CN106833668A - A kind of mineral microorganism soil conditioner and its production and use - Google Patents

A kind of mineral microorganism soil conditioner and its production and use Download PDF

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Publication number
CN106833668A
CN106833668A CN201611262797.8A CN201611262797A CN106833668A CN 106833668 A CN106833668 A CN 106833668A CN 201611262797 A CN201611262797 A CN 201611262797A CN 106833668 A CN106833668 A CN 106833668A
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China
Prior art keywords
parts
powder
soil
soil conditioner
mixed
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Inventor
李峰
朱昌雄
李红娜
郭萍
李莲芳
耿兵
叶婧
张燕荣
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Institute of Environment and Sustainable Development in Agriculturem of CAAS
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Institute of Environment and Sustainable Development in Agriculturem of CAAS
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Priority to CN201611262797.8A priority Critical patent/CN106833668A/en
Publication of CN106833668A publication Critical patent/CN106833668A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01BSOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
    • A01B79/00Methods for working soil
    • A01B79/02Methods for working soil combined with other agricultural processing, e.g. fertilising, planting
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G22/00Cultivation of specific crops or plants not otherwise provided for
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2101/00Agricultural use

Abstract

The present invention relates to a kind of mineral microorganism soil conditioner and its production and use, the soil conditioner contains following raw material components by weight:15 parts of 32 60 parts of clay mineral, 15 30 parts of feldspathoid, 10 15 parts of magnalium hydrotalcite, 5 10 parts of medical stone, 15 parts of plant ash, 14 parts of calcium alginate, 0.1 0.5 parts of microorganism fungus kind, 12 15 parts of natural plant extracts, 5 10 parts of turf, 68 parts of bentonite, 25 parts of rod soil, 5 10 parts of boron magnesium powder, 37 parts of powder of straw, 6 10 parts of methane slag, 25 parts of humic acid, 14 parts of chitin and chitosan oligosaccharide;Crushed by by each mineral matter, sieving, purification and second-time burning, obtain mixed-powder, then microorganism fungus kind, natural plant extracts and other nutritional ingredients are mixed with powder, fermented, sterilizing and it is dry after, obtain the soil conditioner.The soil conditioner that the present invention is provided is higher to the utilization rate of available potassium, uses it in greenhouse vegetable growing, and greenhouse vegetable can be promoted to grow, effective prevention and elimination of disease and pests, and improves quality of vegetable and nutrition.

Description

A kind of mineral microorganism soil conditioner and its production and use
Technical field
The present invention relates to technical field of crop cultivation, and in particular to a kind of mineral microorganism soil conditioner and its preparation Method and purposes.
Background technology
Soil is the basis of growth and development of plants.Plant is fixed in soil with its root system, and by root system in soil Moisture and nutrient are absorbed, to ensure its normal physiological activity.Soil plays a supportive role and supplies plant growth to plant In development to water, fertilizer, air and heat requirement, so the physicochemical property and fertility state of soil to plant growing with weight Want meaning.Soil property it is main by the soil texture and structure, thickness of soil, soil mineral, the soil organism, the soil moisture, The effect of the combined factors such as moisture and edaphon, soil acidity or alkalinity is determined.
Mineral matter, organic matter, moisture and air in soil, the ratio of these four bases decide soil property and Fertility.Soil mineral is the most basic material of soil constitution, and its content is different, the soil texture that granular size difference is constituted Also it is different, soil is generally divided into sand class, clay class, three kinds of loam class according to the size of mineral particle particle diameter.Wherein, sand Containing ore particle is more, sticking grain is few in great soil group soil, therefore looseness of soil, soil stickiness is small, and hole is more, ventilating permeable by force, but retaining Keeping fertility is poor, and soil temperature easily increases easily drop, and day and night temperature is big, and the content of organic matter is few, and because nutriment water loss is fast, fertility is not high, easily It is subjected to drought;Based on sticking grain, flour sand, viscous force is strong, and grogs gap is small, and permeability is poor, impeded drainage for clay class soil, but protects It is aqueous strong, to be glued when wet, hard when doing, more containing mineral element and organic matter, soil temperature day and night temperature is small, especially early spring, in soil temperature Rise slow, it is unfavorable to growth of seedling, often used cooperatively with other great soil groups;Loam class grogs size is placed in the middle, and proterties is between sand and sticks Between soil, sand grains, sticking grain, powder approximate equality, permeability are good, and retain water and nutrients power is strong, and the content of organic matter is more, and soil temperature is more steady It is fixed, it is preferable quality, it is adapted to most of floristic growth.
It is weeding and pest-killing, the master for improving soil nutrient content using chemical pesticide and chemical fertilizer during proportion of crop planting One of means are wanted, but it is long-term a large amount of using chemical pesticide, chemical fertilizer etc., there is soil harmful substance residual, pH value disorder, soil plate The problems such as knot phenomenon, retain water and nutrients ability, the serious degeneration of soil is caused, had a strong impact on the growth of crops.Therefore, such as What improved soil situation, improves the upgrowth situation of crops, it has also become the primary study direction in current agricultural cultivation.
Soil conditioner is by agricultural water-loss reducer and rich in based on organic matter, the natural peat of humic acid or other organic matters Raw material is wanted, is aided with bioactive ingredients and nutrient composition, the product processed through scientific technology has highly significant " water conservation, getting fat, ventilative " three big soil conditioning performances.Soil hardening, chesson can be broken, the gas permeability of soil, drop is improved The low soil weight, promotes soil microbial activities, enhancing soil rich water penetration;Resist with improved soil, improvement desert, water conservation The functions such as drought, enhancing disease-resistant crops ability, raising crop yield, improvement quality of agricultural product and recovery crops original ecological, Crop survival rate and agricultural output are increased substantially, is the novel green means of production of world's agriculture and forestry plantation.
The soil conditioner of current commercial type is primarily present four major problem:1) active ingredient is single, is taken effect after Slowly, and effect is unstable, it is impossible to fundamentally improved soil;2) primary raw material of conventional soil conditioner is extracted from ore Thing, fowl and animal excrement fermentate, food processing and domestic refuse etc., cause more harmful microorganism, heavy metal to be frequently accompanied by In product after processing, the artificial synthesized soil conditioner in part is difficult to degrade in soil, is easily caused to soil after Secondary pollution;3) consumption is big, high cost;4) traditional soil conditioner point acidic soil conditioner, basic soil conditioner It is difficult to grasp its application dosage Deng, user, if using improper, crops can be caused greatly infringement.Therefore it provides one Kind can be effectively improved soil nutrient status, improve vegetation growth state, and easy to use, consumption is few, environment amenable soil Conditioner, has important practical significance.
The content of the invention
To solve the deficiencies in the prior art, the invention provides a kind of mineral microorganism soil conditioner and its preparation side Method and purposes, specifically provide a kind of mineral microorganism soil conditioner and preparation method thereof and in greenhouse vegetable growing Purposes.The soil conditioner is combined using several mineral materials with microorganism fungus kind and natural plant extracts, and is increased Multiple nutritional components are added, it is compared using single mineral matter, single microorganism strain and single natural plant extracts For, with significant synergistic function, soil nutrient status can be improved, improve vegetation growth state, greatly promote plant Growth, and can effectively prevention and elimination of disease and pests.
It is up to this purpose, present invention employs following technical scheme:
In a first aspect, the invention provides a kind of mineral microorganism soil conditioner, the soil conditioner is by weight Amount part contains following raw material components:
Clay mineral 32-60 parts, feldspathoid 15-30 parts, magnalium hydrotalcite 10-15 parts, medical stone 5-10 parts, vegetation It is grey 1-5 parts, calcium alginate 1-4 parts, microorganism fungus kind 0.1-0.5 parts, natural plant extracts 12-15 parts, turf 5-10 parts, it is swollen 6-8 parts of soil of profit, 2-5 parts of rod soil, 5-10 parts of boron magnesium powder, powder of straw 3-7 parts, methane slag 6-10 parts, humic acid 2-5 parts, chitin 1-4 parts and chitosan oligosaccharide 1-5 parts.
The soil conditioner that the present invention is provided is using three kinds of mineral matters and microorganism fungus kind and natural plant extracts It is combined, it is compared for the single mineral matter of use, single microorganism strain and single natural plant extracts, the group There is significant synergistic function between each raw material components for closing.
Clay mineral in the present invention is composite S iO2、Al2O3、Fe2O3, the inorganic matter such as MgO natural crystal, it is from ground Beneath collection do not contain to crops be harmful to heavy metal or radioactive substance and unpolluted natural crystal.Specifically, Clay mineral for example can be kaolin, montmorillonite, illite, chlorite, sepiolite group, mixing crystal layer clay mineral in appoint Meaning it is a kind of or at least two mixtures, the preferably mixture of montmorillonite, chlorite and sepiolite, the quality of the mixture matches somebody with somebody Than being (1-2):(2-5):(1-3), preferably 2:3:1, the clay mineral mixture under this quality proportioning can be farthest Improve the utilization power of available phosphorus in soil.
Feldspathoid in the present invention can be selected from any one in potassium feldspar, albite or nepheline or at least two Mixture, the preferably mixture of albite and nepheline, two kinds of quality proportionings of feldspathoid are (1-3):(5-7), it is excellent Elect 2 as:5, the utilization power of the effective potassium in farthest can improving soil of the feldspathoid under this quality proportioning.
Magnalium hydrotalcite in the present invention can be public using those skilled in the art such as coprecipitation, double drop methods, hydro-thermal methods The method known is prepared, and particular determination is not done herein.
Exemplarily, the magnalium hydrotalcite in the present invention can be adopted and is prepared with the following method:
Magnesium-aluminum hydrotalcite is prepared using unstable state coprecipitation:Take a certain proportion of magnesium salts (MgCl2·6H2O), aluminium salt (AlCl3·6H2O), with deionized water dissolving, mixing salt solution is obtained;By weak aqua ammonia (1:5) it is slowly added in mixing salt solution, Regulation pH to 9.5 or so, production hydroxide co-precipitation;5h, suction filtration are aged after being stirred vigorously, and are constantly washed with deionized water Wash, after suction filtration at 80 DEG C constant temperature drying 24h, cross 80 mesh sieves, be obtained magnalium hydrotalcite.
Present invention preferably employs the magnalium hydrotalcite that surface is modified, the modified mode in its surface can be using following operation:
Magnalium hydrotalcite is diluted to uniform slurries with the deionized water of its three times volume, glycerin monostearate is existed It is added in slurries by the mass fraction of 2-4% under uniform temperature, after stirring 20-60min at 40-60 DEG C, slurries suction filtration, is washed Wash, 105 DEG C dry 6h in drying box, obtain modified magnalium hydrotalcite.
Heretofore described calcium alginate can be prepared using method well known in the art, it would however also be possible to employ commercially available product Product, but, it is preferred to use the calcium alginate that following methods are prepared from, the calcium alginate prepared using the method, it can To play synergistic function between clay mineral and magnalium hydrotalcite, soil conditioner is further enhanced to quick-acting in soil The utilization rate of potassium, further improves the quality of greenhouse vegetable.
The preferred preparation method of the calcium alginate, comprises the following steps:
(1) sea-tangle or brown alga are washed with water logging, then adds 8-10% soda ash, after 40-45 DEG C of insulation digests 4-6 hours, It is diluted with water, is filtrated to get sodium alginate soln;
(2) adding the 5-8% calcium aqueous solution carries out calcification;
(3) adding 1-5% hydrochloric acid solutions carries out decalcification, and add water washing, and is dehydrated to moisture content 70-75%;
(4) after granulating, crushed after being refrigerated to -44 DEG C, grinding particle size is 20-25 mesh;
(5) the alginic acid 10-25kg after Freezing smashing is taken, 10-20% alcohol 10-25kg are added, adds calcium carbonate to adjust pH To neutrality.According to the present invention, the natural plant extracts press (3-7) by chingma abutilon seed, root tuber of aromatic turmeric and Fructus meliae toosendan:(1-6):(3-5) Mass ratio composition, its mass ratio such as can be 3:1:3、4:1:3、5:1:3、6:1:3、3:2:3、3:5:3、3:1:5 or 4: 5:5, preferably 4:2:5.
The natural plant extracts provided in the present invention can cooperate with microorganism fungus kind to be fermented, and it reaches attenuation degree Most fully, the utilization power of available phosphorus and effective potassium in soil is effectively improved.
According to the present invention, the microorganism fungus kind contains bacillus licheniformis, bacillus subtilis and bacillus pumilus, Other strains can also be contained, particular determination is not done herein.
In the present invention, the mass ratio of the bacillus licheniformis, bacillus subtilis and bacillus pumilus is (1-5): (5-1):(1-5), for example, can be 1:1:1、1:5:1、1:3:2、2:5:3、3:3:4 or 5:1:5, preferably 1:1:1.
In the present invention, the shared weight portion in soil conditioner of the clay mineral is 32-60 parts, for example, can be 32 Part, 35 parts, 40 parts, 42 parts, 45 parts, 48 parts, 50 parts, 54 parts, 56 parts, 58 parts or 60 parts;The feldspathoid is adjusted in soil Shared weight portion is 15-30 parts in reason agent, for example can be 15 parts, 16 parts, 18 parts, 20 parts, 21 parts, 22 parts, 23 parts, 25 Part, 28 parts, 29 parts or 30 parts;The shared weight portion in soil conditioner of the magnalium hydrotalcite is 10-15 parts, for example can be with It is 10 parts, 11 parts, 12 parts, 13 parts, 14 parts or 15 parts;The shared weight portion in soil conditioner of the medical stone is 5-10 Part, such as 5 parts, 6 parts, 7 parts, 8 parts or 10 parts;The shared weight portion in soil conditioner of the plant ash is 1-5 parts, for example 1 part, 2 parts, 3 parts or 5 parts;The shared weight portion in soil conditioner of the calcium alginate be 1-4 parts, such as 1 part, 2 parts, 3 Part, 3.2 parts, 3.5 parts or 4 parts;The shared weight portion in soil conditioner of the microorganism fungus kind is 0.1-0.5 parts, for example It can be 0.1 part, 0.2 part, 0.3 part, 0.4 part or 0.5 part;The shared weight in soil conditioner of the natural plant extracts Amount part is 12-15 parts, for example, can be 12 parts, 13 parts, 14 parts or 15 parts.
In the present invention, the shared weight portion in soil conditioner of the turf be 5-10 parts, such as 5 parts, 6 parts, 7 parts, 8 Part, 9 parts or 10 parts;The shared weight portion in soil conditioner of the bentonite is 6-8 parts, such as 6 parts, 7 parts or 8 parts;Institute It is 2-5 parts, such as 2 parts, 3 parts, 4 parts or 5 parts to state the shared weight portion in soil conditioner of rod soil;The boron magnesium powder is in soil Shared weight portion is 5-10 parts, such as 5 parts, 6 parts, 8 parts or 10 parts in conditioner;Powder of straw institute in soil conditioner The weight portion for accounting for is 3-7 parts, such as 3 parts, 4 parts, 5 parts or 7 parts;The shared weight portion in soil conditioner of the methane slag is 6-10 parts, such as 6 parts, 8 parts or 10 parts;The shared weight portion in soil conditioner of the humic acid be 2-5 parts, such as 2 parts, 3 parts, 4 parts or 5 parts;The shared weight portion in soil conditioner of the chitin is 1-4 parts, such as 1 part, 2 parts, 3 parts or 4 Part;The shared weight portion in soil conditioner of the chitosan oligosaccharide is 1-5 parts, such as 1 part, 2 parts, 3 parts, 4 parts or 5 parts.
According to the present invention, the soil conditioner preferably comprises following raw material components by weight:Clay mineral 40-55 Part, feldspathoid 18-25 parts, magnalium hydrotalcite 12-15 parts, medical stone 5-8 parts, plant ash 1-4 parts, calcium alginate 3-4 parts, Microorganism species 0.1-0.2 parts, natural plant extracts 12-14 parts, turf 5-8 parts, bentonite 6-7 parts, 2-4 parts of rod soil, boron Magnesium powder 5-8 parts, powder of straw 3-6 parts, methane slag 6-8 parts, humic acid 2-4 parts, chitin 1-3 parts and chitosan oligosaccharide 1-4 parts.
In second aspect, present invention also offers the preparation side of mineral microorganism soil conditioner as described in relation to the first aspect Method, it is comprised the following steps:
(1) clay mineral, feldspathoid and magnalium hydrotalcite are respectively crushed into the particle of 500-1000 mesh to be formed It is powdered;
(2) powdered clay mineral, feldspathoid and magnalium hydrotalcite are mixed, then purifies and carry out secondary combustion Burn;
(3) mixed-powder after burning is mixed with microorganism fungus kind and natural plant extracts, and is fermented;
(4) mixture after fermentation is sterilized and is dried;
(5) by medical stone, plant ash, calcium alginate, turf, bentonite, rod soil, boron magnesium powder, powder of straw, methane slag, corruption Phytic acid, chitin and chitosan oligosaccharide are added in the mixture of step (4), obtain the soil conditioner.
According to the present invention, in step (1), clay mineral, feldspathoid and magnalium hydrotalcite are respectively crushed into 500- The particle of 1000 mesh is powdered to be formed.
According to the present invention, in step (2), the purpose of the purification is to be purified simultaneously from the mineral powders of powder morphology Separate to human body or crops harmful heavy metal and radioactive substance, can be carried out using method of purification well known in the art, Particular determination is not done herein.
When the preparation of soil conditioner is carried out, prominent technological means is employed the mixed powder of mineral matter to the present invention End carries out second-time burning, and through the second-time burning, it can make mineral matter discharge effective mineral of preventing and treating greenhouse vegetable pest and disease damage Property material, it is ensured that the effective preventing and treating when soil conditioner is applied to greenhouse vegetable to pest and disease damage, promote the growth of plant.
According to the present invention, step (2) described second-time burning is comprised the following steps:
A () is burnt for the first time:Mixed-powder is heated into 2-3h at a temperature of 100-120 DEG C to be calcined;
B () is burnt for second:15- will be heated at a temperature of 880-1000 DEG C through the mixed-powder of first time burning 30min is calcined.
The present invention employs the roasting of lower temperature first, and then heating roasting at relatively high temperatures again, makes ore deposit therein Physical property material has obtained effective release.
Burnt for first time, the heating-up temperature of mixed-powder is 100-120 DEG C, for example can be 100 DEG C, 102 DEG C, 105 DEG C, 108 DEG C, 110 DEG C, 112 DEG C, 115 DEG C, 118 DEG C or 120 DEG C, time of heating is 2-3h, for example can be 2.1h, 2.2h, 2.3h, 2.5h, 2.6h, 2.7h, 2.8h, 2.9h or 3h.
Burnt for second, be 880-1000 DEG C through the heating-up temperature of the mixed-powder of first time burning, for example can be with It it is 880 DEG C, 900 DEG C, 910 DEG C, 920 DEG C, 930 DEG C, 940 DEG C, 950 DEG C, 960 DEG C, 980 DEG C or 1000 DEG C, the time of heating is 15-30min, for example can be 15min, 16min, 18min, 20min, 22min, 23min, 25min, 26min, 28min or 30min。
According to the present invention, step (3) fermentation includes:By the mixed-powder after burning and microorganism fungus kind, natural plant After thing extract and water are mixed, ferment 12-25d at a temperature of 50-90 DEG C, for example 50 DEG C, 52 DEG C, 55 DEG C, 58 DEG C, At a temperature of 60 DEG C, 62 DEG C, 65 DEG C, 70 DEG C, 75 DEG C, 80 DEG C, 82 DEG C, 85 DEG C or 90 DEG C ferment 12d, 15d, 16d, 18d, 20d, 22d, 23d or 25d.
According to the present invention, step (4) sterilizing and drying include:Gone out at a temperature of 100-180 DEG C in roaster Bacterium 30-45min, and be dried with 180-200 DEG C of temperature.
According to the present invention, the preparation method of the soil conditioner specifically may comprise steps of:
(1) clay mineral, feldspathoid and magnalium hydrotalcite are respectively crushed into the particle of 500-1000 mesh to be formed It is powdered;
(2) powdered clay mineral, feldspathoid and magnalium hydrotalcite are mixed, then purification and secondary combustion Burn, the second-time burning is comprised the following steps:
A () is burnt for the first time:Mixed-powder is heated into 2-3h at a temperature of 100-120 DEG C to be calcined;
B () is burnt for second:15- will be heated at a temperature of 880-1000 DEG C through the mixed-powder of first time burning 30min is calcined;
(3) mixed-powder after burning is mixed with microorganism fungus kind and natural plant extracts, and in 50-90 DEG C of temperature The lower fermentation 12-25d of degree;
(4) mixture after fermentation is sterilized 30-45min at a temperature of 100-180 DEG C, and with 180-200 DEG C of temperature Degree is dried;
(5) by medical stone, plant ash, calcium alginate, turf, bentonite, rod soil, boron magnesium powder, powder of straw, methane slag, corruption Phytic acid, chitin and chitosan oligosaccharide are added in the mixture of step (4), obtain the soil conditioner.
Exemplarily, the preparation method of soil conditioner of the present invention is comprised the following steps:
(1) clay mineral, feldspathoid and magnalium hydrotalcite are respectively crushed into the particle of 600-800 mesh to form powder Last shape;
(2) powdered clay mineral, feldspathoid and magnalium hydrotalcite are mixed, then purification and secondary combustion Burn, the second-time burning is comprised the following steps:
A () is burnt for the first time:Mixed-powder is heated into 2h at a temperature of 115 DEG C to be calcined;
B () is burnt for second:Roasted 20min is heated at a temperature of 980 DEG C through the mixed-powder of first time burning Burn;
(3) mixed-powder after burning is mixed with microorganism fungus kind and natural plant extracts, and in 75 DEG C of temperature Lower fermentation 18d;
(4) mixture after fermentation is sterilized 35min at a temperature of 120 DEG C, and is dried with 195 DEG C of temperature;
(5) by medical stone, plant ash, calcium alginate, turf, bentonite, rod soil, boron magnesium powder, powder of straw, methane slag, corruption Phytic acid, chitin and chitosan oligosaccharide are added in the mixture of step (4), obtain the soil conditioner.
Or, the preparation method of soil conditioner of the present invention is comprised the following steps:
(1) clay mineral, feldspathoid and magnalium hydrotalcite are respectively crushed into the particle of 700-800 mesh to form powder Last shape;
(2) powdered clay mineral, feldspathoid and magnalium hydrotalcite are mixed, then purification and secondary combustion Burn, the second-time burning is comprised the following steps:
A () is burnt for the first time:Mixed-powder is heated into 2h at a temperature of 100 DEG C to be calcined;
B () is burnt for second:Roasted 30min is heated at a temperature of 880 DEG C through the mixed-powder of first time burning Burn;
(3) mixed-powder after burning is mixed with microorganism fungus kind and natural plant extracts, and in 60 DEG C of temperature Lower fermentation 12d;
(4) mixture after fermentation is sterilized 40min at a temperature of 120 DEG C, and is dried with 200 DEG C of temperature;
(5) by medical stone, plant ash, calcium alginate, turf, bentonite, rod soil, boron magnesium powder, powder of straw, methane slag, corruption Phytic acid, chitin and chitosan oligosaccharide are added in the mixture of step (4), obtain the soil conditioner.
Convenient in order to apply, soil conditioner need to be processed into certain formulation.In some embodiments that the present invention is provided, The formulation of soil conditioner is pulvis, granule or aqueous suspension agent.But the formulation of soil conditioner of the present invention is not limited to this, Those skilled in the art think feasible formulation within protection scope of the present invention.
In some embodiments that the present invention is provided, auxiliary material when preparing soil conditioner can be carrier, binding agent, prevent The mixture for freezing more than one or both of agent or thickener.But the auxiliary material of soil conditioner of the present invention is not limited to this, Those skilled in the art think feasible auxiliary material within protection scope of the present invention.
Pulvis is one kind of the formulations of pesticide, and it is that one or more medicament and filler and a small amount of auxiliary agent are blended, crushes again Mix to the powderous preparations of certain fineness, can be used directly, or used after the appropriate filler of addition and some auxiliary dilution agents, have Easy to use, powder is thin, compared with can be uniformly distributed, dissemination efficiency is high, save labour and the relatively low advantage of processing charges.In this hair In some embodiments of bright offer, soil conditioner pulvis includes the soil conditioning composition and carrier that the present invention is provided.
Preferably, in soil conditioner pulvis carrier be one or both of calcium sulfate, white carbon or bentonite with On mixture.
It is further preferred that carrier is calcium sulfate, white carbon and bentonitic mixture in soil conditioner pulvis.
In some embodiments that the present invention is provided, in soil conditioner pulvis, the soil conditioning combination that the present invention is provided Thing 11-80 parts, calcium sulfate 1-10 parts, white carbon 1-20 parts, bentonite 1-87 parts.
Soil conditioner of the invention can be prepared in the form of granule or suspending agent, its preparation method and use To the technology that is well known to those skilled in the art of carrier, particular determination is not done herein.
Mineral microorganism soil conditioner provided by the present invention applies to the soil conditioner of greenhouse vegetable, its phase In being planted for field crop etc., advantage is that can significantly more improve quality and the nutrition of vegetables, while can also promote It grows and prevents pest and disease damage.
According to the present invention, the method for application of the soil conditioner includes above-mentioned pulvis, granule or aqueous suspension agent form, It is wherein best with the application effect of pulvis.
According to the present invention, including cucumber, tomato, rape etc., wherein optimum applies soil conditioner to the greenhouse vegetable For tomato, it is most notable with the raising of nutrition to Tomato Quality.
Fourth aspect, present invention also offers the user of mineral microorganism soil conditioner as described in relation to the first aspect Method, it includes with powder or particle being applied to described soil conditioner in greenhouse vegetable;It is preferred that prior to seeding phase, seedling stage enter Row is applied.
Compared with prior art, the present invention at least has the advantages that:
The soil conditioner that the present invention is provided is higher to the utilization rate of available potassium, in using it for greenhouse vegetable growing, can Promote greenhouse vegetable growth, effective prevention and elimination of disease and pests, and improve quality of vegetable and nutrition.
Specific embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art are it will be clearly understood that the implementation Example is only to aid in understanding the present invention, is not construed as to concrete restriction of the invention.
Embodiment 1
A kind of mineral microorganism soil conditioner, is made up of following raw material components by weight:
50 parts of clay mineral, 21 parts of feldspathoid, 15 parts of magnalium hydrotalcite, 5 parts of medical stone, 2 parts of plant ash, alginic acid 3 parts of calcium, 0.15 part of microorganism fungus kind, 13 parts of natural plant extracts, 6 parts of turf, 6 parts of bentonite, rod soil 4 parts, boron magnesium powder 8 Part, 5 parts of powder of straw, 8 parts of methane slag, 3 parts of humic acid, 3 parts of chitin and 4 parts of chitosan oligosaccharide.
Wherein, clay mineral is the mixture of montmorillonite, chlorite and sepiolite, and its quality proportioning is 2:3:1;Feldspar Mineral are the mixture of albite and nepheline, and its quality proportioning is 2:5;Magnalium hydrotalcite is modified through glycerin monostearate;It is micro- Biological inoculum is 1 by bacillus licheniformis, bacillus subtilis and bacillus pumilus in mass ratio:1:1 composition;Natural plants Extract is 4 by chingma abutilon seed, root tuber of aromatic turmeric and Fructus meliae toosendan in mass ratio:2:5 compositions.
The preparation method of mineral microorganism soil conditioner, comprises the following steps:
(1) clay mineral, feldspathoid and magnalium hydrotalcite are respectively crushed into the particle of 600-800 mesh to form powder Last shape;
(2) powdered clay mineral, feldspathoid and magnalium hydrotalcite are mixed, then purification and secondary combustion Burn, the second-time burning is comprised the following steps:
A () is burnt for the first time:Mixed-powder is heated into 2.5h at a temperature of 105 DEG C to be calcined;
B () is burnt for second:Roasted 15min is heated at a temperature of 920 DEG C through the mixed-powder of first time burning Burn;
(3) mixed-powder after burning is mixed with microorganism fungus kind and natural plant extracts, and at 80 DEG C At a temperature of ferment 15d;
(4) the High Temperature Rotating 35min by the mixture after fermentation in roaster below 180 DEG C is sterilized, and with 200 DEG C of temperature is dried;
(5) by medical stone, plant ash, calcium alginate, turf, bentonite, rod soil, boron magnesium powder, powder of straw, methane slag, corruption Phytic acid, chitin and chitosan oligosaccharide are added in the mixture of step (4), obtain the soil conditioner.
Embodiment 2
Compared with Example 1, in addition to being constituted using following raw material, other are same as Example 1.
A kind of mineral microorganism soil conditioner, is made up of following raw material components by weight:
52 parts of clay mineral, 20 parts of feldspathoid, 13 parts of magnalium hydrotalcite, 7 parts of medical stone, 3 parts of plant ash, alginic acid 4 parts of calcium, 0.1 part of microorganism fungus kind, 12 parts of natural plant extracts, 7 parts of turf, 6 parts of bentonite, rod soil 2 parts, 6 parts of boron magnesium powder, 3 parts of 3 parts of powder of straw, 8 parts of methane slag, 4 parts of humic acid, 1 part of chitin and chitosan oligosaccharide.
Wherein, clay mineral is the mixture of montmorillonite, chlorite and sepiolite, and its quality proportioning is 2:4:1;Feldspar Mineral are the mixture of albite and nepheline, and its quality proportioning is 1:5;Magnalium hydrotalcite is modified through glycerin monostearate;It is micro- Biological inoculum is 1 by bacillus licheniformis, bacillus subtilis and bacillus pumilus in mass ratio:1:1 composition;Natural plants Extract is 3 by chingma abutilon seed, root tuber of aromatic turmeric and Fructus meliae toosendan in mass ratio:1:5 compositions.
Embodiment 3
Compared with Example 1, in addition to being constituted using following raw material, other are same as Example 1.
A kind of mineral microorganism soil conditioner, is made up of following raw material components by weight:
58 parts of clay mineral, 25 parts of feldspathoid, 10 parts of magnalium hydrotalcite, 10 parts of medical stone, 1 part of plant ash, marine alga 3 parts of sour calcium, 0.2 part of microorganism fungus kind, 15 parts of natural plant extracts, 5 parts of turf, 8 parts of bentonite, rod soil 2 parts, boron magnesium powder 10 Part, 7 parts of powder of straw, 10 parts of methane slag, 4 parts of humic acid, 4 parts of chitin and 5 parts of chitosan oligosaccharide.
Wherein, clay mineral is montmorillonite, kaolin and illitic mixture, and its quality proportioning is 1:2:1;Feldspar Mineral are the mixture of potassium feldspar and albite, and its quality proportioning is 3:5;Magnalium hydrotalcite is non-modified;Microorganism fungus kind by Bacillus licheniformis, bacillus subtilis and bacillus pumilus are 1 in mass ratio:2:1 composition;Natural plant extracts are by the winter Certain herbaceous plants with big flowers, root tuber of aromatic turmeric and Fructus meliae toosendan are 5 in mass ratio:1:3 compositions.
Embodiment 4
Compared with Example 1, in addition to using following preparation method, other are same as Example 1.
The preparation method of mineral microorganism soil conditioner, comprises the following steps:
(1) clay mineral, feldspathoid and magnalium hydrotalcite are respectively crushed into the particle of 750-1000 mesh to be formed It is powdered;
(2) powdered clay mineral, feldspathoid and magnalium hydrotalcite are mixed, then purification and secondary combustion Burn, the second-time burning is comprised the following steps:
A () is burnt for the first time:Mixed-powder is heated into 2h at a temperature of 120 DEG C to be calcined;
B () is burnt for second:Roasted 30min is heated at a temperature of 880 DEG C through the mixed-powder of first time burning Burn;
(3) mixed-powder after burning is mixed with microorganism fungus kind and natural plant extracts, and at 60 DEG C At a temperature of ferment 20d;
(4) the High Temperature Rotating 45min by the mixture after fermentation in roaster below 120 DEG C is sterilized, and with 190 DEG C of temperature is dried;
(5) by medical stone, plant ash, calcium alginate, turf, bentonite, rod soil, boron magnesium powder, powder of straw, methane slag, corruption Phytic acid, chitin and chitosan oligosaccharide are added in the mixture of step (4), obtain the soil conditioner.
Comparative example 1
Compared with Example 1, in addition to mineral matter only adds clay mineral, other are same as Example 1.
Comparative example 2
Compared with Example 1, in addition to mineral matter only adds feldspathoid, other are same as Example 1.
Comparative example 3
Compared with Example 1, in addition to mineral matter only adds magnalium hydrotalcite, other are same as Example 1.
Comparative example 4
Compared with Example 1, in addition to without natural plant extracts, other are same as Example 1.
Comparative example 5
Compared with Example 1, in addition to without calcium alginate, other are same as Example 1.
Comparative example 6
Compared with Example 1, except only to mixed-powder carrying out one in mineral microorganism soil conditioner preparation method Outside secondary burning, other are same as Example 1.
The preparation method of mineral microorganism soil conditioner, comprises the following steps:
(1) clay mineral, feldspathoid and magnalium hydrotalcite are respectively crushed into the particle of 600-800 mesh to form powder Last shape;
(2) powdered clay mineral, feldspathoid and magnalium hydrotalcite are mixed, is then purified and 105 2.5h is heated at a temperature of DEG C to be calcined;
(3) mixed-powder after burning is mixed with microorganism fungus kind and natural plant extracts, and at 80 DEG C At a temperature of ferment 15d;
(4) the High Temperature Rotating 35min by the mixture after fermentation in roaster below 180 DEG C is sterilized, and with 200 DEG C of temperature is dried;
(5) by medical stone, plant ash, calcium alginate, turf, bentonite, rod soil, boron magnesium powder, powder of straw, methane slag, corruption Phytic acid, chitin and chitosan oligosaccharide are added in the mixture of step (4), obtain the soil conditioner.
Comparative example 7
Compared with Example 1, except only to mixed-powder carrying out one in mineral microorganism soil conditioner preparation method Outside secondary burning, other are same as Example 1.
The preparation method of mineral microorganism soil conditioner, comprises the following steps:
(1) clay mineral, feldspathoid and magnalium hydrotalcite are respectively crushed into the particle of 600-800 mesh to form powder Last shape;
(2) powdered clay mineral, feldspathoid and magnalium hydrotalcite are mixed, is then purified and 920 15min is heated at a temperature of DEG C to be calcined;
(3) mixed-powder after burning is mixed with microorganism fungus kind and natural plant extracts, and at 80 DEG C At a temperature of ferment 15d;
(4) the High Temperature Rotating 35min by the mixture after fermentation in roaster below 180 DEG C is sterilized, and with 200 DEG C of temperature is dried;
(5) by medical stone, plant ash, calcium alginate, turf, bentonite, rod soil, boron magnesium powder, powder of straw, methane slag, corruption Phytic acid, chitin and chitosan oligosaccharide are added in the mixture of step (4), obtain the soil conditioner.
It is used for greenhouse vegetable the following is the mineral microorganism soil conditioner prepared using embodiment 1-4 and comparative example 1-7 The cultivation of dish.
First, basic condition
Date of test:In March, -2016 in October, 2015
Test site:In Shunyi District of Beijing Great Sun Ge Village town Huan Fasuo Shunyi base
Trial crops:Tomato
Research contents:Soil conditioner is to tomato growth facilitation effect and qualitative effects
2nd, experimental design
Mineral microorganism soil prepared by embodiment 1-4 and comparative example 1-7 is applied on the tomato of Cultivation in Greenhouse Conditioner pulvis, with clear water as control group.
Environmental condition:
The canopy of Shunyi base 6 (70 meters of * long are wide 6.8 meters), there is ventilation, insulation, sunshade and pipeline drip irrigation facilities.Experimental plot Cultivation condition (soil types, fertilizer, broadcast load phase, growing stage and crop seeding row spacing etc.) uniformity.
Test material:Tomato, gold hat 28
Tested fertilizer:Composite microbe fertilizer, the production of Divine Land Chinese nation (Beijing) Bioisystech Co., Ltd, active ingredient:N+ P2O5+K2O=25%, bacillus licheniformis >=0.2 hundred million/gram, amino acid >=5%, organic matter >=10%, every mu of use of usage amount 100 Kilogram;Chemical fertilizer, Sinofert Limited, N+P2O5+K2O >=44%, every mu of 50 kilograms of use.
Application method:
Seed soaking:Mineral microorganism soil conditioner pulvis and water prepared by embodiment 1-4 and comparative example 1-7 presses 1:200 The dilute mixing of ratio after, seed is put in sterilization of soaking seed within 2-8h.
Soil treatment:Before sowing, every 100 square metres are uniformly splashed prepared by 1 kilogram of embodiment 1-4 and comparative example 1-7 Mineral microorganism soil conditioner pulvis, and composite microbe fertilizer and chemical fertilizer mixing are turned over, then spray a water.
Production period is sprayed:The cotyledon of vegetable crop starts with soil conditioner and water by 1 when growing to second stage: 200、1:500、1:The water sprinkling of 1000 dilution proportion, sprays once, to results for every 7 days.
3rd, result of the test
(1) tomato growth situation
(two are expressed as in form on November 12nd, 2015 (stage is expressed as in form), on January 26th, 2016 respectively Stage) and the average plant height of on March 16th, 2016 (being expressed as three stages in form) measurement tomato, most branch, linear leaf, and calculate The final crop on March 16 in 2016.
Table 1
(2) Tomato Quality is determined
Its vitamin C, total reducing sugar, lycopene and vitamin A content are determined to the tomato for harvesting using identical standard.
Table 2
By the above results it can be seen that:
(1) measurement data in table 1 can be seen that the mineral microorganism soil conditioner of embodiment 1-4 preparations Product is used for tomato, and its growing way is preferable;Through measurement, average plant height, branch and most linear leaf and total output after its administration refer to Mark is superior to comparative example 1-7, illustrates that mineral microorganism soil conditioner prepared by embodiment 1-4 is produced to tomato growth and raising Measurer is obviously promoted effect.
(2) index of quality in table 2 can be seen that the mineral microorganism soil conditioner of embodiment 1-4 preparations Product is high compared with comparative example 1-7 to the utilization rate of available potassium, after testing, vitamin C, total reducing sugar, tomato in the tomato after its use Red pigment and vitamin A yield are higher than comparative example 1-7, illustrate mineral microorganism soil conditioner prepared by embodiment 1-4 Tomato Quality is significantly improved.
Mineral microorganism soil conditioner prepared by embodiment 1-4 is used in greenhouse cucumber and rape cultivation, and its is same Sample can play the facilitation to greenhouse cucumber and growth of rape and yield, and improve the quality of cucumber and rape.
Applicant states that the present invention illustrates detailed process equipment of the invention and technological process by above-described embodiment, But the invention is not limited in above-mentioned detailed process equipment and technological process, that is, do not mean that the present invention has to rely on above-mentioned detailed Process equipment and technological process could be implemented.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention, Addition, the selection of concrete mode to the equivalence replacement and auxiliary element of each raw material of product of the present invention etc., all fall within of the invention Within the scope of protection domain and disclosure.

Claims (10)

1. a kind of mineral microorganism soil conditioner, it is characterised in that contain following raw material components by weight:
Clay mineral 32-60 parts, feldspathoid 15-30 parts, magnalium hydrotalcite 10-15 parts, medical stone 5-10 parts, plant ash 1- 5 parts, calcium alginate 1-4 parts, microorganism fungus kind 0.1-0.5 parts, natural plant extracts 12-15 parts, turf 5-10 parts, bentonite 6-8 parts, 2-5 parts of rod soil, 5-10 parts, powder of straw 3-7 parts, methane slag 6-10 parts, humic acid 2-5 parts, chitin 1-4 parts of boron magnesium powder With chitosan oligosaccharide 1-5 parts.
2. soil conditioner as claimed in claim 1, it is characterised in that contain following raw material components by weight:
Clay mineral 40-55 parts, feldspathoid 18-25 parts, magnalium hydrotalcite 12-15 parts, medical stone 5-8 parts, plant ash 1-4 Part, calcium alginate 3-4 parts, microorganism species 0.1-0.2 parts, natural plant extracts 12-14 parts, turf 5-8 parts, bentonite 6- 7 parts, 2-4 parts of rod soil, 5-8 parts, powder of straw 3-6 parts, methane slag 6-8 parts, humic acid 2-4 parts, chitin 1-3 parts of boron magnesium powder and shell Oligosaccharides 1-4 parts.
3. soil conditioner as claimed in claim 1 or 2, it is characterised in that the clay mineral is selected from and contains SiO2、Al2O3、 Fe2O3, MgO natural crystal;
Preferably, the feldspathoid is any one in potassium feldspar, albite or nepheline or at least two mixture;
Preferably, the natural plant extracts press (3-7) by chingma abutilon seed, root tuber of aromatic turmeric and Fructus meliae toosendan:(1-6):The mass ratio of (3-5) Composition;
Preferably, the microorganism fungus kind contains bacillus licheniformis, bacillus subtilis and bacillus pumilus;
Preferably, the mass ratio of the bacillus licheniformis, bacillus subtilis and bacillus pumilus is (1-5):(5-1): (1-5)。
4. the preparation method of the soil conditioner as described in one of claim 1-3, it is characterised in that comprise the following steps:
(1) clay mineral, feldspathoid and magnalium hydrotalcite are respectively crushed into the particle of 500-1000 mesh to form powder Shape;
(2) powdered clay mineral, feldspathoid and magnalium hydrotalcite are mixed, then purifies and carry out second-time burning;
(3) mixed-powder after burning is mixed with microorganism fungus kind and natural plant extracts, and is fermented;
(4) mixture after fermentation is sterilized and is dried;
(5) by medical stone, plant ash, calcium alginate, turf, bentonite, rod soil, boron magnesium powder, powder of straw, methane slag, humic acid, Chitin and chitosan oligosaccharide are added in the mixture of step (4), obtain the soil conditioner.
5. method as claimed in claim 4, it is characterised in that step (2) described second-time burning is comprised the following steps:
A () is burnt for the first time:Mixed-powder is heated into 2-3h at a temperature of 100-120 DEG C to be calcined;
B () is burnt for second:Enter 15-30min is heated at a temperature of 880-1000 DEG C through the mixed-powder of first time burning Row roasting.
6. the method as described in claim 4 or 5, it is characterised in that step (3) fermentation is at a temperature of 50-90 DEG C Fermentation 12-25d;
Preferably, step (4) sterilizing and drying includes:Sterilize 30-45min at a temperature of 100-180 DEG C, and with 180- 200 DEG C of temperature is dried.
7. the method as described in one of claim 4-6, it is characterised in that the described method comprises the following steps:
(1) clay mineral, feldspathoid and magnalium hydrotalcite are respectively crushed into the particle of 500-1000 mesh to form powder Shape;
(2) powdered clay mineral, feldspathoid and magnalium hydrotalcite are mixed, then purifies and carry out second-time burning; The second-time burning is comprised the following steps:
A () is burnt for the first time:Mixed-powder is heated into 2-3h at a temperature of 100-120 DEG C to be calcined;
B () is burnt for second:Enter 15-30min is heated at a temperature of 880-1000 DEG C through the mixed-powder of first time burning Row roasting;
(3) mixed-powder after burning is mixed with microorganism fungus kind and natural plant extracts, and at a temperature of 50-90 DEG C Fermentation 12-25d;
(4) mixture after fermentation is sterilized 30-45min at a temperature of 100-180 DEG C, and is entered with 180-200 DEG C of temperature Row drying;
(5) by medical stone, plant ash, calcium alginate, turf, bentonite, rod soil, boron magnesium powder, powder of straw, methane slag, humic acid, Chitin and chitosan oligosaccharide are added in the mixture of step (4), obtain the soil conditioner.
8. as described in one of claim 1-3 mineral microorganism soil conditioner purposes, it is characterised in that by described soil Earth conditioner is applied in greenhouse vegetable plantation with powder or particle.
9. purposes as claimed in claim 8, it is characterised in that the greenhouse vegetable includes cucumber, tomato or rape, preferably kind Eggplant.
10. as described in one of claim 1-3 mineral microorganism soil conditioner application method, it is characterised in that by institute Soil conditioner is stated to be administered in greenhouse vegetable sowing early stage, seedling stage.
CN201611262797.8A 2016-12-30 2016-12-30 A kind of mineral microorganism soil conditioner and its production and use Pending CN106833668A (en)

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