SG11201408289UA - Process for production of adipic acid from 1,6-hexanediol - Google Patents

Process for production of adipic acid from 1,6-hexanediol

Info

Publication number
SG11201408289UA
SG11201408289UA SG11201408289UA SG11201408289UA SG11201408289UA SG 11201408289U A SG11201408289U A SG 11201408289UA SG 11201408289U A SG11201408289U A SG 11201408289UA SG 11201408289U A SG11201408289U A SG 11201408289UA SG 11201408289U A SG11201408289U A SG 11201408289UA
Authority
SG
Singapore
Prior art keywords
international
hexanediol
menlo park
oxygen
publication
Prior art date
Application number
SG11201408289UA
Inventor
Eric L Dias
Vincent J Murphy
James A W Shoemaker
Original Assignee
Rennovia Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rennovia Inc filed Critical Rennovia Inc
Publication of SG11201408289UA publication Critical patent/SG11201408289UA/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 19 December 2013 (19.12.2013) WIPOIPCT (10) International Publication Number WO 2013/188348 A3 (51) International Patent Classification: B01J23/42 (2006.01) C07C 55/14 (2006.01) B01J23/44 (2006.01) B01J21/06 (2006.01) B01J23/52 (2006.01) B01J35/10 (2006.01) C07C 51/235 (2006.01) (21) International Application Number: (22) International Filing Date: (25) Filing Language: (26) Publication Language: PCT/US2013/045096 11 June 2013 (11.06.2013) English English (30) Priority Data: 61/658,364 11 June 2012 (11.06.2012) US (71) Applicant: RENNOVIA, INC. [US/US]; 1080 Hamilton Avenue, Menlo Park, CA 94025 (US). (72) Inventors: DIAS, Eric, L.; 1080 Hamilton Avenue, Menlo Park, CA 94025 (US). MURPHY, Vincent, J.; 1080 Hamilton Avenue, Menlo Park, CA 94025 (US). SHOE­ MAKER, James, A.W.; 1080 Hamilton Avenue, Menlo Park, CA 94025 (US). (74) Agents: ACKERMAN, Lily et al.; Morrison & Foerster LLP, 425 Market Street, San Francisco, CA 94105-2482 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available)'. AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IS, JP, KE, KG, KN, KP, KR, KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available)'. ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: — with international search report (Art. 21(3)) — before the expiration of the time limit for amending the claims and to be republished in the event of receipt of amendments (Rule 48.2(h)) (88) Date of publication of the international search report: 20 March 2014 00 •t m oo oo i-H cn i-H o CJ o & (54) Title: PROCESS FOR PRODUCTION OF ADIPIC ACID FROM 1,6-HEXANEDIOL (57) Abstract: Processes are disclosed for the conversion of 1,6-hexanediol to adipic acid employing chemocatalytic a reaction in which 1,6-hexanediol reacted with is oxygen in the presence of particular heterogeneous catalysts including at least one of platinum or gold. The metals are preferably provided on a support selected from the group of titania, stabilized titania, zirconia, stabilized zir - conia, silica or mixtures thereof, most preferably zirconia stabilized with tungsten. The reaction with oxygen is carried out at tem a - perature from about 100°C to about 300°C and at a partial pressure of oxygen from about 50 psig (344,74 kPa) to about 2000 psig (13,79 MPa).
SG11201408289UA 2012-06-11 2013-06-11 Process for production of adipic acid from 1,6-hexanediol SG11201408289UA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261658364P 2012-06-11 2012-06-11
PCT/US2013/045096 WO2013188348A2 (en) 2012-06-11 2013-06-11 Process for production of adipic acid from 1,6-hexanediol

Publications (1)

Publication Number Publication Date
SG11201408289UA true SG11201408289UA (en) 2015-01-29

Family

ID=48656277

Family Applications (2)

Application Number Title Priority Date Filing Date
SG10201604678PA SG10201604678PA (en) 2012-06-11 2013-06-11 Process for production of adipic acid from 1,6-hexanediol
SG11201408289UA SG11201408289UA (en) 2012-06-11 2013-06-11 Process for production of adipic acid from 1,6-hexanediol

Family Applications Before (1)

Application Number Title Priority Date Filing Date
SG10201604678PA SG10201604678PA (en) 2012-06-11 2013-06-11 Process for production of adipic acid from 1,6-hexanediol

Country Status (15)

Country Link
US (3) US9035094B2 (en)
EP (2) EP2858748B1 (en)
JP (1) JP6209603B2 (en)
KR (1) KR20150018877A (en)
CN (2) CN104364010B (en)
AR (1) AR091409A1 (en)
AU (1) AU2013274530B2 (en)
BR (1) BR112014030857B1 (en)
CA (1) CA2876153A1 (en)
EA (1) EA201492252A1 (en)
HK (1) HK1210087A1 (en)
MX (1) MX2014015180A (en)
SA (1) SA113340632B1 (en)
SG (2) SG10201604678PA (en)
WO (1) WO2013188348A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106008163B (en) 2012-01-18 2019-10-08 阿彻丹尼尔斯米德兰公司 The method for generating hexamethylene diamine from 5 hydroxymethyl furfural
SG11201405045YA (en) 2012-02-23 2014-09-26 Rennovia Inc Production of caprolactam from adipic acid
AU2013274530B2 (en) 2012-06-11 2017-09-28 Rennovia, Inc. Process for production of adipic acid from 1,6-hexanediol
WO2014083309A1 (en) * 2012-11-30 2014-06-05 Johnson Matthey Public Limited Company Bimetallic catalyst
SG10201914057PA (en) 2014-12-02 2020-03-30 Archer Daniels Midland Co Process for production of 2,5-bis-hydroxymethylfuran, 2,5-bis-hydroxymethyltetrahydrofuran, 1,6-hexanediol and 1,2,6-hexanetriol from 5-hydroxymethylfurfural
KR20180107143A (en) 2016-01-13 2018-10-01 스토라 엔소 오와이제이 Process for preparing 2,5-furandicarboxylic acid and its intermediates and derivatives
WO2019014382A1 (en) 2017-07-12 2019-01-17 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products
KR102504661B1 (en) * 2017-08-18 2023-02-27 차이나 페트로리움 앤드 케미컬 코포레이션 Catalyst for producing light aromatics with heavy aromatics, method for preparing the catalyst, and use thereof
WO2019047113A1 (en) * 2017-09-07 2019-03-14 Rhodia Operations Process for oxidation of alcohols

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Also Published As

Publication number Publication date
CA2876153A1 (en) 2013-12-19
AR091409A1 (en) 2015-02-04
SA113340632B1 (en) 2015-12-06
CN104364010A (en) 2015-02-18
EP2858748A2 (en) 2015-04-15
CN104364010B (en) 2020-02-11
US9035094B2 (en) 2015-05-19
US10077226B2 (en) 2018-09-18
EP2858748B1 (en) 2018-04-11
US20170226038A1 (en) 2017-08-10
KR20150018877A (en) 2015-02-24
JP6209603B2 (en) 2017-10-04
WO2013188348A2 (en) 2013-12-19
SG10201604678PA (en) 2016-07-28
US20130331606A1 (en) 2013-12-12
CN111454144A (en) 2020-07-28
BR112014030857B1 (en) 2021-06-22
MX2014015180A (en) 2015-02-17
EA201492252A1 (en) 2015-05-29
HK1210087A1 (en) 2016-04-15
JP2015525229A (en) 2015-09-03
AU2013274530B2 (en) 2017-09-28
EP3363537B1 (en) 2021-10-20
AU2013274530A1 (en) 2015-01-22
BR112014030857A2 (en) 2017-06-27
US20160074835A1 (en) 2016-03-17
WO2013188348A3 (en) 2014-03-20
EP3363537A1 (en) 2018-08-22

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