BR112014030857B1 - Processo de produção de ácido adípico a partir de 1,6-hexanodiol - Google Patents

Processo de produção de ácido adípico a partir de 1,6-hexanodiol Download PDF

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Publication number
BR112014030857B1
BR112014030857B1 BR112014030857-8A BR112014030857A BR112014030857B1 BR 112014030857 B1 BR112014030857 B1 BR 112014030857B1 BR 112014030857 A BR112014030857 A BR 112014030857A BR 112014030857 B1 BR112014030857 B1 BR 112014030857B1
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BR
Brazil
Prior art keywords
hexanediol
process according
heterogeneous catalyst
catalyst
oxygen
Prior art date
Application number
BR112014030857-8A
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English (en)
Portuguese (pt)
Other versions
BR112014030857A2 (pt
Inventor
Eric L. Dias
James A. W. Shoemaker
Vincent J. Murphy
Original Assignee
Archer-Daniels-Midland Company
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Filing date
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Application filed by Archer-Daniels-Midland Company filed Critical Archer-Daniels-Midland Company
Publication of BR112014030857A2 publication Critical patent/BR112014030857A2/pt
Publication of BR112014030857B1 publication Critical patent/BR112014030857B1/pt

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
BR112014030857-8A 2012-06-11 2013-06-11 Processo de produção de ácido adípico a partir de 1,6-hexanodiol BR112014030857B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261658364P 2012-06-11 2012-06-11
US61/658,364 2012-06-11
PCT/US2013/045096 WO2013188348A2 (en) 2012-06-11 2013-06-11 Process for production of adipic acid from 1,6-hexanediol

Publications (2)

Publication Number Publication Date
BR112014030857A2 BR112014030857A2 (pt) 2017-06-27
BR112014030857B1 true BR112014030857B1 (pt) 2021-06-22

Family

ID=48656277

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014030857-8A BR112014030857B1 (pt) 2012-06-11 2013-06-11 Processo de produção de ácido adípico a partir de 1,6-hexanodiol

Country Status (15)

Country Link
US (3) US9035094B2 (enExample)
EP (2) EP2858748B1 (enExample)
JP (1) JP6209603B2 (enExample)
KR (1) KR20150018877A (enExample)
CN (2) CN104364010B (enExample)
AR (1) AR091409A1 (enExample)
AU (1) AU2013274530B2 (enExample)
BR (1) BR112014030857B1 (enExample)
CA (1) CA2876153A1 (enExample)
EA (1) EA201492252A1 (enExample)
HK (1) HK1210087A1 (enExample)
MX (1) MX2014015180A (enExample)
SA (1) SA113340632B1 (enExample)
SG (2) SG11201408289UA (enExample)
WO (1) WO2013188348A2 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HK1204318A1 (en) 2012-01-18 2015-11-13 Archer-Daniels-Midland Company Process for production of hexamethylenediamine from 5 - hydroxymethylfurfural
WO2013126250A1 (en) 2012-02-23 2013-08-29 Rennovia, Inc. Production of caprolactam from adipic acid
EP2858748B1 (en) 2012-06-11 2018-04-11 Rennovia Inc. Process for production of adipic acid from 1,6-hexanediol
DE102013222540A1 (de) * 2012-11-30 2014-06-05 Johnson Matthey Public Limited Company Bimetallischer katalysator
BR112017009754B1 (pt) 2014-12-02 2021-09-14 Archer-Daniels-Midland Company Processo para a preparação de 2,5-bis-hidroximetilfurano, 1,2,6-hexanotriol, e 1,6- exanodiol a partir de 5- hidroximetilfurfural
BR112018014278B1 (pt) 2016-01-13 2022-07-12 Stora Enso Oyj Processos para a preparação de ácido 2,5-furandicarboxílico e intermediários e derivados dos mesmos
SG11201913469PA (en) 2017-07-12 2020-01-30 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products
KR102504661B1 (ko) * 2017-08-18 2023-02-27 차이나 페트로리움 앤드 케미컬 코포레이션 중질 방향족 화합물로 경질 방향족 화합물을 제조하기 위한 촉매 및 이의 제조 방법과 용도
WO2019047113A1 (en) * 2017-09-07 2019-03-14 Rhodia Operations PROCESS FOR OXIDATION OF ALCOHOLS
CN116726913A (zh) * 2023-02-01 2023-09-12 北京化工大学 一种用于生物质甘油氧化制备甘油酸的高效催化剂的制备方法及其应用

Family Cites Families (17)

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US3739020A (en) * 1969-05-13 1973-06-12 Nat Distillers Chem Corp Preparation of carboxylic acids
DE2407146A1 (de) * 1974-02-15 1975-09-04 Erdoelchemie Gmbh Verfahren zur herstellung von dicarbonsaeuren
US4400468A (en) * 1981-10-05 1983-08-23 Hydrocarbon Research Inc. Process for producing adipic acid from biomass
US5128291A (en) * 1990-12-11 1992-07-07 Wax Michael J Porous titania or zirconia spheres
CA2103876A1 (en) * 1992-08-27 1994-02-28 Stuart Leon Soled Group viii metal containing tungsten oxide silica modified zirconia as acid catalyst
JP4075292B2 (ja) 2000-07-24 2008-04-16 トヨタ自動車株式会社 パティキュレート浄化触媒
WO2002016298A1 (en) * 2000-08-18 2002-02-28 E.I. Du Pont De Nemours And Company Gold catalyst for selective oxidation
US7119225B1 (en) * 2000-08-18 2006-10-10 E. I. Du Pont De Nemours And Company Gold catalyst for selective oxidation
WO2004058396A2 (en) * 2002-12-20 2004-07-15 Honda Giken Kogyo Kabushiki Kaisha Methods for the preparation of catalysts for hydrogen generation
US7125536B2 (en) * 2004-02-06 2006-10-24 Millennium Inorganic Chemicals, Inc. Nano-structured particles with high thermal stability
JP2005330225A (ja) * 2004-05-20 2005-12-02 Nippon Shokubai Co Ltd カルボン酸及び／又はその塩の製造方法
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
US8669397B2 (en) * 2009-06-13 2014-03-11 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
EP2390247A1 (en) 2010-05-26 2011-11-30 Netherlands Organisation for Scientific Research (Advanced Chemical Technologies for Sustainability) Preparation of caprolactone, caprolactam, 2,5-tetrahydrofuran dimethanol, 1,6-hexanediol or 1,2,6-hexanetriol from 5-hydroxymethyl-2-furfuraldehyde
US9770705B2 (en) * 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
US8366907B2 (en) 2010-08-02 2013-02-05 Battelle Memorial Institute Deoxygenation of fatty acids for preparation of hydrocarbons
EP2858748B1 (en) 2012-06-11 2018-04-11 Rennovia Inc. Process for production of adipic acid from 1,6-hexanediol

Also Published As

Publication number Publication date
US10077226B2 (en) 2018-09-18
CA2876153A1 (en) 2013-12-19
EP3363537B1 (en) 2021-10-20
EP2858748B1 (en) 2018-04-11
EP3363537A1 (en) 2018-08-22
WO2013188348A3 (en) 2014-03-20
SG11201408289UA (en) 2015-01-29
CN111454144A (zh) 2020-07-28
SA113340632B1 (ar) 2015-12-06
MX2014015180A (es) 2015-02-17
EA201492252A1 (ru) 2015-05-29
AR091409A1 (es) 2015-02-04
BR112014030857A2 (pt) 2017-06-27
CN104364010A (zh) 2015-02-18
US20170226038A1 (en) 2017-08-10
AU2013274530A1 (en) 2015-01-22
CN104364010B (zh) 2020-02-11
US9035094B2 (en) 2015-05-19
SG10201604678PA (en) 2016-07-28
AU2013274530B2 (en) 2017-09-28
WO2013188348A2 (en) 2013-12-19
JP6209603B2 (ja) 2017-10-04
US20130331606A1 (en) 2013-12-12
KR20150018877A (ko) 2015-02-24
CN111454144B (zh) 2024-11-15
JP2015525229A (ja) 2015-09-03
EP2858748A2 (en) 2015-04-15
US20160074835A1 (en) 2016-03-17
HK1210087A1 (en) 2016-04-15

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Legal Events

Date Code Title Description
B25G Requested change of headquarter approved

Owner name: RENNOVIA, INC. (US)

B25A Requested transfer of rights approved

Owner name: ARCHER-DANIELS-MIDLAND COMPANY (US)

B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 11/06/2013, OBSERVADAS AS CONDICOES LEGAIS.