AR091409A1 - Proceso para la produccion de acido adipico a partir de 1,6-hexanodiol - Google Patents

Proceso para la produccion de acido adipico a partir de 1,6-hexanodiol

Info

Publication number
AR091409A1
AR091409A1 ARP130102052A AR091409A1 AR 091409 A1 AR091409 A1 AR 091409A1 AR P130102052 A ARP130102052 A AR P130102052A AR 091409 A1 AR091409 A1 AR 091409A1
Authority
AR
Argentina
Prior art keywords
oxygen
adipic acid
hexanodiol
production
psig
Prior art date
Application number
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English (en)
Original Assignee
Rennovia Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rennovia Inc filed Critical Rennovia Inc
Publication of AR091409A1 publication Critical patent/AR091409A1/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se divulgan procesos para convertir 1,6-hexanodiol en ácido adípico empleando una reacción quimiocatalítica en la cual se hace reaccionar 1,6-hexanodiol con oxígeno en presencia de catalizadores heterogéneos particulares que incluyen al menos uno entre platino y oro. Los metales se proporcionan preferentemente sobre un soporte seleccionado del grupo que consiste en titania, titania estabilizada, circonia, circonia estabilizada, sílice o sus mezclas, más preferentemente circonia estabilizada con tungsteno. La reacción con oxígeno se realiza con una temperatura de aproximadamente 100ºC a aproximadamente 300ºC y con una presión parcial de oxígeno entre aproximadamente 344,74 kPa (50 psig) y aproximadamente 13.789,51 (2.000 psig).
ARP130102052 2012-06-11 2013-06-11 Proceso para la produccion de acido adipico a partir de 1,6-hexanodiol AR091409A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US201261658364P 2012-06-11 2012-06-11

Publications (1)

Publication Number Publication Date
AR091409A1 true AR091409A1 (es) 2015-02-04

Family

ID=48656277

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP130102052 AR091409A1 (es) 2012-06-11 2013-06-11 Proceso para la produccion de acido adipico a partir de 1,6-hexanodiol

Country Status (15)

Country Link
US (3) US9035094B2 (es)
EP (2) EP2858748B1 (es)
JP (1) JP6209603B2 (es)
KR (1) KR20150018877A (es)
CN (2) CN111454144A (es)
AR (1) AR091409A1 (es)
AU (1) AU2013274530B2 (es)
BR (1) BR112014030857B1 (es)
CA (1) CA2876153A1 (es)
EA (1) EA201492252A1 (es)
HK (1) HK1210087A1 (es)
MX (1) MX2014015180A (es)
SA (1) SA113340632B1 (es)
SG (2) SG11201408289UA (es)
WO (1) WO2013188348A2 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2860886A1 (en) 2012-01-18 2013-07-25 Rennovia, Inc. Process for production of hexamethylenediamine from carbohydrate-containing materials and intermediates therefor
US8946411B2 (en) 2012-02-23 2015-02-03 Rennovia, Inc. Production of caprolactam from adipic acid
SG11201408289UA (en) 2012-06-11 2015-01-29 Rennovia Inc Process for production of adipic acid from 1,6-hexanediol
US8986637B2 (en) * 2012-11-30 2015-03-24 Johnson Matthey Public Limited Company Bimetallic catalyst
JP2017537920A (ja) 2014-12-02 2017-12-21 レノビア インコーポレイテッド ５−ヒドロキシメチルフルフラールから２，５−ビスヒドロキシメチルフラン、２，５−ビス−ヒドロキシメチルテトラヒドロフラン、１，６−ヘキサンジオールおよび１，２，６−ヘキサントリオールを生成する工程
SG11201805514VA (en) 2016-01-13 2018-07-30 Stora Enso Oyj Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
SG11201913469PA (en) 2017-07-12 2020-01-30 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products
JP7158953B2 (ja) * 2017-08-18 2022-10-24 中国石油化工股▲ふん▼有限公司 重質芳香族炭化水素から軽質芳香族炭化水素を製造するための触媒、その製造方法及び適用
WO2019047113A1 (en) * 2017-09-07 2019-03-14 Rhodia Operations PROCESS FOR OXIDATION OF ALCOHOLS

Family Cites Families (17)

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Publication number Priority date Publication date Assignee Title
US3739020A (en) * 1969-05-13 1973-06-12 Nat Distillers Chem Corp Preparation of carboxylic acids
DE2407146A1 (de) * 1974-02-15 1975-09-04 Erdoelchemie Gmbh Verfahren zur herstellung von dicarbonsaeuren
US4400468A (en) * 1981-10-05 1983-08-23 Hydrocarbon Research Inc. Process for producing adipic acid from biomass
US5128291A (en) * 1990-12-11 1992-07-07 Wax Michael J Porous titania or zirconia spheres
CA2103876A1 (en) * 1992-08-27 1994-02-28 Stuart Leon Soled Group viii metal containing tungsten oxide silica modified zirconia as acid catalyst
JP4075292B2 (ja) * 2000-07-24 2008-04-16 トヨタ自動車株式会社 パティキュレート浄化触媒
KR20030066599A (ko) * 2000-08-18 2003-08-09 이 아이 듀폰 디 네모아 앤드 캄파니 선택적 산화를 위한 금 촉매
US7119225B1 (en) * 2000-08-18 2006-10-10 E. I. Du Pont De Nemours And Company Gold catalyst for selective oxidation
EP1581339A2 (en) * 2002-12-20 2005-10-05 Honda Giken Kogyo Kabushiki Kaisha Methods for the preparation of catalysts for hydrogen generation
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JP2005330225A (ja) * 2004-05-20 2005-12-02 Nippon Shokubai Co Ltd カルボン酸及び／又はその塩の製造方法
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SG11201408289UA (en) 2012-06-11 2015-01-29 Rennovia Inc Process for production of adipic acid from 1,6-hexanediol

Also Published As

Publication number Publication date
US20170226038A1 (en) 2017-08-10
KR20150018877A (ko) 2015-02-24
EA201492252A1 (ru) 2015-05-29
JP6209603B2 (ja) 2017-10-04
US10077226B2 (en) 2018-09-18
AU2013274530B2 (en) 2017-09-28
EP3363537B1 (en) 2021-10-20
WO2013188348A3 (en) 2014-03-20
SG11201408289UA (en) 2015-01-29
US9035094B2 (en) 2015-05-19
CN104364010A (zh) 2015-02-18
JP2015525229A (ja) 2015-09-03
BR112014030857A2 (pt) 2017-06-27
CN104364010B (zh) 2020-02-11
EP3363537A1 (en) 2018-08-22
US20160074835A1 (en) 2016-03-17
HK1210087A1 (en) 2016-04-15
EP2858748B1 (en) 2018-04-11
CN111454144A (zh) 2020-07-28
EP2858748A2 (en) 2015-04-15
MX2014015180A (es) 2015-02-17
AU2013274530A1 (en) 2015-01-22
SG10201604678PA (en) 2016-07-28
BR112014030857B1 (pt) 2021-06-22
US20130331606A1 (en) 2013-12-12
WO2013188348A2 (en) 2013-12-19
SA113340632B1 (ar) 2015-12-06
CA2876153A1 (en) 2013-12-19

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