KR20150018877A - 1,6-헥산디올로부터 아디프산의 제조방법 - Google Patents

1,6-헥산디올로부터 아디프산의 제조방법 Download PDF

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Publication number
KR20150018877A
KR20150018877A KR20157000572A KR20157000572A KR20150018877A KR 20150018877 A KR20150018877 A KR 20150018877A KR 20157000572 A KR20157000572 A KR 20157000572A KR 20157000572 A KR20157000572 A KR 20157000572A KR 20150018877 A KR20150018877 A KR 20150018877A
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KR
South Korea
Prior art keywords
hexanediol
catalyst
support
oxygen
zirconia
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Withdrawn
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KR20157000572A
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English (en)
Korean (ko)
Inventor
에릭 엘. 디아스
빈센트 제이. 머피
제임스 에이.더블류. 슈마커
Original Assignee
레노비아 인코포레이티드
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Publication of KR20150018877A publication Critical patent/KR20150018877A/ko
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR20157000572A 2012-06-11 2013-06-11 1,6-헥산디올로부터 아디프산의 제조방법 Withdrawn KR20150018877A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261658364P 2012-06-11 2012-06-11
US61/658,364 2012-06-11
PCT/US2013/045096 WO2013188348A2 (en) 2012-06-11 2013-06-11 Process for production of adipic acid from 1,6-hexanediol

Publications (1)

Publication Number Publication Date
KR20150018877A true KR20150018877A (ko) 2015-02-24

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KR20157000572A Withdrawn KR20150018877A (ko) 2012-06-11 2013-06-11 1,6-헥산디올로부터 아디프산의 제조방법

Country Status (15)

Country Link
US (3) US9035094B2 (enExample)
EP (2) EP3363537B1 (enExample)
JP (1) JP6209603B2 (enExample)
KR (1) KR20150018877A (enExample)
CN (2) CN104364010B (enExample)
AR (1) AR091409A1 (enExample)
AU (1) AU2013274530B2 (enExample)
BR (1) BR112014030857B1 (enExample)
CA (1) CA2876153A1 (enExample)
EA (1) EA201492252A1 (enExample)
HK (1) HK1210087A1 (enExample)
MX (1) MX2014015180A (enExample)
SA (1) SA113340632B1 (enExample)
SG (2) SG10201604678PA (enExample)
WO (1) WO2013188348A2 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104066710B (zh) 2012-01-18 2016-06-29 莱诺维亚公司 从5-羟甲基糠醛产生六亚甲基二胺的方法
WO2013126250A1 (en) 2012-02-23 2013-08-29 Rennovia, Inc. Production of caprolactam from adipic acid
KR20150018877A (ko) 2012-06-11 2015-02-24 레노비아 인코포레이티드 1,6-헥산디올로부터 아디프산의 제조방법
US8986637B2 (en) * 2012-11-30 2015-03-24 Johnson Matthey Public Limited Company Bimetallic catalyst
TW201636096A (zh) 2014-12-02 2016-10-16 瑞諾維亞公司 自５－羥甲基糠醛產生己三醇之方法
EP3402787A4 (en) 2016-01-13 2019-11-27 Stora Enso Oyj PROCESS FOR THE PREPARATION OF 2,5-FURANDIC ACETIC ACID AND INTERMEDIATES AND DERIVATIVES THEREOF
SG11201913469PA (en) 2017-07-12 2020-01-30 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products
JP7158953B2 (ja) * 2017-08-18 2022-10-24 中国石油化工股▲ふん▼有限公司 重質芳香族炭化水素から軽質芳香族炭化水素を製造するための触媒、その製造方法及び適用
WO2019047113A1 (en) * 2017-09-07 2019-03-14 Rhodia Operations PROCESS FOR OXIDATION OF ALCOHOLS
CN116726913A (zh) * 2023-02-01 2023-09-12 北京化工大学 一种用于生物质甘油氧化制备甘油酸的高效催化剂的制备方法及其应用

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US3739020A (en) * 1969-05-13 1973-06-12 Nat Distillers Chem Corp Preparation of carboxylic acids
DE2407146A1 (de) * 1974-02-15 1975-09-04 Erdoelchemie Gmbh Verfahren zur herstellung von dicarbonsaeuren
US4400468A (en) * 1981-10-05 1983-08-23 Hydrocarbon Research Inc. Process for producing adipic acid from biomass
US5128291A (en) * 1990-12-11 1992-07-07 Wax Michael J Porous titania or zirconia spheres
CA2103876A1 (en) * 1992-08-27 1994-02-28 Stuart Leon Soled Group viii metal containing tungsten oxide silica modified zirconia as acid catalyst
JP4075292B2 (ja) 2000-07-24 2008-04-16 トヨタ自動車株式会社 パティキュレート浄化触媒
US7119225B1 (en) * 2000-08-18 2006-10-10 E. I. Du Pont De Nemours And Company Gold catalyst for selective oxidation
EP1309536B1 (en) * 2000-08-18 2010-06-09 INVISTA Technologies S.à.r.l. Selective oxidation of an alcohol or ketone using a gold catalyst
WO2004058396A2 (en) * 2002-12-20 2004-07-15 Honda Giken Kogyo Kabushiki Kaisha Methods for the preparation of catalysts for hydrogen generation
US7125536B2 (en) * 2004-02-06 2006-10-24 Millennium Inorganic Chemicals, Inc. Nano-structured particles with high thermal stability
JP2005330225A (ja) * 2004-05-20 2005-12-02 Nippon Shokubai Co Ltd カルボン酸及び／又はその塩の製造方法
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
US8669397B2 (en) * 2009-06-13 2014-03-11 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
EP2390247A1 (en) 2010-05-26 2011-11-30 Netherlands Organisation for Scientific Research (Advanced Chemical Technologies for Sustainability) Preparation of caprolactone, caprolactam, 2,5-tetrahydrofuran dimethanol, 1,6-hexanediol or 1,2,6-hexanetriol from 5-hydroxymethyl-2-furfuraldehyde
US9770705B2 (en) * 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
US8366907B2 (en) * 2010-08-02 2013-02-05 Battelle Memorial Institute Deoxygenation of fatty acids for preparation of hydrocarbons
KR20150018877A (ko) 2012-06-11 2015-02-24 레노비아 인코포레이티드 1,6-헥산디올로부터 아디프산의 제조방법

Also Published As

Publication number Publication date
US20160074835A1 (en) 2016-03-17
BR112014030857B1 (pt) 2021-06-22
CN111454144A (zh) 2020-07-28
JP2015525229A (ja) 2015-09-03
AU2013274530B2 (en) 2017-09-28
SG11201408289UA (en) 2015-01-29
CN104364010B (zh) 2020-02-11
US20130331606A1 (en) 2013-12-12
MX2014015180A (es) 2015-02-17
AR091409A1 (es) 2015-02-04
EP3363537A1 (en) 2018-08-22
EP2858748B1 (en) 2018-04-11
US9035094B2 (en) 2015-05-19
AU2013274530A1 (en) 2015-01-22
WO2013188348A3 (en) 2014-03-20
JP6209603B2 (ja) 2017-10-04
SG10201604678PA (en) 2016-07-28
EP2858748A2 (en) 2015-04-15
EP3363537B1 (en) 2021-10-20
EA201492252A1 (ru) 2015-05-29
CA2876153A1 (en) 2013-12-19
CN104364010A (zh) 2015-02-18
HK1210087A1 (en) 2016-04-15
SA113340632B1 (ar) 2015-12-06
BR112014030857A2 (pt) 2017-06-27
US20170226038A1 (en) 2017-08-10
CN111454144B (zh) 2024-11-15
WO2013188348A2 (en) 2013-12-19
US10077226B2 (en) 2018-09-18

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Patent event date: 20150109

Patent event code: PA01051R01D

Comment text: International Patent Application

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PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20180601

Comment text: Request for Examination of Application

PC1202 Submission of document of withdrawal before decision of registration

Comment text: [Withdrawal of Procedure relating to Patent, etc.] Withdrawal (Abandonment)

Patent event code: PC12021R01D

Patent event date: 20180731