CN106316685A - Soil-structure conditioner capable of stabilizing yield and fixing carbon and preparation method and application thereof - Google Patents

Soil-structure conditioner capable of stabilizing yield and fixing carbon and preparation method and application thereof Download PDF

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CN106316685A
CN106316685A CN201610697566.3A CN201610697566A CN106316685A CN 106316685 A CN106316685 A CN 106316685A CN 201610697566 A CN201610697566 A CN 201610697566A CN 106316685 A CN106316685 A CN 106316685A
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soil
parts
bacillus
million cfu
mineral
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路遥
夏旭
李秀凤
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Zhongyuan (beijing) Soil Improvement Technology Research Institute
Zhongyuan Beijing Green Biotechnology Development Co ltd
Institute of Environment and Sustainable Development in Agriculturem of CAAS
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Zhongyuan (beijing) Soil Improvement Technology Research Institute
Zhongyuan Beijing Green Biotechnology Development Co ltd
Institute of Environment and Sustainable Development in Agriculturem of CAAS
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Fertilizers (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

本发明涉及一种稳产固碳的土壤结构调理剂及其制备方法与应用,所述土壤结构调理剂包括以下质量份的组分:植物材料30‑90份,矿物材料1‑40份;动物材料1‑30份;复合微生物菌剂1‑10份。本发明土壤结构调理剂可促进土壤固碳减排、促进团粒结构形成,提高土壤保水持水能力,增加有效水供应;调节土壤pH值,降低或减少铝毒危害;改良盐碱土,调节土壤盐基饱和度和阳离子交换量;调理失衡的土壤养分体系,促进有效养分供应。

The invention relates to a soil structure conditioner for stabilizing carbon production and sequestration and its preparation method and application. The soil structure conditioner comprises the following components by mass: 30-90 parts of plant materials, 1-40 parts of mineral materials; animal materials 1‑30 parts; 1‑10 parts of compound microbial agent. The soil structure conditioner of the present invention can promote soil carbon sequestration and emission reduction, promote the formation of aggregate structure, improve soil water retention capacity, increase effective water supply; adjust soil pH value, reduce or reduce aluminum toxicity hazard; improve saline-alkali soil, adjust soil salinity Base saturation and cation exchange capacity; adjust the unbalanced soil nutrient system to promote effective nutrient supply.

Description

一种稳产固碳的土壤结构调理剂及其制备方法与应用A soil structure conditioner for stable production and carbon sequestration, its preparation method and application

技术领域technical field

本发明涉及农业固碳减排领域,具体涉及一种可以促进土壤固碳并稳产的土壤调理剂及其制备方法和应用。The invention relates to the field of agricultural carbon sequestration and emission reduction, in particular to a soil conditioner capable of promoting soil carbon sequestration and stabilizing production, and a preparation method and application thereof.

背景技术Background technique

随着全球温室气体排放浓度的不断增加,全球气候变暖已经成为不争的事实。中国是全球温室气体排放第一大国,面临着巨大的减排压力,中国政府已经向世界承诺,到2020年我国减少相对二氧化碳排放量占每单位GDP(国内生产总值)产生排放量的45%,任务艰巨;农业作为在生态系统的碳汇能为减排做什么呢?事实上只有新增的土壤有机碳量才能计入碳汇,目前农田和管理草地能够计入碳汇的数量不足,原因之一是化学品投入过多,目前很多人都在考虑用土壤调理剂等方法来改变现状。With the increasing concentration of global greenhouse gas emissions, global warming has become an indisputable fact. China is the world's largest emitter of greenhouse gases and is facing enormous pressure to reduce emissions. The Chinese government has promised the world that by 2020, my country will reduce relative carbon dioxide emissions to account for 45% of emissions per unit of GDP (gross domestic product). , the task is arduous; what can agriculture do to reduce emissions as a carbon sink in the ecosystem? In fact, only the newly added soil organic carbon can be included in the carbon sink. At present, the amount of farmland and managed grassland that can be included in the carbon sink is insufficient. One of the reasons is that too many chemicals are used. At present, many people are considering using soil conditioners. and other methods to change the status quo.

土壤调理剂(soil conditioner)也称为土壤改良剂(soil modifier)、土壤添加剂(soil amendment),是一类主要用于改良土壤物理、化学和生物化学性质,使其更适宜于植物生长,并实现一定的环境或者生态功能(例如废弃物处理、改善水土流失、防止土壤退化、节水、固碳、防止土壤酸化和盐碱化等等)。近年来,世界各国为了改善耕地质量和提高农作物产量和品质,研制和开发了许多新型固碳改良剂,例如土壤保湿剂、土壤结构剂、松土剂、固沙剂、增肥剂、消毒剂和降酸碱剂等等。如何利用土壤改良剂改善土壤养分供应能力并促进土壤有机质的固定,也成为各国研究土壤改良剂的专家关注的问题之一。经检索,现有土壤调理剂相关专利申请有:Soil conditioner (soil conditioner), also known as soil modifier, soil additive (soil amendment), is a class mainly used to improve soil physical, chemical and biochemical properties, making it more suitable for plant growth, and To achieve certain environmental or ecological functions (such as waste disposal, improvement of soil erosion, prevention of soil degradation, water conservation, carbon sequestration, prevention of soil acidification and salinization, etc.). In recent years, in order to improve the quality of arable land and increase the yield and quality of crops, countries around the world have researched and developed many new carbon-fixing modifiers, such as soil moisturizing agents, soil structure agents, loosening agents, sand-fixing agents, fertilizers, disinfectants and Acid-base reducer and so on. How to use soil amendments to improve soil nutrient supply capacity and promote the fixation of soil organic matter has also become one of the concerns of experts studying soil amendments in various countries. After retrieval, the existing patent applications related to soil conditioners include:

CN101391930A公开了一种具有保水作用的边坡人工土壤调理剂,包括畜禽粪便、高吸水树脂、磷矿粉、硬石膏粉、腐植酸、沸石粉、壳聚糖、膨润土、磷酸脂、柠檬酸。所述调理剂对增强土壤持水性能、减少水土流失、改善土壤理化特性、促进植被恢复方面具有显著的效果。CN01136114.X公开了一种利用多种复合材料配置而成的能够快速有效改善土壤质地和肥力的新型改良剂。CN103897704A公开了一种保水松土土壤调理剂,具有较好的保水松土效果。CN103756684A公开了利用生物炭、聚丙烯酰胺、腐殖酸钾、月桂醇乙氧基硫酸按聚合物和膨润土组成的土壤结构调理剂,具有提高土壤保水持水能力、调节土壤pH值、改良土壤结构、促进团粒结构形成等多重效益。CN101391930A discloses a slope artificial soil conditioner with water retention function, which includes livestock manure, superabsorbent resin, phosphate rock powder, anhydrite powder, humic acid, zeolite powder, chitosan, bentonite, phosphate ester, citric acid . The conditioner has remarkable effects on enhancing soil water holding capacity, reducing water and soil loss, improving soil physical and chemical properties, and promoting vegetation restoration. CN01136114.X discloses a novel improver which is configured by using various composite materials and can quickly and effectively improve soil texture and fertility. CN103897704A discloses a soil conditioner for retaining water and loosening soil, which has better effect of retaining water and loosening soil. CN103756684A discloses a soil structure conditioner that utilizes biochar, polyacrylamide, potassium humate, lauryl alcohol ethoxysulfuric acid to form a polymer and bentonite, has the ability to improve soil water retention, adjust soil pH, and improve soil structure , Promote the formation of aggregate structure and other multiple benefits.

但是现有土壤结构调理技术主要围绕提高土壤保水性能、改良土壤盐碱化、改善土壤结构、钝化重金属等环境问题展开,对固碳稳产的效果考虑较少。However, the existing soil structure conditioning technology mainly focuses on improving soil water retention performance, improving soil salinization, improving soil structure, passivating heavy metals and other environmental issues, and less consideration is given to the effect of carbon sequestration and stable production.

发明内容Contents of the invention

本发明旨在提供一种可以促进土壤固碳、减少肥料投入并且稳定作物产量的具有多重效益的土壤结构调理剂。The invention aims to provide a soil structure conditioner with multiple benefits that can promote soil carbon sequestration, reduce fertilizer input and stabilize crop yield.

实现本发明目的的技术方案如下:The technical scheme that realizes the object of the present invention is as follows:

一种稳产固碳的土壤结构调理剂,包括以下质量份的组分:植物材料30-90份,矿物材料1-40份;动物材料1-30份;复合微生物菌剂1-10份。A soil structure conditioner for stably producing and sequestering carbon, comprising the following components by mass: 30-90 parts of plant materials, 1-40 parts of mineral materials; 1-30 parts of animal materials; and 1-10 parts of compound microbial agent.

优选地,所述稳产固碳的土壤结构调理剂,包括以下质量份的组分:植物材料36-80份;矿物材料12-30份;动物材料6-20份;复合微生物菌剂2-7份。Preferably, the soil structure conditioner for stably producing and fixing carbon comprises the following components by mass: 36-80 parts of plant material; 12-30 parts of mineral material; 6-20 parts of animal material; 2-7 parts of compound microbial bacterial agent share.

上述植物材料以作物秸秆为主体,具体由作物秸秆、天然中草药与植物氨基酸粉混合而成,按质量份数,其组成为:作物秸秆60-80份,天然中草药10-30份;植物氨基酸粉1-40份。The above-mentioned plant material mainly takes crop straw as the main body, and is specifically composed of crop straw, natural Chinese herbal medicine and plant amino acid powder. According to parts by mass, the composition is: 60-80 parts of crop straw, 10-30 parts of natural Chinese herbal medicine; plant amino acid powder 1-40 servings.

上述作物秸秆为田间种植的任意植物秸秆,优选为玉米秸秆、小麦秸秆、水稻秸秆、大豆秸秆、甘蔗秸秆等中的一种或几种;进一步优选上述作物秸秆为田间种植的上茬作物秸秆。The above-mentioned crop straws are any plant straws grown in the field, preferably one or more of corn straw, wheat straw, rice straw, soybean straw, sugarcane straw, etc.; more preferably, the above-mentioned crop straws are crop straws grown in the field.

上述天然中草药为万寿菊、续随子、丁香、苦参、百部、川穹、黄荆、五倍子、烟草、蓖麻、苍耳、水蓼、狼毒、大蒜、艾叶、香蕉皮或核桃皮中的一种或几种的任意比混合物。The above-mentioned natural Chinese herbal medicines are marigold, capers, cloves, flavescens, herbaceae, Chuanqiong, huangjing, Galla, tobacco, castor, cocklebur, polygonum, chamaejasma, garlic, mugwort leaves, banana peel or walnut peel One or more mixtures in any ratio.

上述植物氨基酸粉以棉籽粕、豆粕、油菜粕、花生粕、葵花子粕、油茶粕、乌桕粕或蓖麻粕为原料生产的氨基酸原粉,其所含氨基酸的质量百分比≥8%。The above-mentioned vegetable amino acid powder is an amino acid raw powder produced from cottonseed meal, soybean meal, rapeseed meal, peanut meal, sunflower meal, camellia oleifera meal, tallow tree meal or castor meal, and the mass percentage of amino acids contained in it is ≥8%.

上述矿物材料由含钾矿物组分、含磷矿物组分、含钙与镁矿物组分、含硫与铁矿物组分、稀土矿物组分以及辅料矿物组分混合而成,按质量份数,其组成为:含钾矿物组分40-70份;含磷矿物组分15-30份;含钙与镁矿物组分5-10份;含硫与铁矿物组分5-10份;稀土矿物组分1-5份;辅料矿物组分3-5份。The above-mentioned mineral materials are composed of potassium-containing mineral components, phosphorus-containing mineral components, calcium- and magnesium-containing mineral components, sulfur- and iron-containing mineral components, rare earth mineral components and auxiliary mineral components. The composition is as follows: 40-70 parts of potassium mineral components; 15-30 parts of phosphorus mineral components; 5-10 parts of calcium and magnesium mineral components; 5-10 parts of sulfur and iron mineral components parts; 1-5 parts of rare earth mineral components; 3-5 parts of auxiliary mineral components.

上述含钾矿物组分为钾长石、霞石、白榴石、海绿石或云母中的一种或几种的任意比混合物;含磷矿物组分为磷灰石;含钙与镁矿物组分为方解石、白云岩、石灰岩或蛇纹石中的一种或几种的任意比混合物;含硫与铁矿物组分为硫铁矿;稀土矿物组分为稀土矿;辅料矿物组分为凹凸棒石粘土、膨润土、沸石、蛭石或麦饭石中的一种或几种的任意比混合物。The above-mentioned potassium-containing mineral components are potassium feldspar, nepheline, leucite, glauconite or mica or any mixture of several kinds; the phosphorus-containing mineral components are apatite; calcium and magnesium The mineral component is calcite, dolomite, limestone or serpentine or a mixture of several in any ratio; the sulfur and iron mineral component is pyrite; the rare earth mineral component is rare earth ore; the auxiliary mineral component Divided into attapulgite clay, bentonite, zeolite, vermiculite or medical stone or a mixture of any ratio.

上述动物材料为牡蛎粉、贝壳粉、甲壳素或壳聚糖中的一种或几种的任意比混合物。The above-mentioned animal material is one or a mixture in any ratio of oyster powder, shell powder, chitin or chitosan.

所述复合微生物菌剂含有枯草芽孢杆菌(Bacillus subtilis)1-3亿cfu/g、地衣芽孢杆菌(Bacillus licheniformis)1-2亿cfu/g、巨大芽孢杆菌(Bacillus megaterium)0.1-2亿cfu/g、凝结芽孢杆菌(Bacillus coagulans)0.1-3亿cfu/g、嗜酸乳杆菌(Lactobacillus acidophilus)0.1-3亿cfu/g、侧孢芽孢杆菌(Latin Name Bacilluslaterosporus Laubach)0.01-0.5亿cfu/g、5406放线菌(Actinobacteria-5406)0.01-0.5亿cfu/g、光合细菌(简称PSB Photosynthetic Bacteria Abbr)0.01-0.5亿cfu/g、胶冻样芽孢杆菌(又名硅酸盐细菌Bacillus mucilaginosus)0.01-0.3亿cfu/g、绿色木霉菌(Trichoderma viride)0.01-0.3亿cfu/g。The composite microbial agent contains 100-300 million cfu/g of Bacillus subtilis, 100-200 million cfu/g of Bacillus licheniformis, and 0.1-200 million cfu/g of Bacillus megaterium. g. Bacillus coagulans 0.1-300 million cfu/g, Lactobacillus acidophilus 0.1-300 million cfu/g, Latin Name Bacilluslaterosporus Laubach 0.01-050 million cfu/g , 5406 actinomycetes (Actinobacteria-5406) 0.01-050 million cfu/g, photosynthetic bacteria (referred to as PSB Photosynthetic Bacteria Abbr) 0.01-050 million cfu/g, jelly-like Bacillus (also known as silicate bacteria Bacillus mucilaginosus) 0.01-0.3 million cfu/g, Trichoderma viride (Trichoderma viride) 0.01-0.3 million cfu/g.

优选地,所述复合微生物菌剂含有枯草芽孢杆菌1-3亿cfu/g、地衣芽孢杆菌1.3-1.8亿cfu/g、巨大芽孢杆菌1-2亿cfu/g、凝结芽孢杆菌2-4亿cfu/g、嗜酸乳杆菌1-3亿cfu/g、侧孢芽孢杆菌0.1-0.5亿cfu/g、5406放线菌0.1-0.5亿cfu/g、光合细菌0.1-0.3亿cfu/g、胶冻样芽孢杆菌0.05-0.2亿cfu/g、绿色木霉菌0.05-0.2亿cfu/g。Preferably, the composite microbial agent contains 1-300 million cfu/g of Bacillus subtilis, 130-180 million cfu/g of Bacillus licheniformis, 1-200 million cfu/g of Bacillus megaterium, and 2-400 million cfu/g of Bacillus coagulans cfu/g, Lactobacillus acidophilus 100-300 million cfu/g, Bacillus lateralis 0.1-050 million cfu/g, 5406 actinomycetes 0.1-050 million cfu/g, photosynthetic bacteria 0.1-030 million cfu/g, Jelly-like Bacillus 0.05-0.2 million cfu/g, Trichoderma viride 0.05-0.2 million cfu/g.

优选地,所述复合微生物菌剂中枯草芽孢杆菌、地衣芽孢杆菌、巨大芽孢杆菌、凝结芽孢杆菌和嗜酸乳杆菌五种菌的重量之和是侧孢芽孢杆菌、5406放线菌、光合细菌、胶冻样芽孢杆菌、绿色木霉菌五种菌的重量之和的9倍。Preferably, the weight sum of the five bacteria of Bacillus subtilis, Bacillus licheniformis, Bacillus megaterium, Bacillus coagulans and Lactobacillus acidophilus in the composite microbial agent is Bacillus lateralosporus, 5406 actinomycetes, photosynthetic bacteria 9 times of the weight sum of five kinds of bacteria, jelly-like bacillus and trichoderma viride.

上述复合微生物菌剂中各微生物均为本领域常规菌种,均可通过常规途径获得。Each of the microorganisms in the above-mentioned composite microbial bacterial agent is a conventional strain in the field, and can be obtained by conventional means.

上述复合微生物菌剂的制备方法可以是将上述各微生物菌粉按比例混匀即可。所述各微生物菌粉可按本领域常规方法制备,例如将所述各微生物原始菌种在无菌条件下依次进行斜面培养、摇床培养、发酵罐培养和/或固体发酵产孢后,将得到的发酵产物干燥制备成微生物菌粉。The preparation method of the above-mentioned composite microbial bacterial agent may be to mix the above-mentioned microbial bacterial powders in proportion. Each of the microbial powders can be prepared according to conventional methods in the art. For example, the original strains of each of the microorganisms are subjected to slant culture, shaker culture, fermenter culture and/or solid fermentation spore production in sequence under sterile conditions. The obtained fermentation product is dried and prepared into microbial powder.

本发明还提供上述稳产固碳的土壤结构调理剂的制备方法,包括以下步骤:The present invention also provides a preparation method of the soil structure conditioner for stable production and carbon sequestration, comprising the following steps:

1)将矿物材料混合,并经过900-1500℃高温煅烧5-20小时,冷却后粉碎过60-150目筛;1) The mineral materials are mixed and calcined at a high temperature of 900-1500°C for 5-20 hours, and then crushed through a 60-150 mesh sieve after cooling;

2)将植物材料分别烘干粉碎,然后混合;2) drying and pulverizing the plant materials respectively, and then mixing;

3)将动物材料烘干,粉碎,过30-100目筛;3) drying the animal material, pulverizing it, and passing through a 30-100 mesh sieve;

4)将复合微生物菌剂各原料混合,过60-150目筛;4) mixing the raw materials of the composite microbial bacterial agent, and passing through a 60-150 mesh sieve;

5)将以上原料按配比混合均匀,即可。5) Mix the above raw materials evenly according to the proportion.

进一步地,控制所述稳产固碳的土壤结构调理剂含水量在8-10wt%。Further, the water content of the soil structure conditioner for stable production and carbon fixation is controlled at 8-10wt%.

本发明还包括上述土壤结构调理剂在土壤稳产固碳方面的应用。特别适用于作物稳产前提下华北、东北等地区旱地的土壤固碳。The present invention also includes the application of the above-mentioned soil structure conditioner in the aspects of stable soil production and carbon fixation. It is especially suitable for soil carbon sequestration in drylands in North China, Northeast China and other regions under the premise of stable crop production.

推荐所述土壤结构调理剂的用量:15-50公斤/亩(大田作物)。The dosage of the soil structure conditioner is recommended: 15-50 kg/mu (field crops).

推荐所述土壤结构调理剂的使用方法:与秸秆配合使用;具体包括,土壤表面撒施秸秆(优选将秸秆粉粹至长度1-5cm左右或粉末状),或者在作物收获后将秸秆粉粹成长度1-5cm左右或粉末状后直接还田,然后在秸秆上撒施所述土壤结构调理剂,深翻土壤(优选翻耕深度25-35厘米)。可采用耕幅2米、深25-30厘米的迪尔754拖拉机或耕幅2米、深30-35厘米的迪尔1204拖拉机进行深翻。技术要点是秸秆和土壤结构调理剂均匀撒施,复合微生物菌剂均与喷施在秸秆上。优选地,所述土壤结构调理剂原料中的作物秸秆为上茬作物秸秆。The method of using the soil structure conditioner is recommended: use in conjunction with straw; specifically, spreading the straw on the soil surface (preferably crushing the straw to a length of about 1-5cm or powder), or crushing the straw after the crops are harvested The growth length is about 1-5cm or the powdered form is directly returned to the field, and then the soil structure conditioner is sprinkled on the straw, and the soil is deeply plowed (preferably the plowing depth is 25-35 cm). Deere 754 tractor with a tillage width of 2 meters and a depth of 25-30 cm or a Deere 1204 tractor with a tillage width of 2 meters and a depth of 30-35 cm can be used for deep plowing. The key point of the technology is that the straw and the soil structure conditioner are evenly spread, and the compound microbial agent is sprayed on the straw. Preferably, the crop stalks in the raw material of the soil structure conditioner are last crop stalks.

本发明土壤结构调理剂各原材料来自我国广泛存在的天然矿物,采用先进的低温物理加工技术,按照一定的加料顺序,将天然矿物的晶体结构转化为非晶体物质,成为植物可利用的枸溶性鳌合态的具有多重效益的土壤结构调理剂。The raw materials of the soil structure conditioning agent of the present invention come from the natural minerals that widely exist in my country, adopt advanced low-temperature physical processing technology, and convert the crystal structure of the natural minerals into amorphous substances according to a certain feeding sequence, and become citrus soluble chelatin that can be used by plants. Synthetic multi-benefit soil conditioner.

本发明土壤结构调理剂,富含60多种作物必需的营养元素、有益元素和生命元素,其中主要养分:钾≥4%、镁≥4%、硫≥3%、硅≥15%、钙≥20%。产品具有缓释性和高吸收率,作物根系通过分泌有机酸主动吸收自身需求的营养,避免了养分的奢嗜吸收,养分在土壤中不挥发不流失,当季用不完可供下季作物利用,养分利用率100%,能调节减少化肥投入。The soil structure conditioner of the present invention is rich in more than 60 kinds of crop essential nutrients, beneficial elements and life elements, wherein the main nutrients are: potassium ≥ 4%, magnesium ≥ 4%, sulfur ≥ 3%, silicon ≥ 15%, calcium ≥ 20%. The product has slow-release and high absorption rate. The root system of crops actively absorbs the nutrients they need by secreting organic acids, avoiding excessive absorption of nutrients. Nutrients are not volatile or lost in the soil, and can be used for next season's crops if they are not used up in the current season. Utilization, nutrient utilization rate is 100%, can adjust and reduce chemical fertilizer input.

本发明土壤结构调理剂,与各种秸秆配合使用,可以起到效果叠加的作用,能快速形成土壤腐殖质,提升土壤有机质1~2%。腐殖质占有机质的50~70%,腐殖质的主要组成元素为碳、氮、磷、硫比值大约为100:10:1:1;按照有机质提升1%计算相当于固碳量0.88吨/亩,如果在我国20%的耕地上应用此项技术相当于碳减排3亿吨/年。The soil structure conditioner of the present invention, when used in conjunction with various straws, can play the role of superimposed effects, can quickly form soil humus, and increase soil organic matter by 1-2%. Humus accounts for 50-70% of organic matter, and the main components of humus are carbon, nitrogen, phosphorus, and sulfur. Applying this technology to 20% of my country's arable land is equivalent to reducing carbon emissions by 300 million tons per year.

本发明土壤结构调理剂可促进土壤固碳减排、促进团粒结构形成,提高土壤保水持水能力,增加有效水供应;调节土壤pH值,降低或减少铝毒危害;改良盐碱土,调节土壤盐基饱和度和阳离子交换量;调理失衡的土壤养分体系,促进有效养分供应;因此被称为土壤结构调理剂。The soil structure conditioner of the present invention can promote soil carbon sequestration and emission reduction, promote the formation of aggregate structure, improve soil water retention capacity, increase effective water supply; adjust soil pH value, reduce or reduce aluminum toxicity hazard; improve saline-alkali soil, adjust soil salinity Base saturation and cation exchange capacity; adjust the unbalanced soil nutrient system to promote effective nutrient supply; therefore it is called soil structure conditioner.

有益效果:Beneficial effect:

第一,选择富含植物所需的大量元素、中量元素、微量元素、有益元素的各种天然矿物优化组合,经过煅烧、粉碎、混合等方法,活化矿物中的各种营养元素,有效提供微生物和植物所需的矿物质营养元素,可达到植物营养均衡的目的,从而有效提高植物所需的肥料的利用率,并增强植物的健康状态。First, select the optimal combination of various natural minerals rich in macronutrients, secondary elements, microelements, and beneficial elements needed by plants, and activate various nutrient elements in the minerals through methods such as calcination, crushing, and mixing to effectively provide The mineral nutrients needed by microorganisms and plants can achieve the purpose of balanced plant nutrition, thereby effectively improving the utilization rate of fertilizers needed by plants and enhancing the health of plants.

第二,通过天然中草药与植物氨基酸粉进行优化配比,加上特殊动物材料与甲壳素、壳聚糖等优化组合,不仅进一步提供植物所需的各种营养,还可以有效刺激植物健康生长,进一步提高植物抗逆能力。Second, through the optimized ratio of natural Chinese herbal medicine and plant amino acid powder, coupled with the optimized combination of special animal materials and chitin, chitosan, etc., it can not only further provide various nutrients needed by plants, but also effectively stimulate the healthy growth of plants. Further improve plant stress resistance.

第三,添加微生物菌群从而增加根际土壤中有益菌群的数量与活性,抑制土壤中有害微生物的数量与活动,与秸秆配合使用可快速降解纤维素,同时促进土壤团粒结构的形成,提高土壤有机质。此外,土壤改良效果明显,可持续利用能力可得到显著加强。Third, add microbial flora to increase the number and activity of beneficial flora in the rhizosphere soil, inhibit the number and activities of harmful microorganisms in the soil, and use it in conjunction with straw to quickly degrade cellulose, and at the same time promote the formation of soil aggregate structure and improve Soil organic matter. In addition, the effect of soil improvement is obvious, and the sustainable utilization capacity can be significantly enhanced.

附图说明Description of drawings

图1为本发明土壤结构调理剂制备方法工艺流程示意图。Fig. 1 is a schematic flow chart of the preparation method of the soil structure conditioner of the present invention.

具体实施方式detailed description

以下实施例用于说明本发明,但不用来限制本发明的范围。实施例中未注明具体技术或条件者,按照本领域内的文献所描述的技术或条件,或者按照产品说明书进行。所用试剂或仪器未注明生产厂商者,均为可通过正规渠道商购买得到的常规产品。The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention. If no specific technique or condition is indicated in the examples, it shall be carried out according to the technique or condition described in the literature in this field, or according to the product specification. The reagents or instruments used were not indicated by the manufacturer, and they were all conventional products that can be purchased through formal channels.

其中,植物氨基酸粉购自新疆塔城市星河生物工程有限责任公司。以下所述固碳测定方法为重络酸钾氧化法,参考鲁如坤.土壤农业化学分析方法.北京:中国农业科技出版社.2000。所述有机质测定方法为NY/T1121.2-2006土壤检测第六部分:土壤有机质的测定。Among them, plant amino acid powder was purchased from Xinjiang Tacheng Xinghe Biological Engineering Co., Ltd. The carbon fixation method described below is the oxidation method of potassium dicatalyst, with reference to Lu Rukun. Soil Agricultural Chemical Analysis Methods. Beijing: China Agricultural Science and Technology Press. 2000. The organic matter determination method is NY/T1121.2-2006 Soil Detection Part Six: Determination of Soil Organic Matter.

实施例1Example 1

一种稳产固碳的土壤结构调理剂,包括以下质量份的组分:植物材料60份;矿物材料20份,动物材料6份,复合微生物菌剂2份。A soil structure conditioner for stably producing and sequestering carbon, comprising the following components by mass: 60 parts of plant material; 20 parts of mineral material, 6 parts of animal material, and 2 parts of compound microbial agent.

其中植物材料按质量份数计其组成为:玉米、水稻和小麦三种秸秆(三者重量比为1:1:1)共70份,天然中草药10份,植物氨基酸粉20份。Among them, the plant material consists of 70 parts of corn, rice and wheat straw (the weight ratio of the three is 1:1:1), 10 parts of natural Chinese herbal medicine, and 20 parts of plant amino acid powder in terms of parts by mass.

上述天然中草药为万寿菊、续随子、烟草、蓖麻、艾叶、苍耳、五倍子、川芎、苦参、百部等重量比例的混合物。植物氨基酸粉所含氨基酸的质量百分比≥8%。The above-mentioned natural Chinese herbal medicine is a mixture of marigold, capers, tobacco, castor, mugwort leaves, cocklebur, gall, chuanxiong, flavescens, and hundred parts by weight. The mass percentage of amino acid contained in the plant amino acid powder is more than or equal to 8%.

矿物材料为天然矿石,按质量份数计含钾矿物组分40份;磷矿物组分20份;含钙与镁矿物5份;含硫与铁矿物组分5份。稀土矿物组分2份;辅助矿物材料组分3份。其中含钾矿物组分为钾长石、霞石、云母、海藻石中等重量比例的混合物;含磷矿物组分为磷灰石;含钙与镁矿物组分为方解石、白云岩、石灰岩、蛇纹石等重量比例的混合物;含硫与铁矿物组分为硫铁矿;稀土矿物组分为稀土矿;辅料矿物组分为凹凸棒石粘土、膨润土、沸石、蛭石、麦饭石等重量比例的混合物。The mineral material is natural ore, and in parts by mass, it contains 40 parts of potassium-containing mineral components; 20 parts of phosphorus mineral components; 5 parts of calcium- and magnesium-containing minerals; and 5 parts of sulfur- and iron-containing mineral components. 2 parts of rare earth mineral components; 3 parts of auxiliary mineral material components. Among them, the potassium-containing mineral component is a mixture of potassium feldspar, nepheline, mica, and seaweed stone; the phosphorus-containing mineral component is apatite; the calcium-magnesium-containing mineral component is calcite, dolomite, limestone, A mixture of serpentine in equal weight proportions; sulfur and iron mineral components are pyrite; rare earth mineral components are rare earth ore; auxiliary mineral components are attapulgite clay, bentonite, zeolite, vermiculite, medical stone mixture in equal weight proportions.

动物材料为牡蛎粉、贝壳粉、甲壳素、壳聚糖等重量比例的混合物。The animal material is a mixture of oyster powder, shell powder, chitin, chitosan and other weight ratios.

复合微生物菌剂含有枯草芽孢杆菌2.5亿cfu/g、地衣芽孢杆菌1.5亿cfu/g、巨大芽孢杆菌1.5亿cfu/g、凝结芽孢杆菌3亿cfu/g、嗜酸乳杆菌2亿cfu/g、侧孢芽孢杆菌0.3亿cfu/g、5406放线菌0.4亿cfu/g、光合细菌0.1亿cfu/g、胶冻样芽孢杆菌0.1亿cfu/g、绿色木霉菌0.1亿cfu/g。The compound microbial agent contains 250 million cfu/g of Bacillus subtilis, 150 million cfu/g of Bacillus licheniformis, 150 million cfu/g of Bacillus megaterium, 300 million cfu/g of Bacillus coagulans, and 200 million cfu/g of Lactobacillus acidophilus , Bacillus lateralis 0.3 billion cfu/g, 5406 actinomycetes 0.4 billion cfu/g, photosynthetic bacteria 0.1 billion cfu/g, jelly-like Bacillus 0.1 billion cfu/g, Trichoderma viride 0.1 billion cfu/g.

该稳产固碳的土壤结构调理剂的制备方法包括:将矿物材料混合,并经过900℃高温煅烧5小时,冷却后粉碎过150目筛;将玉米、水稻和小麦三种秸秆、天然中草药、植物氨基酸粉分别烘干粉碎,过100目筛,然后混合;将动物材料烘干,粉碎,过100目筛;将复合微生物菌剂各原料混合,过150目筛;将以上植物材料、矿物材料、动物材料、复合微生物菌剂按比例倒入搅拌器中,充分混拌均匀;将混拌均匀的材料计量、包装。含水量控制在8-10wt%,制得产品。The preparation method of the soil structure conditioner for stable production and sequestration of carbon comprises: mixing mineral materials, calcining at 900°C for 5 hours, and pulverizing through a 150-mesh sieve after cooling; The amino acid powder is dried and crushed separately, passed through a 100-mesh sieve, and then mixed; the animal materials are dried, crushed, and passed through a 100-mesh sieve; the raw materials of the compound microbial agent are mixed, and passed through a 150-mesh sieve; the above plant materials, mineral materials, Pour the animal material and compound microbial agent into the mixer according to the proportion, and fully mix them evenly; measure and pack the evenly mixed materials. The water content is controlled at 8-10wt% to obtain the product.

实施例2Example 2

一种稳产固碳的土壤结构调理剂,包括以下质量份的组分:植物材料80份;矿物材料30份,动物材料20份,复合微生物菌剂7份。A soil structure conditioner for stably producing and sequestering carbon, comprising the following components by mass: 80 parts of plant material; 30 parts of mineral material, 20 parts of animal material, and 7 parts of compound microbial bacterial agent.

其中植物材料按质量份数计其组成为:玉米、水稻和小麦三种秸秆(三者重量比为1:1:1)共70份,天然中草药15份,植物氨基酸粉15份。Among them, the plant material consists of 70 parts of corn, rice and wheat straw (the weight ratio of the three is 1:1:1), 15 parts of natural Chinese herbal medicine, and 15 parts of plant amino acid powder in terms of parts by mass.

上述天然中草药为万寿菊、续随子、烟草、蓖麻、艾叶、苍耳、五倍子、川芎、苦参、百部等重量比例的混合物。植物氨基酸粉所含氨基酸的质量百分比≥8%。The above-mentioned natural Chinese herbal medicine is a mixture of marigold, capers, tobacco, castor, mugwort leaves, cocklebur, gall, chuanxiong, flavescens, and hundred parts by weight. The mass percentage of amino acid contained in the plant amino acid powder is more than or equal to 8%.

矿物材料为天然矿石,含钾矿物组分60份;磷矿物组分20份;含钙与镁矿物8份;含硫与铁矿物组分8份;稀土矿物组分3份;辅助矿物材料组分4份。其中含钾矿物组分为钾长石、霞石、云母、海藻石等重量比例的混合物;含磷矿物组分为磷灰石;含钙与镁矿物组分为方解石、白云岩、石灰岩、蛇纹石等重量比例的混合物;含硫与铁矿物组分为硫铁矿;稀土矿物组分为稀土矿;辅料矿物组分为凹凸棒石粘土、膨润土、沸石、蛭石、麦饭石等重量比例的混合物。Mineral materials are natural ores, 60 parts of potassium mineral components; 20 parts of phosphorus mineral components; 8 parts of calcium and magnesium mineral components; 8 parts of sulfur and iron mineral components; 3 parts of rare earth mineral components; auxiliary minerals There are 4 parts of material components. Among them, the potassium-containing mineral component is a mixture of potassium feldspar, nepheline, mica, alginite and other weight ratios; the phosphorus-containing mineral component is apatite; the calcium and magnesium-containing mineral components are calcite, dolomite, limestone, A mixture of serpentine in equal weight proportions; sulfur and iron mineral components are pyrite; rare earth mineral components are rare earth ore; auxiliary mineral components are attapulgite clay, bentonite, zeolite, vermiculite, medical stone mixture in equal weight proportions.

动物材料为牡蛎粉、贝壳粉、甲壳素、壳聚糖等重量比例的混合物。The animal material is a mixture of oyster powder, shell powder, chitin, chitosan and other weight ratios.

复合微生物菌剂含有枯草芽孢杆菌2.5亿cfu/g、地衣芽孢杆菌1.5亿cfu/g、巨大芽孢杆菌1.5亿cfu/g、凝结芽孢杆菌3亿cfu/g、嗜酸乳杆菌2亿cfu/g、侧孢芽孢杆菌0.3亿cfu/g、5406放线菌0.4亿cfu/g、光合细菌0.1亿cfu/g、胶冻样芽孢杆菌0.1亿cfu/g、绿色木霉菌0.1亿cfu/g。The compound microbial agent contains 250 million cfu/g of Bacillus subtilis, 150 million cfu/g of Bacillus licheniformis, 150 million cfu/g of Bacillus megaterium, 300 million cfu/g of Bacillus coagulans, and 200 million cfu/g of Lactobacillus acidophilus , Bacillus lateralis 0.3 billion cfu/g, 5406 actinomycetes 0.4 billion cfu/g, photosynthetic bacteria 0.1 billion cfu/g, jelly-like Bacillus 0.1 billion cfu/g, Trichoderma viride 0.1 billion cfu/g.

该稳产固碳的土壤结构调理剂的制备方法同实施例1。The preparation method of the soil structure conditioner for stable production and sequestration of carbon is the same as in Example 1.

实施例3Example 3

一种稳产固碳的土壤结构调理剂,包括以下质量份的组分:植物材料36公斤,矿物材料12公斤,动物材料9公斤,复合微生物菌剂3公斤。A soil structure conditioner for stably producing and sequestering carbon, comprising the following components by mass: 36 kg of plant material, 12 kg of mineral material, 9 kg of animal material, and 3 kg of compound microbial agent.

取水稻秸秆65公斤,烘干粉碎过100目筛;取等重量比例的万寿菊、苦参、百部、川芎、蓖麻、烟草、狼毒混合物18公斤,烘干粉碎过100目筛;取植物氨基酸粉烘18公斤干粉碎过100目筛;将以上原料混合均匀,制得植物材料;Take 65 kg of rice straw, dry and pulverize it through a 100-mesh sieve; take 18 kg of a mixture of marigold, sophora flavescens, centipede, Chuanxiong, castor, tobacco, and chamaejasma in equal weight ratios, dry and pulverize it through a 100-mesh sieve; Dry 18 kg of plant amino acid powder and dry crush it through a 100-mesh sieve; mix the above raw materials evenly to obtain plant material;

称取钾长石40公斤,方解石3公斤,硫铁矿5公斤,磷灰石10公斤,膨润土和蛭石混合物1公斤,稀土1公斤,混合后于1500℃煅烧5小时,冷却后粉碎过150目筛,得矿物材料。Weigh 40 kilograms of potassium feldspar, 3 kilograms of calcite, 5 kilograms of pyrite, 10 kilograms of apatite, 1 kilogram of bentonite and vermiculite mixture, and 1 kilogram of rare earth. Mesh sieve to obtain mineral materials.

称取贝壳粉5公斤,过100目筛,与4公斤壳聚糖混合,得动物材料。Weigh 5 kg of shell powder, pass through a 100-mesh sieve, and mix with 4 kg of chitosan to obtain animal material.

复合微生物菌剂含有枯草芽孢杆菌2.5亿cfu/g、地衣芽孢杆菌1.5亿cfu/g、巨大芽孢杆菌1.5亿cfu/g、凝结芽孢杆菌3亿cfu/g、嗜酸乳杆菌2亿cfu/g、侧孢芽孢杆菌0.3亿cfu/g、5406放线菌0.4亿cfu/g、光合细菌0.1亿cfu/g、胶冻样芽孢杆菌0.1亿cfu/g、绿色木霉菌0.1亿cfu/g。The compound microbial agent contains 250 million cfu/g of Bacillus subtilis, 150 million cfu/g of Bacillus licheniformis, 150 million cfu/g of Bacillus megaterium, 300 million cfu/g of Bacillus coagulans, and 200 million cfu/g of Lactobacillus acidophilus , Bacillus lateralis 0.3 billion cfu/g, 5406 actinomycetes 0.4 billion cfu/g, photosynthetic bacteria 0.1 billion cfu/g, jelly-like Bacillus 0.1 billion cfu/g, Trichoderma viride 0.1 billion cfu/g.

将复合微生物菌剂各原料混合,过60-150目筛;得复合微生物菌剂。The raw materials of the compound microbial bacterial agent are mixed and passed through a 60-150 mesh sieve to obtain the compound microbial bacterial agent.

将以上植物材料、矿物材料、动物材料、复合微生物菌剂按比例倒入搅拌器中,充分混拌均匀;将混拌均匀的材料计量、包装。含水量控制在8-10wt%,制得稳产固碳的土壤结构调理剂产品。Pour the above plant materials, mineral materials, animal materials, and compound microbial agents into the mixer in proportion, and fully mix them; measure and pack the evenly mixed materials. The water content is controlled at 8-10 wt%, and a soil structure conditioner product with stable carbon sequestration can be obtained.

对比例1Comparative example 1

一种土壤结构调理剂,与实施例1的区别仅在于复合微生物菌剂不同。本对比例复合微生物菌剂仅含有枯草芽孢杆菌0.8亿cfu/g、凝结芽孢杆菌0.8亿cfu/g、嗜酸乳杆菌0.4亿cfu/g、光合细菌0.1亿cfu/g、胶冻样芽孢杆菌0.08亿cfu/g、绿色木霉菌0.02亿cfu/g。A kind of soil structure conditioning agent, and the difference of embodiment 1 only lies in that the composite microbial bacterial agent is different. The composite microbial agent of this comparative example only contains 0.8 billion cfu/g of Bacillus subtilis, 0.8 billion cfu/g of Bacillus coagulans, 0.4 billion cfu/g of Lactobacillus acidophilus, 0.1 billion cfu/g of photosynthetic bacteria, and jelly-like Bacillus 080 million cfu/g, Trichoderma viride 02 million cfu/g.

对比例2Comparative example 2

一种土壤结构调理剂,与实施例2的区别仅在于复合微生物菌剂不同。本对比例复合微生物菌剂仅含有地衣芽孢杆菌1亿cfu/g、凝结芽孢杆菌0.5亿cfu/g、嗜酸乳杆菌0.3亿cfu/g、侧孢芽孢杆菌0.1亿cfu/g、胶冻样芽孢杆菌0.05亿cfu/g、绿色木霉菌0.05亿cfu/g。A kind of soil structure conditioning agent, and the difference of embodiment 2 only lies in that the composite microbial bacterial agent is different. The composite microbial agent of this comparative example only contains 100 million cfu/g of Bacillus licheniformis, 0.5 billion cfu/g of Bacillus coagulans, 0.3 billion cfu/g of Lactobacillus acidophilus, 0.1 billion cfu/g of Bacillus lateralis, jelly sample Bacillus 0.05 billion cfu/g, Trichoderma viride 0.05 billion cfu/g.

对比例3Comparative example 3

一种土壤结构调理剂,与实施例3的区别仅在于复合微生物菌剂不同。本对比例复合微生物菌剂仅含有枯草芽孢杆菌0.5亿cfu/g、地衣芽孢杆菌0.5亿cfu/g、巨大芽孢杆菌0.4亿cfu/g、凝结芽孢杆菌0.3亿cfu/g、嗜酸乳杆菌0.1亿cfu/g、侧孢芽孢杆菌0.06亿cfu/g、5406放线菌0.04亿cfu/g、光合细菌0.04亿cfu/g、胶冻样芽孢杆菌0.03亿cfu/g、绿色木霉菌0.03亿cfu/g。A kind of soil structure conditioning agent, and the difference of embodiment 3 only lies in that the composite microbial bacterial agent is different. The composite microbial agent of this comparative example only contains 0.5 billion cfu/g of Bacillus subtilis, 0.5 billion cfu/g of Bacillus licheniformis, 0.4 billion cfu/g of Bacillus megaterium, 0.3 billion cfu/g of Bacillus coagulans, and 0.1 million cfu/g of Lactobacillus acidophilus. 100 million cfu/g, 0.06 billion cfu/g of Bacillus lateralis, 0.04 billion cfu/g of 5406 actinomycetes, 0.4 billion cfu/g of photosynthetic bacteria, 0.3 billion cfu/g of Bacillus jelly-like, 0.03 billion cfu of Trichoderma viride /g.

实验例1Experimental example 1

在北京顺义某番茄生产基地进行土壤固碳实验:Soil carbon sequestration experiment was carried out in a tomato production base in Shunyi, Beijing:

对照组1:施用50公斤/亩复合肥(N:P2O5:K2O=15-15-15),2000公斤/亩有机肥;Control group 1: apply 50 kg/mu of compound fertilizer (N:P 2 O 5 :K 2 O=15-15-15), 2000 kg/mu of organic fertilizer;

对照组2:施用2000公斤/亩有机肥和100公斤/亩粉碎的玉米秸秆同作基肥,另施用对比例1制备的土壤结构调理剂50公斤/亩;Control group 2: use 2000 kg/mu of organic fertilizer and 100 kg/mu of crushed corn stalks as base fertilizer, and use 50 kg/mu of soil structure conditioner prepared in Comparative Example 1;

实验组:施用2000公斤/亩有机肥和100公斤/亩粉碎的玉米秸秆同作基肥,另施用实施例1制备的土壤结构调理剂50公斤/亩。Experimental group: 2000 kg/mu of organic fertilizer and 100 kg/mu of crushed corn stalks were used as base fertilizer, and 50 kg/mu of the soil structure conditioner prepared in Example 1 was applied.

对照组2和实验组均不使用任何化肥肥料。Both the control group 2 and the experimental group did not use any chemical fertilizers.

实验结果见表1。结果表明,对照组2与对照组1相比,番茄产量、土壤固碳及有机质均有所最佳,但差异不显著;实验组与对照组2、对照组1相比,番茄产量、土壤固碳及有机质均显著增加,表明对土壤的可持续能力增加。The experimental results are shown in Table 1. The results showed that the control group 2 had the best tomato yield, soil carbon sequestration and organic matter compared with the control group 1, but the difference was not significant; Both carbon and organic matter increased significantly, indicating increased sustainability of the soil.

表1Table 1

实验例2Experimental example 2

在北京通州某樱桃园基地开展土壤改良实验:Soil improvement experiments were carried out at a cherry orchard base in Tongzhou, Beijing:

对照组1:施用50公斤/亩复混肥(N:P2O5:K2O=15-15-15),3000公斤/亩有机肥;Control group 1: apply 50 kg/mu compound fertilizer (N:P 2 O 5 :K 2 O=15-15-15), 3000 kg/mu organic fertilizer;

对照组2:施用3000公斤/亩有机肥和200公斤/亩粉碎的玉米秸秆同作基肥,另施用对比例2制备的土壤结构调理剂50公斤/亩;Control group 2: use 3000 kg/mu of organic fertilizer and 200 kg/mu of crushed corn stalks as base fertilizer, and use 50 kg/mu of soil structure conditioner prepared in comparative example 2;

实验组:施用3000公斤/亩有机肥和200公斤/亩粉碎的玉米秸秆同作基肥,另施用实施例2制备的土壤结构调理剂50公斤/亩。Experimental group: 3000 kg/mu of organic fertilizer and 200 kg/mu of crushed corn stalks were used as base fertilizer, and 50 kg/mu of the soil structure conditioner prepared in Example 2 was applied.

对照组2和实验组均不使用任何化肥肥料。Both the control group 2 and the experimental group did not use any chemical fertilizers.

实验结果见表2。结果表明,对照组2与对照组1相比,樱桃产量、土壤固碳及有机质均有所最佳,但差异不显著;实验组与对照组2、对照组1相比,樱桃产量、土壤固碳及有机质均显著增加,表明对土壤的可持续能力增加。The experimental results are shown in Table 2. The results showed that the cherry yield, soil carbon sequestration and organic matter in the control group 2 were the best compared with the control group 1, but the difference was not significant; Both carbon and organic matter increased significantly, indicating increased sustainability of the soil.

表2Table 2

实验例3Experimental example 3

在黑龙江省密山某水稻种植基地进行实验:Experiments were conducted in a rice planting base in Mishan, Heilongjiang Province:

对照组1:施用17公斤/亩复混肥(N:P2O5:K2O=15-15-15),17公斤/亩尿素、5公斤/亩钾肥;Control group 1: Apply 17 kg/mu compound fertilizer (N:P 2 O 5 :K 2 O=15-15-15), 17 kg/mu urea, 5 kg/mu potassium fertilizer;

对照组2:施用15公斤/亩复混肥(N:P2O5:K2O=15-15-15),4公斤/亩钾肥以及上茬水稻秸秆粉碎后全部还田同作基肥,追肥尿素10公斤/亩;另施用对比例3制备的土壤结构调理剂25公斤/亩;Control group 2: Apply 15 kg/mu of compound fertilizer (N:P 2 O 5 :K 2 O=15-15-15), 4 kg/mu of potassium fertilizer and crushed rice stalks from the last stubble, all returned to the field as base fertilizer, 10 kilograms/mu of topdressing urea; 25 kilograms/mu of the soil structure conditioning agent that uses comparative example 3 preparations in addition;

实验组:施用15公斤/亩复混肥(N:P2O5:K2O=15-15-15),4公斤/亩钾肥以及上茬水稻秸秆粉碎后全部还田同作基肥,追肥尿素10公斤/亩;另施用实施例3制备的土壤结构调理剂25公斤/亩。Experimental group: apply 15 kg/mu of compound fertilizer (N:P 2 O 5 :K 2 O=15-15-15), 4 kg/mu of potassium fertilizer and crushed rice stalks from the last stubble, all returned to the field as base fertilizer, topdressing 10 kilograms/mu of urea; 25 kilograms/mu of the soil structure conditioner that uses embodiment 3 preparations in addition.

实验结果见表3。结果表明,对照组2与对照组1相比,水稻产量、土壤固碳及有机质均有所最佳,但差异不显著;实验组与对照组2、对照组1相比,水稻产量、土壤固碳及有机质均显著增加,表明对土壤的可持续能力增加。The experimental results are shown in Table 3. The results showed that compared with control group 1, control group 2 had the best rice yield, soil carbon sequestration and organic matter, but the difference was not significant; Both carbon and organic matter increased significantly, indicating increased sustainability of the soil.

表3table 3

实验例4Experimental example 4

2014年和2016年连续两年在山东淄博进行玉米-小麦肥效试验,实验组同时施用复合肥底肥(N:P2O5:K2O=15:15:15)20公斤/亩(比常规施肥量减少1/3),本发明实施例1制备的土壤结构调理剂30公斤/亩;对照组常规使用复合肥。玉米季结束实验组有机质含量比对照组增加14%;实验组小麦产量8978公斤/公顷,玉米产量10377公斤/公顷,分别比对照组增加2%和11%,固碳比对照增加20%。In 2014 and 2016, corn-wheat fertilizer efficiency experiments were carried out in Zibo, Shandong Province for two consecutive years, and the experimental group was simultaneously applied with compound fertilizer base fertilizer (N:P 2 O 5 :K 2 O=15:15:15) 20 kg/mu (compared with conventional The amount of fertilization is reduced by 1/3), and the soil structure conditioner prepared in Example 1 of the present invention is 30 kg/mu; the control group routinely uses compound fertilizers. At the end of the corn season, the organic matter content of the experimental group increased by 14% compared with the control group; the wheat yield of the experimental group was 8978 kg/ha, and the corn yield was 10377 kg/ha, which were 2% and 11% higher than the control group respectively, and the carbon sequestration increased by 20% compared with the control group.

虽然,上文中已经用一般性说明及具体实施方案对本发明作了详尽的描述,但在本发明基础上,可以对之作一些修改或改进,这对本领域技术人员而言是显而易见的。因此,在不偏离本发明精神的基础上所做的这些修改或改进,均属于本发明要求保护的范围。Although the present invention has been described in detail with general descriptions and specific embodiments above, it is obvious to those skilled in the art that some modifications or improvements can be made on the basis of the present invention. Therefore, the modifications or improvements made on the basis of not departing from the spirit of the present invention all belong to the protection scope of the present invention.

Claims (9)

1.一种稳产固碳的土壤结构调理剂,其特征在于,包括以下质量份的组分:植物材料30-90份,矿物材料1-40份;动物材料1-30份;复合微生物菌剂1-10份;1. A soil structure conditioner for stable production and carbon fixation, characterized in that it comprises the following components by mass: 30-90 parts of plant material, 1-40 parts of mineral material; 1-30 parts of animal material; composite microbial bacterial agent 1-10 copies; 所述植物材料按质量份数计其组成为:作物秸秆60-80份,天然中草药10-30份;植物氨基酸粉1-40份;The plant material consists of: 60-80 parts of crop straw, 10-30 parts of natural Chinese herbal medicine; 1-40 parts of plant amino acid powder; 所述矿物材料按质量份数计其组成为:含钾矿物组分40-70份;含磷矿物组分15-30份;含钙与镁矿物组分5-10份;含硫与铁矿物组分5-10份;稀土矿物组分1-5份;辅料矿物组分3-5份;The mineral material is composed by mass parts: 40-70 parts of mineral components containing potassium; 15-30 parts of mineral components containing phosphorus; 5-10 parts of mineral components containing calcium and magnesium; 5-10 parts of mineral components; 1-5 parts of rare earth mineral components; 3-5 parts of auxiliary mineral components; 所述动物材料为牡蛎粉、贝壳粉、甲壳素或壳聚糖中的一种或几种的任意比混合物;The animal material is one or a mixture of any ratio of oyster powder, shell powder, chitin or chitosan; 所述复合微生物菌剂含有枯草芽孢杆菌1-3亿cfu/g、地衣芽孢杆菌1-2亿cfu/g、巨大芽孢杆菌0.1-2亿cfu/g、凝结芽孢杆菌0.1-1亿cfu/g、嗜酸乳杆菌0.1-1亿cfu/g、侧孢芽孢杆菌0.01-0.1亿cfu/g、5406放线菌0.01-0.1亿cfu/g、光合细菌0.01-0.1亿cfu/g、胶冻样芽孢杆菌0.01-0.1亿cfu/g、绿色木霉菌0.01-0.1亿cfu/g。The composite microbial agent contains 100-300 million cfu/g of Bacillus subtilis, 100-200 million cfu/g of Bacillus licheniformis, 0.1-200 million cfu/g of Bacillus megaterium, and 0.1-100 million cfu/g of Bacillus coagulans , Lactobacillus acidophilus 0.1-100 million cfu/g, Bacillus lateralis 0.01-0.1 million cfu/g, 5406 actinomycetes 0.01-0.1 million cfu/g, photosynthetic bacteria 0.01-0.1 million cfu/g, jelly sample Bacillus 0.01-010 million cfu/g, Trichoderma viride 0.01-010 million cfu/g. 2.根据权利要求1所述的土壤结构调理剂,其特征在于,包括以下质量份的组分:植物材料36-80份;矿物材料12-30份;动物材料6-20份;复合微生物菌剂2-7份。2. soil structure conditioner according to claim 1, is characterized in that, comprises the component of following mass parts: plant material 36-80 parts; Mineral material 12-30 part; Animal material 6-20 part; Composite microbial bacterium 2-7 doses. 3.根据权利要求1所述的土壤结构调理剂,其特征在于,所述复合微生物菌剂含有枯草芽孢杆菌1-3亿cfu/g、地衣芽孢杆菌1.3-1.8亿cfu/g、巨大芽孢杆菌1-2亿cfu/g、凝结芽孢杆菌2-4亿cfu/g、嗜酸乳杆菌1-3亿cfu/g、侧孢芽孢杆菌0.1-0.5亿cfu/g、5406放线菌0.1-0.5亿cfu/g、光合细菌0.1-0.3亿cfu/g、胶冻样芽孢杆菌0.05-0.2亿cfu/g、绿色木霉菌0.05-0.2亿cfu/g。3. soil structure conditioning agent according to claim 1, is characterized in that, described composite microbial inoculant contains 1-300 million cfu/g of Bacillus subtilis, 1.3-180 million cfu/g of Bacillus licheniformis, Bacillus megaterium 100-200 million cfu/g, Bacillus coagulans 200-400 million cfu/g, Lactobacillus acidophilus 100-300 million cfu/g, Bacillus lateralis 0.1-050 million cfu/g, 5406 actinomycetes 0.1-0.5 0.1-0.3 billion cfu/g for photosynthetic bacteria, 0.05-0.2 billion cfu/g for Bacillus jelly-like, 0.05-0.2 billion cfu/g for Trichoderma viride. 4.根据权利要求1-3任一项所述的土壤结构调理剂,其特征在于,4. according to the soil structure conditioning agent described in any one of claim 1-3, it is characterized in that, 所述作物秸秆为玉米秸秆、小麦秸秆、水稻秸秆、大豆秸秆、甘蔗秸秆中的一种或几种;和/或,The crop straw is one or more of corn straw, wheat straw, rice straw, soybean straw, and sugarcane straw; and/or, 所述天然中草药为万寿菊、续随子、丁香、苦参、百部、川穹、黄荆、五倍子、烟草、蓖麻、苍耳、水蓼、狼毒、大蒜、艾叶、香蕉皮或核桃皮中的一种或几种的任意比混合物;和/或,The natural Chinese herbal medicines are marigold, capers, cloves, flavescens, basil, chuanqiong, huangjing, Galla, tobacco, castor, cocklebur, polygonum, chamaejama, garlic, mugwort, banana peel or walnut One or more arbitrary ratio mixtures in the skin; and/or, 所述植物氨基酸粉以棉籽粕、豆粕、油菜粕、花生粕、葵花子粕、油茶粕、乌桕粕或蓖麻粕为原料生产的氨基酸原粉,其所含氨基酸的质量百分比≥8%;和/或,The plant amino acid powder is an amino acid raw powder produced from cottonseed meal, soybean meal, rapeseed meal, peanut meal, sunflower seed meal, camellia oleifera meal, tallow tree meal or castor oil meal, and the mass percentage of the amino acid contained in it is ≥ 8%; and /or, 所述含钾矿物组分为钾长石、霞石、白榴石、海绿石或云母中的一种或几种的任意比混合物;含磷矿物组分为磷灰石;含钙与镁矿物组分为方解石、白云岩、石灰岩或蛇纹石中的一种或几种的任意比混合物;含硫与铁矿物组分为硫铁矿;稀土矿物组分为稀土矿;辅料矿物组分为凹凸棒石粘土、膨润土、沸石、蛭石或麦饭石中的一种或几种的任意比混合物。The potassium-containing mineral component is a mixture of one or more of potassium feldspar, nepheline, leucite, glauconite or mica; the phosphorus-containing mineral component is apatite; calcium and The magnesium mineral component is calcite, dolomite, limestone or serpentine or a mixture of several of them; the sulfur and iron mineral component is pyrite; the rare earth mineral component is rare earth ore; auxiliary minerals The components are attapulgite clay, bentonite, zeolite, vermiculite or medical stone or a mixture of several in any ratio. 5.根据权利要求1-3任一项所述的土壤结构调理剂,其特征在于,所述复合微生物菌剂中枯草芽孢杆菌、地衣芽孢杆菌、巨大芽孢杆菌、凝结芽孢杆菌和嗜酸乳杆菌五种菌的重量之和是侧孢芽孢杆菌、5406放线菌、光合细菌、胶冻样芽孢杆菌、绿色木霉菌五种菌的重量之和的9倍。5. according to the described soil structure conditioning agent of any one of claim 1-3, it is characterized in that, in the described composite microbial bacterial agent, bacillus subtilis, bacillus licheniformis, bacillus megaterium, bacillus coagulans and lactobacillus acidophilus The sum of the weights of the five bacteria is 9 times the weight of the five bacteria of Bacillus lateralis, 5406 actinomycetes, photosynthetic bacteria, jelly-like bacillus and Trichoderma viride. 6.根据权利要求1-3任一项所述的土壤结构调理剂,其特征在于,所述稳产固碳的土壤结构调理剂含水量为8-10wt%。6. The soil structure conditioner according to any one of claims 1-3, characterized in that, the water content of the soil structure conditioner for stably producing and fixing carbon is 8-10wt%. 7.权利要求1-6任一项所述土壤结构调理剂的制备方法,其特征在于,包括以下步骤:7. the preparation method of any one of claim 1-6 soil structure conditioner, is characterized in that, comprises the following steps: 1)将矿物材料混合,并经过900-1500℃高温煅烧5-20小时,冷却后粉碎过60-150目筛;1) The mineral materials are mixed and calcined at a high temperature of 900-1500°C for 5-20 hours, and then crushed through a 60-150 mesh sieve after cooling; 2)将植物材料分别烘干粉碎,然后混合;2) drying and pulverizing the plant materials respectively, and then mixing; 3)将动物材料烘干,粉碎,过30-100目筛;3) drying the animal material, pulverizing it, and passing through a 30-100 mesh sieve; 4)将复合微生物菌剂各原料混合,过60-150目筛;4) mixing the raw materials of the composite microbial bacterial agent, and passing through a 60-150 mesh sieve; 5)将以上原料按配比混合均匀,即可。5) Mix the above raw materials evenly according to the proportion. 8.权利要求1-6任一项所述的土壤结构调理剂在土壤稳产固碳方面的应用。8. The application of the soil structure conditioner described in any one of claims 1-6 in the stable production and sequestration of carbon in soil. 9.根据权利要求8所述的应用,其特征在于,所述土壤结构调理剂的用量:15-50公斤/亩。9. The application according to claim 8, characterized in that, the dosage of the soil structure conditioner: 15-50 kg/mu.
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CN106883052A (en) * 2017-04-18 2017-06-23 广东丰康生物科技有限公司 A kind of soil structure conditioner of stable yields carbon sequestration and preparation method and application
CN107011911A (en) * 2017-03-30 2017-08-04 深圳市铁汉生态环境股份有限公司 Beach saline land modifying agent, its preparation method and beach saline land modification method
CN107033922A (en) * 2017-06-20 2017-08-11 合肥卓畅农业科技有限公司 A kind of soil conditioner and preparation method thereof
CN107118777A (en) * 2017-03-21 2017-09-01 深圳市芭田生态工程股份有限公司 Soil conditioner and preparation method thereof
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CN107760314A (en) * 2017-11-08 2018-03-06 河南省农业科学院园艺研究所 A kind of special anti-continuous cropping composite soil modifier of industrialized agriculture
CN107793233A (en) * 2017-11-23 2018-03-13 史锦洋 Multielement functionality biological organic fertilizer
CN107935769A (en) * 2017-11-24 2018-04-20 张家口根力多生态农业科技有限公司 A kind of new soil recuperation agent and preparation method thereof
CN108640225A (en) * 2018-06-11 2018-10-12 苏州础润生态科技有限公司 Efficient minerals water body activator
CN108752131A (en) * 2018-06-22 2018-11-06 安吉溪龙茗岙茶场 Reduce the soil conditioner and its application method of mountainous region white tee tree content of beary metal
CN109320347A (en) * 2018-10-31 2019-02-12 山东航天旭洋农业科技发展有限公司 Organic fertilizer additive and the preparation method and application thereof
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CN109593530A (en) * 2018-11-07 2019-04-09 河北德龙环境工程股份有限公司 It is a kind of to adsorb multiple heavy metal cation passivator and preparation method thereof
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CN112159289A (en) * 2020-09-28 2021-01-01 广东省科学院生态环境与土壤研究所 Soil organic matter stabilizer and application thereof
CN112430155A (en) * 2020-12-01 2021-03-02 山东京青农业科技有限公司 Microbial fertilizer for farmland
CN113248309A (en) * 2021-05-21 2021-08-13 勤耕生态农业(武汉)有限公司 Organic fertilizer microbial inoculum formula special for citrus
CN114262245A (en) * 2020-09-16 2022-04-01 通海县金元有机肥有限公司 Organic fertilizer capable of preventing soil hardening damage and production method thereof
CN114394867A (en) * 2022-02-12 2022-04-26 辽宁省农业科学院 Dry farmland soil carbon fixing agent and preparation method and application thereof
CN114456000A (en) * 2022-02-11 2022-05-10 辽宁省农业科学院 Paddy field soil carbon fixing agent and application thereof
CN114916277A (en) * 2022-06-27 2022-08-19 辽宁省农业发展服务中心 Method for improving carbon sequestration potential of black soil
CN115287077A (en) * 2022-08-11 2022-11-04 江西普瑞丰生态科技有限公司 Soil carbon fixing agent and preparation method thereof
CN116082082A (en) * 2022-12-01 2023-05-09 四川农业大学 A kind of phosphorus-rich biochar based on Polygonum hydroponica and its preparation method and application
CN116789494A (en) * 2023-05-31 2023-09-22 山东亚太海华生物科技有限公司 Cherry composite organic fertilizer and preparation method thereof
CN116813406A (en) * 2023-06-28 2023-09-29 深圳市芭田生态工程股份有限公司 A kind of biofertilizer and its application in combination with microplastics to enhance soil carbon sequestration capacity
CN117142900A (en) * 2023-09-14 2023-12-01 云南省热带作物科学研究所 Preparation method of green tangerine peel organic fertilizer, preparation method of organic-inorganic compound fertilizer and application
CN117546649A (en) * 2023-11-23 2024-02-13 福建顿丰碳汇农业科技有限公司 A method for silicon-titanium composite microorganisms to increase photosynthetic efficiency and improve soil organic matter carbon fixation
CN117567212A (en) * 2023-11-28 2024-02-20 井冈山红壤研究所(江西省农业科学院井冈山分院) Multifunctional composite conditioner for reducing acid, fixing carbon and enhancing efficiency of paddy field, and preparation method and application thereof
CN117602979A (en) * 2023-11-27 2024-02-27 云南省农业科学院质量标准与检测技术研究所 A kind of biological fertilizer that promotes soil carbon sequestration and reduces damage and its application
CN117837611A (en) * 2024-01-02 2024-04-09 上海芯生机农业科技有限公司 Preparation method and application of composite microecological preparation
CN119385030A (en) * 2024-10-24 2025-02-07 海南省烟草公司儋州公司 A method for intercropping tobacco and snakewort
CN119908286A (en) * 2025-04-02 2025-05-02 内蒙古蒙钾矿物科技有限公司 A method for synthesizing artificial soil using solid waste

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CN106866300A (en) * 2017-01-23 2017-06-20 重庆恒佳工程技术咨询有限公司 Desert area salt-soda soil land modifying agent and preparation method
CN107118777A (en) * 2017-03-21 2017-09-01 深圳市芭田生态工程股份有限公司 Soil conditioner and preparation method thereof
CN107011911A (en) * 2017-03-30 2017-08-04 深圳市铁汉生态环境股份有限公司 Beach saline land modifying agent, its preparation method and beach saline land modification method
CN106883052A (en) * 2017-04-18 2017-06-23 广东丰康生物科技有限公司 A kind of soil structure conditioner of stable yields carbon sequestration and preparation method and application
CN107033922A (en) * 2017-06-20 2017-08-11 合肥卓畅农业科技有限公司 A kind of soil conditioner and preparation method thereof
CN107118996B (en) * 2017-06-30 2020-02-21 厦门六维生物科技有限公司 Organic fertilizer starter, preparation method and use method thereof
CN107118996A (en) * 2017-06-30 2017-09-01 厦门六维生物科技有限公司 Organic fertilizer fermentation agent and preparation method thereof and application method
CN107760314A (en) * 2017-11-08 2018-03-06 河南省农业科学院园艺研究所 A kind of special anti-continuous cropping composite soil modifier of industrialized agriculture
CN107760314B (en) * 2017-11-08 2018-08-28 河南省农业科学院园艺研究所 A kind of dedicated anti-continuous cropping composite soil modifier of industrialized agriculture
CN107793233A (en) * 2017-11-23 2018-03-13 史锦洋 Multielement functionality biological organic fertilizer
CN107935769A (en) * 2017-11-24 2018-04-20 张家口根力多生态农业科技有限公司 A kind of new soil recuperation agent and preparation method thereof
CN108640225A (en) * 2018-06-11 2018-10-12 苏州础润生态科技有限公司 Efficient minerals water body activator
CN108752131A (en) * 2018-06-22 2018-11-06 安吉溪龙茗岙茶场 Reduce the soil conditioner and its application method of mountainous region white tee tree content of beary metal
CN109320347A (en) * 2018-10-31 2019-02-12 山东航天旭洋农业科技发展有限公司 Organic fertilizer additive and the preparation method and application thereof
CN109320346A (en) * 2018-10-31 2019-02-12 山东航天旭洋农业科技发展有限公司 Organic fertilizer additive and the preparation method and application thereof
CN109336676A (en) * 2018-10-31 2019-02-15 山东航天旭洋农业科技发展有限公司 Organic fertilizer additive and the preparation method and application thereof
CN109354532A (en) * 2018-10-31 2019-02-19 山东航天旭洋农业科技发展有限公司 Organic fertilizer additive and the preparation method and application thereof
CN109438026A (en) * 2018-10-31 2019-03-08 山东航天旭洋农业科技发展有限公司 Organic fertilizer additive and the preparation method and application thereof
CN109593530A (en) * 2018-11-07 2019-04-09 河北德龙环境工程股份有限公司 It is a kind of to adsorb multiple heavy metal cation passivator and preparation method thereof
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CN111138225A (en) * 2020-01-14 2020-05-12 肖免 Soil nutrition conditioner and preparation method and application thereof
CN111345293A (en) * 2020-04-08 2020-06-30 江门海关技术中心 Mothproofing agent for insect specimen and preparation method thereof
CN111345293B (en) * 2020-04-08 2021-08-27 江门海关技术中心 Mothproofing agent for insect specimen and preparation method thereof
CN111500294A (en) * 2020-05-20 2020-08-07 山东根力多农业发展有限公司 Biological soil conditioner and preparation method thereof
CN114262245A (en) * 2020-09-16 2022-04-01 通海县金元有机肥有限公司 Organic fertilizer capable of preventing soil hardening damage and production method thereof
CN112159289A (en) * 2020-09-28 2021-01-01 广东省科学院生态环境与土壤研究所 Soil organic matter stabilizer and application thereof
CN112430155A (en) * 2020-12-01 2021-03-02 山东京青农业科技有限公司 Microbial fertilizer for farmland
CN113248309A (en) * 2021-05-21 2021-08-13 勤耕生态农业(武汉)有限公司 Organic fertilizer microbial inoculum formula special for citrus
CN114456000A (en) * 2022-02-11 2022-05-10 辽宁省农业科学院 Paddy field soil carbon fixing agent and application thereof
CN114394867A (en) * 2022-02-12 2022-04-26 辽宁省农业科学院 Dry farmland soil carbon fixing agent and preparation method and application thereof
CN114916277A (en) * 2022-06-27 2022-08-19 辽宁省农业发展服务中心 Method for improving carbon sequestration potential of black soil
CN115287077A (en) * 2022-08-11 2022-11-04 江西普瑞丰生态科技有限公司 Soil carbon fixing agent and preparation method thereof
CN116082082B (en) * 2022-12-01 2024-05-10 四川农业大学 Phosphorus-rich biochar based on polygonum hydropiper and preparation method and application thereof
CN116082082A (en) * 2022-12-01 2023-05-09 四川农业大学 A kind of phosphorus-rich biochar based on Polygonum hydroponica and its preparation method and application
CN116789494A (en) * 2023-05-31 2023-09-22 山东亚太海华生物科技有限公司 Cherry composite organic fertilizer and preparation method thereof
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CN117142900A (en) * 2023-09-14 2023-12-01 云南省热带作物科学研究所 Preparation method of green tangerine peel organic fertilizer, preparation method of organic-inorganic compound fertilizer and application
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CN117567212A (en) * 2023-11-28 2024-02-20 井冈山红壤研究所(江西省农业科学院井冈山分院) Multifunctional composite conditioner for reducing acid, fixing carbon and enhancing efficiency of paddy field, and preparation method and application thereof
CN117837611A (en) * 2024-01-02 2024-04-09 上海芯生机农业科技有限公司 Preparation method and application of composite microecological preparation
CN119385030A (en) * 2024-10-24 2025-02-07 海南省烟草公司儋州公司 A method for intercropping tobacco and snakewort
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Application publication date: 20170111