CN105050714B - 用于在二氧化碳存在下重整烃的含六铝酸镍的催化剂 - Google Patents
用于在二氧化碳存在下重整烃的含六铝酸镍的催化剂 Download PDFInfo
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- CN105050714B CN105050714B CN201480012079.8A CN201480012079A CN105050714B CN 105050714 B CN105050714 B CN 105050714B CN 201480012079 A CN201480012079 A CN 201480012079A CN 105050714 B CN105050714 B CN 105050714B
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- catalyst
- nickel
- hexaaluminate
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- reforming hydrocarbons
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- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
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- B01J23/74—Iron group metals
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- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
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- Chemical & Material Sciences (AREA)
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- Organic Chemistry (AREA)
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- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
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Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13158074.8 | 2013-03-07 | ||
| EP13158074 | 2013-03-07 | ||
| EP13194345 | 2013-11-26 | ||
| EP13194345.8 | 2013-11-26 | ||
| PCT/EP2014/054362 WO2014135642A1 (de) | 2013-03-07 | 2014-03-06 | Nickelhexaaluminathaltiger katalysator zur reformierung von kohlenwasserstoffen in gegenwart von kohlendioxid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105050714A CN105050714A (zh) | 2015-11-11 |
| CN105050714B true CN105050714B (zh) | 2018-06-26 |
Family
ID=50231185
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480012079.8A Expired - Fee Related CN105050714B (zh) | 2013-03-07 | 2014-03-06 | 用于在二氧化碳存在下重整烃的含六铝酸镍的催化剂 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9475037B2 (https=) |
| EP (1) | EP2964385A1 (https=) |
| JP (1) | JP2016510687A (https=) |
| KR (1) | KR20150129786A (https=) |
| CN (1) | CN105050714B (https=) |
| DE (1) | DE112014001125A5 (https=) |
| RU (1) | RU2662221C2 (https=) |
| WO (1) | WO2014135642A1 (https=) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2886514A1 (de) * | 2013-12-20 | 2015-06-24 | Basf Se | Verfahren zur Reformierung von Gemischen aus Kohlenwasserstoffen und Kohlendioxid |
| US9416087B2 (en) | 2014-10-08 | 2016-08-16 | Chevron Phillips Chemical Company Lp | Methods for the production of α,β-unsaturated carboxylic acids and salts thereof |
| US9725393B2 (en) | 2014-10-08 | 2017-08-08 | Chevron Phillips Chemical Company Lp | Methods for the production of α,β-unsaturated carboxylic acids and salts thereof |
| RU2732326C2 (ru) | 2015-07-22 | 2020-09-15 | Басф Се | Способ получения фуран-2,5-дикарбоновой кислоты |
| EP3371161A1 (en) | 2015-11-04 | 2018-09-12 | Basf Se | A process for preparing furan-2,5-dicarboxylic acid |
| JP2018536656A (ja) | 2015-11-04 | 2018-12-13 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 5−(ヒドロキシメチル)フルフラール及び特定のhmfエステルを含む混合物を調製する方法 |
| US10160711B2 (en) | 2015-12-15 | 2018-12-25 | Chevron Phillips Chemical Company Lp | Formation of α,β-unsaturated carboxylic acids and salts thereof from metalalactones and anionic polyelectrolytes |
| US10544080B2 (en) | 2017-06-14 | 2020-01-28 | Chevron Phillips Chemical Company Lp | Continuous process for the conversion of olefins and carbon dioxide to acrylates via solution phase reactor |
| US10550061B2 (en) | 2017-06-14 | 2020-02-04 | Chevron Phillips Chemical Company Lp | Sulfur oxoacid-substituted and phosphorus oxoacid-substituted polyaromatic resins and salts thereof as promoters in acrylate production from coupling reactions of olefins and carbon dioxide |
| IL272552B2 (en) * | 2017-08-11 | 2023-09-01 | Idac Holdings Inc | Traffic routing and switching between multiple access networks |
| CN107673383A (zh) * | 2017-09-06 | 2018-02-09 | 新地能源工程技术有限公司 | 六铝酸盐、包含其的载体及其制备方法和高温甲烷化催化剂 |
| CN107597199A (zh) * | 2017-09-13 | 2018-01-19 | 武汉凯迪工程技术研究总院有限公司 | 循环流化床烃重整催化剂及其制备方法和应用 |
| CN109012144B (zh) * | 2018-07-19 | 2021-03-30 | 中国科学院大学 | 六铝酸盐复合氧化物材料在h2s催化分解反应中的应用 |
| US11174213B2 (en) | 2018-10-12 | 2021-11-16 | Chevron Phillips Chemical Company, Lp | Effects of catalyst concentration and solid activator on nickel-mediated olefin/carbon dioxide coupling to acrylates |
| EP3917666B1 (en) * | 2019-01-31 | 2024-08-07 | Basf Se | A molding comprising a mixed oxide comprising oxygen, lanthanum, aluminum, and cobalt |
| WO2022015484A1 (en) * | 2020-07-14 | 2022-01-20 | Basf Corporation | Strontium-catalyzed boehmite formation |
| CN119486807A (zh) | 2022-07-01 | 2025-02-18 | 巴斯夫欧洲公司 | 用于将烃转化为合成气的钴基催化剂 |
| CN119486808A (zh) | 2022-07-01 | 2025-02-18 | 巴斯夫欧洲公司 | 用于将烃转化为合成气的基于钴和锶的催化剂 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050232857A1 (en) * | 2004-04-16 | 2005-10-20 | H2Gen Innovations, Inc. | Catalyst for hydrogen generation through steam reforming of hydrocarbons |
| CN102836718A (zh) * | 2011-06-20 | 2012-12-26 | 中国科学院过程工程研究所 | 一种介孔六铝酸盐负载镍基的甲烷化催化剂及其制备方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2721837B1 (fr) * | 1994-07-01 | 1996-08-30 | Inst Francais Du Petrole | Catalyseur d'oxydation resistant a des temperatures elevees, son procede de preparation et procede de combustion utilisant un tel catalyseur |
| WO2001025142A1 (en) * | 1999-10-01 | 2001-04-12 | Bp Amoco Corporation | Preparing synthesis gas using hydrotalcite-derived nickel catalysts |
| GB0115850D0 (en) * | 2001-06-28 | 2001-08-22 | Isis Innovations Ltd | Catalyst |
| US20050265920A1 (en) * | 2002-11-11 | 2005-12-01 | Conocophillips Company | Supports and catalysts comprising rare earth aluminates, and their use in partial oxidation |
| CA2504206A1 (en) * | 2002-11-11 | 2004-05-27 | Conocophillips Company | Stabilized alumina supports, catalysts made therefrom, and their use in partial oxidation |
| JP4096096B2 (ja) * | 2002-12-25 | 2008-06-04 | 独立行政法人産業技術総合研究所 | ヘキサアルミネート多孔質セラミックス及びその製造方法 |
| DE10322339A1 (de) * | 2003-05-17 | 2004-12-02 | Mtu Aero Engines Gmbh | Einlaufbelag für Gasturbinen |
| DE102004025798A1 (de) * | 2004-05-26 | 2005-12-22 | Mtu Aero Engines Gmbh | Wärmedämmschichtsystem |
| JP4976656B2 (ja) * | 2005-03-07 | 2012-07-18 | 電気化学工業株式会社 | 触媒担体及びその製造方法 |
| US8142756B1 (en) * | 2006-03-28 | 2012-03-27 | The United States Of America As Represented By The U.S. Department Of Energy | Methods of reforming hydrocarbon fuels using hexaaluminate catalysts |
| US7736536B2 (en) * | 2006-07-11 | 2010-06-15 | Intematix Corporation | Compositions comprising a mixture of a BAM phosphor and at least one other hexaaluminate |
| RU2366503C1 (ru) * | 2008-04-14 | 2009-09-10 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Катализатор, способ его приготовления (варианты) и способ получения биотоплива |
| RU2388535C1 (ru) * | 2009-04-15 | 2010-05-10 | Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (статус государственного учреждения) | Катализатор, способ его приготовления и способ окисления метана |
| WO2011020194A1 (en) * | 2009-08-21 | 2011-02-24 | Universite De Sherbrooke | Steam reforming of hydrocarbonaceous fuels over a ni-alumina spinel catalyst |
| US8916491B2 (en) | 2011-11-08 | 2014-12-23 | Basf Se | Process for producing a methanation catalyst and a process for the methanation of synthesis gas |
| US9259712B2 (en) | 2011-11-08 | 2016-02-16 | Basf Se | Process for producing a reforming catalyst and the reforming of methane |
| US9566571B2 (en) * | 2012-02-10 | 2017-02-14 | Basf Se | Hexaaluminate-comprising catalyst for the reforming of hydrocarbons and a reforming process |
| US20140001407A1 (en) | 2012-06-29 | 2014-01-02 | Basf Se | High-pressure process for the carbon dioxide reforming of hydrocarbons in the presence of iridium-comprising active compositions |
| WO2014097142A1 (de) | 2012-12-21 | 2014-06-26 | Basf Se | Parallele herstellung von wasserstoff, kohlenstoffmonoxid und einem kohlenstoffhaltigen produkt |
-
2014
- 2014-03-06 JP JP2015560691A patent/JP2016510687A/ja not_active Ceased
- 2014-03-06 CN CN201480012079.8A patent/CN105050714B/zh not_active Expired - Fee Related
- 2014-03-06 EP EP14708059.2A patent/EP2964385A1/de not_active Withdrawn
- 2014-03-06 KR KR1020157027681A patent/KR20150129786A/ko not_active Withdrawn
- 2014-03-06 DE DE112014001125.8T patent/DE112014001125A5/de not_active Withdrawn
- 2014-03-06 WO PCT/EP2014/054362 patent/WO2014135642A1/de not_active Ceased
- 2014-03-06 US US14/771,888 patent/US9475037B2/en not_active Expired - Fee Related
- 2014-03-06 RU RU2015142397A patent/RU2662221C2/ru not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050232857A1 (en) * | 2004-04-16 | 2005-10-20 | H2Gen Innovations, Inc. | Catalyst for hydrogen generation through steam reforming of hydrocarbons |
| CN102836718A (zh) * | 2011-06-20 | 2012-12-26 | 中国科学院过程工程研究所 | 一种介孔六铝酸盐负载镍基的甲烷化催化剂及其制备方法 |
Non-Patent Citations (5)
| Title |
|---|
| "Effect of nickel hexaaluminate mirror cation on structure-sensitive reactions during n-tetradecane partial oxidation";Todd H. Gardner et al.;《Applied Catalysis A:General》;20070206;第323卷;pages 1-8 * |
| "Steam reforming of methane over Ni-substituted Sr hexaaluminates";Marina V. Bukhiyarova et al.;《Catalysis for Sustainable Energy》;20120809;第1卷;pages11-21 * |
| "The partial oxidation of methane to syngas over the nickel-modified hexaaluminate catalysts BaNiyAl12-yO19-δ";Wenling Chu et al.;《Applied Catalysis A:General》;20020517;第235卷;pages 39-45页 * |
| "六铝酸盐SrNiAl11O19-δ催化二氧化碳重整甲烷制合成气反应研究";徐占林等;<化学研究与应用>;20000428;第12卷(第2期);第148-151页 * |
| Marina V. Bukhiyarova et al.."Steam reforming of methane over Ni-substituted Sr hexaaluminates".《Catalysis for Sustainable Energy》.2012,第1卷pages11-21. * |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2015142397A (ru) | 2017-04-17 |
| DE112014001125A5 (de) | 2015-11-19 |
| WO2014135642A1 (de) | 2014-09-12 |
| CN105050714A (zh) | 2015-11-11 |
| US9475037B2 (en) | 2016-10-25 |
| US20160008791A1 (en) | 2016-01-14 |
| JP2016510687A (ja) | 2016-04-11 |
| RU2662221C2 (ru) | 2018-07-25 |
| EP2964385A1 (de) | 2016-01-13 |
| KR20150129786A (ko) | 2015-11-20 |
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