CN104736239B - 用于获得高级醇的方法 - Google Patents

用于获得高级醇的方法 Download PDF

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Publication number
CN104736239B
CN104736239B CN201380034303.9A CN201380034303A CN104736239B CN 104736239 B CN104736239 B CN 104736239B CN 201380034303 A CN201380034303 A CN 201380034303A CN 104736239 B CN104736239 B CN 104736239B
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catalyst
reagent
ethanol
butanol
hydrotalcite
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CN201380034303.9A
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Chinese (zh)
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CN104736239A (zh
Inventor
R·阿尔霍纳安托林
J·L·桑斯阿格
A·科尔曼卡诺斯
M·E·多米内
F·维达尔巴雷罗
F·A·莱德仑德格瓦拉维达尔
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Carterix Corp
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A Wengeya Bioenergy Technew SA
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6562—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/896—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • C07C29/34—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
CN201380034303.9A 2012-06-29 2013-07-01 用于获得高级醇的方法 Active CN104736239B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12382261.1 2012-06-29
EP12382261.1A EP2679304A1 (en) 2012-06-29 2012-06-29 Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide
PCT/ES2013/070448 WO2014001597A1 (es) 2012-06-29 2013-07-01 Procedimiento de obtención de alcoholes superiores

Publications (2)

Publication Number Publication Date
CN104736239A CN104736239A (zh) 2015-06-24
CN104736239B true CN104736239B (zh) 2018-06-08

Family

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CN201380034303.9A Active CN104736239B (zh) 2012-06-29 2013-07-01 用于获得高级醇的方法

Country Status (13)

Country Link
US (1) US9475741B2 (enExample)
EP (2) EP2679304A1 (enExample)
KR (1) KR102100714B1 (enExample)
CN (1) CN104736239B (enExample)
BR (1) BR112014032466B1 (enExample)
CA (1) CA2877974C (enExample)
ES (1) ES2545132T3 (enExample)
HU (1) HUE025461T2 (enExample)
IN (1) IN2014MN02648A (enExample)
MX (1) MX346356B (enExample)
RU (1) RU2014152879A (enExample)
WO (1) WO2014001597A1 (enExample)
ZA (1) ZA201409539B (enExample)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2679304A1 (en) 2012-06-29 2014-01-01 Abengoa Bioenergía Nuevas Tecnologías, S. A. Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide
EP3048090B1 (en) * 2013-09-17 2022-03-30 LG Chem, Ltd. Method for preparing alkanol
ES2732019T3 (es) 2013-12-27 2019-11-20 Abengoa Bioenergia Nuevas Tecnologias Sa Proceso para la preparación de alcoholes superiores a partir de alcoholes inferiores por condensación de Guerbet
CN104892362A (zh) * 2014-03-04 2015-09-09 中国科学院大连化学物理研究所 一种催化转化甲醇制备丁醇的方法
CN104892361A (zh) * 2014-03-04 2015-09-09 中国科学院大连化学物理研究所 一种催化转化甲醇制备丙醇的方法
US10118880B2 (en) 2014-11-14 2018-11-06 Abengoa Bioenergia Nuevas Tecnologies, S.A. Process for the preparation of higher alcohols from ethanol and N-hexanol by guerbet condensation
ES2570227B1 (es) * 2014-11-14 2017-04-19 Abengoa Bioenergia Nuevas Tecnologias, S.A. Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet
ES2570231B1 (es) * 2014-11-14 2017-04-19 Abengoa Bioenergia Nuevas Tecnologias, S.A. Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet
ES2570233B1 (es) 2014-11-14 2017-02-22 Abengoa Bioenergía Nuevas Tecnologías, S.A. Procedimiento de obtención de 1-octanol
WO2017031439A1 (en) * 2015-08-19 2017-02-23 Greenyug, Llc Composition of catalysts for converion of ethanol to n-butanol and higher alcohols
ES2647963B1 (es) 2016-05-26 2018-10-03 Abengoa Bioenergía Nuevas Tecnologías, S.A. Procedimiento de obtención de 1-octanol
CN108686671A (zh) * 2018-06-11 2018-10-23 福州大学 一种低温甲醇分解催化剂的制备
CN109529897B (zh) * 2018-12-04 2020-07-31 西南化工研究设计院有限公司 一种生产正丁醇的钯镓双金属催化剂及其制备方法及应用
CN111715252B (zh) * 2019-03-21 2022-03-25 北京大学 一种催化合成有机化合物的方法及其催化剂和应用
US12466778B2 (en) * 2020-09-14 2025-11-11 Uop Llc Catalysts for isobutanol synthesis from syngas and ethanol or propanol
CN113019404B (zh) * 2021-03-23 2022-02-18 中国科学院兰州化学物理研究所 用于合成高碳醇的镍基催化剂及其制备方法与应用
CN114588904B (zh) * 2022-03-08 2024-11-26 中国科学院青岛生物能源与过程研究所 Cu基金属氧化物催化剂、其制备方法以及采用其的2,3-丁二醇的合成方法
CN115445630B (zh) * 2022-08-30 2023-11-17 广东工业大学 一种聚丙烯基锡掺杂碳包镍催化剂及其制备方法和应用
CN118059885B (zh) * 2024-01-30 2024-09-27 南京工业大学 一种负载金多相催化剂及其制备方法和应用

Citations (3)

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Publication number Priority date Publication date Assignee Title
WO2009097312A1 (en) * 2008-01-28 2009-08-06 E.I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate
WO2009097310A1 (en) * 2008-01-28 2009-08-06 E. I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite containing the anion of ethylenediaminetetraacetic acid
US20100160693A1 (en) * 2008-12-22 2010-06-24 E.I. Du Pont De Nemours And Company Process for producing guerbet alcohols using water tolerant basic catalysts

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US5300695A (en) 1992-12-07 1994-04-05 Amoco Corporation Process for preparing alcohols
US5387570A (en) 1993-05-07 1995-02-07 Exxon Research & Engineering Co. Catalysts for iso-alcohol synthesis from CO + H2
NO312126B1 (no) * 1998-12-23 2002-03-25 Norske Stats Oljeselskap Forbedret fremgangsmåte for fremstilling av katalysatorer bestående av metaller på hydrotalcitt-baserte b¶rermaterialer
WO2006059729A1 (ja) 2004-12-03 2006-06-08 Kabushiki Kaisha Sangi 高分子アルコールの合成法
WO2009026510A1 (en) 2007-08-22 2009-02-26 E. I. Du Pont De Nemours And Company Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite catalyst
US7700811B2 (en) 2007-08-22 2010-04-20 E.I. Du Pont De Namours And Company Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate
EP2679304A1 (en) 2012-06-29 2014-01-01 Abengoa Bioenergía Nuevas Tecnologías, S. A. Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide
US20140179958A1 (en) * 2012-12-20 2014-06-26 Celanese International Corporation Catalysts and processes for producing butanol

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009097312A1 (en) * 2008-01-28 2009-08-06 E.I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate
WO2009097310A1 (en) * 2008-01-28 2009-08-06 E. I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite containing the anion of ethylenediaminetetraacetic acid
US20100160693A1 (en) * 2008-12-22 2010-06-24 E.I. Du Pont De Nemours And Company Process for producing guerbet alcohols using water tolerant basic catalysts

Also Published As

Publication number Publication date
BR112014032466B1 (pt) 2021-11-30
RU2014152879A (ru) 2016-08-20
KR102100714B1 (ko) 2020-04-16
CN104736239A (zh) 2015-06-24
ZA201409539B (en) 2015-11-25
EP2767336B1 (en) 2015-07-01
EP2679304A1 (en) 2014-01-01
BR112014032466A2 (pt) 2017-08-01
CA2877974C (en) 2021-06-22
MX346356B (es) 2017-03-15
MX2015000224A (es) 2015-10-09
WO2014001597A1 (es) 2014-01-03
HUE025461T2 (en) 2016-02-29
US9475741B2 (en) 2016-10-25
EP2767336A1 (en) 2014-08-20
IN2014MN02648A (enExample) 2015-08-21
ES2545132T3 (es) 2015-09-08
US20150166443A1 (en) 2015-06-18
KR20150088235A (ko) 2015-07-31
CA2877974A1 (en) 2014-01-03

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