DE112014001125A5 - Nickelhexaaluminathaltiger Katalysator zur Reformierung von Kohlenwasserstoffen in Gegenwart von Kohlendioxid - Google Patents

Nickelhexaaluminathaltiger Katalysator zur Reformierung von Kohlenwasserstoffen in Gegenwart von Kohlendioxid Download PDF

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Publication number
DE112014001125A5
DE112014001125A5 DE112014001125.8T DE112014001125T DE112014001125A5 DE 112014001125 A5 DE112014001125 A5 DE 112014001125A5 DE 112014001125 T DE112014001125 T DE 112014001125T DE 112014001125 A5 DE112014001125 A5 DE 112014001125A5
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Prior art keywords
carbon dioxide
containing catalyst
reforming hydrocarbons
hexaaluminate
nickel
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Withdrawn
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DE112014001125.8T
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English (en)
Inventor
Guido Wasserschaff
Bernd Hinrichs
Ulrich Flörchinger
Stephan A. Schunk
Dr. Schwab Ekkehard
Andrian Milanov
Thomas Roussiere
Dr. Cox Gerhard
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BASF SE
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BASF SE
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    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/755Nickel
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    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
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    • B01J23/83Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
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    • B01J35/391Physical properties of the active metal ingredient
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P20/50Improvements relating to the production of bulk chemicals
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
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  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
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  • Dispersion Chemistry (AREA)
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  • Hydrogen, Water And Hydrids (AREA)
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DE112014001125.8T 2013-03-07 2014-03-06 Nickelhexaaluminathaltiger Katalysator zur Reformierung von Kohlenwasserstoffen in Gegenwart von Kohlendioxid Withdrawn DE112014001125A5 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP13158074.8 2013-03-07
EP13158074 2013-03-07
EP13194345.8 2013-11-26
EP13194345 2013-11-26
PCT/EP2014/054362 WO2014135642A1 (de) 2013-03-07 2014-03-06 Nickelhexaaluminathaltiger katalysator zur reformierung von kohlenwasserstoffen in gegenwart von kohlendioxid

Publications (1)

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DE112014001125A5 true DE112014001125A5 (de) 2015-11-19

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DE112014001125.8T Withdrawn DE112014001125A5 (de) 2013-03-07 2014-03-06 Nickelhexaaluminathaltiger Katalysator zur Reformierung von Kohlenwasserstoffen in Gegenwart von Kohlendioxid

Country Status (8)

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US (1) US9475037B2 (de)
EP (1) EP2964385A1 (de)
JP (1) JP2016510687A (de)
KR (1) KR20150129786A (de)
CN (1) CN105050714B (de)
DE (1) DE112014001125A5 (de)
RU (1) RU2662221C2 (de)
WO (1) WO2014135642A1 (de)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9416087B2 (en) 2014-10-08 2016-08-16 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US9725393B2 (en) 2014-10-08 2017-08-08 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US10160711B2 (en) 2015-12-15 2018-12-25 Chevron Phillips Chemical Company Lp Formation of α,β-unsaturated carboxylic acids and salts thereof from metalalactones and anionic polyelectrolytes
US10544080B2 (en) 2017-06-14 2020-01-28 Chevron Phillips Chemical Company Lp Continuous process for the conversion of olefins and carbon dioxide to acrylates via solution phase reactor
US10550061B2 (en) 2017-06-14 2020-02-04 Chevron Phillips Chemical Company Lp Sulfur oxoacid-substituted and phosphorus oxoacid-substituted polyaromatic resins and salts thereof as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
US11174213B2 (en) 2018-10-12 2021-11-16 Chevron Phillips Chemical Company, Lp Effects of catalyst concentration and solid activator on nickel-mediated olefin/carbon dioxide coupling to acrylates

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2886514A1 (de) * 2013-12-20 2015-06-24 Basf Se Verfahren zur Reformierung von Gemischen aus Kohlenwasserstoffen und Kohlendioxid
BR112018000606B1 (pt) 2015-07-22 2022-01-18 Basf Se Processo para preparação de ácido furan-2,5- dicarboxílico e uso de um catalisador
CA3003762A1 (en) 2015-11-04 2017-05-11 Basf Se A process for preparing furan-2,5-dicarboxylic acid
BR112018008730A8 (pt) 2015-11-04 2019-02-26 Basf Se ?processo para preparar uma mistura e uso de um éster de ácido carboxílico?
CN118433934A (zh) 2017-08-11 2024-08-02 交互数字专利控股公司 多个接入网络之间的业务引导和切换
CN107673383A (zh) * 2017-09-06 2018-02-09 新地能源工程技术有限公司 六铝酸盐、包含其的载体及其制备方法和高温甲烷化催化剂
CN107597199A (zh) * 2017-09-13 2018-01-19 武汉凯迪工程技术研究总院有限公司 循环流化床烃重整催化剂及其制备方法和应用
CN109012144B (zh) * 2018-07-19 2021-03-30 中国科学院大学 六铝酸盐复合氧化物材料在h2s催化分解反应中的应用
JP7516396B2 (ja) * 2019-01-31 2024-07-16 ビーエーエスエフ ソシエタス・ヨーロピア 酸素、ランタン、アルミニウム及びコバルトを含む混合酸化物を含む成形物
CN115776916A (zh) * 2020-07-14 2023-03-10 巴斯夫公司 锶催化的勃姆石形成
WO2024003347A1 (en) 2022-07-01 2024-01-04 Basf Se Cobalt- and strontium-based catalyst for the conversion of hydrocarbons to synthesis gas
WO2024003354A1 (en) 2022-07-01 2024-01-04 Basf Se Cobalt-based catalyst for the conversion of hydrocarbons to synthesis gas

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2721837B1 (fr) * 1994-07-01 1996-08-30 Inst Francais Du Petrole Catalyseur d'oxydation resistant a des temperatures elevees, son procede de preparation et procede de combustion utilisant un tel catalyseur
DK1135327T3 (da) * 1999-10-01 2004-10-18 Bp Corp North America Inc Fremstilling af syntesegas under anvendelse af hydrotalcit-afledte nikkelkatalysatorer
GB0115850D0 (en) * 2001-06-28 2001-08-22 Isis Innovations Ltd Catalyst
US20040138317A1 (en) * 2002-11-11 2004-07-15 Conocophillips Company Supports for high surface area catalysts
US20050265920A1 (en) * 2002-11-11 2005-12-01 Conocophillips Company Supports and catalysts comprising rare earth aluminates, and their use in partial oxidation
JP4096096B2 (ja) * 2002-12-25 2008-06-04 独立行政法人産業技術総合研究所 ヘキサアルミネート多孔質セラミックス及びその製造方法
DE10322339A1 (de) * 2003-05-17 2004-12-02 Mtu Aero Engines Gmbh Einlaufbelag für Gasturbinen
US7309480B2 (en) * 2004-04-16 2007-12-18 H2Gen Innovations, Inc. Catalyst for hydrogen generation through steam reforming of hydrocarbons
DE102004025798A1 (de) * 2004-05-26 2005-12-22 Mtu Aero Engines Gmbh Wärmedämmschichtsystem
JP4976656B2 (ja) * 2005-03-07 2012-07-18 電気化学工業株式会社 触媒担体及びその製造方法
US8142756B1 (en) * 2006-03-28 2012-03-27 The United States Of America As Represented By The U.S. Department Of Energy Methods of reforming hydrocarbon fuels using hexaaluminate catalysts
US7736536B2 (en) * 2006-07-11 2010-06-15 Intematix Corporation Compositions comprising a mixture of a BAM phosphor and at least one other hexaaluminate
RU2366503C1 (ru) * 2008-04-14 2009-09-10 Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук Катализатор, способ его приготовления (варианты) и способ получения биотоплива
RU2388535C1 (ru) * 2009-04-15 2010-05-10 Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (статус государственного учреждения) Катализатор, способ его приготовления и способ окисления метана
EP2467454A4 (de) * 2009-08-21 2014-01-22 Univ Sherbrooke Dampfreformierung von kohlenwasserstoffbrennstoffen über einen ni-al-spinellkatalysator
CN102836718B (zh) * 2011-06-20 2014-06-04 中国科学院过程工程研究所 一种介孔六铝酸盐负载镍基的甲烷化催化剂及其制备方法
US9259712B2 (en) 2011-11-08 2016-02-16 Basf Se Process for producing a reforming catalyst and the reforming of methane
US8916491B2 (en) 2011-11-08 2014-12-23 Basf Se Process for producing a methanation catalyst and a process for the methanation of synthesis gas
US9566571B2 (en) * 2012-02-10 2017-02-14 Basf Se Hexaaluminate-comprising catalyst for the reforming of hydrocarbons and a reforming process
US20140001407A1 (en) 2012-06-29 2014-01-02 Basf Se High-pressure process for the carbon dioxide reforming of hydrocarbons in the presence of iridium-comprising active compositions
CN104918882B (zh) 2012-12-21 2019-03-01 巴斯夫欧洲公司 平行制备氢气、一氧化碳和含碳产物的方法

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US10926247B2 (en) 2017-06-14 2021-02-23 Chevron Phillips Chemical Company Lp Sulfur oxoacid-substituted and phosphorus oxoacid-substituted polyaromatic resins and salts thereof as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
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US11174213B2 (en) 2018-10-12 2021-11-16 Chevron Phillips Chemical Company, Lp Effects of catalyst concentration and solid activator on nickel-mediated olefin/carbon dioxide coupling to acrylates

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US20160008791A1 (en) 2016-01-14
RU2015142397A (ru) 2017-04-17
JP2016510687A (ja) 2016-04-11
KR20150129786A (ko) 2015-11-20
CN105050714B (zh) 2018-06-26
CN105050714A (zh) 2015-11-11
WO2014135642A1 (de) 2014-09-12

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