CN104918987B - 环氧树脂组合物、预浸料坯、纤维增强塑料材料和纤维增强塑料材料的制造方法 - Google Patents

环氧树脂组合物、预浸料坯、纤维增强塑料材料和纤维增强塑料材料的制造方法 Download PDF

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CN104918987B
CN104918987B CN201480004156.5A CN201480004156A CN104918987B CN 104918987 B CN104918987 B CN 104918987B CN 201480004156 A CN201480004156 A CN 201480004156A CN 104918987 B CN104918987 B CN 104918987B
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epoxy resin
prepreg
resin
composition epoxy
resin combination
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CN104918987A (zh
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J·C·休斯
坂田宏明
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Toray Industries Inc
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Toray Industries Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1477—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/3227—Compounds containing acyclic nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014—Nitrogen containing compounds
    • C08G59/4021—Ureas; Thioureas; Guanidines; Dicyandiamides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Reinforced Plastic Materials (AREA)
  • Epoxy Resins (AREA)
CN201480004156.5A 2013-01-07 2014-01-07 环氧树脂组合物、预浸料坯、纤维增强塑料材料和纤维增强塑料材料的制造方法 Expired - Fee Related CN104918987B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201361749703P 2013-01-07 2013-01-07
US61/749,703 2013-01-07
US201361911386P 2013-12-03 2013-12-03
US61/911,386 2013-12-03
PCT/US2014/010497 WO2014107725A1 (en) 2013-01-07 2014-01-07 Epoxy resin composition, prepreg, fiber reinforced plastic material, and manufacturing method for fiber reinforced plastic material

Publications (2)

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CN104918987A CN104918987A (zh) 2015-09-16
CN104918987B true CN104918987B (zh) 2018-11-06

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Country Link
US (1) US9982086B2 (https=)
EP (1) EP2941452B1 (https=)
JP (1) JP6394610B2 (https=)
KR (1) KR102102191B1 (https=)
CN (1) CN104918987B (https=)
TW (1) TWI621639B (https=)
WO (1) WO2014107725A1 (https=)

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JP6612498B2 (ja) * 2014-11-21 2019-11-27 スリーエム イノベイティブ プロパティズ カンパニー エポキシ接着剤、並びに自動車用部材及びその製造方法
JP6658747B2 (ja) * 2014-12-02 2020-03-04 東レ株式会社 エポキシ樹脂組成物、プリプレグ、繊維強化プラスチック材料および繊維強化プラスチック材料の製造方法
US10344117B2 (en) * 2015-02-09 2019-07-09 Toray Industries, Inc. Epoxy resin composition, prepreg, and fiber reinforced composite material
US10327429B2 (en) 2015-06-02 2019-06-25 G-Rods International Llc Incorporation of graphene in various components and method of manufacturing
US10064400B2 (en) 2015-06-02 2018-09-04 G-Rods International Llc Fishing rod with graphene and method of manufacturing
KR20180048454A (ko) * 2015-09-03 2018-05-10 도레이 카부시키가이샤 에폭시 수지 조성물, 프리프레그 및 탄소섬유 강화 복합 재료
JP6938897B2 (ja) * 2015-12-10 2021-09-22 三菱ケミカル株式会社 内圧成形用プリプレグ、及び繊維強化複合材料の製造方法
WO2017222339A1 (ko) * 2016-06-24 2017-12-28 에스케이케미칼주식회사 섬유강화 복합재료용 에폭시 수지 조성물 및 이를 이용한 프리프레그
CN109312057B (zh) * 2016-06-24 2021-09-03 Sk化学株式会社 用于纤维增强复合材料的环氧树脂组合物及利用它的预浸料
CN105949962B (zh) * 2016-07-18 2019-01-04 郑州四维特种材料有限责任公司 一种自发光环氧树脂液及其制备方法，自发光环氧树脂复合材料，自发光碳纤维预浸料
KR102428285B1 (ko) * 2016-09-13 2022-08-08 주식회사 테크위드 자전거 림을 위한 고온 수지 조성물 및 이를 이용한 자전거 림
CN106626617B (zh) * 2016-09-14 2018-12-18 四川东材科技集团股份有限公司 一种玻璃纤维毡层压板及其制备方法
KR20180035990A (ko) * 2016-09-29 2018-04-09 현대자동차주식회사 복층 프리프레그 구조 및 그 제조방법
CN110114385B (zh) 2016-12-27 2022-03-01 日铁化学材料株式会社 固化性环氧树脂组合物和使用其的纤维强化复合材料
JP6928908B2 (ja) * 2017-04-07 2021-09-01 パナソニックＩｐマネジメント株式会社 プリプレグ、金属張積層板、プリント配線板及びフレックスリジッドプリント配線板
JP6573029B2 (ja) * 2017-05-10 2019-09-11 東レ株式会社 繊維強化複合材料の製造方法
JP2020524187A (ja) * 2017-06-20 2020-08-13 ダウ グローバル テクノロジーズ エルエルシー 繊維強化複合材を製造するためのエポキシ樹脂系
KR102341161B1 (ko) * 2017-08-10 2021-12-20 도레이첨단소재 주식회사 저밀도 프리프레그 및 이를 포함하는 샌드위치 복합 성형품
WO2019065470A1 (ja) 2017-09-29 2019-04-04 日鉄ケミカル＆マテリアル株式会社 硬化性エポキシ樹脂組成物、及びそれを用いた繊維強化複合材料
CN111868149A (zh) * 2018-03-01 2020-10-30 塞特工业公司 具有一致处理特征的快速固化树脂配制品
JP7092263B2 (ja) * 2019-05-28 2022-06-28 Dic株式会社 成形材料、シートモールディングコンパウンド、及び成形品
CN111073219A (zh) * 2019-12-31 2020-04-28 达森(天津)材料科技有限公司 海绵城市建设高强度抗黄变抗冻融环氧树脂的制备方法
CN112250999A (zh) * 2020-10-21 2021-01-22 广德龙泰电子科技有限公司 一种耐热性环氧树脂组合物、无卤中Tg覆铜板及其制备方法
JPWO2023053834A1 (https=) * 2021-09-29 2023-04-06
CN116178894A (zh) * 2023-02-03 2023-05-30 安徽恒泰新材料科技股份有限公司 一种环氧树脂复合材料及其处理装置

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JP2016504472A (ja) 2016-02-12
TW201430007A (zh) 2014-08-01
JP6394610B2 (ja) 2018-09-26
EP2941452B1 (en) 2018-12-26
US20160002390A1 (en) 2016-01-07
US9982086B2 (en) 2018-05-29
KR20150104120A (ko) 2015-09-14
WO2014107725A1 (en) 2014-07-10
CN104918987A (zh) 2015-09-16
EP2941452A1 (en) 2015-11-11
WO2014107725A9 (en) 2014-09-18
TWI621639B (zh) 2018-04-21
KR102102191B1 (ko) 2020-04-21
EP2941452A4 (en) 2016-08-10

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