CN106436368A - 一种三向织物的涂料印花工艺 - Google Patents

一种三向织物的涂料印花工艺 Download PDF

Info

Publication number
CN106436368A
CN106436368A CN201610766286.3A CN201610766286A CN106436368A CN 106436368 A CN106436368 A CN 106436368A CN 201610766286 A CN201610766286 A CN 201610766286A CN 106436368 A CN106436368 A CN 106436368A
Authority
CN
China
Prior art keywords
agent
dimensional weave
printing
treatment
pigment printing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610766286.3A
Other languages
English (en)
Inventor
温明华
陶建玉
尹寿虎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Hengxin Knitting Printing & Dyeing Co Ltd
Original Assignee
Suzhou Hengxin Knitting Printing & Dyeing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Hengxin Knitting Printing & Dyeing Co Ltd filed Critical Suzhou Hengxin Knitting Printing & Dyeing Co Ltd
Priority to CN201610766286.3A priority Critical patent/CN106436368A/zh
Publication of CN106436368A publication Critical patent/CN106436368A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/41—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using basic dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
    • D06P1/5235—Polyalkenyl halides, e.g. PVC
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D06P1/5257—(Meth)acrylic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67391—Salts or oxidising-compounds mixtures
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Coloring (AREA)

Abstract

本发明公开了一种三向织物的涂料印花工艺，采用生物酶改性前处理→水洗前处理→漂白前处理→印花前处理→印花→蒸化固色→后整理→水洗烘干的工艺流程，在印花前首先进行了生物酶改性前处理，对三向织物进行改性处理，再进行了水洗前处理以及漂白前处理，一方面改善三向织物染色上色难的缺点，另一方面有效避免涂料印花工艺中因三向织物的缩水或其纹理特点造成的印花出现参差现象的发生，此外采用特制的涂料印花颜料墨水进行印花，水洗工艺采用温水水洗+热风烘干，刺激颜料的化学耐受性，增强其耐水洗性能和吸着率；本发明具有印花流畅、色彩鲜艳、上色深度适宜、不易褪色，工艺简单等优点。

Description

一种三向织物的涂料印花工艺
技术领域
本发明涉及织物的加工方法，尤其涉及一种三向织物的涂料印花工艺。
背景技术
涂料印花是使用高分子化合物作为粘合剂，把颜料机械的粘附于织物上，经后期处理获得有一定弹性、耐磨、耐手搓、耐褶皱的透明树脂花纹的印花方法，涂料骨着在纤维上的机理同其他染料固着在纤维上的机理不同，它是靠粘合剂在织物上形成监牢、无色透明的膜，将涂料机械地覆盖在织物上，因此，用涂料印花适用于大多数纤维，且工艺简单，印制效果较好。
三向织物是由相互相交角度为60°的三系统纱线织成的织物，它具有较好的结构稳定性和各向相同的力学性质，在航空(如飞机翼布、气球外罩)、医疗绷带、塑料增强用织物等方面具有特殊的用途。但也正是由于三向织物其结构上的特殊性，由三系统纱线交错而成，三种角度的纱线导致了对织物的涂料印花存在了一定的困难，具有印花不均，容易产生印位相错的现象的问题。
因此，需要一种新的技术方案来解决上述问题。
发明内容
发明目的：为了解决现有技术所存在的问题，本发明提供了一种印花效果流畅，无异位错位现象、上色深度适宜、色牢度好、美观大方的三向织物的涂料印花工艺。
技术方案：为达到上述目的，本发明采用以下技术方案：一种三向织物的涂料印花工艺，包括以下步骤：
(1)生物酶改性前处理：将三向织物进行生物酶改性前处理，浴比1:6-1:9，使用的生物酶为酸性纤维素酶、蛋白酶、淀粉酶三者3:2:1的混合物，生物酶用量0.8-1.5g/L，处理时间18-32min，pH调节为4.5-5.5；
(2)水洗前处理：将经过生物酶改性前处理的织物装袋投入水洗机进行水洗，加入6-9g/L的表面活性剂，温度为30-45℃、浴比为1:20-1:25，水洗时间为35-45min；水洗后的三向织物脱水至7成干；
(3)漂白前处理：将进行水洗后的三向织物进行漂白处理，浴比1:6-1:9，加入2-4g/L的硅酸钠、4-6g/L的混合漂白剂，采用冷轧堆一浴法工艺进行漂白处理；
(4)印花前处理：印花前先对漂白后水洗至7成干的织物进行预烘处理，采用低温-高温-低温相结合的方式，具体首先55-65℃低温预烘4-6min，升温至105-115℃高温预烘3-5min，再降温至55-65℃低温预烘2-4min；
(5)印花：配制涂料印花色浆，所述涂料印花色浆的配制按照以下配方以重量计进行配制：活性染料5％-12％、阳离子染料6-18％、纳米材料4-7％、填料1-4％、分散剂2-4％、甲壳质5-9％、聚丙烯酸多元酯类4-6％、染色增深剂4-6％、织物粘合剂6-9％、合成增稠剂1-4％、抗皱整理剂1-2％、织物表面涂层剂0.3-0.7％、pH调节剂0.2-3％、余量的水；使用上述颜料墨水采用涂料印花装置对三向织物进行喷印；
(6)蒸化固色：采用快速蒸化机，温度为130-140℃，蒸化固色时间为4-8min；
(7)后整理：采用高温热定型工艺进行后整理；
(8)水洗烘干：将经过后整理的三向织物采用温水洗涤后热风烘干。
更为优选的，步骤(2)中表面活性剂为非离子型表面活性剂。
更为优选的，步骤(3)中所述混合漂白剂为烷基二酚醚二磺酸盐表面活性剂、次氯酸钠、双氧水质量比为1:3:2的混合物。
更为优选的，步骤(3)中漂白的处理温度为55-65℃、处理时间为25-35min。
更为优选的，步骤(5)中所述阳离子染料为共轭型阳离子染料。
更为优选的，步骤(5)中所述染色增深剂为壳聚糖与柠檬酸质量比为1:4的混合物。
更为优选的，步骤(5)中所述填料为钛白粉与轻质碳酸钙质量比为3:2的混合物。
更为优选的，步骤(5)中所述合成增稠剂为碱溶性增稠剂。
更为优选的，步骤(5)中抗皱整理剂为带有环氧基基团或巯基基团的有机硅化合物。
更为优选的，步骤(5)中所述织物表面涂层剂为丙烯酸酯聚合物与聚氯乙烯质量比为1:3的混合物。
有益效果：本发明所提供的一种三向织物的涂料印花工艺，采用生物酶改性前处理→水洗前处理→漂白前处理→印花前处理→印花→蒸化固色→后整理→水洗烘干的工艺流程，在印花前首先进行了生物酶改性前处理，对三向织物进行改性处理，再进行了水洗前处理以及漂白前处理，一方面改善三向织物染色上色难的缺点，另一方面有效避免涂料印花工艺中因三向织物的缩水或其纹理特点造成的印花出现参差现象的发生，此外采用特制的涂料印花颜料墨水进行印花，水洗工艺采用温水水洗+热风烘干，刺激颜料的化学耐受性，增强其耐水洗性能和吸着率；本发明具有印花流畅、色彩鲜艳、上色深度适宜、不易褪色，工艺简单等优点。
具体实施方式
下面结合具体实施例对本发明进行进一步说明：
实施例1：
一种三向织物的涂料印花工艺，包括以下步骤：
(1)生物酶改性前处理：将三向织物进行生物酶改性前处理，浴比1:6，使用的生物酶为酸性纤维素酶、蛋白酶、淀粉酶三者3:2:1的混合物，生物酶用量0.8g/L，处理时间18min，pH调节为4.5；
(2)水洗前处理：将经过生物酶改性前处理的织物装袋投入水洗机进行水洗，加入6g/L的非离子型表面活性剂，温度为30℃、浴比为1:20，水洗时间为35min；水洗后的三向织物脱水至7成干；
(3)漂白前处理：将进行水洗后的三向织物进行漂白处理，浴比1:6，加入2g/L的硅酸钠、4g/L的混合漂白剂，采用冷轧堆一浴法工艺进行漂白处理；所述混合漂白剂为烷基二酚醚二磺酸盐表面活性剂、次氯酸钠、双氧水质量比为1:3:2的混合物，漂白的处理温度为55℃、处理时间为25min；
(4)印花前处理：印花前先对漂白后水洗至7成干的织物进行预烘处理，采用低温-高温-低温相结合的方式，具体首先55℃低温预烘4min，升温至105-115℃高温预烘3min，再降温至55℃低温预烘2min；
(5)印花：配制涂料印花色浆，所述涂料印花色浆的配制按照以下配方以重量计进行配制：活性染料5％、阳离子染料6％、纳米材料4％、填料1％、分散剂2％、甲壳质5％、聚丙烯酸多元酯类4％、染色增深剂4％、织物粘合剂6％、合成增稠剂1％、抗皱整理剂1％、织物表面涂层剂0.3％、pH调节剂0.2％、余量的水；使用上述颜料墨水采用涂料印花装置对三向织物进行喷印；
(6)蒸化固色：采用快速蒸化机，温度为130℃，蒸化固色时间为4min；
(7)后整理：采用高温热定型工艺进行后整理；
(8)水洗烘干：将经过后整理的三向织物采用温水洗涤后热风烘干。
其中，所述阳离子染料为共轭型阳离子染料，染色增深剂为壳聚糖与柠檬酸质量比为1:4的混合物，填料为钛白粉与轻质碳酸钙质量比为3:2的混合物，合成增稠剂为碱溶性增稠剂，抗皱整理剂为带有环氧基基团的有机硅化合物，织物表面涂层剂为丙烯酸酯聚合物与聚氯乙烯质量比为1:3的混合物。
实施例2：
一种三向织物的涂料印花工艺，包括以下步骤：
(1)生物酶改性前处理：将三向织物进行生物酶改性前处理，浴比1:9，使用的生物酶为酸性纤维素酶、蛋白酶、淀粉酶三者3:2:1的混合物，生物酶用量1.5g/L，处理时间32min，pH调节为5.5；
(2)水洗前处理：将经过生物酶改性前处理的织物装袋投入水洗机进行水洗，加入9g/L的非离子型表面活性剂，温度为45℃、浴比为1:25，水洗时间为45min；水洗后的三向织物脱水至7成干；
(3)漂白前处理：将进行水洗后的三向织物进行漂白处理，浴比1:9，加入4g/L的硅酸钠、6g/L的混合漂白剂，采用冷轧堆一浴法工艺进行漂白处理；所述混合漂白剂为烷基二酚醚二磺酸盐表面活性剂、次氯酸钠、双氧水质量比为1:3:2的混合物，漂白的处理温度为65℃、处理时间为35min；
(4)印花前处理：印花前先对漂白后水洗至7成干的织物进行预烘处理，采用低温-高温-低温相结合的方式，具体首先65℃低温预烘6min，升温至115℃高温预烘5min，再降温至65℃低温预烘4min；
(5)印花：配制涂料印花色浆，所述涂料印花色浆的配制按照以下配方以重量计进行配制：活性染料12％、阳离子染料18％、纳米材料7％、填料4％、分散剂4％、甲壳质9％、聚丙烯酸多元酯类6％、染色增深剂6％、织物粘合剂9％、合成增稠剂4％、抗皱整理剂2％、织物表面涂层剂0.7％、pH调节剂3％、余量的水；使用上述颜料墨水采用涂料印花装置对三向织物进行喷印；
(6)蒸化固色：采用快速蒸化机，温度为140℃，蒸化固色时间为8min；
(7)后整理：采用高温热定型工艺进行后整理；
(8)水洗烘干：将经过后整理的三向织物采用温水洗涤后热风烘干。
其中，所述阳离子染料为共轭型阳离子染料，染色增深剂为壳聚糖与柠檬酸质量比为1:4的混合物，填料为钛白粉与轻质碳酸钙质量比为3:2的混合物，合成增稠剂为碱溶性增稠剂，抗皱整理剂为带有巯基基团的有机硅化合物，织物表面涂层剂为丙烯酸酯聚合物与聚氯乙烯质量比为1:3的混合物。
实施例3：
一种三向织物的涂料印花工艺，包括以下步骤：
(1)生物酶改性前处理：将三向织物进行生物酶改性前处理，浴比1:7，使用的生物酶为酸性纤维素酶、蛋白酶、淀粉酶三者3:2:1的混合物，生物酶用量1.3g/L，处理时间24min，pH调节为5.0；
(2)水洗前处理：将经过生物酶改性前处理的织物装袋投入水洗机进行水洗，加入7g/L的非离子型表面活性剂，温度为38℃、浴比为1:23，水洗时间为40min；水洗后的三向织物脱水至7成干；
(3)漂白前处理：将进行水洗后的三向织物进行漂白处理，浴比1:7，加入3g/L的硅酸钠、5g/L的混合漂白剂，采用冷轧堆一浴法工艺进行漂白处理；所述混合漂白剂为烷基二酚醚二磺酸盐表面活性剂、次氯酸钠、双氧水质量比为1:3:2的混合物，漂白的处理温度为60℃、处理时间为30min；
(4)印花前处理：印花前先对漂白后水洗至7成干的织物进行预烘处理，采用低温-高温-低温相结合的方式，具体首先60℃低温预烘5min，升温至110℃高温预烘4min，再降温至60℃低温预烘3min；
(5)印花：配制涂料印花色浆，所述涂料印花色浆的配制按照以下配方以重量计进行配制：活性染料8％、阳离子染料12％、纳米材料6％、填料2％、分散剂3％、甲壳质7％、聚丙烯酸多元酯类5％、染色增深剂5％、织物粘合剂8％、合成增稠剂3％、抗皱整理剂1.5％、织物表面涂层剂0.6％、pH调节剂1.7％、余量的水；使用上述颜料墨水采用涂料印花装置对三向织物进行喷印；
(6)蒸化固色：采用快速蒸化机，温度为135℃，蒸化固色时间为6min；
(7)后整理：采用高温热定型工艺进行后整理；
(8)水洗烘干：将经过后整理的三向织物采用温水洗涤后热风烘干。
其中，所述阳离子染料为共轭型阳离子染料，染色增深剂为壳聚糖与柠檬酸质量比为1:4的混合物，填料为钛白粉与轻质碳酸钙质量比为3:2的混合物，合成增稠剂为碱溶性增稠剂，抗皱整理剂为带有环氧基基团的有机硅化合物，织物表面涂层剂为丙烯酸酯聚合物与聚氯乙烯质量比为1:3的混合物。
取上述完成涂料印花得到的三向织物成品各20cm×20cm，采用ISO105 C06：1994+Corl：2002的方法，25℃条件下，机洗自然晾干，测试耐水洗等级，测试结果如下表所示：
从上表数据可看出，采用实施例1-3所制成的涂料印花三向织物，较现有技术相比，具有明显的耐水洗优势，且印花效果流畅，上色深度适宜、不易褪色，无异位错位现象、色牢度好。
应当指出，以上具体实施方式仅用于说明本发明而不用于限制本发明的范围，在阅读了本发明之后，本领域技术人员对本发明的各种等价形式的修改均落于本申请所附权利要求所限定的范围。

Claims (10)

1.一种三向织物的涂料印花工艺，其特征在于包括以下步骤：
(1)生物酶改性前处理：将三向织物进行生物酶改性前处理，浴比1:6-1:9，使用的生物酶为酸性纤维素酶、蛋白酶、淀粉酶三者3:2:1的混合物，生物酶用量0.8-1.5g/L，处理时间18-32min，pH调节为4.5-5.5；
(2)水洗前处理：将经过生物酶改性前处理的织物装袋投入水洗机进行水洗，加入6-9g/L的表面活性剂，温度为30-45℃、浴比为1:20-1:25，水洗时间为35-45min；水洗后的三向织物脱水至7成干；
(3)漂白前处理：将进行水洗后的三向织物进行漂白处理，浴比1:6-1:9，加入2-4g/L的硅酸钠、4-6g/L的混合漂白剂，采用冷轧堆一浴法工艺进行漂白处理；
(4)印花前处理：印花前先对漂白后水洗至7成干的织物进行预烘处理，采用低温-高温-低温相结合的方式，具体首先55-65℃低温预烘4-6min，升温至105-115℃高温预烘3-5min，再降温至55-65℃低温预烘2-4min；
(5)印花：配制涂料印花色浆，所述涂料印花色浆的配制按照以下配方以重量计进行配制：活性染料5％-12％、阳离子染料6-18％、纳米材料4-7％、填料1-4％、分散剂2-4％、甲壳质5-9％、聚丙烯酸多元酯类4-6％、染色增深剂4-6％、织物粘合剂6-9％、合成增稠剂1-4％、抗皱整理剂1-2％、织物表面涂层剂0.3-0.7％、pH调节剂0.2-3％、余量的水；使用上述颜料墨水采用涂料印花装置对三向织物进行喷印；
(6)蒸化固色：采用快速蒸化机，温度为130-140℃，蒸化固色时间为4-8min；
(7)后整理：采用高温热定型工艺进行后整理；
(8)水洗烘干：将经过后整理的三向织物采用温水洗涤后热风烘干。
2.根据权利要求1所述的三向织物的涂料印花工艺，其特征在于：步骤(2)中表面活性剂为非离子型表面活性剂。
3.根据权利要求1所述的三向织物的涂料印花工艺，其特征在于：步骤(3)中所述混合漂白剂为烷基二酚醚二磺酸盐表面活性剂、次氯酸钠、双氧水质量比为1:3:2的混合物。
4.根据权利要求1所述的三向织物的涂料印花工艺，其特征在于：步骤(3)中漂白的处理温度为55-65℃、处理时间为25-35min。
5.根据权利要求1所述的三向织物的涂料印花工艺，其特征在于：步骤(5)中所述阳离子染料为共轭型阳离子染料。
6.根据权利要求1所述的三向织物的涂料印花工艺，其特征在于：步骤(5)中所述染色增深剂为壳聚糖与柠檬酸质量比为1:4的混合物。
7.根据权利要求1所述的三向织物的涂料印花工艺，其特征在于：步骤(5)中所述填料为钛白粉与轻质碳酸钙质量比为3:2的混合物。
8.根据权利要求1所述的三向织物的涂料印花工艺，其特征在于：步骤(5)中所述合成增稠剂为碱溶性增稠剂。
9.根据权利要求1所述的三向织物的涂料印花工艺，其特征在于：步骤(5)中抗皱整理剂为带有环氧基基团或巯基基团的有机硅化合物。
10.根据权利要求1所述的三向织物的涂料印花工艺，其特征在于：步骤(5)中所述织物表面涂层剂为丙烯酸酯聚合物与聚氯乙烯质量比为1:3的混合物。
CN201610766286.3A 2016-08-30 2016-08-30 一种三向织物的涂料印花工艺 Pending CN106436368A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610766286.3A CN106436368A (zh) 2016-08-30 2016-08-30 一种三向织物的涂料印花工艺

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610766286.3A CN106436368A (zh) 2016-08-30 2016-08-30 一种三向织物的涂料印花工艺

Publications (1)

Publication Number Publication Date
CN106436368A true CN106436368A (zh) 2017-02-22

Family

ID=58091034

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610766286.3A Pending CN106436368A (zh) 2016-08-30 2016-08-30 一种三向织物的涂料印花工艺

Country Status (1)

Country Link
CN (1) CN106436368A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110016821A (zh) * 2019-04-16 2019-07-16 吉林工程技术师范学院 一种环保生态服装印花工艺

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103469621A (zh) * 2013-09-13 2013-12-25 句容市后白镇迎瑞印花厂 一种三向织物的染整工艺
CN103469622A (zh) * 2013-09-13 2013-12-25 句容市后白镇迎瑞印花厂 一种三向织物的印花工艺
CN104762838A (zh) * 2015-04-27 2015-07-08 苏州市吴中区甪直明达漂染厂 一种棉麻混纺面料的染色工艺

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103469621A (zh) * 2013-09-13 2013-12-25 句容市后白镇迎瑞印花厂 一种三向织物的染整工艺
CN103469622A (zh) * 2013-09-13 2013-12-25 句容市后白镇迎瑞印花厂 一种三向织物的印花工艺
CN104762838A (zh) * 2015-04-27 2015-07-08 苏州市吴中区甪直明达漂染厂 一种棉麻混纺面料的染色工艺

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
贾静茹: "《实用丝网印刷技术 第2版》", 31 January 2008 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110016821A (zh) * 2019-04-16 2019-07-16 吉林工程技术师范学院 一种环保生态服装印花工艺

Similar Documents

Publication Publication Date Title
CN104213349B (zh) Tr布退浆、精炼与分散染色一浴染色的生产方法
CN104213398B (zh) 用于涤棉氧漂与分散染料染色一浴法的生产方法
CN100432319C (zh) 一种织物涂料染色工艺
CN103711008B (zh) 丝棉交织服装面料半料染色工艺
CN105803828B (zh) 一种分散/活性同浆印花染料及其印花工艺
CN104452283B (zh) 改性棉纤维、牛仔效果布及其制备方法
CN104018369B (zh) 蚕丝交织提花织物染色工艺
CN103469623B (zh) 一种活性染料对未煮漂棉纺织品进行无盐染色的方法
CN101195952A (zh) 一种棉纤维及混纺织物印染加工方法
CN106436373A (zh) 一种棉麻纤维织物的涂料印花工艺
CN107385979B (zh) 一种玉米纱线地毯喷墨印花工艺
CN104278551A (zh) 一种丝棉交织物直接印花工艺
CN104213434B (zh) 用于阳粘产品前处理、阳离子染料一浴法染色的生产方法
CN103572580B (zh) 一种锦纶或锦纶/棉混纺印花织物及其制备方法
CN109853262A (zh) 一种羊毛织物的酶处理方法和羊毛织物喷墨印花的方法
CN105155301A (zh) 一种棉织物混拼泡沫染色液及其应用
CN110939002A (zh) 一种涤棉混纺面料及其制备方法和应用
CN106436368A (zh) 一种三向织物的涂料印花工艺
CN102912654A (zh) 一种织物的染色方法
CN108589326A (zh) 一种印染的工艺流程
CN105064083A (zh) 部份退浆的牛仔混纺经纱浆染工艺
CN104131478A (zh) 活性墨水染料在亚麻纺织物上彩色印染工艺
KR20020007556A (ko) 실크직물의 새로운 정련과 발염에 의한 정련날염,정련발염 및 정련특수염색 기술
CN107059444B (zh) 涤阳莫代尔提花织物二浴法染色工艺
CN108130763A (zh) 一种含棉织物除毛、染色同浴生产工艺

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170222

RJ01 Rejection of invention patent application after publication