JP5956573B2 - マグネシウム電池用電解液 - Google Patents
マグネシウム電池用電解液 Download PDFInfo
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- JP5956573B2 JP5956573B2 JP2014519405A JP2014519405A JP5956573B2 JP 5956573 B2 JP5956573 B2 JP 5956573B2 JP 2014519405 A JP2014519405 A JP 2014519405A JP 2014519405 A JP2014519405 A JP 2014519405A JP 5956573 B2 JP5956573 B2 JP 5956573B2
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- 239000011777 magnesium Substances 0.000 title claims description 110
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims description 77
- 229910052749 magnesium Inorganic materials 0.000 title claims description 77
- 239000003792 electrolyte Substances 0.000 title claims description 33
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 32
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 22
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 10
- -1 organometallic magnesium salt Chemical class 0.000 claims description 9
- 229910052796 boron Inorganic materials 0.000 claims description 8
- 159000000003 magnesium salts Chemical class 0.000 claims description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 7
- 239000002841 Lewis acid Substances 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 5
- 239000002798 polar solvent Substances 0.000 claims description 4
- 239000002879 Lewis base Substances 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004407 fluoroaryl group Chemical group 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 150000007517 lewis acids Chemical class 0.000 claims description 3
- 150000007527 lewis bases Chemical class 0.000 claims description 3
- 125000000719 pyrrolidinyl group Chemical group 0.000 claims description 2
- 230000002194 synthesizing effect Effects 0.000 claims description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 2
- 150000002170 ethers Chemical class 0.000 claims 2
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 claims 2
- VDFVNEFVBPFDSB-UHFFFAOYSA-N 1,3-dioxane Chemical compound C1COCOC1 VDFVNEFVBPFDSB-UHFFFAOYSA-N 0.000 claims 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 claims 1
- QYHKLBKLFBZGAI-UHFFFAOYSA-N boron magnesium Chemical compound [B].[Mg] QYHKLBKLFBZGAI-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 1
- 239000012046 mixed solvent Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000008151 electrolyte solution Substances 0.000 description 19
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- 229940021013 electrolyte solution Drugs 0.000 description 11
- 238000010828 elution Methods 0.000 description 11
- 238000000151 deposition Methods 0.000 description 10
- 230000008021 deposition Effects 0.000 description 10
- 238000011161 development Methods 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 238000001556 precipitation Methods 0.000 description 10
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 9
- 229910052744 lithium Inorganic materials 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000012300 argon atmosphere Substances 0.000 description 7
- 230000002441 reversible effect Effects 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 238000011160 research Methods 0.000 description 6
- 229910052697 platinum Inorganic materials 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- WJIFKOVZNJTSGO-UHFFFAOYSA-N 1-bromo-3-methylbenzene Chemical compound CC1=CC=CC(Br)=C1 WJIFKOVZNJTSGO-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 239000002608 ionic liquid Substances 0.000 description 4
- 238000002161 passivation Methods 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- KZMGYPLQYOPHEL-UHFFFAOYSA-N Boron trifluoride etherate Chemical compound FB(F)F.CCOCC KZMGYPLQYOPHEL-UHFFFAOYSA-N 0.000 description 3
- 239000007818 Grignard reagent Substances 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004070 electrodeposition Methods 0.000 description 3
- 150000004795 grignard reagents Chemical class 0.000 description 3
- 229910001416 lithium ion Inorganic materials 0.000 description 3
- 229910052987 metal hydride Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000002048 anodisation reaction Methods 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000007774 positive electrode material Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000007784 solid electrolyte Substances 0.000 description 2
- LMFRTSBQRLSJHC-UHFFFAOYSA-N 1-bromo-3,5-dimethylbenzene Chemical compound CC1=CC(C)=CC(Br)=C1 LMFRTSBQRLSJHC-UHFFFAOYSA-N 0.000 description 1
- QDFKKJYEIFBEFC-UHFFFAOYSA-N 1-bromo-3-fluorobenzene Chemical compound FC1=CC=CC(Br)=C1 QDFKKJYEIFBEFC-UHFFFAOYSA-N 0.000 description 1
- 125000004180 3-fluorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C(F)=C1[H] 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910020366 ClO 4 Inorganic materials 0.000 description 1
- 229910020599 Co 3 O 4 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 239000005486 organic electrolyte Substances 0.000 description 1
- 125000002734 organomagnesium group Chemical group 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- FQUDFFQBTZLJEN-UHFFFAOYSA-N tris(1,5-dimethylcyclohexa-2,4-dien-1-yl)borane Chemical compound CC1(CC(=CC=C1)C)B(C1(CC(=CC=C1)C)C)C1(CC(=CC=C1)C)C FQUDFFQBTZLJEN-UHFFFAOYSA-N 0.000 description 1
- PBPBAJWEAPGLOC-UHFFFAOYSA-N tris(3-fluorophenyl)borane Chemical compound FC1=CC=CC(B(C=2C=C(F)C=CC=2)C=2C=C(F)C=CC=2)=C1 PBPBAJWEAPGLOC-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0028—Organic electrolyte characterised by the solvent
- H01M2300/0037—Mixture of solvents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
Description
不活性気体雰囲気で有機ハロゲン化物、金属マグネシウム、ホウ素ハロゲン化物を乾燥後の無水エチルエーテルにおいて反応させ、反応が開始した後に、反応液をゆっくり滴下し、微沸騰を保持しながら反応させた後、不活性気体雰囲気において濾過を行い、得られた濾過液に対して真空抽出を行うことによりエチルエーテル溶媒を除去し、ホウ素を中心としたルイス酸が得られる。
調製された0.2〜1mol/Lの電解液をinLab 710導電率測定セル(Mettler Toledo, Switzerland)に入れて、FE30導電率計により導電率を測定する。
実施例1
0.528gのMg、2.05gの三フッ化ホウ素エチルエーテル、及び少量のI2を、100mLの丸底フラスコに入れて、少量のm-メチル-ブロモベンゼンのエチルエーテル溶液を滴下した。反応が開始した後、m-メチル-ブロモベンゼンのエチルエーテル溶液をゆっくり滴下した。滴下完了後に、続いて3〜5時間攪拌し、その後、得られた反応液を窒素雰囲気で濾過した。濾過液に対して真空抽出を行うことによりエチルエーテルを除去し、トリ(メタトリル)ホウ素のろう状固体が得られた。アルゴン雰囲気のグローブ・ボックスにおいて、当該固体とPhMgClとを複合させることで、0.4MのR3B−(PhMgCl)2(Rはメタトリル)のテトラヒドロフラン溶液、即ち、新型マグネシウム二次電池用電解液が得られた。4mlの電解液をinLab 710導電率測定セル(Mettler Toledo, Switzerland)に入れて、FE30導電率計により導電率を測定した結果、電解液の導電率の値が1.2 mS/cmであった。
実施例2
0.528gのMg、2.05gの三フッ化ホウ素エチルエーテル、及び少量のI2を、100mLの丸底フラスコに入れて、少量のm-メチル-ブロモベンゼンのエチルエーテル溶液を滴下した。反応が開始した後、1−ブロモ−3,5−ジメチルベンゼンのエチルエーテル溶液をゆっくり滴下した。滴下完了後に、続いて10時間攪拌し、その後、得られた反応液を窒素雰囲気で濾過した。濾過液に対して真空抽出を行うことによりエチルエーテル溶媒を除去し、トリ(メタジメチルフェニル)ホウ素のピンク色固体が得られた。アルゴン雰囲気のグローブ・ボックスにおいて、上記固体とPhMgClとを複合させることで、0.25MのR3B−(PhMgCl)2(Rはメタジメチルフェニル)のテトラヒドロフラン溶液、即ち、新型マグネシウム二次電池用電解液が得られた。4mlの電解液をinLab 710導電率測定セル(Mettler Toledo, Switzerland)に入れて、FE30 導電率計により導電率を測定した結果、電解液の導電率の値が1.3 mS/cmであった。
実施例3
0.528gのMg、2.05gの三フッ化ホウ素エチルエーテル、及び少量のI2を、100mLの丸底フラスコに入れて、少量のm-メチル-ブロモベンゼンのエチルエーテル溶液を滴下した。反応が開始した後、m−フルオロ−ブロモベンゼンのエチルエーテル溶液をゆっくり滴下した。滴下完了後に、続いて2時間攪拌し、その後、得られた反応液を窒素雰囲気で濾過した。濾過液に対して真空抽出を行うことによりエーテル溶媒を除去し、トリ(メタフルオロフェニル)ホウ素の黄色固体が得られた。アルゴン雰囲気のグローブ・ボックスにおいて、上記固体とPhMgClとを複合させることで、0.25MのR3B−(PhMgCl)2(Rはメタフルオロフェニル)のテトラヒドロフラン溶液、即ち、新型マグネシウム二次電池用電解液が得られた。4mlの電解液をinLab 710導電率測定セル(Mettler Toledo, Switzerland)に入れて、FE30 導電率計により導電率を測定した結果、電解液の導電率の値が1.08mS/cmであった。
実施例4
実施例2で調製されたトリアリールホウ素R3B(Rは3,5−ジメチルフェニル)とPhMgClを複合させることで、0.25MのR3B−(PhMgCl)2の混合エーテル溶液(テトラエチレングリコールジメチルエーテル:テトラヒドロフラン=3:1)、即ち、新型マグネシウム二次電池用電解液を得た。この電解液は、溶媒としてのテトラヒドロフランの揮発性を大幅に低減することで、安全性が大幅に向上させた。4mlの電解液をinLab 710導電率測定セル(Mettler Toledo, Switzerland)に入れて、FE30 導電率計により導電率を測定した結果、電解液の導電率の値が0.91mS/cmであった。
Claims (5)
- 有機ホウ素マグネシウム塩を溶質として、0.2〜1mol/Lの濃度で有機エーテル類の非プロトン性極性溶媒に配合してなり、
前記有機ホウ素マグネシウム塩は、ホウ素を中心としたルイス酸R3Bとマグネシウム含有のルイス塩基R’MgXとを合成してなる有機ホウ素マグネシウム塩錯体であって、RとR’は、それぞれフルオロアリール基、アルキル化アリール基、アリール基、アルキル基、又はピロリジニル基を示し、Xはハロゲンを示すことを特徴とするマグネシウム電池用電解液。 - 前記ホウ素を中心としたルイス酸の化学式はR3Bであって、Rはアルキル化アリール基、フルオロアリール基、アリール基、又はアルキル基を示すことを特徴とする請求項1に記載のマグネシウム電池用電解液。
- 前記ホウ素を中心としたルイス酸は、以下の構造式で示す化合物からなる群から選ばれた少なくとも一つであることを特徴とする請求項2に記載のマグネシウム電池用電解液。
- 前記有機ホウ素マグネシウム塩錯体において、ルイス酸とルイス塩基とのモル配合比率は1:1〜1:3であることを特徴とする請求項1に記載のマグネシウム電池用電解液。
- 前記有機エーテル類の非プロトン性極性溶媒及びそれらの混合溶媒は、溶媒として有機マグネシウム塩を溶解するとともに、有機金属マグネシウム塩と配位し、有機エーテル類の非プロトン性極性溶媒として、テトラヒドロフラン、2‐メチルテトラヒドロフラン、ジェチルエーテル、ジブチルエーテル、1,3−ジオキサン、1,2−ジメトキシエタン、ジメチルエーテル、ジエチレングリコールジメチルエーテル、テトラエチレングリコールジメチルエーテルを含むことを特徴とする請求項1に記載のマグネシウム電池用電解液。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110254585.6A CN102916220B (zh) | 2011-08-05 | 2011-08-05 | 镁电池电解液 |
CN201110254585.6 | 2011-08-05 | ||
PCT/CN2012/079376 WO2013020463A1 (zh) | 2011-08-05 | 2012-07-30 | 镁电池电解液 |
Publications (2)
Publication Number | Publication Date |
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JP2014521195A JP2014521195A (ja) | 2014-08-25 |
JP5956573B2 true JP5956573B2 (ja) | 2016-07-27 |
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JP2014519405A Active JP5956573B2 (ja) | 2011-08-05 | 2012-07-30 | マグネシウム電池用電解液 |
Country Status (4)
Country | Link |
---|---|
US (1) | US10559851B2 (ja) |
JP (1) | JP5956573B2 (ja) |
CN (1) | CN102916220B (ja) |
WO (1) | WO2013020463A1 (ja) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103367735B (zh) * | 2013-07-15 | 2015-10-21 | 中国科学院化学研究所 | 一种镁二次电池负极材料及其应用 |
KR101611400B1 (ko) * | 2014-04-02 | 2016-04-12 | 울산과학기술원 | 마그네슘 이차전지용 전해질 및 이를 포함하는 마그네슘 이차전지 |
CN104616907A (zh) * | 2015-01-27 | 2015-05-13 | 上海奥威科技开发有限公司 | 镁离子超级电容器及制作方法 |
KR102180394B1 (ko) * | 2015-12-28 | 2020-11-19 | 중국 과학원, 쑤저우 나노기술 및 나노바이오닉스 연구소 | 단핵 마그네슘 양이온화 염, 그의 제조방법 및 응용 |
CN105633467B (zh) * | 2016-03-30 | 2018-11-06 | 宁德时代新能源科技股份有限公司 | 一种电解液及采用该电解液的锂离子电池 |
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CN109417202A (zh) * | 2016-05-27 | 2019-03-01 | 富士胶片和光纯药株式会社 | 含磷系镁离子的电解液 |
CN106299455A (zh) * | 2016-08-24 | 2017-01-04 | 扬州市喜来太阳能科技有限公司 | 具有高安全性的电池电解液及其制备方法 |
CN106450448B (zh) * | 2016-10-14 | 2019-08-02 | 中国科学院青岛生物能源与过程研究所 | 非水电解液、非水电解液的镁二次电池 |
CN108878970B (zh) * | 2018-06-29 | 2021-05-18 | 华中科技大学 | 一种复合聚合物固体电解质、固态锂电池及其制备方法 |
CN109473714B (zh) * | 2018-11-19 | 2021-08-03 | 哈尔滨工业大学 | 一种镁硫电池电解液的制备方法及其应用 |
CN111527637A (zh) * | 2018-12-05 | 2020-08-11 | 松下知识产权经营株式会社 | 镁二次电池用非水电解液和使用它的镁二次电池 |
CN109713368A (zh) * | 2018-12-06 | 2019-05-03 | 上海交通大学 | 一种可充镁电池的电解液 |
JP6917581B2 (ja) * | 2019-05-22 | 2021-08-11 | パナソニックIpマネジメント株式会社 | マグネシウム二次電池用非水電解液及びそれを用いたマグネシウム二次電池 |
TW202105821A (zh) * | 2019-05-23 | 2021-02-01 | 日商富士軟片和光純藥股份有限公司 | 鎂電池 |
CN110336079B (zh) * | 2019-06-24 | 2020-11-10 | 清华大学 | 镁电池电解液、其制备方法以及镁电池 |
JP7500050B2 (ja) | 2020-05-15 | 2024-06-17 | 国立研究開発法人物質・材料研究機構 | ホウ素系マグネシウム塩の製造方法、電解液の製造方法、ホウ素系マグネシウム塩、電解液、及び、二次電池 |
CN113258138B (zh) * | 2021-05-18 | 2022-10-21 | 重庆大学 | 一种全无机盐型可充镁电池电解液及其制备方法 |
CN113363578B (zh) * | 2021-06-08 | 2022-10-14 | 重庆大学 | 一种硼基非亲核型可充镁电池电解液及其制备方法 |
WO2023108501A1 (zh) * | 2021-12-15 | 2023-06-22 | 深圳先进技术研究院 | 钙盐电解液和电解质及其制备方法和应用 |
CN115882071A (zh) * | 2022-11-01 | 2023-03-31 | 南京工业大学 | 应用于钠离子电池的电解液及其制备方法 |
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JP5471036B2 (ja) * | 2008-06-05 | 2014-04-16 | ソニー株式会社 | マグネシウムイオン含有非水電解液及びこれを用いた電気化学デバイス |
CN101924213B (zh) * | 2010-09-07 | 2012-09-05 | 上海交通大学 | 一种硅酸钴镁在可充镁电池正极材料中的应用方法 |
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