EA201492252A1 - Способ получения адипиновой кислоты из 1,6-гександиола - Google Patents
Способ получения адипиновой кислоты из 1,6-гександиолаInfo
- Publication number
- EA201492252A1 EA201492252A1 EA201492252A EA201492252A EA201492252A1 EA 201492252 A1 EA201492252 A1 EA 201492252A1 EA 201492252 A EA201492252 A EA 201492252A EA 201492252 A EA201492252 A EA 201492252A EA 201492252 A1 EA201492252 A1 EA 201492252A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- oxygen
- adipic acid
- hexandiol
- hexanediol
- metals
- Prior art date
Links
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 title abstract 4
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 title abstract 3
- 235000011037 adipic acid Nutrition 0.000 title abstract 2
- 239000001361 adipic acid Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- 229910002076 stabilized zirconia Inorganic materials 0.000 abstract 2
- 239000004408 titanium dioxide Substances 0.000 abstract 2
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 1
- 239000010931 gold Substances 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 239000002638 heterogeneous catalyst Substances 0.000 abstract 1
- 230000003993 interaction Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6527—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/651—50-500 nm
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/50—Use of additives, e.g. for stabilisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
- B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Nanotechnology (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261658364P | 2012-06-11 | 2012-06-11 | |
| PCT/US2013/045096 WO2013188348A2 (en) | 2012-06-11 | 2013-06-11 | Process for production of adipic acid from 1,6-hexanediol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EA201492252A1 true EA201492252A1 (ru) | 2015-05-29 |
Family
ID=48656277
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201492252A EA201492252A1 (ru) | 2012-06-11 | 2013-06-11 | Способ получения адипиновой кислоты из 1,6-гександиола |
Country Status (15)
| Country | Link |
|---|---|
| US (3) | US9035094B2 (enExample) |
| EP (2) | EP3363537B1 (enExample) |
| JP (1) | JP6209603B2 (enExample) |
| KR (1) | KR20150018877A (enExample) |
| CN (2) | CN104364010B (enExample) |
| AR (1) | AR091409A1 (enExample) |
| AU (1) | AU2013274530B2 (enExample) |
| BR (1) | BR112014030857B1 (enExample) |
| CA (1) | CA2876153A1 (enExample) |
| EA (1) | EA201492252A1 (enExample) |
| HK (1) | HK1210087A1 (enExample) |
| MX (1) | MX2014015180A (enExample) |
| SA (1) | SA113340632B1 (enExample) |
| SG (2) | SG10201604678PA (enExample) |
| WO (1) | WO2013188348A2 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104066710B (zh) | 2012-01-18 | 2016-06-29 | 莱诺维亚公司 | 从5-羟甲基糠醛产生六亚甲基二胺的方法 |
| WO2013126250A1 (en) | 2012-02-23 | 2013-08-29 | Rennovia, Inc. | Production of caprolactam from adipic acid |
| KR20150018877A (ko) | 2012-06-11 | 2015-02-24 | 레노비아 인코포레이티드 | 1,6-헥산디올로부터 아디프산의 제조방법 |
| US8986637B2 (en) * | 2012-11-30 | 2015-03-24 | Johnson Matthey Public Limited Company | Bimetallic catalyst |
| TW201636096A (zh) | 2014-12-02 | 2016-10-16 | 瑞諾維亞公司 | 自５－羥甲基糠醛產生己三醇之方法 |
| EP3402787A4 (en) | 2016-01-13 | 2019-11-27 | Stora Enso Oyj | PROCESS FOR THE PREPARATION OF 2,5-FURANDIC ACETIC ACID AND INTERMEDIATES AND DERIVATIVES THEREOF |
| SG11201913469PA (en) | 2017-07-12 | 2020-01-30 | Stora Enso Oyj | Purified 2,5-furandicarboxylic acid pathway products |
| JP7158953B2 (ja) * | 2017-08-18 | 2022-10-24 | 中国石油化工股▲ふん▼有限公司 | 重質芳香族炭化水素から軽質芳香族炭化水素を製造するための触媒、その製造方法及び適用 |
| WO2019047113A1 (en) * | 2017-09-07 | 2019-03-14 | Rhodia Operations | PROCESS FOR OXIDATION OF ALCOHOLS |
| CN116726913A (zh) * | 2023-02-01 | 2023-09-12 | 北京化工大学 | 一种用于生物质甘油氧化制备甘油酸的高效催化剂的制备方法及其应用 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3739020A (en) * | 1969-05-13 | 1973-06-12 | Nat Distillers Chem Corp | Preparation of carboxylic acids |
| DE2407146A1 (de) * | 1974-02-15 | 1975-09-04 | Erdoelchemie Gmbh | Verfahren zur herstellung von dicarbonsaeuren |
| US4400468A (en) * | 1981-10-05 | 1983-08-23 | Hydrocarbon Research Inc. | Process for producing adipic acid from biomass |
| US5128291A (en) * | 1990-12-11 | 1992-07-07 | Wax Michael J | Porous titania or zirconia spheres |
| CA2103876A1 (en) * | 1992-08-27 | 1994-02-28 | Stuart Leon Soled | Group viii metal containing tungsten oxide silica modified zirconia as acid catalyst |
| JP4075292B2 (ja) | 2000-07-24 | 2008-04-16 | トヨタ自動車株式会社 | パティキュレート浄化触媒 |
| US7119225B1 (en) * | 2000-08-18 | 2006-10-10 | E. I. Du Pont De Nemours And Company | Gold catalyst for selective oxidation |
| EP1309536B1 (en) * | 2000-08-18 | 2010-06-09 | INVISTA Technologies S.à.r.l. | Selective oxidation of an alcohol or ketone using a gold catalyst |
| WO2004058396A2 (en) * | 2002-12-20 | 2004-07-15 | Honda Giken Kogyo Kabushiki Kaisha | Methods for the preparation of catalysts for hydrogen generation |
| US7125536B2 (en) * | 2004-02-06 | 2006-10-24 | Millennium Inorganic Chemicals, Inc. | Nano-structured particles with high thermal stability |
| JP2005330225A (ja) * | 2004-05-20 | 2005-12-02 | Nippon Shokubai Co Ltd | カルボン酸及び／又はその塩の製造方法 |
| DE102007025444A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| US8669397B2 (en) * | 2009-06-13 | 2014-03-11 | Rennovia, Inc. | Production of adipic acid and derivatives from carbohydrate-containing materials |
| EP2390247A1 (en) | 2010-05-26 | 2011-11-30 | Netherlands Organisation for Scientific Research (Advanced Chemical Technologies for Sustainability) | Preparation of caprolactone, caprolactam, 2,5-tetrahydrofuran dimethanol, 1,6-hexanediol or 1,2,6-hexanetriol from 5-hydroxymethyl-2-furfuraldehyde |
| US9770705B2 (en) * | 2010-06-11 | 2017-09-26 | Rennovia Inc. | Oxidation catalysts |
| US8366907B2 (en) * | 2010-08-02 | 2013-02-05 | Battelle Memorial Institute | Deoxygenation of fatty acids for preparation of hydrocarbons |
| KR20150018877A (ko) | 2012-06-11 | 2015-02-24 | 레노비아 인코포레이티드 | 1,6-헥산디올로부터 아디프산의 제조방법 |
-
2013
- 2013-06-11 KR KR20157000572A patent/KR20150018877A/ko not_active Withdrawn
- 2013-06-11 HK HK15110086.7A patent/HK1210087A1/xx unknown
- 2013-06-11 SA SA113340632A patent/SA113340632B1/ar unknown
- 2013-06-11 JP JP2015517344A patent/JP6209603B2/ja not_active Expired - Fee Related
- 2013-06-11 AU AU2013274530A patent/AU2013274530B2/en not_active Expired - Fee Related
- 2013-06-11 EP EP18166286.7A patent/EP3363537B1/en active Active
- 2013-06-11 WO PCT/US2013/045096 patent/WO2013188348A2/en not_active Ceased
- 2013-06-11 MX MX2014015180A patent/MX2014015180A/es unknown
- 2013-06-11 AR ARP130102052 patent/AR091409A1/es unknown
- 2013-06-11 CN CN201380030851.4A patent/CN104364010B/zh active Active
- 2013-06-11 US US13/915,120 patent/US9035094B2/en active Active
- 2013-06-11 SG SG10201604678PA patent/SG10201604678PA/en unknown
- 2013-06-11 EA EA201492252A patent/EA201492252A1/ru unknown
- 2013-06-11 CA CA2876153A patent/CA2876153A1/en not_active Abandoned
- 2013-06-11 CN CN202010014532.6A patent/CN111454144B/zh active Active
- 2013-06-11 SG SG11201408289UA patent/SG11201408289UA/en unknown
- 2013-06-11 BR BR112014030857-8A patent/BR112014030857B1/pt active IP Right Grant
- 2013-06-11 EP EP13730095.0A patent/EP2858748B1/en active Active
-
2015
- 2015-04-20 US US14/691,356 patent/US20160074835A1/en not_active Abandoned
-
2016
- 2016-10-17 US US15/295,351 patent/US10077226B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20160074835A1 (en) | 2016-03-17 |
| BR112014030857B1 (pt) | 2021-06-22 |
| CN111454144A (zh) | 2020-07-28 |
| JP2015525229A (ja) | 2015-09-03 |
| AU2013274530B2 (en) | 2017-09-28 |
| SG11201408289UA (en) | 2015-01-29 |
| CN104364010B (zh) | 2020-02-11 |
| US20130331606A1 (en) | 2013-12-12 |
| MX2014015180A (es) | 2015-02-17 |
| AR091409A1 (es) | 2015-02-04 |
| EP3363537A1 (en) | 2018-08-22 |
| EP2858748B1 (en) | 2018-04-11 |
| US9035094B2 (en) | 2015-05-19 |
| AU2013274530A1 (en) | 2015-01-22 |
| WO2013188348A3 (en) | 2014-03-20 |
| JP6209603B2 (ja) | 2017-10-04 |
| SG10201604678PA (en) | 2016-07-28 |
| EP2858748A2 (en) | 2015-04-15 |
| EP3363537B1 (en) | 2021-10-20 |
| CA2876153A1 (en) | 2013-12-19 |
| KR20150018877A (ko) | 2015-02-24 |
| CN104364010A (zh) | 2015-02-18 |
| HK1210087A1 (en) | 2016-04-15 |
| SA113340632B1 (ar) | 2015-12-06 |
| BR112014030857A2 (pt) | 2017-06-27 |
| US20170226038A1 (en) | 2017-08-10 |
| CN111454144B (zh) | 2024-11-15 |
| WO2013188348A2 (en) | 2013-12-19 |
| US10077226B2 (en) | 2018-09-18 |
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