CN109320347A - Organic fertilizer additive and the preparation method and application thereof - Google Patents

Organic fertilizer additive and the preparation method and application thereof Download PDF

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Publication number
CN109320347A
CN109320347A CN201811288080.XA CN201811288080A CN109320347A CN 109320347 A CN109320347 A CN 109320347A CN 201811288080 A CN201811288080 A CN 201811288080A CN 109320347 A CN109320347 A CN 109320347A
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China
Prior art keywords
parts
organic fertilizer
fertilizer additive
ore
powder
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CN201811288080.XA
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Chinese (zh)
Inventor
张东旭
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Shandong Aerospace Xuyang Agricultural Science And Technology Development Co Ltd
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Shandong Aerospace Xuyang Agricultural Science And Technology Development Co Ltd
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Priority to CN201811288080.XA priority Critical patent/CN109320347A/en
Publication of CN109320347A publication Critical patent/CN109320347A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B17/00Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners

Abstract

The invention discloses organic fertilizer additives and the preparation method and application thereof.Organic fertilizer additive provided by the invention is mainly made of mass ratio of the herbal component and ore composition of 1:1.5-3: including herbal component and mineral component;The herbal component includes the raw material of following parts by weight: 1-3 parts of the root of gansui, 2-5 parts of gingko, 1-3 parts of the tuber of stemona, 1-3 parts and sweet wormwood 1-3 parts of Radix Angelicae Sinensis;The ore composition includes the raw material of following parts by weight: 2-6 parts of medical stone, 1-3 parts of gypsum rubrum, 1-3 parts of calamine, 1-3 parts of alum, 2-4 parts of rock phosphate in powder, 2-4 parts and talcum 1-3 parts of potassium feldspar.Organic fertilizer additive provided by the present invention can increase Trace Elements in Soil content, improve crop yield and quality, reduce the content of mycotoxin in soil.

Description

Organic fertilizer additive and the preparation method and application thereof
Technical field
The present invention relates to agricultural fertilizer field, in particular to organic fertilizer additive and the preparation method and application thereof.
Background technique
Organic fertilizer can improve soil, culture fertility, and the main matter in organic fertilizer is organic matter, application of organic fertilizers Material increases the content of organic matter in soil.Organic matter can improve soil physics, chemistry and biological nature, vegetable soil, training Fertile soil fertility.Chinese countryside " by excrement support, seedling by excrement grow " proverb, reflect to a certain extent application of organic fertilizers material for Improve the effect of soil.
The most of existing organic fertilizer are animal wastes and straw.Organic fertilizer organic matter rich in With various nutrients, have the advantages that quantity is big, source is wide, nutrient is comprehensive, but there is also dirty, smelly, unhygienic, nutrient contents Low, the disadvantages of fertilizer efficiency is slow, inconvenient to use.Inorganic fertilizer just has nutrient content high in contrast, and fertilizer efficiency is fast, easy to use The advantages that, but the deficiency single there is also nutrient, and chemical fertilizer is used in agricultural production, it will lead to environmental pollution, cause soil Earth is hardened.
Meanwhile the problem of soil pollution at present, is increasingly serious, the heavy metal in soil, mycotoxin is to influence plant life Long development and the harmful substance being detrimental to health.Once the content of beary metal excess or mycotoxin in plant are exceeded, Huge damage will be generated to eater's human health.
Summary of the invention
To solve the above-mentioned problems, the present invention provides one kind and can increase Trace Elements in Soil content, improve farming produce Amount and quality reduce organic fertilizer additive of content and preparation method thereof of mycotoxin in soil.
The present invention adopts the following technical solutions:
It is an object of the present invention to provide a kind of organic fertilizer additives.
Organic fertilizer additive provided by the present invention, the herbal component and ore group for being mainly 1:1.5-3 by mass ratio Divide and is made;The herbal component includes the raw material of following parts by weight: 1-3 parts of the root of gansui, 2-5 parts of gingko, and 1-3 parts of the tuber of stemona, Radix Angelicae Sinensis 1-3 parts and sweet wormwood 1-3 parts;The ore composition includes the raw material of following parts by weight: 2-6 parts of medical stone, 1-3 parts of gypsum rubrum, and furnace Sweet stone 1-3 parts, 1-3 parts of alum, 2-4 parts of rock phosphate in powder, 2-4 parts and talcum 1-3 parts of potassium feldspar.
The herbal component includes the raw material of following parts by weight: 2 parts of the root of gansui, 4 parts of gingko, 2 parts of the tuber of stemona, 2 parts of Radix Angelicae Sinensis and 2 parts of sweet wormwood.
The ore composition includes the raw material of following parts by weight: 4 parts of medical stone, 2 parts of gypsum rubrum, and 2 parts of calamine, alum 2 Part, 3 parts of rock phosphate in powder, 3 parts and 2 parts of talcum of potassium feldspar.
The herbal component and the mass ratio of the mineral component are 1:2.
The herbal component is ground into 100-200 mesh powder after dry in terms of the weight after drying.
The ore composition is ground into 100-200 mesh powder after dry in terms of the weight after drying.
Another object of the present invention is to provide the preparation methods of organic fertilizer additive.
The preparation method of organic fertilizer additive provided by the present invention comprising the steps of:
(1) it is crushed after drying the root of gansui, gingko, the tuber of stemona, Radix Angelicae Sinensis and sweet wormwood, obtains herbal component;
(2) rock phosphate in powder and potassium feldspar are crushed, then flotation, is enriched with P elements and potassium element, obtained ore group 1 is simultaneously ground At powder;Medical stone, gypsum rubrum, alum, calamine and talcum are crushed, ore group 2 is obtained;By ore group 1 and ore group 2 Powder is mixed to get ore composition;
(3) by herbal component that the step (1) obtains and ore composition that the step (2) obtains mix to get To organic fertilizer additive.
The herbal component is ground into 100-200 mesh powder.
The ore composition is ground into 100-200 mesh powder.
The present invention also provides a kind of organic fertilizers, are made of the raw material for including following mass percent: organic fertilizer additive 30%, fermented cow dung 55%, ammonium humate 5%, calcium humate 8%, surplus are active powdered carbon.
The structure of the root of gansui is in cellular, and large specific surface area, and irritant has harmful substance and drive in absorption soil The effect of worm.Meanwhile the tuber of stemona also plays the role of expelling parasite, has inhibiting effect to insect pest.
Gingko has antifungi, Escherichia coli, corynebacterium diphtheriae, staphylococcus, tubercle bacillus, streptococcic effect.Exosper Alcohols intermediate is 81% to the inhibition effective percentage of 22 kinds of clinical common causative fungies;The exosper extract of ginkgo is to apple charcoal The inhibiting rate of 11 kinds of phytopathogens such as subcutaneous ulcer disease is up to 88%~100%;To control rate in silk flosssilk wadding gold looper 3 days up to 100%, while can Prevent and treat the pests such as tetranychid, black peach aphid, striped rice borer.
Radix Angelicae Sinensis is to external dysentery, typhoid fever, paratyphoid, Escherichia coli, corynebacterium diphtheriae, comma bacillus and A, B hemolytic hammer Bacterium etc. has antibacterial action.On the other hand sweet wormwood, one side anti-schistosome, spray testis fluke have resisting pathogenic microbes effect.
Carrying out flotation to rock phosphate in powder and potassium feldspar is the phosphorus and potassium element in order to be enriched in the two, and producing for making is organic Fertilizer additive active constituent content is higher, is more advantageous to the growth and development of plant, and potassium ion is also helped due to being monovalent ion Improve soil hardening situation.
Medical stone, gypsum rubrum, calamine in organic fertilizer additive, alum, rock phosphate in powder, potassium feldspar and talcum, on the one hand Rich in the microelement that how empty a variety of human bodies are, including iron, zinc, manganese, copper etc., on the other hand its loose porous structure is even more to suction Heavy metal and mycotoxin in attached soil have significant effect.
Since mould easily breeds in the soil, the mycotoxin contained in soil, mycotoxin refers to that mould is dirty in its institute The toxic metabolic products generated in the food of dye, they can be entered in humans and animals body by feed or food, caused people and moved The acute or chronic toxicity of object, damages liver, kidney, nerve fiber, hematopoietic tissue and skin histology of body etc..It is of the invention public The organic fertilizer additive opened can effectively remove the mycotoxin in soil, because its traditional Chinese medicinal components can effectively inhibit mould The porous loose structure of bacterium, ore composition can effective absorbing mycotoxin.
The rotten of Chinese medicinal plant itself also generates organic matter and fertilizer.
Organic fertilizer additive provided by the invention has following effects:
(1) organic fertilizer additive of the invention contains the inorganic matters element such as iron needed by human, calcium, potassium, magnesium, is had using this The fertilizer of machine fertilizer additive is higher than the micronutrient levels only contained with fertilizer growing plants;
(2) strong adsorption forces such as organic fertilizer additive primary raw material medical stone of the invention, medical stone main component are dioxy SiClx, aluminium oxide have porosity and huge surface area, the heavy metal element in soil can be adsorbed, so that the huge sum of money in soil Belonging to element significantly reduces, while porous structure can also store oxygen, and the growth of the root of plant also be unable to do without oxygen;
(3) organic fertilizer additive of the invention is nontoxic to plant, has stronger absorption to remove energy mycotoxin Power, absorption clearance rate is 98%, and medicinal herb components therein also have anthelmintic action;
(4) it can effectively reduce diseases and pests of agronomic crop incidence using the organic fertilizer of organic fertilizer additive of the invention, mention High crop yield and quality improve soil texture, increase organic matter, nitrogen, phosphorus, potassium and various micronutrient levels, have fertilizer Effect is high, absorbs fast, safety.
Specific embodiment
The root of gansui and gingko are purchased from Bozhou cold-scarce medicinal material wholesale;
The tuber of stemona, sweet wormwood are purchased from Meizhou City Shang Shanruoshui Chinese medicine Co., Ltd;
Radix Angelicae Sinensis is purchased from Fuling District the Changjiang river commerce and trade business department.
Calamine, gypsum rubrum, alum, talcum sell Co., Ltd purchased from Hui nationality's Nine-Dragon Wall;
Medical stone, potassium feldspar are purchased from Lingshou County Ze En mineral products processing factory;
Rock phosphate in powder is purchased from Jinan Hao Shuo Chemical Co., Ltd..
Embodiment 1, organic fertilizer additive I and preparation method thereof
Prepare organic fertilizer additive I:
Organic fertilizer additive that the present embodiment is prepared, the herbal component and ore composition for being 1:1.5 by mass ratio It is made;Herbal component includes the raw material of following parts by weight: 1 part of the root of gansui, 2 parts of gingko, 1 part of the tuber of stemona, 1 part and 1 part of sweet wormwood of Radix Angelicae Sinensis; Ore composition includes the raw material of following parts by weight: 2 parts of medical stone, 1 part of gypsum rubrum, and 1 part of calamine, 1 part of alum, 2 parts of rock phosphate in powder, 2 parts and 1 part of talcum of potassium feldspar.
It is specific the preparation method is as follows:
(1) it is crushed after drying the root of gansui, gingko, the tuber of stemona, Radix Angelicae Sinensis and sweet wormwood, obtains herbal component;Herbal component quilt It is ground into 100-200 mesh powder;
(2) rock phosphate in powder and potassium feldspar are crushed, then flotation, is enriched with P elements and potassium element, obtained ore group 1 is simultaneously ground At powder;Medical stone, gypsum rubrum, alum, calamine and talcum are crushed, ore group 2 is obtained;By ore group 1 and ore group 2 Powder is mixed to get ore composition;Ore composition is smashed into 100~200 mesh powder;
(3) herbal component and the ore composition are crushed to the organic fertilizer additive I for being uniformly mixed so as to obtain the present embodiment.
Embodiment 2, organic fertilizer additive II
Prepare organic fertilizer additive II:
Organic fertilizer additive that the present embodiment is prepared, the herbal component and ore composition system for being 1:2 by mass ratio At;Herbal component includes the raw material of following parts by weight: 3 parts of the root of gansui, 5 parts of gingko, 3 parts of the tuber of stemona, 3 parts and 3 parts of sweet wormwood of Radix Angelicae Sinensis;Mine Stone component includes the raw material of following parts by weight: 6 parts of medical stone, 3 parts of gypsum rubrum, and 3 parts of calamine, 3 parts of alum, 4 parts of rock phosphate in powder, potassium 4 parts and 3 parts of talcum of feldspar.
It is specific the preparation method is as follows:
(1) it is crushed after drying the root of gansui, gingko, the tuber of stemona, Radix Angelicae Sinensis and sweet wormwood, obtains herbal component;Herbal component quilt It is ground into 100-200 mesh powder;
(2) rock phosphate in powder and potassium feldspar are crushed, then flotation, is enriched with P elements and potassium element, obtained ore group 1 is simultaneously ground At powder;Medical stone, gypsum rubrum, alum, calamine and talcum are crushed, ore group 2 is obtained;By ore group 1 and ore group 2 Powder is mixed to get ore composition;Ore composition is smashed into 100-200 mesh powder;
(3) herbal component and the ore composition are crushed to the organic fertilizer additive for being uniformly mixed so as to obtain the present embodiment Ⅱ。
Embodiment 3: organic fertilizer additive III
Prepare organic fertilizer additive III:
Organic fertilizer additive that the present embodiment is prepared, the herbal component and ore composition for being 1:2.5 by mass ratio It is made;Herbal component includes the raw material of following parts by weight: 2 parts of the root of gansui, 4 parts of gingko, 2 parts of the tuber of stemona, 2 parts and 2 parts of sweet wormwood of Radix Angelicae Sinensis; Ore composition includes the raw material of following parts by weight: 4 parts of medical stone, 2 parts of gypsum rubrum, and 2 parts of calamine, 2 parts of alum, 3 parts of rock phosphate in powder, 3 parts and 2 parts of talcum of potassium feldspar.
It is specific the preparation method is as follows:
(1) it is crushed after drying the root of gansui, gingko, the tuber of stemona, Radix Angelicae Sinensis and sweet wormwood, obtains herbal component;Herbal component quilt It is ground into 100-200 mesh powder;
(2) rock phosphate in powder and potassium feldspar are crushed, then flotation, is enriched with P elements and potassium element, obtained ore group 1 is simultaneously ground At powder;Medical stone, gypsum rubrum, alum, calamine and talcum are crushed, ore group 2 is obtained;By ore group 1 and ore group 2 Powder is mixed to get ore composition;Ore composition is smashed into 100-200 powder;
(3) herbal component and the ore composition are crushed to the organic fertilizer additive for being uniformly mixed so as to obtain the present embodiment Ⅲ。
Embodiment 4, organic fertilizer additive IV
Prepare organic fertilizer additive IV:
Organic fertilizer additive that the present embodiment is prepared is made of mass ratio of the herbal component and ore of 1:3;In Herbal ingredients include the raw material of following parts by weight: 1 part of the root of gansui, 2 parts of gingko, 1 part of the tuber of stemona, 1 part and 1 part of sweet wormwood of Radix Angelicae Sinensis;Ore group Raw material of the subpackage containing following parts by weight: 3 parts of medical stone, 2 parts of gypsum rubrum, 3 parts of calamine, 3 parts of alum, 4 parts of rock phosphate in powder, potassium feldspar 4 parts and 3 parts of talcum.
It is specific the preparation method is as follows:
(1) it is crushed after drying the root of gansui, gingko, the tuber of stemona, Radix Angelicae Sinensis and sweet wormwood, obtains herbal component;Herbal component quilt It is ground into 100-200 mesh powder;
(2) rock phosphate in powder and potassium feldspar are crushed, then flotation, is enriched with P elements and potassium element, obtained ore group 1 is simultaneously ground At powder;Medical stone, gypsum rubrum, alum, calamine and talcum are crushed, ore group 2 is obtained;By ore group 1 and ore group 2 Powder is mixed to get ore composition;Ore composition is smashed into 100-200 powder;
(3) herbal component and the ore composition are crushed to the organic fertilizer additive for being uniformly mixed so as to obtain the present embodiment Ⅳ。
Experimental example 1: contrast test of fertilizer efficiency
It is prepared according to the following steps the organic fertilizer 1-4:(1 of the addition organic fertilizer additive of embodiment 1-4) by organic fertilizer additive Levigate is 100-200 mesh powder;(2) component of column mass percent: fermented cow dung 55%, ammonium humate 5%, humic is removed Sour calcium 8%, organic fertilizer additive 30%, surplus are active powdered carbon, are mixed the above components evenly, 60 DEG C of drying pack to get To organic fertilizer 1-4.
Test is compared to the organic fertilizer of embodiment and comparative example, following group is arranged altogether, and (all fertilizer are divided equally Four applications, every minor tick one month, until obtaining test result when crop harvesting):
A1 group: the organic fertilizer 1 containing the organic fertilizer additive of embodiment 1 is used to use as celery base manure, usage amount 60kg/ 300m2
A2 group: the organic fertilizer 2 containing the organic fertilizer additive of embodiment 2 is used to use as celery base manure, usage amount 60kg/ 300m2
A3 group: the organic fertilizer 3 containing the organic fertilizer additive of embodiment 3 is used to use as celery base manure, usage amount 60kg/ 300m2
A4 group: the organic fertilizer 4 containing the organic fertilizer additive of embodiment 4 is used to use as celery base manure, usage amount 60kg/ 300m2
B group: it is used used as celery base manure, usage amount 60kg/300m2;(organic fertilizer of reference examples includes quality percentage Than for 78.5% fermented cow dung, 7.1% ammonium humate, 11.4% calcium humate and 3% active carbon)
C group: organic fertilizer is not used.
1 contrast test of fertilizer efficiency result of table
Micronutrient levels test is carried out to the celery stems of above-mentioned six groups: in plant microelement test according to HNO3-H2O2Microwave, which disappears, boils method (China Agricultural University's micro elements by plants battalion of-ICP measurement plant sample micronutrient levels Support and human health group) it carries out, micronutrient levels is as shown in table 2.
2 micronutrient levels table of table
By above-mentioned contrast test of fertilizer efficiency and it is found that the organic fertilizer additive of the present invention, can be such that the nutrient in organic fertilizer obtains To making full use of, to effectively improve crops quality, crop yield is enabled to improve.
Experimental example 2: the experiment of mycotoxin is removed
Instrument: Shenzhen's sweet smell analyzer device Manufacturing Co., Ltd CSY-JAZ mycotoxin fast detector
Fresh soil is taken, is divided into two groups, the organic fertilizer additive mixing for the embodiment 1 that mass fraction is 10% is added in A group Uniformly, after 72h, the aflatoxin of two parts of soil, zearalenone and vomitoxin are detected, B group is control group, what is all It is not added, as a result such as table 3.
The experimental result of the removing mycotoxin of table 3
As shown in Table 3, each mycotoxin content of B group is significantly higher than A group, to typical mycotoxin aflatoxin, The clearance rate of zearalenone and vomitoxin can reach 90% or so, it was demonstrated that organic fertilizer additive disclosed in embodiment 1 The mycotoxin that soil contains can effectively be removed.
Organic fertilizer additive that embodiment 2-4 is provided has the similar elimination effect to mycotoxin, to Gibberella zeae The clearance rate of ketenes and vomitoxin can reach 90% or so.

Claims (10)

1. organic fertilizer additive, which is characterized in that the herbal component and ore composition system for being mainly 1:1.5-3 by mass ratio At: the herbal component includes the raw material of following parts by weight: 1-3 parts of the root of gansui, 2-5 parts of gingko, 1-3 parts of the tuber of stemona, 1-3 parts of Radix Angelicae Sinensis With 1-3 parts of sweet wormwood;The ore composition includes the raw material of following parts by weight: 2-6 parts of medical stone, 1-3 parts of gypsum rubrum, and calamine 1- 3 parts, 1-3 parts of alum, 2-4 parts of rock phosphate in powder, 2-4 parts and talcum 1-3 parts of potassium feldspar.
2. organic fertilizer additive according to claim 1, which is characterized in that the herbal component includes following parts by weight Raw material: 2 parts of the root of gansui, 4 parts of gingko, 2 parts of the tuber of stemona, 2 parts of Radix Angelicae Sinensis and 2 parts of sweet wormwood.
3. organic fertilizer additive according to claim 1, which is characterized in that the ore composition includes following parts by weight Raw material: 4 parts of medical stone, 2 parts of gypsum rubrum, 2 parts of calamine, 2 parts of alum, 3 parts of rock phosphate in powder, 3 parts and 2 parts of talcum of potassium feldspar.
4. organic fertilizer additive according to claim 1, which is characterized in that the herbal component and the minerals group The mass ratio divided is 1:2.
5. organic fertilizer additive according to claim 1, which is characterized in that the herbal component is with the weight after drying Meter is ground into 100-200 mesh powder after dry.
6. organic fertilizer additive according to claim 1, which is characterized in that the ore composition is with the weight after drying Meter is ground into 100-200 mesh powder after dry.
7. according to claim 1 in -6 any organic fertilizer additive preparation method comprising the steps of:
(1) it is crushed after drying the root of gansui, gingko, the tuber of stemona, Radix Angelicae Sinensis and sweet wormwood, obtains herbal component;
(2) rock phosphate in powder and potassium feldspar are crushed, carries out flotation, be enriched with P elements and potassium element, obtained ore group 1 and grinds End;Medical stone, gypsum rubrum, alum, calamine and talcum are crushed, ore group 2 is obtained;By the powder of ore group 1 and ore group 2 It is mixed to get ore composition;
(3) herbal component that the step (1) obtains and ore composition that the step (2) obtains are mixed to get to institute State organic fertilizer additive.
8. the preparation method of organic fertilizer additive according to claim 7, it is characterised in that: the herbal component is pulverized At 100-200 mesh powder.
9. the preparation method of organic fertilizer additive according to claim 7, it is characterised in that: the ore composition is ground into 100-200 mesh powder.
10. a kind of organic fertilizer is made: organic fertilizer additive 30%, fermented cow dung of the raw material for including following mass percent 55%, ammonium humate 5%, calcium humate 8%, surplus are active powdered carbon.
CN201811288080.XA 2018-10-31 2018-10-31 Organic fertilizer additive and the preparation method and application thereof Pending CN109320347A (en)

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