CN104349834B - 用于酸性溶剂的渗透蒸发脱水的耐酸pbi膜 - Google Patents

用于酸性溶剂的渗透蒸发脱水的耐酸pbi膜 Download PDF

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Publication number
CN104349834B
CN104349834B CN201380027431.0A CN201380027431A CN104349834B CN 104349834 B CN104349834 B CN 104349834B CN 201380027431 A CN201380027431 A CN 201380027431A CN 104349834 B CN104349834 B CN 104349834B
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acid
pbi
membrane
film
acidproof
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Expired - Fee Related
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CN201380027431.0A
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English (en)
Chinese (zh)
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CN104349834A (zh
Inventor
王艳
迈克尔·格兰德尔
钟台生
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PBI Performance Products Inc
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PBI Performance Products Inc
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/36Pervaporation; Membrane distillation; Liquid permeation
    • B01D61/362Pervaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/36Pervaporation; Membrane distillation; Liquid permeation
    • B01D61/366Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/08Flat membrane modules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • B01D67/0006Organic membrane manufacture by chemical reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0083Thermal after-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0093Chemical modification
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/06Flat membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08Hollow fibre membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10Supported membranes; Membrane supports
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • B01D69/1213Laminated layers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/18Polybenzimidazoles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/80Water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2315/00Details relating to the membrane module operation
    • B01D2315/22Membrane contactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/30Cross-linking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/22Thermal or heat-resistance properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/30Chemical resistance

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
CN201380027431.0A 2012-05-25 2013-04-24 用于酸性溶剂的渗透蒸发脱水的耐酸pbi膜 Expired - Fee Related CN104349834B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610623848.9A CN106178997A (zh) 2012-05-25 2013-04-24 用于酸性溶剂的渗透蒸发脱水的耐酸pbi膜

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/480,522 2012-05-25
US13/480,522 US9283523B2 (en) 2012-05-25 2012-05-25 Acid resistant PBI membrane for pervaporation dehydration of acidic solvents
PCT/US2013/037901 WO2013176818A1 (en) 2012-05-25 2013-04-24 Acid resistant pbi membrane for pervaporation dehydration of acidic solvents

Related Child Applications (1)

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CN201610623848.9A Division CN106178997A (zh) 2012-05-25 2013-04-24 用于酸性溶剂的渗透蒸发脱水的耐酸pbi膜

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CN104349834A CN104349834A (zh) 2015-02-11
CN104349834B true CN104349834B (zh) 2016-12-21

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CN201610623848.9A Pending CN106178997A (zh) 2012-05-25 2013-04-24 用于酸性溶剂的渗透蒸发脱水的耐酸pbi膜

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Country Status (7)

Country Link
US (3) US9283523B2 (https=)
EP (2) EP2855000B1 (https=)
JP (2) JP2015518781A (https=)
KR (2) KR20150020594A (https=)
CN (2) CN104349834B (https=)
IN (1) IN2014DN09968A (https=)
WO (1) WO2013176818A1 (https=)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9283523B2 (en) * 2012-05-25 2016-03-15 Pbi Performance Products, Inc. Acid resistant PBI membrane for pervaporation dehydration of acidic solvents
US11959196B2 (en) * 2015-07-06 2024-04-16 Pbi Performance Products, Inc. Phosphonated PBI fiber
US10648107B2 (en) 2016-02-08 2020-05-12 Pbi Performance Products, Inc. Fabric containing PBI-p fiber
BR112018016979B8 (pt) * 2016-02-19 2023-01-10 Alliance Sustainable Energy Sistemas e métodos para produção de nitrilas
GB201609873D0 (en) * 2016-06-06 2016-07-20 Imp Innovations Ltd Process
JP6797632B2 (ja) * 2016-10-20 2020-12-09 オルガノ株式会社 フッ素含有水の処理方法及び処理装置
KR102357048B1 (ko) * 2017-09-15 2022-02-08 다이킨 고교 가부시키가이샤 폴리벤조이미다졸, 그 전구체 폴리아미드 및 그것들의 제조 방법
US11732385B2 (en) 2018-04-30 2023-08-22 Alliance For Sustainable Energy, Llc Emulsion polymerization of nitriles and other compounds
CN114057568B (zh) * 2020-07-29 2024-04-19 三达膜科技(厦门)有限公司 将精对苯二甲酸生产中主装置外排稀醋酸水回收的方法
CN112552512B (zh) * 2020-12-09 2022-11-01 华南师范大学 一种聚苯并咪唑衍生物及其制备方法和金属离子循环吸附的应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4634530A (en) * 1980-09-29 1987-01-06 Celanese Corporation Chemical modification of preformed polybenzimidazole semipermeable membrane
US20030159980A1 (en) * 1999-03-19 2003-08-28 Barss Robert P. Solvent-resistant microporous polybenzimidazole membranes
CN102196856A (zh) * 2009-02-25 2011-09-21 科学与工业研究委员会 用于脱酸的基于聚苯并咪唑的膜
US20110266222A1 (en) * 2010-04-29 2011-11-03 Yan Wang Polybenzimidazole-based membranes for the dehydration of organic liquids via pervaporation

Family Cites Families (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE26065E (en) 1966-07-19 Folybenzimidazoles and their preparation
US4020142A (en) * 1975-08-21 1977-04-26 Celanese Corporation Chemical modification of polybenzimidazole semipermeable
JPS5929003A (ja) 1982-08-09 1984-02-16 Agency Of Ind Science & Technol 半透性を有する高分子膜体
US4506068A (en) * 1983-03-21 1985-03-19 Celanese Corporation Two stage high molecular weight polybenzimidazole production with phosphorus containing catalyst
JPS60106504A (ja) 1983-11-14 1985-06-12 Daicel Chem Ind Ltd 有機物水溶液の膜分離法
JPS61200817A (ja) * 1985-02-28 1986-09-05 Nitto Electric Ind Co Ltd スルホン化ポリスルホン複合半透膜の製造方法
CA1263572A (en) 1984-06-15 1989-12-05 Kenichi Ikeda Sulfonated polysulfone composite semipermeable membranes and process for producing the same
JPS61204009A (ja) * 1985-03-08 1986-09-10 Agency Of Ind Science & Technol 混合液分離用の膜
US4933083A (en) * 1985-04-15 1990-06-12 Hoechst Celanese Corp. Polybenzimidazole thin film composite membranes
US5143526A (en) 1985-10-11 1992-09-01 Sepracor, Inc. Process of treating alcoholic beverages by vapor-arbitrated pervaporation
JPS637803A (ja) * 1986-06-30 1988-01-13 Agency Of Ind Science & Technol 水/有機物分離膜
US4814530A (en) * 1987-09-03 1989-03-21 Hoechst Celanese Corporation Sintered polybenzimidazole article
JPH04110028A (ja) * 1990-08-31 1992-04-10 Daicel Chem Ind Ltd 有機物分離用ポリイミド膜
US5264171A (en) 1991-12-31 1993-11-23 Hoechst Celanese Corporation Method of making spiral-wound hollow fiber membrane fabric cartridges and modules having flow-directing baffles
JPH10309449A (ja) * 1997-05-09 1998-11-24 Daicel Chem Ind Ltd 有機物分離用高分子膜及びその製造方法
US6248469B1 (en) * 1997-08-29 2001-06-19 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
US7550216B2 (en) * 1999-03-03 2009-06-23 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
CA2300519C (en) * 1999-03-19 2008-02-12 Bend Research, Inc. Solvent-resistant microporous polybenzimidazole membranes
DE10117686A1 (de) * 2001-04-09 2002-10-24 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
DE10129458A1 (de) * 2001-06-19 2003-01-02 Celanese Ventures Gmbh Verbesserte Polymerfolien auf Basis von Polyazolen
DE10239701A1 (de) * 2002-08-29 2004-03-11 Celanese Ventures Gmbh Polymerfolie auf Basis von Polyazolen und deren Verwendung
DE10242708A1 (de) * 2002-09-13 2004-05-19 Celanese Ventures Gmbh Protonenleitende Membranen und deren Verwendung
DE10258580A1 (de) * 2002-12-16 2004-06-24 Celanese Ventures Gmbh Hochmolekular Polyazole
US6946015B2 (en) * 2003-06-26 2005-09-20 The Regents Of The University Of California Cross-linked polybenzimidazole membrane for gas separation
DE102004005389A1 (de) * 2004-02-04 2005-08-25 Sartorius Ag Membranen für Brennstoffzellen, Verfahren zur Herstellung der Membranen und Brennstoffzellen unter Verwendung derartiger Membranen
US6997971B1 (en) * 2004-07-28 2006-02-14 The Regents Of The University Of California Cross-linked polybenzimidazole membrane for gas separation
KR100684730B1 (ko) * 2004-10-14 2007-02-20 삼성에스디아이 주식회사 직접 산화형 연료 전지용 고분자 전해질 막, 이의 제조 방법 및 이를 포함하는 직접 산화형 연료 전지 장치
JP4435745B2 (ja) * 2005-03-23 2010-03-24 三洋電機株式会社 燃料電池用電解質、膜電極接合体、および燃料電池用電解質の製造方法
US20080308491A1 (en) * 2005-09-14 2008-12-18 Thomas Haring Electrolyte
US20070087248A1 (en) * 2005-10-18 2007-04-19 Samsung Sdi Co., Ltd. Proton conductive electrolyte membrane, method of preparing the same and fuel cell including the proton conductive electrolyte membrane
KR101366808B1 (ko) * 2007-10-11 2014-02-25 삼성전자주식회사 폴리벤즈이미다졸-염기 복합체, 이로부터 형성된폴리벤조옥사진계 화합물의 가교체 및 이를 이용한연료전지
CN101220164B (zh) * 2007-12-06 2010-06-02 上海交通大学 马来酸酐改性聚苯并咪唑交联膜的制备方法
JP2011150789A (ja) * 2008-05-13 2011-08-04 Sharp Corp 膜電極複合体およびその製造方法
US7950529B2 (en) * 2008-09-30 2011-05-31 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Separation membrane made from blends of polyimides with polyimidazoles
US8561812B2 (en) * 2009-03-27 2013-10-22 Uop Llc Blend polymer membranes comprising thermally rearranged polymers derived from aromatic polyimides containing ortho-positioned functional groups
US8459469B2 (en) * 2009-06-25 2013-06-11 Uop Llc Polybenzoxazole membranes prepared from aromatic polyamide membranes
US20110311901A1 (en) * 2010-05-31 2011-12-22 Basf Se Mechanically stabilized polyazoles
US9006339B2 (en) * 2011-05-10 2015-04-14 Basf Se Mechanically stabilized polyazoles comprising at least one polyvinyl alcohol
US20120305484A1 (en) * 2011-06-03 2012-12-06 Board Of Regents, The University Of Texas System Thermally Rearranged (TR) Polymers as Membranes for Ethanol Dehydration
US20130105383A1 (en) * 2011-10-27 2013-05-02 Nanyang Technological University Nanofiltration-type thin film composite forward osmosis membrane and a method of synthesizing the same
US9283523B2 (en) * 2012-05-25 2016-03-15 Pbi Performance Products, Inc. Acid resistant PBI membrane for pervaporation dehydration of acidic solvents

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4634530A (en) * 1980-09-29 1987-01-06 Celanese Corporation Chemical modification of preformed polybenzimidazole semipermeable membrane
US20030159980A1 (en) * 1999-03-19 2003-08-28 Barss Robert P. Solvent-resistant microporous polybenzimidazole membranes
CN102196856A (zh) * 2009-02-25 2011-09-21 科学与工业研究委员会 用于脱酸的基于聚苯并咪唑的膜
US20110266222A1 (en) * 2010-04-29 2011-11-03 Yan Wang Polybenzimidazole-based membranes for the dehydration of organic liquids via pervaporation

Also Published As

Publication number Publication date
JP2015518781A (ja) 2015-07-06
KR20170098982A (ko) 2017-08-30
EP3653286A1 (en) 2020-05-20
US20130313192A1 (en) 2013-11-28
JP2017039129A (ja) 2017-02-23
US9827532B2 (en) 2017-11-28
IN2014DN09968A (https=) 2015-08-14
USRE46720E1 (en) 2018-02-20
US20160114291A1 (en) 2016-04-28
CN104349834A (zh) 2015-02-11
US9283523B2 (en) 2016-03-15
KR20150020594A (ko) 2015-02-26
EP2855000A4 (en) 2016-03-09
EP2855000B1 (en) 2020-04-01
CN106178997A (zh) 2016-12-07
WO2013176818A1 (en) 2013-11-28
JP6240286B2 (ja) 2017-11-29
EP2855000A1 (en) 2015-04-08
KR101918029B1 (ko) 2018-11-13

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