CN104364010B - 由1,6-己二醇生产己二酸的方法 - Google Patents

由1,6-己二醇生产己二酸的方法 Download PDF

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Publication number
CN104364010B
CN104364010B CN201380030851.4A CN201380030851A CN104364010B CN 104364010 B CN104364010 B CN 104364010B CN 201380030851 A CN201380030851 A CN 201380030851A CN 104364010 B CN104364010 B CN 104364010B
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Prior art keywords
hexanediol
oxygen
heterogeneous catalyst
catalyst
adipic acid
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Chinese (zh)
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CN104364010A (zh
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E·L·迪亚斯
V·J·墨菲
J·A·W·舒梅克
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Archer Daniels Midland Co
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Archer Daniels Midland Co
Rennovia Inc
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201380030851.4A 2012-06-11 2013-06-11 由1,6-己二醇生产己二酸的方法 Active CN104364010B (zh)

Priority Applications (1)

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CN202010014532.6A CN111454144B (zh) 2012-06-11 2013-06-11 由1,6-己二醇生产己二酸的方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261658364P 2012-06-11 2012-06-11
US61/658,364 2012-06-11
PCT/US2013/045096 WO2013188348A2 (en) 2012-06-11 2013-06-11 Process for production of adipic acid from 1,6-hexanediol

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CN104364010B true CN104364010B (zh) 2020-02-11

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US (3) US9035094B2 (enExample)
EP (2) EP3363537B1 (enExample)
JP (1) JP6209603B2 (enExample)
KR (1) KR20150018877A (enExample)
CN (2) CN104364010B (enExample)
AR (1) AR091409A1 (enExample)
AU (1) AU2013274530B2 (enExample)
BR (1) BR112014030857B1 (enExample)
CA (1) CA2876153A1 (enExample)
EA (1) EA201492252A1 (enExample)
HK (1) HK1210087A1 (enExample)
MX (1) MX2014015180A (enExample)
SA (1) SA113340632B1 (enExample)
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WO (1) WO2013188348A2 (enExample)

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Publication number Priority date Publication date Assignee Title
CN104066710B (zh) 2012-01-18 2016-06-29 莱诺维亚公司 从5-羟甲基糠醛产生六亚甲基二胺的方法
WO2013126250A1 (en) 2012-02-23 2013-08-29 Rennovia, Inc. Production of caprolactam from adipic acid
KR20150018877A (ko) 2012-06-11 2015-02-24 레노비아 인코포레이티드 1,6-헥산디올로부터 아디프산의 제조방법
US8986637B2 (en) * 2012-11-30 2015-03-24 Johnson Matthey Public Limited Company Bimetallic catalyst
TW201636096A (zh) 2014-12-02 2016-10-16 瑞諾維亞公司 自５－羥甲基糠醛產生己三醇之方法
EP3402787A4 (en) 2016-01-13 2019-11-27 Stora Enso Oyj PROCESS FOR THE PREPARATION OF 2,5-FURANDIC ACETIC ACID AND INTERMEDIATES AND DERIVATIVES THEREOF
SG11201913469PA (en) 2017-07-12 2020-01-30 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products
JP7158953B2 (ja) * 2017-08-18 2022-10-24 中国石油化工股▲ふん▼有限公司 重質芳香族炭化水素から軽質芳香族炭化水素を製造するための触媒、その製造方法及び適用
WO2019047113A1 (en) * 2017-09-07 2019-03-14 Rhodia Operations PROCESS FOR OXIDATION OF ALCOHOLS
CN116726913A (zh) * 2023-02-01 2023-09-12 北京化工大学 一种用于生物质甘油氧化制备甘油酸的高效催化剂的制备方法及其应用

Citations (5)

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US3739020A (en) * 1969-05-13 1973-06-12 Nat Distillers Chem Corp Preparation of carboxylic acids
DE2407146A1 (de) * 1974-02-15 1975-09-04 Erdoelchemie Gmbh Verfahren zur herstellung von dicarbonsaeuren
CN1454201A (zh) * 2000-08-18 2003-11-05 纳幕尔杜邦公司 选择性氧化用金催化剂
WO2011155964A1 (en) * 2010-06-11 2011-12-15 Rennovia, Inc. Catalyst comprising platinum and gold nano - particles and its use for oxidation of glucose and preparation method of such a catalyst
WO2012018739A1 (en) * 2010-08-02 2012-02-09 Battelle Memorial Institute Deoxygenation of fatty acids for preparation of hydrocarbons

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US4400468A (en) * 1981-10-05 1983-08-23 Hydrocarbon Research Inc. Process for producing adipic acid from biomass
US5128291A (en) * 1990-12-11 1992-07-07 Wax Michael J Porous titania or zirconia spheres
CA2103876A1 (en) * 1992-08-27 1994-02-28 Stuart Leon Soled Group viii metal containing tungsten oxide silica modified zirconia as acid catalyst
JP4075292B2 (ja) 2000-07-24 2008-04-16 トヨタ自動車株式会社 パティキュレート浄化触媒
US7119225B1 (en) * 2000-08-18 2006-10-10 E. I. Du Pont De Nemours And Company Gold catalyst for selective oxidation
WO2004058396A2 (en) * 2002-12-20 2004-07-15 Honda Giken Kogyo Kabushiki Kaisha Methods for the preparation of catalysts for hydrogen generation
US7125536B2 (en) * 2004-02-06 2006-10-24 Millennium Inorganic Chemicals, Inc. Nano-structured particles with high thermal stability
JP2005330225A (ja) * 2004-05-20 2005-12-02 Nippon Shokubai Co Ltd カルボン酸及び／又はその塩の製造方法
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
EP2390247A1 (en) 2010-05-26 2011-11-30 Netherlands Organisation for Scientific Research (Advanced Chemical Technologies for Sustainability) Preparation of caprolactone, caprolactam, 2,5-tetrahydrofuran dimethanol, 1,6-hexanediol or 1,2,6-hexanetriol from 5-hydroxymethyl-2-furfuraldehyde
US9770705B2 (en) * 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
KR20150018877A (ko) 2012-06-11 2015-02-24 레노비아 인코포레이티드 1,6-헥산디올로부터 아디프산의 제조방법

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3739020A (en) * 1969-05-13 1973-06-12 Nat Distillers Chem Corp Preparation of carboxylic acids
DE2407146A1 (de) * 1974-02-15 1975-09-04 Erdoelchemie Gmbh Verfahren zur herstellung von dicarbonsaeuren
CN1454201A (zh) * 2000-08-18 2003-11-05 纳幕尔杜邦公司 选择性氧化用金催化剂
WO2011155964A1 (en) * 2010-06-11 2011-12-15 Rennovia, Inc. Catalyst comprising platinum and gold nano - particles and its use for oxidation of glucose and preparation method of such a catalyst
WO2012018739A1 (en) * 2010-08-02 2012-02-09 Battelle Memorial Institute Deoxygenation of fatty acids for preparation of hydrocarbons

Also Published As

Publication number Publication date
US20160074835A1 (en) 2016-03-17
BR112014030857B1 (pt) 2021-06-22
CN111454144A (zh) 2020-07-28
JP2015525229A (ja) 2015-09-03
AU2013274530B2 (en) 2017-09-28
SG11201408289UA (en) 2015-01-29
US20130331606A1 (en) 2013-12-12
MX2014015180A (es) 2015-02-17
AR091409A1 (es) 2015-02-04
EP3363537A1 (en) 2018-08-22
EP2858748B1 (en) 2018-04-11
US9035094B2 (en) 2015-05-19
AU2013274530A1 (en) 2015-01-22
WO2013188348A3 (en) 2014-03-20
JP6209603B2 (ja) 2017-10-04
SG10201604678PA (en) 2016-07-28
EP2858748A2 (en) 2015-04-15
EP3363537B1 (en) 2021-10-20
EA201492252A1 (ru) 2015-05-29
CA2876153A1 (en) 2013-12-19
KR20150018877A (ko) 2015-02-24
CN104364010A (zh) 2015-02-18
HK1210087A1 (en) 2016-04-15
SA113340632B1 (ar) 2015-12-06
BR112014030857A2 (pt) 2017-06-27
US20170226038A1 (en) 2017-08-10
CN111454144B (zh) 2024-11-15
WO2013188348A2 (en) 2013-12-19
US10077226B2 (en) 2018-09-18

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