RU2014152879A - Способ получения высших спиртов - Google Patents
Способ получения высших спиртов Download PDFInfo
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- RU2014152879A RU2014152879A RU2014152879A RU2014152879A RU2014152879A RU 2014152879 A RU2014152879 A RU 2014152879A RU 2014152879 A RU2014152879 A RU 2014152879A RU 2014152879 A RU2014152879 A RU 2014152879A RU 2014152879 A RU2014152879 A RU 2014152879A
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- 150000001298 alcohols Chemical class 0.000 title claims abstract 5
- 238000004519 manufacturing process Methods 0.000 title claims abstract 3
- 238000000034 method Methods 0.000 claims abstract 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract 9
- 239000003054 catalyst Substances 0.000 claims abstract 9
- 229910052751 metal Inorganic materials 0.000 claims abstract 9
- 239000002184 metal Substances 0.000 claims abstract 9
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract 7
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract 7
- 150000004706 metal oxides Chemical class 0.000 claims abstract 7
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical group [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims abstract 6
- 229960001545 hydrotalcite Drugs 0.000 claims abstract 6
- 229910001701 hydrotalcite Inorganic materials 0.000 claims abstract 6
- 150000001875 compounds Chemical class 0.000 claims abstract 5
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims abstract 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract 4
- 238000000975 co-precipitation Methods 0.000 claims abstract 4
- 229910052742 iron Inorganic materials 0.000 claims abstract 4
- 229910052748 manganese Inorganic materials 0.000 claims abstract 4
- 229910052759 nickel Inorganic materials 0.000 claims abstract 4
- 229910000510 noble metal Inorganic materials 0.000 claims abstract 4
- AREPHAPHABGCQP-UHFFFAOYSA-N 1-(dimethylamino)-3-[2-[2-(4-methoxyphenyl)ethyl]phenoxy]propan-2-ol Chemical compound C1=CC(OC)=CC=C1CCC1=CC=CC=C1OCC(O)CN(C)C AREPHAPHABGCQP-UHFFFAOYSA-N 0.000 claims abstract 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims abstract 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract 3
- 150000001450 anions Chemical class 0.000 claims abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract 3
- 238000005979 thermal decomposition reaction Methods 0.000 claims abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910002651 NO3 Inorganic materials 0.000 claims abstract 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910019142 PO4 Inorganic materials 0.000 claims abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract 2
- 150000004703 alkoxides Chemical class 0.000 claims abstract 2
- 229910052782 aluminium Inorganic materials 0.000 claims abstract 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052791 calcium Inorganic materials 0.000 claims abstract 2
- 229910052804 chromium Inorganic materials 0.000 claims abstract 2
- 229910052802 copper Inorganic materials 0.000 claims abstract 2
- YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 claims abstract 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims abstract 2
- UETZVSHORCDDTH-UHFFFAOYSA-N iron(2+);hexacyanide Chemical compound [Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] UETZVSHORCDDTH-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract 2
- 229910052749 magnesium Inorganic materials 0.000 claims abstract 2
- 150000002736 metal compounds Chemical class 0.000 claims abstract 2
- 150000002739 metals Chemical class 0.000 claims abstract 2
- 229910052763 palladium Inorganic materials 0.000 claims abstract 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims abstract 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 claims abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract 2
- 239000010452 phosphate Substances 0.000 claims abstract 2
- 229910052697 platinum Inorganic materials 0.000 claims abstract 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052702 rhenium Inorganic materials 0.000 claims abstract 2
- 229910052703 rhodium Inorganic materials 0.000 claims abstract 2
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims abstract 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052725 zinc Inorganic materials 0.000 claims abstract 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 claims 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 6
- 239000013067 intermediate product Substances 0.000 claims 4
- 239000000376 reactant Substances 0.000 claims 4
- 238000001354 calcination Methods 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 229910052757 nitrogen Inorganic materials 0.000 claims 3
- 239000000243 solution Substances 0.000 claims 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 238000005470 impregnation Methods 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- 229910052786 argon Inorganic materials 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 230000018044 dehydration Effects 0.000 claims 1
- 238000006297 dehydration reaction Methods 0.000 claims 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 238000011084 recovery Methods 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/007—Mixed salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6562—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/896—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with gallium, indium or thallium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J25/00—Catalysts of the Raney type
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
- C07C29/34—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12382261.1 | 2012-06-29 | ||
| EP12382261.1A EP2679304A1 (en) | 2012-06-29 | 2012-06-29 | Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide |
| PCT/ES2013/070448 WO2014001597A1 (es) | 2012-06-29 | 2013-07-01 | Procedimiento de obtención de alcoholes superiores |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2014152879A true RU2014152879A (ru) | 2016-08-20 |
Family
ID=49111231
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2014152879A RU2014152879A (ru) | 2012-06-29 | 2013-07-01 | Способ получения высших спиртов |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9475741B2 (enExample) |
| EP (2) | EP2679304A1 (enExample) |
| KR (1) | KR102100714B1 (enExample) |
| CN (1) | CN104736239B (enExample) |
| BR (1) | BR112014032466B1 (enExample) |
| CA (1) | CA2877974C (enExample) |
| ES (1) | ES2545132T3 (enExample) |
| HU (1) | HUE025461T2 (enExample) |
| IN (1) | IN2014MN02648A (enExample) |
| MX (1) | MX346356B (enExample) |
| RU (1) | RU2014152879A (enExample) |
| WO (1) | WO2014001597A1 (enExample) |
| ZA (1) | ZA201409539B (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2679304A1 (en) | 2012-06-29 | 2014-01-01 | Abengoa Bioenergía Nuevas Tecnologías, S. A. | Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide |
| EP3048090B1 (en) * | 2013-09-17 | 2022-03-30 | LG Chem, Ltd. | Method for preparing alkanol |
| ES2732019T3 (es) | 2013-12-27 | 2019-11-20 | Abengoa Bioenergia Nuevas Tecnologias Sa | Proceso para la preparación de alcoholes superiores a partir de alcoholes inferiores por condensación de Guerbet |
| CN104892362A (zh) * | 2014-03-04 | 2015-09-09 | 中国科学院大连化学物理研究所 | 一种催化转化甲醇制备丁醇的方法 |
| CN104892361A (zh) * | 2014-03-04 | 2015-09-09 | 中国科学院大连化学物理研究所 | 一种催化转化甲醇制备丙醇的方法 |
| US10118880B2 (en) | 2014-11-14 | 2018-11-06 | Abengoa Bioenergia Nuevas Tecnologies, S.A. | Process for the preparation of higher alcohols from ethanol and N-hexanol by guerbet condensation |
| ES2570227B1 (es) * | 2014-11-14 | 2017-04-19 | Abengoa Bioenergia Nuevas Tecnologias, S.A. | Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet |
| ES2570231B1 (es) * | 2014-11-14 | 2017-04-19 | Abengoa Bioenergia Nuevas Tecnologias, S.A. | Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet |
| ES2570233B1 (es) | 2014-11-14 | 2017-02-22 | Abengoa Bioenergía Nuevas Tecnologías, S.A. | Procedimiento de obtención de 1-octanol |
| WO2017031439A1 (en) * | 2015-08-19 | 2017-02-23 | Greenyug, Llc | Composition of catalysts for converion of ethanol to n-butanol and higher alcohols |
| ES2647963B1 (es) | 2016-05-26 | 2018-10-03 | Abengoa Bioenergía Nuevas Tecnologías, S.A. | Procedimiento de obtención de 1-octanol |
| CN108686671A (zh) * | 2018-06-11 | 2018-10-23 | 福州大学 | 一种低温甲醇分解催化剂的制备 |
| CN109529897B (zh) * | 2018-12-04 | 2020-07-31 | 西南化工研究设计院有限公司 | 一种生产正丁醇的钯镓双金属催化剂及其制备方法及应用 |
| CN111715252B (zh) * | 2019-03-21 | 2022-03-25 | 北京大学 | 一种催化合成有机化合物的方法及其催化剂和应用 |
| US12466778B2 (en) * | 2020-09-14 | 2025-11-11 | Uop Llc | Catalysts for isobutanol synthesis from syngas and ethanol or propanol |
| CN113019404B (zh) * | 2021-03-23 | 2022-02-18 | 中国科学院兰州化学物理研究所 | 用于合成高碳醇的镍基催化剂及其制备方法与应用 |
| CN114588904B (zh) * | 2022-03-08 | 2024-11-26 | 中国科学院青岛生物能源与过程研究所 | Cu基金属氧化物催化剂、其制备方法以及采用其的2,3-丁二醇的合成方法 |
| CN115445630B (zh) * | 2022-08-30 | 2023-11-17 | 广东工业大学 | 一种聚丙烯基锡掺杂碳包镍催化剂及其制备方法和应用 |
| CN118059885B (zh) * | 2024-01-30 | 2024-09-27 | 南京工业大学 | 一种负载金多相催化剂及其制备方法和应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5300695A (en) | 1992-12-07 | 1994-04-05 | Amoco Corporation | Process for preparing alcohols |
| US5387570A (en) | 1993-05-07 | 1995-02-07 | Exxon Research & Engineering Co. | Catalysts for iso-alcohol synthesis from CO + H2 |
| NO312126B1 (no) * | 1998-12-23 | 2002-03-25 | Norske Stats Oljeselskap | Forbedret fremgangsmåte for fremstilling av katalysatorer bestående av metaller på hydrotalcitt-baserte b¶rermaterialer |
| WO2006059729A1 (ja) | 2004-12-03 | 2006-06-08 | Kabushiki Kaisha Sangi | 高分子アルコールの合成法 |
| WO2009026510A1 (en) | 2007-08-22 | 2009-02-26 | E. I. Du Pont De Nemours And Company | Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite catalyst |
| US7700811B2 (en) | 2007-08-22 | 2010-04-20 | E.I. Du Pont De Namours And Company | Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate |
| WO2009097310A1 (en) | 2008-01-28 | 2009-08-06 | E. I. Du Pont De Nemours And Company | Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite containing the anion of ethylenediaminetetraacetic acid |
| US8071823B2 (en) | 2008-01-28 | 2011-12-06 | E.I. Du Pont De Nemours And Company | Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate |
| US8318989B2 (en) | 2008-12-22 | 2012-11-27 | E I Du Pont De Nemours And Company | Process for producing guerbet alcohols using water tolerant basic catalysts |
| EP2679304A1 (en) | 2012-06-29 | 2014-01-01 | Abengoa Bioenergía Nuevas Tecnologías, S. A. | Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide |
| US20140179958A1 (en) * | 2012-12-20 | 2014-06-26 | Celanese International Corporation | Catalysts and processes for producing butanol |
-
2012
- 2012-06-29 EP EP12382261.1A patent/EP2679304A1/en not_active Withdrawn
-
2013
- 2013-07-01 HU HUE13756520A patent/HUE025461T2/en unknown
- 2013-07-01 US US14/411,752 patent/US9475741B2/en active Active
- 2013-07-01 WO PCT/ES2013/070448 patent/WO2014001597A1/es not_active Ceased
- 2013-07-01 CA CA2877974A patent/CA2877974C/en active Active
- 2013-07-01 EP EP13756520.6A patent/EP2767336B1/en active Active
- 2013-07-01 IN IN2648MUN2014 patent/IN2014MN02648A/en unknown
- 2013-07-01 BR BR112014032466-2A patent/BR112014032466B1/pt active IP Right Grant
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- 2013-07-01 RU RU2014152879A patent/RU2014152879A/ru unknown
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- 2013-07-01 KR KR1020157002188A patent/KR102100714B1/ko active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| BR112014032466B1 (pt) | 2021-11-30 |
| KR102100714B1 (ko) | 2020-04-16 |
| CN104736239A (zh) | 2015-06-24 |
| ZA201409539B (en) | 2015-11-25 |
| CN104736239B (zh) | 2018-06-08 |
| EP2767336B1 (en) | 2015-07-01 |
| EP2679304A1 (en) | 2014-01-01 |
| BR112014032466A2 (pt) | 2017-08-01 |
| CA2877974C (en) | 2021-06-22 |
| MX346356B (es) | 2017-03-15 |
| MX2015000224A (es) | 2015-10-09 |
| WO2014001597A1 (es) | 2014-01-03 |
| HUE025461T2 (en) | 2016-02-29 |
| US9475741B2 (en) | 2016-10-25 |
| EP2767336A1 (en) | 2014-08-20 |
| IN2014MN02648A (enExample) | 2015-08-21 |
| ES2545132T3 (es) | 2015-09-08 |
| US20150166443A1 (en) | 2015-06-18 |
| KR20150088235A (ko) | 2015-07-31 |
| CA2877974A1 (en) | 2014-01-03 |
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