CN104449713B - 一种非稀土掺杂黄色荧光体及其制作方法和应用 - Google Patents
一种非稀土掺杂黄色荧光体及其制作方法和应用 Download PDFInfo
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- CN104449713B CN104449713B CN201410609988.1A CN201410609988A CN104449713B CN 104449713 B CN104449713 B CN 104449713B CN 201410609988 A CN201410609988 A CN 201410609988A CN 104449713 B CN104449713 B CN 104449713B
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- earth
- yellow fluorophor
- powder
- doped
- doped yellow
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- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000010949 copper Substances 0.000 claims abstract description 32
- 239000000843 powder Substances 0.000 claims abstract description 26
- 239000000126 substance Substances 0.000 claims abstract description 11
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000012190 activator Substances 0.000 claims abstract description 5
- 229910052802 copper Inorganic materials 0.000 claims abstract description 5
- 229910001431 copper ion Inorganic materials 0.000 claims abstract description 5
- 230000005284 excitation Effects 0.000 claims abstract description 5
- 239000011159 matrix material Substances 0.000 claims abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000011343 solid material Substances 0.000 claims description 12
- 206010013786 Dry skin Diseases 0.000 claims description 6
- 101100513612 Microdochium nivale MnCO gene Proteins 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000001354 calcination Methods 0.000 claims description 6
- 229910052593 corundum Inorganic materials 0.000 claims description 6
- 239000010431 corundum Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 239000004570 mortar (masonry) Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 20
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 18
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 3
- -1 rare earth ion Chemical class 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000007858 starting material Substances 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 28
- 150000002910 rare earth metals Chemical class 0.000 description 16
- MPDDQFGQTCEFIX-UHFFFAOYSA-N [F].[Ca] Chemical compound [F].[Ca] MPDDQFGQTCEFIX-UHFFFAOYSA-N 0.000 description 14
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 14
- 239000011575 calcium Substances 0.000 description 8
- 238000001228 spectrum Methods 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 238000000695 excitation spectrum Methods 0.000 description 5
- BFWVMUCQKQYLLG-UHFFFAOYSA-K [F].P(=O)([O-])([O-])[O-].[Ca+2].[Ca+2].[Ca+2].[Ca+2] Chemical compound [F].P(=O)([O-])([O-])[O-].[Ca+2].[Ca+2].[Ca+2].[Ca+2] BFWVMUCQKQYLLG-UHFFFAOYSA-K 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000004913 activation Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- GBNXLQPMFAUCOI-UHFFFAOYSA-H tetracalcium;oxygen(2-);diphosphate Chemical group [O-2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GBNXLQPMFAUCOI-UHFFFAOYSA-H 0.000 description 2
- 238000010953 Ames test Methods 0.000 description 1
- 231100000039 Ames test Toxicity 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910019990 cerium-doped yttrium aluminum garnet Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000003745 diagnosis Methods 0.000 description 1
- 238000002059 diagnostic imaging Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B20/00—Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
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- Luminescent Compositions (AREA)
Abstract
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CN201410609988.1A CN104449713B (zh) | 2014-11-03 | 2014-11-03 | 一种非稀土掺杂黄色荧光体及其制作方法和应用 |
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CN201410609988.1A CN104449713B (zh) | 2014-11-03 | 2014-11-03 | 一种非稀土掺杂黄色荧光体及其制作方法和应用 |
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CN104449713A CN104449713A (zh) | 2015-03-25 |
CN104449713B true CN104449713B (zh) | 2016-04-20 |
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CN201410609988.1A Expired - Fee Related CN104449713B (zh) | 2014-11-03 | 2014-11-03 | 一种非稀土掺杂黄色荧光体及其制作方法和应用 |
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Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104927854B (zh) * | 2015-07-02 | 2019-01-11 | 华北电力大学(保定) | 一种非稀土离子激活的黄色荧光粉及其制备方法 |
CN105038788B (zh) * | 2015-07-02 | 2019-01-15 | 华北电力大学(保定) | 一种非稀土离子激活的发黄绿光的荧光粉及其制备方法 |
WO2017038712A1 (ja) * | 2015-08-28 | 2017-03-09 | 宇部興産株式会社 | 蛍光体及びその製造方法並びに生体イメージング方法 |
CN105199720A (zh) * | 2015-09-21 | 2015-12-30 | 安徽科发信息科技有限公司 | 一种应用于led的荧光材料制备方法 |
CN109437561B (zh) * | 2018-10-23 | 2021-09-03 | 广东工业大学 | 一种荧光玻璃材料及其制备方法、灯罩和灯具 |
CN111154487B (zh) * | 2020-01-19 | 2022-11-08 | 齐鲁工业大学 | 一种铜掺杂的硼/磷/锶/钙荧光粉及其制备方法 |
CN116200195A (zh) * | 2023-01-06 | 2023-06-02 | 齐鲁工业大学(山东省科学院) | Cu,Eu掺杂的荧光粉及其制备方法和应用 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102074644A (zh) * | 2010-11-09 | 2011-05-25 | 四川新力光源有限公司 | 交流led白光发光装置 |
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JPS59171545A (ja) * | 1983-03-18 | 1984-09-28 | 株式会社 吉田製作所 | リン酸カルシウム複合剤 |
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Patent Citations (1)
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CN102074644A (zh) * | 2010-11-09 | 2011-05-25 | 四川新力光源有限公司 | 交流led白光发光装置 |
Non-Patent Citations (3)
Title |
---|
"A Single-Phase Emission-Tunable Ca5(PO4)3F:Eu2+,Mn2+ Phosphor with Efficient Energy Transfer for White LEDs";W. Tang et al.,;《Eur. J. Inorg. Chem.》;20140617;第2014卷(第21期);第3387-3392页 * |
"Ca4(PO4)2O:Eu2+ red-emitting phosphor for solid-state lighting: structure, luminescent properties and white light emitting diode application";D. Deng et al.,;《J. Mater. Chem. C》;20130319;第1卷(第19期);第3194-3199页 * |
"Microstructural investigation into calcium phosphate biomaterials by spatially resolved cathodoluminescence";J. Gotze et al.,;《Mat.-wiss.u.Werkstofftech.》;20011231;第32卷(第2期);第130-136页 * |
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