2].[I-].[I-] BLQJIBCZHWBKSL-UHFFFAOYSA-L 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- ATDYVUAGTYSTHS-UHFFFAOYSA-N 2-methyl-1-methylsulfonylpropane Chemical compound CC(C)CS(C)(=O)=O ATDYVUAGTYSTHS-UHFFFAOYSA-N 0.000 claims description 2
- MPCRDALPQLDDFX-UHFFFAOYSA-L Magnesium perchlorate Chemical compound [Mg+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O MPCRDALPQLDDFX-UHFFFAOYSA-L 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 claims description 2
- 229910001641 magnesium iodide Inorganic materials 0.000 claims description 2
- PNGLEYLFMHGIQO-UHFFFAOYSA-M sodium;3-(n-ethyl-3-methoxyanilino)-2-hydroxypropane-1-sulfonate;dihydrate Chemical compound O.O.[Na+].[O-]S(=O)(=O)CC(O)CN(CC)C1=CC=CC(OC)=C1 PNGLEYLFMHGIQO-UHFFFAOYSA-M 0.000 claims description 2
- 150000001408 amides Chemical group 0.000 claims 1
- 150000001413 amino acids Chemical class 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 229910001623 magnesium bromide Inorganic materials 0.000 claims 1
- 150000004702 methyl esters Chemical class 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 155
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 23
- 238000000034 method Methods 0.000 description 21
- 238000009835 boiling Methods 0.000 description 20
- 239000000243 solution Substances 0.000 description 19
- 238000002484 cyclic voltammetry Methods 0.000 description 18
- 238000004519 manufacturing process Methods 0.000 description 17
- 238000005259 measurement Methods 0.000 description 17
- 230000008859 change Effects 0.000 description 12
- 239000000460 chlorine Substances 0.000 description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 239000004210 ether based solvent Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 230000003647 oxidation Effects 0.000 description 10
- 238000007254 oxidation reaction Methods 0.000 description 10
- 238000001556 precipitation Methods 0.000 description 10
- 238000001228 spectrum Methods 0.000 description 10
- 229910052717 sulfur Inorganic materials 0.000 description 10
- 239000011593 sulfur Substances 0.000 description 10
- 238000005160 1H NMR spectroscopy Methods 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
- 239000008151 electrolyte solution Substances 0.000 description 7
- 230000002441 reversible effect Effects 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 238000005868 electrolysis reaction Methods 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 229910001494 silver tetrafluoroborate Inorganic materials 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 235000011147 magnesium chloride Nutrition 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 238000010248 power generation Methods 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 4
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
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- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- 229910021607 Silver chloride Inorganic materials 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000004891 communication Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000013049 sediment Substances 0.000 description 3
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- 229910017048 AsF6 Inorganic materials 0.000 description 2
- 229910000861 Mg alloy Inorganic materials 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical group CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- 238000001069 Raman spectroscopy Methods 0.000 description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 159000000013 aluminium salts Chemical class 0.000 description 2
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 229910001914 chlorine tetroxide Inorganic materials 0.000 description 2
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- 150000002431 hydrogen Chemical class 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000002253 near-edge X-ray absorption fine structure spectrum Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000011255 nonaqueous electrolyte Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 238000010525 oxidative degradation reaction Methods 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000007774 positive electrode material Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
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- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- PVSJGAIWOIMZFG-UHFFFAOYSA-N 1-ethylsulfonylbutane Chemical compound CCCCS(=O)(=O)CC PVSJGAIWOIMZFG-UHFFFAOYSA-N 0.000 description 1
- INLAPHKWYICSSF-UHFFFAOYSA-N 2-ethylsulfonyl-2-methylpropane Chemical compound CCS(=O)(=O)C(C)(C)C INLAPHKWYICSSF-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910019384 Mg:BF4 Inorganic materials 0.000 description 1
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- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/58—Liquid electrolytes
- H01G11/60—Liquid electrolytes characterised by the solvent
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/58—Liquid electrolytes
- H01G11/62—Liquid electrolytes characterised by the solute, e.g. salts, anions or cations therein
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/035—Liquid electrolytes, e.g. impregnating materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
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- H—ELECTRICITY
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- H—ELECTRICITY
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- H01M2300/0028—Organic electrolyte characterised by the solvent
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Inorganic Chemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Sustainable Energy (AREA)
- Molecular Biology (AREA)
- Sustainable Development (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Secondary Cells (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Hybrid Cells (AREA)
- Fuel Cell (AREA)
Abstract
Description
Claims (21)
Applications Claiming Priority (3)
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JP2012216811A JP5861606B2 (ja) | 2012-09-28 | 2012-09-28 | 電解液、電解液の製造方法および電気化学デバイス |
JP2012-216811 | 2012-09-28 | ||
CN201310425675.6A CN103715455B (zh) | 2012-09-28 | 2013-09-17 | 电解液、电解液的制造方法、以及电化学装置 |
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CN201710010333.6A Pending CN107069092A (zh) | 2012-09-28 | 2013-09-17 | 电解液、电化学装置、电池组、电子装置、电动车辆、电力系统以及蓄电电源 |
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JP2013029722A (ja) | 2011-07-29 | 2013-02-07 | Sony Corp | 表示装置および電子機器 |
US11075382B2 (en) * | 2014-05-30 | 2021-07-27 | Duracell U.S. Operations, Inc. | Cathode for an electrochemical cell including at least one cathode additive |
JP6287649B2 (ja) * | 2014-07-08 | 2018-03-07 | 株式会社村田製作所 | 電解液及び電気化学デバイス |
CN112652806A (zh) * | 2014-11-07 | 2021-04-13 | A123系统有限责任公司 | 非水性电解质溶液、可充电电池、微混合电池及电池系统 |
CN107004906B (zh) * | 2014-11-28 | 2020-04-21 | 富士胶片和光纯药株式会社 | 含镁电解液 |
KR101771330B1 (ko) * | 2014-12-09 | 2017-08-24 | 주식회사 엘지화학 | 전해질 및 이를 포함하는 이차 전지 |
JP6613573B2 (ja) * | 2015-02-06 | 2019-12-04 | 株式会社村田製作所 | 電極およびその製造方法、ならびに電気化学デバイス |
JP6677405B2 (ja) * | 2015-06-10 | 2020-04-08 | 学校法人東京理科大学 | マグネシウム二次電池用正極活物質、マグネシウム二次電池用正極、及びマグネシウム二次電池 |
CN107851849A (zh) * | 2015-07-03 | 2018-03-27 | 株式会社村田制作所 | 电解液及电化学装置 |
US9985290B2 (en) * | 2016-02-15 | 2018-05-29 | Dyson Technology Limited | Magnesium salts |
JP6863604B2 (ja) * | 2016-03-01 | 2021-04-21 | 国立研究開発法人産業技術総合研究所 | マグネシウム二次電池及びマグネシウム二次電池用非水電解液 |
WO2017168976A1 (ja) * | 2016-03-30 | 2017-10-05 | ソニー株式会社 | 多価イオン二次電池用正極活物質、多価イオン二次電池用正極、多価イオン二次電池、電池パック、電動車両、電力貯蔵システム、電動工具及び電子機器 |
TWI735558B (zh) * | 2016-04-01 | 2021-08-11 | 日商富士軟片和光純藥股份有限公司 | 含有鎂離子的電解液 |
WO2018020811A1 (ja) * | 2016-07-26 | 2018-02-01 | 株式会社村田製作所 | 電解液及び電気化学デバイス |
US11830672B2 (en) | 2016-11-23 | 2023-11-28 | KYOCERA AVX Components Corporation | Ultracapacitor for use in a solder reflow process |
JP7112084B2 (ja) * | 2017-01-31 | 2022-08-03 | 学校法人 関西大学 | 電解液、二次電池および電解液の製造方法 |
JP6863453B2 (ja) * | 2017-04-14 | 2021-04-21 | 株式会社村田製作所 | マグネシウム−硫黄二次電池用正極及びその製造方法、並びに、マグネシウム−硫黄二次電池 |
CN110799671A (zh) | 2017-06-21 | 2020-02-14 | 株式会社村田制作所 | 硫化镁材料、硫化镁复合材料、二次电池用正极部件、宽带隙半导体材料及镁二次电池以及闪锌矿型硫化镁的制造方法 |
WO2019013165A1 (ja) * | 2017-07-12 | 2019-01-17 | 株式会社村田製作所 | マグネシウム二次電池及び電解液、並びに、電解液の製造方法 |
GB2566472B (en) | 2017-09-14 | 2020-03-04 | Dyson Technology Ltd | Magnesium salts |
GB2566473B (en) | 2017-09-14 | 2020-03-04 | Dyson Technology Ltd | Magnesium salts |
GB2569387B (en) | 2017-12-18 | 2022-02-02 | Dyson Technology Ltd | Electrode |
GB2569388B (en) | 2017-12-18 | 2022-02-02 | Dyson Technology Ltd | Compound |
GB2569390A (en) | 2017-12-18 | 2019-06-19 | Dyson Technology Ltd | Compound |
GB2569392B (en) | 2017-12-18 | 2022-01-26 | Dyson Technology Ltd | Use of aluminium in a cathode material |
JP2019192631A (ja) * | 2018-04-23 | 2019-10-31 | パナソニックIpマネジメント株式会社 | アルカリ土類金属二次電池用非水電解液及びそれを用いたアルカリ土類金属二次電池 |
JP2021193638A (ja) * | 2018-08-01 | 2021-12-23 | 株式会社村田製作所 | 電気化学デバイス |
KR20220099646A (ko) * | 2021-01-07 | 2022-07-14 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 전해액 및 이를 포함하는 리튬 이차전지 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4894302A (en) * | 1985-06-14 | 1990-01-16 | The Dow Chemical Company | Alkaline earth metal anode-containing cell having electrolyte of organometallic alkaline earth metal salt and organic solvent |
CN1411086A (zh) * | 2001-09-26 | 2003-04-16 | 株式会社东芝 | 非水性电解质电池和非水性电解溶液 |
JP2009093983A (ja) * | 2007-10-11 | 2009-04-30 | Toyota Central R&D Labs Inc | 二次電池 |
US20120126231A1 (en) * | 2010-11-19 | 2012-05-24 | Semiconductor Energy Laboratory Co., Ltd. | Electric Double Layer Capacitor, Lithium Ion Capacitor, and Charging Device |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4370638B2 (ja) * | 1999-06-04 | 2009-11-25 | ソニー株式会社 | 非水電解質電池 |
US6316141B1 (en) | 1999-10-18 | 2001-11-13 | Bar Ilan University | High-energy, rechargeable, electrochemical cells with non-aqueous electrolytes |
CN101261900B (zh) * | 2001-05-11 | 2011-02-02 | 三菱化学株式会社 | 电解电容器用电解液及使用该电解液的电解电容器 |
JP4374820B2 (ja) | 2002-02-25 | 2009-12-02 | 日油株式会社 | 電気化学デバイス用電解質および二次電池 |
JP5245108B2 (ja) | 2007-07-11 | 2013-07-24 | ソニー株式会社 | マグネシウムイオン含有非水電解液及びその製造方法、並びに電気化学デバイス |
JP5428274B2 (ja) * | 2008-10-09 | 2014-02-26 | 宇部興産株式会社 | 非水電解液及びそれを用いたリチウム電池 |
JP2011060577A (ja) * | 2009-09-10 | 2011-03-24 | Sony Corp | 非水電解質電池 |
US8541133B2 (en) * | 2010-10-27 | 2013-09-24 | Toyota Motor Engineering & Manufacturing North America, Inc. | Electrochemical device with a magnesium anode and a stable, safe electrolyte compatible with sulfur |
EP2667445A4 (en) * | 2011-01-21 | 2015-06-03 | Nippon Catalytic Chem Ind | IONIC COMPOUND AND METHOD OF MANUFACTURING THEREOF, AND ELECTROLYTIC SOLUTION AND ELECTRICAL MEMORY DEVICE WITH THE IONIC COMPOUND |
KR101958181B1 (ko) | 2011-07-28 | 2019-03-14 | 후지필름 와코 준야꾸 가부시키가이샤 | 전기화학 디바이스용 전해액 |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4894302A (en) * | 1985-06-14 | 1990-01-16 | The Dow Chemical Company | Alkaline earth metal anode-containing cell having electrolyte of organometallic alkaline earth metal salt and organic solvent |
CN1411086A (zh) * | 2001-09-26 | 2003-04-16 | 株式会社东芝 | 非水性电解质电池和非水性电解溶液 |
JP2009093983A (ja) * | 2007-10-11 | 2009-04-30 | Toyota Central R&D Labs Inc | 二次電池 |
US20120126231A1 (en) * | 2010-11-19 | 2012-05-24 | Semiconductor Energy Laboratory Co., Ltd. | Electric Double Layer Capacitor, Lithium Ion Capacitor, and Charging Device |
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EP3306730A1 (en) | 2018-04-11 |
US9541516B2 (en) | 2017-01-10 |
KR102150727B1 (ko) | 2020-09-01 |
KR20140042673A (ko) | 2014-04-07 |
CN103715455B (zh) | 2017-03-01 |
EP2713431A1 (en) | 2014-04-02 |
EP2713431B1 (en) | 2018-02-28 |
CN103715455A (zh) | 2014-04-09 |
US20140127594A1 (en) | 2014-05-08 |
JP5861606B2 (ja) | 2016-02-16 |
US20160380310A1 (en) | 2016-12-29 |
US9575025B2 (en) | 2017-02-21 |
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