SG11201405045YA - Production of caprolactam from adipic acid - Google Patents

Production of caprolactam from adipic acid

Info

Publication number
SG11201405045YA
SG11201405045YA SG11201405045YA SG11201405045YA SG11201405045YA SG 11201405045Y A SG11201405045Y A SG 11201405045YA SG 11201405045Y A SG11201405045Y A SG 11201405045YA SG 11201405045Y A SG11201405045Y A SG 11201405045YA SG 11201405045Y A SG11201405045Y A SG 11201405045YA
Authority
SG
Singapore
Prior art keywords
caprolactam
production
adipic acid
adipic
acid
Prior art date
Application number
SG11201405045YA
Inventor
Eric L Dias
Vincent J Murphy
James Longmire
Hong Jiang
Original Assignee
Rennovia Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rennovia Inc filed Critical Rennovia Inc
Publication of SG11201405045YA publication Critical patent/SG11201405045YA/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/08—Oxygen atoms
    • C07D223/10—Oxygen atoms attached in position 2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906—Iron and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/02—Preparation of lactams
    • C07D201/08—Preparation of lactams from carboxylic acids or derivatives thereof, e.g. hydroxy carboxylic acids, lactones or nitriles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
SG11201405045YA 2012-02-23 2013-02-13 Production of caprolactam from adipic acid SG11201405045YA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261602533P 2012-02-23 2012-02-23
PCT/US2013/025846 WO2013126250A1 (en) 2012-02-23 2013-02-13 Production of caprolactam from adipic acid

Publications (1)

Publication Number Publication Date
SG11201405045YA true SG11201405045YA (en) 2014-09-26

Family

ID=47748790

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201405045YA SG11201405045YA (en) 2012-02-23 2013-02-13 Production of caprolactam from adipic acid

Country Status (12)

Country Link
US (1) US8946411B2 (en)
EP (1) EP2817293A1 (en)
JP (1) JP2015517977A (en)
KR (1) KR20140129076A (en)
CN (1) CN104169259B (en)
AR (1) AR089980A1 (en)
BR (1) BR112014020642B1 (en)
HK (1) HK1205121A1 (en)
IN (1) IN2014DN07028A (en)
SA (1) SA113340296B1 (en)
SG (1) SG11201405045YA (en)
WO (1) WO2013126250A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9487465B2 (en) 2011-12-14 2016-11-08 Rennovia Inc. Process for the separation of mono- and di-carboxylic acid compounds
US9216937B2 (en) 2011-12-14 2015-12-22 Rennovia Inc. Water concentration reduction process
CN104557705B (en) * 2013-10-15 2017-06-09 中国石油化工股份有限公司 A kind of method and apparatus of caprolactam refining
CA3205339A1 (en) 2014-09-29 2016-04-07 Archer-Daniels-Midland Company Preparation and separation of a dicarboxylic acid-containing mixture using a dicarboxylate form of an anion exchange chromatogrpahy resin
CN107074761B (en) * 2014-10-30 2020-04-14 东丽株式会社 Process for producing epsilon-caprolactam
EP3348544A4 (en) * 2015-09-11 2019-03-27 Toray Industries, Inc. Method for producing -caprolactam
CN110023285B (en) * 2016-12-06 2023-01-17 东丽株式会社 Process for producing epsilon-caprolactam
KR20200024578A (en) * 2018-08-28 2020-03-09 현대자동차주식회사 Manufacturing method of adipamide which is an Intermediate for bio nylon composition
CN114160120B (en) * 2021-12-24 2024-01-26 郑州中科新兴产业技术研究院 Preparation method of catalyst for producing adiponitrile from adipate

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GB778253A (en) * 1955-02-02 1957-07-03 Inventa Ag Process for the manufacture of -e-caprolactam
US3652549A (en) * 1968-07-18 1972-03-28 Kanegafuchi Spinning Co Ltd Production of epsilon-caprolactam
JPS4919250B1 (en) * 1969-01-09 1974-05-16
JPS4919250A (en) * 1972-06-16 1974-02-20
US4042490A (en) 1973-12-26 1977-08-16 Texaco Inc. Hydrocarbon upgrading process
US4800227A (en) 1984-08-20 1989-01-24 Phillips Petroleum Company Process for the production of lactams
IT1214622B (en) 1985-07-10 1990-01-18 Montedipe Spa CATALYTIC PROCESS FOR THE PRODUCTION OF CYCLOHEXANONE.
US5717089A (en) * 1995-03-01 1998-02-10 Dsm N.V. Process for the preparation of E-caprolactam
DE19548289A1 (en) * 1995-12-22 1997-06-26 Basf Ag Process for the simultaneous production of caprolactam and hexamethylenediamine
US5780623A (en) * 1996-02-23 1998-07-14 Dsm N.V. Process to prepare ε-caprolactam from 6-aminocaproic acid
US5977356A (en) * 1997-07-02 1999-11-02 Industrial Technology Research Institute Process for preparing caprolactam
EP0984002A1 (en) 1998-09-03 2000-03-08 Dsm N.V. Process to continuously prepare an aqueous mixture of epsilon-caprolactam and epsilon-caprolactam precursors
DE19842900A1 (en) 1998-09-18 2000-03-23 Basf Ag Combined production of cyclic lactam and cyclic amine, e.g. caprolactam and azepane, involves gas phase reaction of aliphatic alpha,omega-diamine with water over heterogeneous catalyst
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US6414179B1 (en) * 2000-02-18 2002-07-02 Bristol-Myers Squibb Company Alpha-and beta-substituted trifluoromethyl ketones as phospholipase inhibitors
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US9216937B2 (en) 2011-12-14 2015-12-22 Rennovia Inc. Water concentration reduction process
US9487465B2 (en) 2011-12-14 2016-11-08 Rennovia Inc. Process for the separation of mono- and di-carboxylic acid compounds
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US9035094B2 (en) 2012-06-11 2015-05-19 Rennovia, Inc. Process for production of adipic acid from 1,6-hexanediol

Also Published As

Publication number Publication date
CN104169259B (en) 2016-09-21
JP2015517977A (en) 2015-06-25
WO2013126250A1 (en) 2013-08-29
EP2817293A1 (en) 2014-12-31
BR112014020642B1 (en) 2020-12-29
SA113340296B1 (en) 2015-09-06
US8946411B2 (en) 2015-02-03
IN2014DN07028A (en) 2015-04-10
AR089980A1 (en) 2014-10-01
HK1205121A1 (en) 2015-12-11
US20130225785A1 (en) 2013-08-29
BR112014020642A2 (en) 2019-09-10
CN104169259A (en) 2014-11-26
KR20140129076A (en) 2014-11-06

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