CN104334599A - 聚异氰脲酸酯泡沫面板的制造 - Google Patents
聚异氰脲酸酯泡沫面板的制造 Download PDFInfo
- Publication number
- CN104334599A CN104334599A CN201380027444.8A CN201380027444A CN104334599A CN 104334599 A CN104334599 A CN 104334599A CN 201380027444 A CN201380027444 A CN 201380027444A CN 104334599 A CN104334599 A CN 104334599A
- Authority
- CN
- China
- Prior art keywords
- polyvalent alcohol
- reaction mixture
- acid
- foams
- total amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006260 foam Substances 0.000 title claims abstract description 79
- 239000011495 polyisocyanurate Substances 0.000 title claims abstract description 46
- 229920000582 polyisocyanurate Polymers 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 103
- 238000000034 method Methods 0.000 claims abstract description 39
- 230000008569 process Effects 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 73
- 239000003063 flame retardant Substances 0.000 claims description 49
- 229920005862 polyol Polymers 0.000 claims description 43
- 229920005906 polyester polyol Polymers 0.000 claims description 42
- 150000003077 polyols Chemical class 0.000 claims description 40
- 125000003118 aryl group Chemical group 0.000 claims description 37
- 239000000126 substance Substances 0.000 claims description 32
- 239000012948 isocyanate Substances 0.000 claims description 26
- 239000003054 catalyst Substances 0.000 claims description 25
- 150000002513 isocyanates Chemical class 0.000 claims description 25
- 239000011541 reaction mixture Substances 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 20
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 19
- 229920003986 novolac Polymers 0.000 claims description 18
- 238000005829 trimerization reaction Methods 0.000 claims description 14
- 238000007711 solidification Methods 0.000 claims description 13
- 230000008023 solidification Effects 0.000 claims description 13
- 239000004088 foaming agent Substances 0.000 claims description 12
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 12
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 11
- 239000004604 Blowing Agent Substances 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 235000019253 formic acid Nutrition 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 230000000977 initiatory effect Effects 0.000 claims description 4
- 239000004616 structural foam Substances 0.000 claims description 3
- 238000009472 formulation Methods 0.000 abstract description 43
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 51
- 150000005846 sugar alcohols Polymers 0.000 description 37
- -1 aromatic polyol Chemical class 0.000 description 32
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 29
- 238000006243 chemical reaction Methods 0.000 description 27
- 239000003795 chemical substances by application Substances 0.000 description 27
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 23
- 150000002148 esters Chemical class 0.000 description 20
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 17
- 229910052757 nitrogen Inorganic materials 0.000 description 17
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 17
- 238000005187 foaming Methods 0.000 description 16
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 15
- 239000004721 Polyphenylene oxide Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 15
- 229920000570 polyether Polymers 0.000 description 15
- 239000000047 product Substances 0.000 description 14
- 239000012973 diazabicyclooctane Substances 0.000 description 12
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 12
- 238000000465 moulding Methods 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 11
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- 239000000654 additive Substances 0.000 description 9
- 230000000996 additive effect Effects 0.000 description 9
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 150000002430 hydrocarbons Chemical class 0.000 description 9
- 239000003999 initiator Substances 0.000 description 9
- 229920001228 polyisocyanate Polymers 0.000 description 9
- 239000005056 polyisocyanate Substances 0.000 description 9
- 239000013543 active substance Substances 0.000 description 8
- 239000012298 atmosphere Substances 0.000 description 8
- 238000011049 filling Methods 0.000 description 7
- 235000011187 glycerol Nutrition 0.000 description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 235000019256 formaldehyde Nutrition 0.000 description 6
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 6
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 5
- 238000001879 gelation Methods 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 5
- 230000009257 reactivity Effects 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 150000003512 tertiary amines Chemical class 0.000 description 5
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 230000006837 decompression Effects 0.000 description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 150000002334 glycols Chemical class 0.000 description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 4
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 4
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 3
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- 150000004702 methyl esters Chemical class 0.000 description 3
- 125000002524 organometallic group Chemical group 0.000 description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- 229960004418 trolamine Drugs 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- YFMFNYKEUDLDTL-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)C(F)(F)F YFMFNYKEUDLDTL-UHFFFAOYSA-N 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-xylenol Chemical compound CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 description 2
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 2
- YQUQWHNMBPIWGK-UHFFFAOYSA-N 4-isopropylphenol Chemical compound CC(C)C1=CC=C(O)C=C1 YQUQWHNMBPIWGK-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 2
- AKNUHUCEWALCOI-UHFFFAOYSA-N N-ethyldiethanolamine Chemical compound OCCN(CC)CCO AKNUHUCEWALCOI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 229920013701 VORANOL™ Polymers 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229920003232 aliphatic polyester Polymers 0.000 description 2
- 150000001409 amidines Chemical class 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 229960002887 deanol Drugs 0.000 description 2
- 150000001983 dialkylethers Chemical class 0.000 description 2
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 2
- 239000012972 dimethylethanolamine Substances 0.000 description 2
- 230000006353 environmental stress Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- CKFGINPQOCXMAZ-UHFFFAOYSA-N methanediol Chemical compound OCO CKFGINPQOCXMAZ-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- 229940059574 pentaerithrityl Drugs 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 description 2
- 229960003656 ricinoleic acid Drugs 0.000 description 2
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
- PBWHJRFXUPLZDS-UHFFFAOYSA-N (1-Ethylpropyl)benzene Chemical compound CCC(CC)C1=CC=CC=C1 PBWHJRFXUPLZDS-UHFFFAOYSA-N 0.000 description 1
- LSFYCRUFNRBZNC-UHFFFAOYSA-N (2-hydroxyphenyl) acetate Chemical compound CC(=O)OC1=CC=CC=C1O LSFYCRUFNRBZNC-UHFFFAOYSA-N 0.000 description 1
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 description 1
- LDTMPQQAWUMPKS-OWOJBTEDSA-N (e)-1-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)\C=C\Cl LDTMPQQAWUMPKS-OWOJBTEDSA-N 0.000 description 1
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 description 1
- ISCYUDAHBJMFNT-UHFFFAOYSA-N 1,1-dichloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C=C(Cl)Cl ISCYUDAHBJMFNT-UHFFFAOYSA-N 0.000 description 1
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- ZWVMLYRJXORSEP-UHFFFAOYSA-N 1,2,6-Hexanetriol Chemical compound OCCCCC(O)CO ZWVMLYRJXORSEP-UHFFFAOYSA-N 0.000 description 1
- ZFDWWDZLRKHULH-UHFFFAOYSA-N 1,2-dimethyl-5,6-dihydro-4h-pyrimidine Chemical compound CN1CCCN=C1C ZFDWWDZLRKHULH-UHFFFAOYSA-N 0.000 description 1
- GIWQSPITLQVMSG-UHFFFAOYSA-N 1,2-dimethylimidazole Chemical compound CC1=NC=CN1C GIWQSPITLQVMSG-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical group C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- AATNZNJRDOVKDD-UHFFFAOYSA-N 1-[ethoxy(ethyl)phosphoryl]oxyethane Chemical compound CCOP(=O)(CC)OCC AATNZNJRDOVKDD-UHFFFAOYSA-N 0.000 description 1
- GEEGPFGTMRWCID-UHFFFAOYSA-N 1-n,1-n,1-n',1-n'-tetramethylbutane-1,1-diamine Chemical compound CCCC(N(C)C)N(C)C GEEGPFGTMRWCID-UHFFFAOYSA-N 0.000 description 1
- AXFVIWBTKYFOCY-UHFFFAOYSA-N 1-n,1-n,3-n,3-n-tetramethylbutane-1,3-diamine Chemical compound CN(C)C(C)CCN(C)C AXFVIWBTKYFOCY-UHFFFAOYSA-N 0.000 description 1
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 1
- JOLVYUIAMRUBRK-UHFFFAOYSA-N 11',12',14',15'-Tetradehydro(Z,Z-)-3-(8-Pentadecenyl)phenol Natural products OC1=CC=CC(CCCCCCCC=CCC=CCC=C)=C1 JOLVYUIAMRUBRK-UHFFFAOYSA-N 0.000 description 1
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- RLYCRLGLCUXUPO-UHFFFAOYSA-N 2,6-diaminotoluene Chemical compound CC1=C(N)C=CC=C1N RLYCRLGLCUXUPO-UHFFFAOYSA-N 0.000 description 1
- HOLHYSJJBXSLMV-UHFFFAOYSA-N 2,6-dichlorophenol Chemical compound OC1=C(Cl)C=CC=C1Cl HOLHYSJJBXSLMV-UHFFFAOYSA-N 0.000 description 1
- RZEWIYUUNKCGKA-UHFFFAOYSA-N 2-(2-hydroxyethylamino)ethanol;octadecanoic acid Chemical compound OCCNCCO.CCCCCCCCCCCCCCCCCC(O)=O RZEWIYUUNKCGKA-UHFFFAOYSA-N 0.000 description 1
- HQIVJIVEUGNTQM-UHFFFAOYSA-N 2-(2-hydroxypropyl)phenol Chemical compound CC(O)CC1=CC=CC=C1O HQIVJIVEUGNTQM-UHFFFAOYSA-N 0.000 description 1
- OHKOAJUTRVTYSW-UHFFFAOYSA-N 2-[(2-aminophenyl)methyl]aniline Chemical compound NC1=CC=CC=C1CC1=CC=CC=C1N OHKOAJUTRVTYSW-UHFFFAOYSA-N 0.000 description 1
- UTNMPUFESIRPQP-UHFFFAOYSA-N 2-[(4-aminophenyl)methyl]aniline Chemical compound C1=CC(N)=CC=C1CC1=CC=CC=C1N UTNMPUFESIRPQP-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- OJPDDQSCZGTACX-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)anilino]ethanol Chemical compound OCCN(CCO)C1=CC=CC=C1 OJPDDQSCZGTACX-UHFFFAOYSA-N 0.000 description 1
- BQBWUVWMUXGILF-UHFFFAOYSA-N 2-anthrol Chemical compound C1=CC=CC2=CC3=CC(O)=CC=C3C=C21 BQBWUVWMUXGILF-UHFFFAOYSA-N 0.000 description 1
- DSYPBKQKCSJRHB-UHFFFAOYSA-N 2-bromo-4-cyclohexylphenol Chemical compound C1=C(Br)C(O)=CC=C1C1CCCCC1 DSYPBKQKCSJRHB-UHFFFAOYSA-N 0.000 description 1
- VADKRMSMGWJZCF-UHFFFAOYSA-N 2-bromophenol Chemical compound OC1=CC=CC=C1Br VADKRMSMGWJZCF-UHFFFAOYSA-N 0.000 description 1
- OQISUJXQFPPARX-UHFFFAOYSA-N 2-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C(Cl)=C OQISUJXQFPPARX-UHFFFAOYSA-N 0.000 description 1
- FZIIBDOXPQOKBP-UHFFFAOYSA-N 2-methyloxetane Chemical compound CC1CCO1 FZIIBDOXPQOKBP-UHFFFAOYSA-N 0.000 description 1
- SYDNSSSQVSOXTN-UHFFFAOYSA-N 2-nitro-p-cresol Chemical compound CC1=CC=C(O)C([N+]([O-])=O)=C1 SYDNSSSQVSOXTN-UHFFFAOYSA-N 0.000 description 1
- FWQNYUYRXNWOOM-UHFFFAOYSA-N 2-nonylpropanedioic acid Chemical compound CCCCCCCCCC(C(O)=O)C(O)=O FWQNYUYRXNWOOM-UHFFFAOYSA-N 0.000 description 1
- OKJQSUPURXTNME-UHFFFAOYSA-N 2-prop-2-enylpent-4-enoic acid Chemical compound C=CCC(C(=O)O)CC=C OKJQSUPURXTNME-UHFFFAOYSA-N 0.000 description 1
- IIVBUJGYWCCLNG-UHFFFAOYSA-N 3-(dimethylamino)propylurea Chemical compound CN(C)CCCNC(N)=O IIVBUJGYWCCLNG-UHFFFAOYSA-N 0.000 description 1
- YLKVIMNNMLKUGJ-UHFFFAOYSA-N 3-Delta8-pentadecenylphenol Natural products CCCCCCC=CCCCCCCCC1=CC=CC(O)=C1 YLKVIMNNMLKUGJ-UHFFFAOYSA-N 0.000 description 1
- WADQOGCINABPRT-UHFFFAOYSA-N 3-chloro-2-methylphenol Chemical compound CC1=C(O)C=CC=C1Cl WADQOGCINABPRT-UHFFFAOYSA-N 0.000 description 1
- BZGBTLYQQQASEF-UHFFFAOYSA-N 3-dodecylbenzene-1,2-disulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC(S(O)(=O)=O)=C1S(O)(=O)=O BZGBTLYQQQASEF-UHFFFAOYSA-N 0.000 description 1
- AXNUJYHFQHQZBE-UHFFFAOYSA-N 3-methylbenzene-1,2-diamine Chemical compound CC1=CC=CC(N)=C1N AXNUJYHFQHQZBE-UHFFFAOYSA-N 0.000 description 1
- HHDUMDVQUCBCEY-UHFFFAOYSA-N 4-[10,15,20-tris(4-carboxyphenyl)-21,23-dihydroporphyrin-5-yl]benzoic acid Chemical compound OC(=O)c1ccc(cc1)-c1c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc([nH]2)c(-c2ccc(cc2)C(O)=O)c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc1[nH]2 HHDUMDVQUCBCEY-UHFFFAOYSA-N 0.000 description 1
- ZMSQJSMSLXVTKN-UHFFFAOYSA-N 4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine Chemical compound C1COCCN1CCOCCN1CCOCC1 ZMSQJSMSLXVTKN-UHFFFAOYSA-N 0.000 description 1
- IWJGMJHAIUBWKT-UHFFFAOYSA-N 4-bromo-2-methylphenol Chemical compound CC1=CC(Br)=CC=C1O IWJGMJHAIUBWKT-UHFFFAOYSA-N 0.000 description 1
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 1
- BRKHZWFIIVVNTA-UHFFFAOYSA-N 4-cyclohexylmorpholine Chemical compound C1CCCCC1N1CCOCC1 BRKHZWFIIVVNTA-UHFFFAOYSA-N 0.000 description 1
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 description 1
- AOFIWCXMXPVSAZ-UHFFFAOYSA-N 4-methyl-2,6-bis(methylsulfanyl)benzene-1,3-diamine Chemical compound CSC1=CC(C)=C(N)C(SC)=C1N AOFIWCXMXPVSAZ-UHFFFAOYSA-N 0.000 description 1
- DGRGLKZMKWPMOH-UHFFFAOYSA-N 4-methylbenzene-1,2-diamine Chemical compound CC1=CC=C(N)C(N)=C1 DGRGLKZMKWPMOH-UHFFFAOYSA-N 0.000 description 1
- FIBBSIRCVZWBML-UHFFFAOYSA-N 4-nitro-2-phenylphenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1C1=CC=CC=C1 FIBBSIRCVZWBML-UHFFFAOYSA-N 0.000 description 1
- BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical class OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 description 1
- 244000226021 Anacardium occidentale Species 0.000 description 1
- AWPKPVHZTWNBGB-UHFFFAOYSA-N C(C)C(C)(P(O)(=O)O)CC.C(C)OP(OCC)(=O)CC Chemical compound C(C)C(C)(P(O)(=O)O)CC.C(C)OP(OCC)(=O)CC AWPKPVHZTWNBGB-UHFFFAOYSA-N 0.000 description 1
- QBTUCBKAWGUMMK-UHFFFAOYSA-N C=CC.[F] Chemical group C=CC.[F] QBTUCBKAWGUMMK-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- JOLVYUIAMRUBRK-UTOQUPLUSA-N Cardanol Chemical compound OC1=CC=CC(CCCCCCC\C=C/C\C=C/CC=C)=C1 JOLVYUIAMRUBRK-UTOQUPLUSA-N 0.000 description 1
- FAYVLNWNMNHXGA-UHFFFAOYSA-N Cardanoldiene Natural products CCCC=CCC=CCCCCCCCC1=CC=CC(O)=C1 FAYVLNWNMNHXGA-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 1
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 1
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- QHWKHLYUUZGSCW-UHFFFAOYSA-N Tetrabromophthalic anhydride Chemical compound BrC1=C(Br)C(Br)=C2C(=O)OC(=O)C2=C1Br QHWKHLYUUZGSCW-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- CUHPVMGLZJHFLC-UHFFFAOYSA-N [Cl].[F].C=CC Chemical group [Cl].[F].C=CC CUHPVMGLZJHFLC-UHFFFAOYSA-N 0.000 description 1
- CQQXCSFSYHAZOO-UHFFFAOYSA-L [acetyloxy(dioctyl)stannyl] acetate Chemical compound CCCCCCCC[Sn](OC(C)=O)(OC(C)=O)CCCCCCCC CQQXCSFSYHAZOO-UHFFFAOYSA-L 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 206010000269 abscess Diseases 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 229950011260 betanaphthol Drugs 0.000 description 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 1
- 150000001621 bismuth Chemical class 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 125000005340 bisphosphate group Chemical group 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- RGTXVXDNHPWPHH-UHFFFAOYSA-N butane-1,3-diamine Chemical compound CC(N)CCN RGTXVXDNHPWPHH-UHFFFAOYSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- PTFIPECGHSYQNR-UHFFFAOYSA-N cardanol Natural products CCCCCCCCCCCCCCCC1=CC=CC(O)=C1 PTFIPECGHSYQNR-UHFFFAOYSA-N 0.000 description 1
- 235000020226 cashew nut Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000004786 cone calorimetry Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 238000006006 cyclotrimerization reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 229940106012 diethylene glycol adipate Drugs 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- WOZUGDXHVLSOHV-UHFFFAOYSA-L dodecanoate tin(4+) Chemical compound [Sn+4].C(CCCCCCCCCCC)(=O)[O-].C(CCCCCCCCCCC)(=O)[O-].[Sn+4] WOZUGDXHVLSOHV-UHFFFAOYSA-L 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- HCPOCMMGKBZWSJ-UHFFFAOYSA-N ethyl 3-hydrazinyl-3-oxopropanoate Chemical compound CCOC(=O)CC(=O)NN HCPOCMMGKBZWSJ-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000023597 hemostasis Effects 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- SVTBMSDMJJWYQN-UHFFFAOYSA-N hexylene glycol Natural products CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 125000001261 isocyanato group Chemical group *N=C=O 0.000 description 1
- 229910052743 krypton Inorganic materials 0.000 description 1
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000004620 low density foam Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- QATBRNFTOCXULG-UHFFFAOYSA-N n'-[2-(methylamino)ethyl]ethane-1,2-diamine Chemical compound CNCCNCCN QATBRNFTOCXULG-UHFFFAOYSA-N 0.000 description 1
- SWVGZFQJXVPIKM-UHFFFAOYSA-N n,n-bis(methylamino)propan-1-amine Chemical compound CCCN(NC)NC SWVGZFQJXVPIKM-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 150000002883 o-cresols Chemical class 0.000 description 1
- 125000005474 octanoate group Chemical group 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-M oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC([O-])=O ZQPPMHVWECSIRJ-KTKRTIGZSA-M 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- FGFWCOVNCKWNLU-UHFFFAOYSA-N oxalic acid;tin Chemical compound [Sn].OC(=O)C(O)=O FGFWCOVNCKWNLU-UHFFFAOYSA-N 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- 239000013500 performance material Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- 150000003008 phosphonic acid esters Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- WQKGAJDYBZOFSR-UHFFFAOYSA-N potassium;propan-2-olate Chemical compound [K+].CC(C)[O-] WQKGAJDYBZOFSR-UHFFFAOYSA-N 0.000 description 1
- 239000010909 process residue Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- ADRDEXBBJTUCND-UHFFFAOYSA-N pyrrolizidine Chemical compound C1CCN2CCCC21 ADRDEXBBJTUCND-UHFFFAOYSA-N 0.000 description 1
- SBYHFKPVCBCYGV-UHFFFAOYSA-N quinuclidine Chemical compound C1CC2CCN1CC2 SBYHFKPVCBCYGV-UHFFFAOYSA-N 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 229940066675 ricinoleate Drugs 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical class [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- REZQBEBOWJAQKS-UHFFFAOYSA-N triacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO REZQBEBOWJAQKS-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- 239000002699 waste material Chemical group 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/12—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
- B29C44/1228—Joining preformed parts by the expanding material
- B29C44/1233—Joining preformed parts by the expanding material the preformed parts being supported during expanding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3403—Foaming under special conditions, e.g. in sub-atmospheric pressure, in or on a liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3415—Heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/38—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
- B29C44/42—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length using pressure difference, e.g. by injection or by vacuum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
- C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/14—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
- C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1816—Catalysts containing secondary or tertiary amines or salts thereof having carbocyclic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4027—Mixtures of compounds of group C08G18/54 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
- C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
- C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
- C08G18/4213—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from terephthalic acid and dialcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
- C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
- C08G18/4252—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids derived from polyols containing polyether groups and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4829—Polyethers containing at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/487—Polyethers containing cyclic groups
- C08G18/4879—Polyethers containing cyclic groups containing aromatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/487—Polyethers containing cyclic groups
- C08G18/4883—Polyethers containing cyclic groups containing cyclic groups having at least one oxygen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/54—Polycondensates of aldehydes
- C08G18/542—Polycondensates of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/54—Polycondensates of aldehydes
- C08G18/546—Oxyalkylated polycondensates of aldehydes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/794—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aromatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0004—Use of compounding ingredients, the chemical constitution of which is unknown, broadly defined, or irrelevant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0019—Use of organic additives halogenated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0038—Use of organic additives containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/125—Water, e.g. hydrated salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/35—Composite foams, i.e. continuous macromolecular foams containing discontinuous cellular particles or fragments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
- B29K2105/0026—Flame proofing or flame retarding agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2009/00—Layered products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0058—≥50 and <150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2120/00—Compositions for reaction injection moulding processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/02—CO2-releasing, e.g. NaHCO3 and citric acid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/10—Water or water-releasing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/184—Binary blends of expanding agents of chemical foaming agent and physical blowing agent, e.g. azodicarbonamide and fluorocarbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/20—Ternary blends of expanding agents
- C08J2203/204—Ternary blends of expanding agents of chemical foaming agent and physical blowing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Composite Materials (AREA)
- Polyurethanes Or Polyureas (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
本发明公开了通过不连续法制备面板。面板通过在减压下将形成聚异氰脲酸酯泡沫体的组合物注射进模具空腔来制备。某些形成聚异氰脲酸酯泡沫体的制剂和模具空腔中的减压的组合使得能够在不连续法中制备所得夹芯板,其中制得的面板的特征在于改善的阻燃性。
Description
背景技术
聚异氰脲酸酯泡沫体通常如下制备:使化学计量过量的多异氰脲酸酯与多元醇或多元醇混合物在催化剂、发泡剂、和通常其它任选的添加剂如表面活性剂等的存在下反应。聚异氰脲酸酯泡沫体通常按150至500的异氰酸酯指数制备;本申请使用的术语异氰酸酯指数是相对于异氰酸酯的与所有活性H的(1:1)反应的理论量而言过量的异氰酸酯且表示为百分比的术语(即,1:1=100)。
与聚氨酯泡沫体相比,聚异氰脲酸酯(PIR)泡沫体、特别是具有高指数(即,指数高于250,更优选高于300)的那些表现出改善的热稳定性和阻燃性能。它们较好的阻燃性能是由于存在异氰脲酸酯环,该环是由异氰酸酯的环三聚反应形成的。对于给定的多元醇制剂,异氰酸酯过量的量(表示为异氰酸酯指数)越高,聚合物泡沫体主链中的异氰脲酸酯环相比氨基甲酸酯和/或脲键的相对浓度越高,而阻燃性能也将越好。这是以下事实的实际结果:相比于氨基甲酸酯键,与类芳族异氰脲酸酯三聚物结构相连的较高键能。
因此,这样的聚异氰脲酸酯泡沫体在制造用于建筑行业的夹芯板中广泛用作绝缘材料。通常,这些泡沫体是闭孔的、硬质低密度泡沫体,其在泡孔中包含低传导性气体例如氢氟烃(HFC)或烃。
具有PIR-泡沫体芯的夹芯板现今最常用连续法制备。连续层压法的制造特征(包括反应混合物在面板宽度上的分布,快速的反应性等)可允许在PIR泡沫体化学方面具有较大的范围,包括使用高指数制剂和/或高含量的高粘性芳族多元醇。这种化学方面的多变性由此使得能够获得优越的泡沫体阻燃性质,甚至是在使用烃发泡剂和无卤素阻燃剂的情况下也是如此。
对于某些应用,期望使用不连续法,因为其在设计沿外围的边缘时更多样,例如在生产具有原地发泡的锁闭装置(foamed-in-place locking device)和密封带的冷库(walk-in cooler)中。这样的面板容易就地组装。这样的夹芯板通常如下提供:在用于保持泡沫体以及锁闭装置和密封带的外围框架内将两个隔开的外壳(由铁板或其它适当的材料制成)排布在压机或夹具的平面之间,将聚异氰脲酸酯反应混合物与发泡剂例如戊烷依次进料到面板的限定的发泡空腔内。但是,在不连续闭合模具注射法中难以使用PIR泡沫体化学,这是由于差的流动性(高的应用密度(applied densities))、差的粘合强度等。已经努力尝试改善一些特性,例如拉伸粘合强度,如WO 2010/114695A1中公开的通过使用脂族聚酯进行,但是代价是其它特性较差,例如较差的阻燃性能。
由于高指数聚异氰脲酸酯制剂(特别是当包含高含量的粘性芳族聚酯时)流动和填充不连续面板的发泡空腔的能力较差,这样的面板通常需要某些额外装载的聚异氰脲酸酯反应性混合物(过填充),以便于完全充满发泡空腔以及使物料适当分布,从而得到具有适当机械性能和热性能的泡沫体。而且,在泡沫体膨胀阶段结束时,需将面板在压机或夹具的平面之间保持长的时间段以对抗聚异氰脲酸酯物料在发泡期间施加的推力,因此过早取出面板可能导致不可接受的聚异氰脲酸酯泡沫体芯的后膨胀和凸出。
现在已知,将模具空腔的压力降至低于大气压对填充过程具有正面影响。例如,WO 2007/058793和EP 0854025都证实可使用真空/低于大气压压力注射技术生产改善的聚氨酯泡沫体。该方法可均匀填充模具空腔,因此避免出现空隙,并且也可以使待注射的聚氨酯混合物的量与不存在减压的情况相比较低。Taverna等人的综述“Sandwich Panels:Innovative Solutions usingVacuum-assisted Foam Injection”(Cannon at UTECH 2000)陈述了真空/低于大气压压力注射技术也用于生产聚异氰脲酸酯夹芯板。
但是,仍需要改善的方法来使用不连续法制备夹芯板,其具有的泡沫体性能特性类似于目前用连续法可得到的那些性能特性;特别地,夹芯板具有改善的阻燃性能,而仍能保持良好的与面(facers)的粘合。
发明内容
本发明的目的如下实现:将适当量的芳族聚酯多元醇结合到包括阻燃剂的多元醇制剂中,在降低的大气压力下将多元醇制剂、异氰酸酯和发泡剂注射进闭合的面板模具中。构造模具的边缘,使得成品面板具有允许容易组装的沿外围的边缘。
第一方面,本发明提供制备聚异氰脲酸酯泡沫体的方法,包括:
A)将反应混合物注射进闭合的模具空腔,其中所述模具空腔处于300至950毫巴的绝压下,所述反应混合物包含以下组分:
a)有机多异氰酸酯;
b)多元醇混合物,其中所述多元醇混合物包含芳族聚酯多元醇,其中所述芳族聚酯多元醇占多元醇总量的至少35wt%;
c)三聚催化剂;
d)至少一种阻燃剂;
e)任选的辅助物质;和
f)发泡剂组分,
其中所述反应混合物的异氰酸酯指数大于250;和
B)固化以形成聚异氰脲酸酯泡沫体。
第二方面,本发明提供制备结构夹芯板或自支承夹芯板的方法,该夹芯板具有两个外壳和一个粘接于所述外壳的中间的聚异氰脲酸酯泡沫体芯,所述方法包括:
A)将反应混合物注射进闭合的模具空腔,其中所述模具空腔处于300至950毫巴的绝压下,所述反应混合物包含以下组分:
a)有机多异氰酸酯;
b)多元醇混合物,其中所述多元醇混合物包含芳族聚酯多元醇,其中所述芳族聚酯多元醇占多元醇总量的至少35wt%;
c)三聚催化剂;
d)至少一种阻燃剂;
e)任选的辅助物质;和
f)发泡剂组分,
其中所述闭合的模具空腔由两个外壳和一个环形框架限定,其中所述反应混合物的异氰酸酯指数大于250;和
B)固化以形成粘接于所述外壳的聚异氰脲酸酯泡沫体。
本发明也是根据第一方面的方法制备的聚异氰脲酸酯泡沫体,其中所述PIR泡沫体芯由包含以下组分的反应混合物制备:
a)有机多异氰酸酯;
b)多元醇混合物,其中所述多元醇混合物包含大于35重量%的芳族聚酯多元醇和10至65重量%线型酚醛清漆引发的多元醇,基于多元醇的总重量;
c)至少一种固化和/或发泡催化剂;
d)至少一种三聚催化剂;
e)至少一种阻燃剂;
f)任选的至少一种有机硅表面活性剂;
g)至少一种选自水和甲酸的化学发泡剂;和
h)戊烷,
其中所述反应混合物的异氰酸酯指数大于250。
本发明也是根据第二方面的方法制备的夹芯板,其包括两个外壳和一个中间的聚异氰脲酸酯结构泡沫体芯,其中所述PIR泡沫体芯由包含以下组分的反应混合物制备:
a)有机多异氰酸酯;
b)多元醇混合物,其中所述多元醇混合物包含大于35重量%的芳族聚酯多元醇和10至65重量%线型酚醛清漆引发的多元醇,基于多元醇的总重量;
c)至少一种固化和/或发泡催化剂;
d)至少一种三聚催化剂;
e)至少一种阻燃剂;
f)任选的至少一种有机硅表面活性剂;
g)至少一种选自水和甲酸的化学发泡剂;和
h)戊烷,
其中所述反应混合物的异氰酸酯指数大于250。
在进一步的实施方式中,上述实施方式中的阻燃剂是无卤素阻燃剂。
具体实施方式
用于本发明上下文的各种术语具有以下含义:
多元醇混合物:多元醇混合物是用于制备PIR泡沫体的多元醇的共混物。
多元醇制剂:多元醇混合物与任何添加剂的组合,所述添加剂例如为催化剂、阻燃剂、表面活性剂和化学发泡剂,但是不包括物理发泡剂。
压力:本申请使用的模具内的减压是指具有单位毫巴(或hPa)的绝压。基准压力为1000毫巴=1000hPa=海平面处约1个大气压=0巴表压。尽管可参考海平面处的大气压,但是应该理解表压将比测得的大气压低至少50毫巴。为进一步说明,海平面处800至950毫巴的绝压近似于-50至-200毫巴的表压。
在聚合空腔内保持的低内部压力有助于聚异氰脲酸酯反应性混合物更均匀地填充可用空间,因此可降低所需的过填充以及所带来的在压机平面上的额外压力。在本发明中,由于多元醇或异氰酸酯的类型和/或较快反应的体系,可能加工较粘性的组分。本发明也可以减少物理发泡剂的绝对含量,这可降低聚异氰脲酸酯制剂成本,特别是当使用新开发的发泡剂例如氢氟烯烃(hydro-fluoroolefin)时以及当在弃置包含这样的泡沫体的制品后降低挥发性有机化合物的释放量。
组合物包含在下文更详细描述的各种组分。
关于本发明任何方面描述的所有特征可以用于本发明的任何其它方面。
用于本发明的适宜的多异氰酸酯是脂族、脂环族、芳基脂族、芳族的多异氰酸酯及其衍生物。这样的衍生物包括脲基甲酸酯、缩二脲和NCO封端的预聚物。优选芳族异氰酸酯、特别是芳族多异氰酸酯。优选使用芳族二异氰酸酯,例如甲苯二异氰酸酯(TDI)的异构体,粗制TDI,二苯基甲烷二异氰酸酯的异构体,和较高官能的聚亚甲基聚苯基多异氰酸酯(pMDI)。
异氰酸酯和粗制多异氰酸酯以及MDI和TDI预聚物的混合物、及其与聚合MDI和单体MDI的共混物也可用于本发明的实践。用于制备本发明泡沫体的多异氰酸酯的总量应该足以提供250至500的异氰酸酯反应指数。优选地,该指数为300至450。更优选地,该指数为300至400。100的异氰酸酯反应指数对应于一个异氰酸酯基团/存在(例如来自水和多元醇混合物)的异氰酸酯反应性氢原子。
在某些实施方式中,多异氰酸酯是聚合MDI产品,其为聚亚甲基聚亚苯基多异氰酸酯在单体MDI中的混合物,其平均异氰酸酯官能度为2.5至3.3个异氰酸酯基团/分子且异氰酸酯当量为130至170。适宜的可商购的该类型产品包括PAPITM27,VoranateTMM229,VoranateTM220,VoranateTMM595和VoranateTMM600,Voranate M647,全部购自The Dow Chemical Company。
在本发明中,可以优选使用在25℃测得的粘度为至多2,000cps的异氰酸酯。
本发明的多元醇混合物包含芳族聚酯多元醇。芳族聚酯多元醇基于至少一种芳族组分和至少一种多元醇组分的酯交换产物。
如本申请使用,"芳族"表示具有至少一个由交替单键和双键构成的共轭环的有机化合物,这赋予化合物整体稳定性。本申请使用的术语"聚酯多元醇"包括任何较少量的未反应的化合物,例如,在聚酯多元醇的制备之后剩余的多元醇化合物。优选地,芳族组分基于:基于邻苯二甲酸的物质,例如邻苯二甲酸酐,邻苯二甲酸,间苯二甲酸,对苯二甲酸,邻苯二甲酸的甲酯、间苯二甲酸的甲酯、或对苯二甲酸的甲酯,对苯二甲酸二甲酯,偏苯三甲酸酐,均苯四甲酸二酐,或其混合物。尽管芳族聚酯多元醇可以由基本上纯的反应物原料制备,但是较复杂的起始原料例如聚对苯二甲酸乙二醇酯可能是有利的。其它残留物是对苯二甲酸二甲酯(DMT)工艺残留物,它们是来自DMT的制备的废物或废料残留物。
适宜的多元醇组分是分子量为60至1000的那些。在进一步的实施方式中,分子量小于800,小于600,或甚至小于500。在进一步的实施方式中,分子量小于400。适宜的多元醇化合物例如二醇类的实例包括乙二醇,丙二醇,二甘醇(DEG),一缩二丙二醇,三甘醇;聚乙二醇(PEG)和聚丙二醇。
通常,芳族组分占最终聚酯多元醇的至少20wt%、23wt%、25wt%、或至少28wt%。在进一步的实施方式中,芳族组分占聚酯多元醇的小于50wt%、45wt%、40wt%、或小于35wt%。聚酯多元醇的剩余重量百分比为多元醇组分。
在一种实施方式中,聚酯多元醇基于对苯二甲酸、DEG和PEG,如公开于专利公开WO2010/015642。
聚酯多元醇通过芳族组分和多元醇组分在本领域公知条件下的缩聚/酯交换反应和聚合反应形成。例如,参见,G.Oertel,Polyurethane Handbook,Carl Hanser Verlag,Munich,Germany 1985,pp 54-62;和Mihail Ionescu,Chemistry and Technology of Polyols for Polyurethanes,Rapra Technology,2005,pp 263-294。通常,反应在180至280℃的温度进行。在另一种实施方式中,反应在至少200℃的温度进行。在进一步的实施方式中,反应在215℃或更高的温度进行。在进一步的实施方式中,酯交换在260℃或更低的温度进行。
尽管反应可以在降低或增加的压力进行,但是反应通常在接近大气压的条件进行。
芳族化合物和多元醇化合物通常按一定比率反应,使得得到的芳族聚酯多元醇的羟值为150mg KOH/g至400mg KOH/g,优选为175mg KOH/g至300mgKOH/g,在进一步的实施方式中为200mg KOH/g至250mg KOH/g。
芳族聚酯多元醇优选用量为占多元醇混合物总量的至少35wt%,优选地,芳族聚酯多元醇占多元醇总量的至少40wt%,更优选地,芳族聚酯多元醇占多元醇总量的至少50wt%。在一些实施方式中,芳族聚酯多元醇占多元醇总量的至少60wt%。芳族聚酯多元醇优选占多元醇总量的小于90wt%;优选地,芳族聚酯多元醇占多元醇总量的小于80wt%。
在本发明的特定实施方式中,除了聚酯多元醇之外,线型酚醛清漆型聚醚多元醇也可用于多元醇混合物。
线型酚醛清漆型聚醚多元醇是酚醛树脂的烷氧基化产物。线型酚醛清漆树脂通过将苯酚和甲醛在酸催化剂的存在下缩合来制备。线型酚醛清漆多元醇的生产方法是本领域已知的,如描述于,例如,美国专利2,838,473;2,938,884;3,470,118;3,686,101;和4,046,721。
通常,线型酚醛清漆树脂反应的适宜的酸性催化剂包括草酸,乙酸锌,盐酸,冰醋酸,盐酸,硫酸或其组合。缩合反应通常在60至160℃的反应温度进行。
可用于制备线型酚醛清漆引发剂的酚类包括:邻-甲酚,间-甲酚,或对-甲酚,乙基苯酚,腰果酚(包括得自腰果的那些),壬基苯酚,对-苯基苯酚,2,2-二(4-羟基苯酚)丙烷,β-萘酚,β-羟基蒽,对-氯苯酚,邻-溴苯酚,2,6-二氯-苯酚,对-硝基苯酚,4-硝基-6-苯基苯酚,2-硝基-4-甲基苯酚,3,5-二甲基苯酚,对-异丙基苯酚,2-溴-4-环己基苯酚,4-叔丁基苯酚,2-甲基-4-溴苯酚,2-(2-羟基丙基)苯酚,2-(4-羟基苯酚)乙醇,2-乙酸基苯酚,4-氯-甲基苯酚,及其混合物。特别优选的是,用于制备线型酚醛清漆型聚醚多元醇的酚类可以是未取代的。
尽管甲醛或其衍生物例如三聚甲醛通常用作醛反应物,但是也可以使用乙醛、丙醛或丁醛。
通常,线型酚醛清漆起始原料如下制备:使酚(例如,甲酚)与约0.8至约1.0摩尔甲醛/摩尔酚在酸性催化剂的存在下反应,从而形成多核缩合产物,该产物包含2.1至12个酚单元/分子、优选2.2至6个酚单元/分子、更优选2.5至5个酚单元/分子。
然后线型酚醛清漆树脂与环氧烷烃例如环氧乙烷、环氧丙烷、环氧丁烷、或甲基环氧丙烷反应,从而将分子量构建到所需水平。通常,最终多元醇具有的分子量期望地为约300至约1500,在某些非限制性实施方式中为约400至约1000。优选的线型酚醛清漆多元醇是下述那些,其平均每分子具有3至6个羟基部分,且平均羟值为约100至约500mg KOH/g、优选为约100至约300mg KOH/g。
线型酚醛清漆多元醇优选的用量为占多元醇混合物总量的至少10wt%,优选地,线型酚醛清漆多元醇占多元醇总量的至少15wt%,更优选地,线型酚醛清漆多元醇占多元醇总量的至少20wt%,更优选地,线型酚醛清漆多元醇占多元醇混合物总量的至少30wt%。线型酚醛清漆多元醇优选占多元醇总量的小于65wt%,优选地,线型酚醛清漆多元醇占多元醇总量的小于60wt%,在进一步的实施方式中,占多元醇混合物总量的小于50wt%。
本发明的多元醇混合物也可以包含不同于以上所需芳族聚酯和线型酚醛清漆多元醇的一种或多种多元醇。另外的多元醇的实例包括聚醚多元醇和脂族聚酯。
另外的聚醚多元醇可以是聚环氧丙烷、聚环氧乙烷或其组合,它们或为嵌段共聚物或为无规共聚物。这样的多元醇的引发剂包括,例如,多元醇,例如,甘油,季戊四醇,乙二醇,1,2-丙二醇和1,3-丙二醇,二甘醇,一缩二丙二醇,1,4-丁二醇,1,6-己二醇,三羟甲基丙烷,例如,和糖例如山梨糖醇、蔗糖、葡萄糖、果糖或其它糖。多元醇也可以由引发剂的混合物例如高官能度起始物(starter)(山梨糖醇/蔗糖)和较低官能度起始物如甘油的混合物形成,得到官能度为3至5且优选羟值为300至550mg KOH/g的共引发的多元醇。其它多元醇可以选自含脂族胺的化合物和含芳族胺的化合物两者。这样的引发剂分子的实例包括具有1至4个碳原子的脂族和芳族的、未取代或N-单烷基取代、N,N-二烷基取代和N,N’-二烷基取代的二胺。烷基胺引发剂的实例包括未取代或单烷基取代或二烷基取代的乙二胺,二亚乙基三胺,三亚乙基四胺,1,3-丙二胺,1,3-丁二胺和1,4-丁二胺,1,2-六亚甲基二胺,1,3-六亚甲基二胺,1,4-六亚甲基二胺,1,5-六亚甲基二胺和1,6-六亚甲基二胺。包含芳族胺的引发剂的实例包括苯胺,苯二胺,2,3-甲苯二胺,2,4-甲苯二胺,3,4-甲苯二胺和2,6-甲苯二胺,和4,4’-二氨基二苯基甲烷,2,4’-二氨基二苯基甲烷和2,2’-二氨基二苯基甲烷。
其它适宜的引发剂分子是链烷醇胺,例如,乙醇胺,N-甲基-乙醇胺和N-乙基乙醇胺;二链烷醇胺,例如,二乙醇胺,N-甲基-二乙醇胺和N-乙基二乙醇胺;和三链烷醇胺,例如,三乙醇胺。
可用的另一类基于芳族的聚醚多元醇是酚/甲醛/链烷醇胺树脂的环氧烷烃加合物,常称为“Mannich”多元醇,如公开于美国专利4,883,826;4,939,182;和5,120,815。
可用的基于酚的多元醇的一个实例是双酚A的烷氧基化产物。双酚A通过丙酮与两个酚的缩合产物制备。
如果存在,聚醚多元醇(不包括线型酚醛清漆引发的多元醇)的用量为占多元醇混合物总量的至少2wt%。聚醚多元醇的存在量可以为占多元醇总量的至少5wt%、占多元醇总量的至少10wt%、或占多元醇总量的至少20wt%。聚醚多元醇优选占多元醇总量的小于55wt%;优选地,聚醚多元醇占多元醇总量的小于50wt%,更优选地,聚醚多元醇占多元醇总量的小于45wt%。
当使用时,聚醚多元醇的羟值为20mg KOH/g至700mg KOH/g,更优选为25mg KOH/g至700mg KOH/g。
本发明的多元醇混合物也可以包含一种或多种脂族聚酯多元醇。
说明性的脂族聚酯多元醇可以由具有2至12个碳原子的有机二羧酸和具有2至12个碳原子、优选2至8、更优选2至6个碳原子的多元醇(优选二醇)制备。二羧酸的实例是琥珀酸,戊二酸,己二酸,辛二酸,壬二酸,癸二酸,癸烷二甲酸,丙二酸,庚二酸,2-甲基-l,6-己酸,十二烷二酸,马来酸和富马酸。这些酸可以单独使用或作为混合物使用。二元醇和多元醇的实例包括乙二醇,二甘醇,亚甲基二醇,1,2-丙二醇和1,3-丙二醇,一缩二丙二醇,1,4-丁二醇和其它丁二醇,1,5-戊二醇和其它戊二醇,1,6-己二醇,1,10-癸烷二醇,甘油,和三羟甲基丙烷。聚酯多元醇的实例是聚(己二酸己二醇酯),聚(己二醇丁二醇酯),聚(己二酸乙二醇酯),聚(己二酸二甘醇酯),聚(草酸己二醇酯),聚(癸二酸乙二醇酯)等。
如果存在,聚酯多元醇优选占多元醇总量的至少1wt%,优选地聚酯多元醇占多元醇总量的至少2wt%,更优选地聚酯多元醇占多元醇总量的至少5wt%。聚酯多元醇优选占多元醇总量的小于55wt%;优选地聚酯多元醇占多元醇总量的小于50wt%,更优选地聚酯多元醇占多元醇总量的小于45wt%。
多元醇混合物的羟值通常为100mg KOH/g至400mg KOH/g。优选地,该羟值为150mg KOH/g至350mg KOH/g,更优选为200mg KOH/g至30mg KOH/g。
多元醇混合物形成多元醇制剂的主要部分。优选的是,多元醇混合物占多元醇制剂的30至95wt%,优选占40至85wt%,更优选占45至80wt%。
多元醇制剂的其余部分由催化剂、交联剂、增链剂、表面活性剂、填料、阻燃剂、化学发泡剂和其它添加剂构成。
在本发明的优选实施方式中,提供一种或多种催化剂。
聚异氰脲酸酯催化剂提供三种主要目的,即,用作固化催化剂、发泡催化剂和三聚催化剂。本发明使用至少一种三聚催化剂。优选的是,本发明的催化包提供至少一种另外的固化或发泡催化剂。进一步优选的是,全部三种催化剂类型都存在。包含三聚催化剂意在使异氰脲酸酯环形成,对于反应到燃烧性质是必要的,而使用其它提及的催化剂类型必须进行微调,以便于得到所需的反应概况和最佳的加工性能,提供的作为反应性参数的胶凝时间大于50秒,在借助于高压发泡机器在典型环境温度(20-25℃)注塑的泡沫体上测量。
三聚催化剂能够促进异氰酸酯在其本身上的反应。三聚催化剂的实例包括三(二烷基氨基烷基)-s-六氢三嗪,例如1,3,5-三(N,N-二甲基氨基丙基)-s-六氢三嗪;醋酸钾,乙基己酸钾;四烷基氢氧化铵,例如四甲基氢氧化铵;碱金属氢氧化物,例如氢氧化钠;碱金属醇盐,例如甲醇钠和异丙醇钾;和具有10至20个碳原子以及在一些实施方式中具有悬垂羟基的长链脂肪酸的碱金属盐。可商购的三聚催化剂的实例包括DABCOTMTMR-30;DABCOTMK-2097,POLYCATTM41,POLYCATTM43,POLYCATTM46,DABCOTMTMR,CURITHANETM52,DABCO K15。
三聚催化剂优选占多元醇制剂总量的至少0.3wt%,优选占多元醇制剂总量的至少0.6wt%,更优选占多元醇制剂总量的至少0.7wt%。另外,三聚催化剂优选占多元醇制剂总量的小于5wt%,优选占多元醇制剂总量的小于4wt%,更优选占多元醇制剂总量的小于3wt%。
这些催化剂的一些是固体或晶体,并且可以溶解于适当的溶剂中,所述溶剂可以是多元醇、水、一缩二丙二醇或可与聚异氰脲酸酯发泡组合物相容的任何其它载体。
尽管已知一些催化剂可以促进发泡和固化两者(所谓的“平衡”催化剂),但是它们的区别通常在于:它们是倾向利于发泡反应(脲或水和异氰酸酯反应)(在发泡催化剂的情况下),还是它们倾向于利于固化反应(氨基甲酸酯或多元醇和异氰酸酯反应)(在固化催化剂的情况下)。在一些非限制性实施方式中,可以针对其偏向的趋势(例如,固化)选择技术上可以催化发泡和固化两者的催化剂,并将其与较为指向其它目的(例如,发泡)的另一种催化剂组合,反之亦然。
可倾向于偏向脲反应的适宜发泡催化剂的实例是短链叔胺或包含至少一个氧原子的叔胺,并且可以包括二(2-二甲基氨基乙基)醚;无甲基二亚乙基三胺,三乙胺,三丁胺,N,N-二甲基氨基丙胺,二甲基乙醇胺,或N,N,N’,N’-四-甲基乙二胺。在一种实施方式中,二(二甲基氨基乙基)醚和一缩二丙二醇的组合可以是有效的发泡催化剂,例如,它们按70/30wt%的比率的催化剂。也可以选择上述任何物质的组合。
增加发泡催化剂的量,从而得到至少50秒的胶凝时间。调整催化剂含量以获得所需胶凝时间是本领域技术人员已知的。通常,发泡催化剂占多元醇制剂总量的至少0.1wt%,优选占多元醇制剂总量的至少0.15wt%,更优选占多元醇制剂总量的至少0.2wt%。另外,发泡催化剂优选占多元醇制剂总量的小于0.4wt%。
可倾向于偏向氨基甲酸酯反应的适宜固化催化剂的实例通常包括,脒,叔胺,金属有机化合物,及其组合。这些可以包括但不限于,脒,例如1,8-二氮杂双环[5.4.0]十一碳-7-烯和2,3-二甲基-3,4,5,6-四氢嘧啶,以及它们的盐。
金属有机化合物可以包括有机锡化合物,例如有机羧酸的锡(II)盐,例如,二乙酸锡(II),二辛酸锡(II),二乙基己酸锡(II),和二月桂酸锡(II),以及有机羧酸的二烷基锡(IV)盐,例如,二乙酸二丁基锡,二月桂酸二丁基锡,马来酸二丁基锡和二乙酸二辛基锡。也可以选择有机羧酸的铋盐,例如,辛酸铋。可以选择金属有机化合物以单独使用或组合使用,或者在一些实施方式中与一种或多种上文列出的高碱性胺组合使用。
如果存在,固化催化剂通常占多元醇制剂总量的至少0.05wt%,优选占多元醇制剂总量的至少0.1wt%。另外,固化催化剂通常占多元醇制剂总量的小于0.4wt%,优选占多元醇制剂总量的小于0.3wt%。
能够促进发泡反应和固化反应两者的催化剂的实例是叔胺,例如三乙胺,三丁胺,二甲基苄基胺,N-甲基-吗啉,N-乙基-吗啉,和N-环己基吗啉,N,N,N’,N’-四-甲基乙二胺,N,N,N’,N’-四甲基丁二胺和N,N,N’,N’-四甲基己二胺,四甲基二氨基乙基醚,二(二甲基氨基丙基)脲,二甲基哌嗪,二甲基环己基胺,1,2-二甲基-咪唑,1-氮杂-双环[3.3.0]辛烷,三亚乙基二胺(TEDA)。
用于发泡反应和固化反应两者的另一类催化剂是链烷醇胺化合物,例如也可以选择三乙醇胺,三异丙醇胺,N-甲基-二乙醇胺和N-乙基-二乙醇胺,和二甲基乙醇胺。也可以有效使用任何上述物质的组合。
可商购的发泡、固化或发泡/固化催化剂的实例包括NIAX A-4,NIAXA6,POLYCAT 6,POLYCAT 5,POLYCAT 8,Niax A1;POLYCAT 58,DABCOT,DABCO NE 300,TOYOCAT RX 20,DABCO DMDEE,JEFFCAT ZR 70,DABCOTM33 LV,NIAX A-33,DABCO R-8020,NIAX TMBDA,POLYCAT77,POLYCAT 6,POLYCAT 9,POLYCAT 15,JEFFCAT ZR 50,TOYOCATNP,TOYOCAT F94,DABCO NEM等。POLYCAT和DABCO催化剂购自Air Products;TOYOCAT催化剂购自Tosho Corporation;NIAX催化剂购自Momentive Performance Material;JEFFCAT催化剂购自Huntsman。
为固体或晶体的这些催化剂的一些溶解于适当的溶剂中,所述溶剂可以是多元醇、水、发泡剂、DPG或可与形成聚异氰脲酸酯泡沫体的组分相容的任何载体。
在本发明一种特定的实施方式中,在不考虑溶剂的情况下,催化剂的总量为0.6至5wt%,优选为0.7至4wt%,更优选为0.8至3wt%,基于多元醇制剂的重量。
正如本领域技术人员已知,催化剂的量可以根据物料的温度变化。
根据本发明的方法,存在一种或多种阻燃剂。
阻燃剂是用于多种消费产品(例如塑料、纺织品、皮革、纸、橡胶等)以抑制或抵抗火势蔓延的化学添加剂。阻燃剂通过物理或化学作用干扰燃烧的特定阶段,即在加热、分解、点燃或火焰蔓延的过程中。
可以用作阻燃剂的化学品可以是矿物化学品,含卤素化学品,含氮化学品和含磷化学品,基于硅的化学品等。术语"阻滞"表示一类用途而非一类化学结构。
近年来,越来越关注卤化阻燃化学品的安全问题、以及它们对环境的影响。因此,高度需要使用非卤化阻燃材料的多异氰酸酯泡沫体夹芯板。美国出现很多倡议计划例如能源与环境设计(LEED)认证计划主持下的美国绿色建筑委员会(The U.S.Green Building Council)(US GBC)以促使负有环境责任的建筑物成为既可有利益又健康的生活和工作的场所。LEED绿色建筑定级系统是自愿标准,其确认建筑构造的生命周期评估(LCA)和生命周期成本(LCC)。对于建筑物绝缘产品的选择可有助于在几种类别例如能源管理和室内空气质量中获得LEED信誉。
因此,在本发明的一种实施方式中,提供了制备仅包含无卤素阻燃剂的聚异氰脲酸酯泡沫体的方法。
适宜的无卤素阻燃剂的实例包括:金属氢氧化物例如氢氧化铝和氢氧化镁;基于磷的阻燃剂,包括有机和无机的磷酸酯、膦酸酯、亚磷酸酯,次膦酸酯等;和基于氮的阻燃剂,例如三聚氰胺和三聚氰胺衍生物(例如,三聚氰胺氰脲酸盐,三聚氰胺多磷酸盐,蜜勒胺,蜜弄)。适宜的含磷有机化合物的实例描述于EP 1023367 B1,第[0026]至[0032]段,参考的段落通过参考并入本申请。
优选地,无卤素阻燃剂是有机磷酸酯,例如磷酸三乙酯(TEP)。
优选地,无卤素阻燃剂是有机膦酸酯,例如乙基膦酸二乙基酯(diethylethyl phosphonate)(DEEP)。
通常,无卤素阻燃剂的添加量为5至50重量份的阻燃剂每100重量份的多元醇制剂,优选为10至40重量份的阻燃剂每100重量份的多元醇制剂,更优选为15至30重量份的阻燃剂每100重量份的多元醇制剂。
因为仍认为某些类型的卤化阻燃剂是有用的,因此本发明也提供使用至少一种卤化阻燃剂制备聚异氰脲酸酯泡沫体的方法。
通常,这样的阻燃剂是卤化的芳族化合物,或卤素取代的磷酸酯。常见的卤素取代的磷酸酯包括磷酸三(2-氯乙基)酯,磷酸三(1,3-二氯丙基)酯,磷酸三(2-氯丙基)酯,磷酸三(2,3-二溴丙基)酯,磷酸氯丙基二(溴丙基)酯和二磷酸四(2-氯乙基)亚乙基酯。
可以使用具有反应性且永久键接于聚合物中的卤化多元醇。常用的卤化多元醇的实例是PHT-4二醇和/或SAYTEX RB79。
通常,卤化阻燃剂的添加量为5至60重量份的阻燃剂每100重量份的多元醇制剂,优选为5至50重量份的阻燃剂每100重量份的多元醇制剂,更优选为10至40重量份的阻燃剂每100重量份的多元醇制剂。
如果期望,可以将各种添加剂混入到用于制备本发明泡沫体的反应混合物中。实例是增链剂,交联剂,表面活性物质,泡沫稳定剂,泡孔调节剂(cellregulators),填料,染料,颜料,水解抑制剂,抑制真菌和抑制细菌的物质。
在一种优选的实施方式中,包括增链剂和/或交联剂有助于调节聚合物交联。不同于多元醇,这些物质本身的性质不是聚合物。增链剂通常归类为官能度等于2。它们的代表性实例通常是相对短链或低分子量的分子,例如对苯二酚二(β-羟基乙基)醚,乙二醇(EG),二甘醇(DEG),三甘醇,四甘醇,丙二醇,一缩二丙二醇,二缩三丙二醇,1,3-丙二醇,1,3-丁二醇,1,4-丁二醇(BDO),新戊二醇,1,6-己二醇,1,4-环己烷二甲醇,甲基二乙醇胺,苯基二乙醇胺,其组合,和类似物。特别频繁使用的是一缩二丙二醇(DPG),1,4-丁二醇(BDO),二甘醇(DEG)及其组合。
交联剂通常归类为官能度等于3或更大。它们的代表性实例通常也是相对短链或低分子量的分子,例如甘油,乙醇胺,二乙醇胺,三羟甲基丙烷(TMP),1,2,6-己三醇,三乙醇胺,季戊四醇,N,N,N',N'-四(2-羟基丙基)-乙二胺,二乙基-甲苯二胺,二甲基硫代甲苯二胺,其组合等。特别频繁使用的是甘油,1,4-三羟甲基丙烷(TMP),及其组合。
本领域技术人员熟悉多种适宜的增链剂和/或交联剂。当使用时,交联剂和/或增链剂的用量可以为多元醇制剂的至多8wt%。
适宜的表面活性物质(表面活性剂和乳化剂)是,例如,用于帮助起始原料的均化并且也适用于调节泡沫体的泡孔结构的化合物。
可以添加表面活性剂(包括基于有机硅的那些和有机的那些)以用作泡孔稳定剂。一些代表性材料通常是,聚硅氧烷聚环氧烷烃嵌段共聚物,例如公开于美国专利2,834,748;2,917,480;和2,846,458的那些,其公开内容完全通过参考并入本申请。也包括的是包含聚环氧乙烷-聚环氧丁烷嵌段共聚物的有机表面活性剂,如描述于美国专利5,600,019,其公开内容完全通过参考并入本申请。其它表面活性剂包括长链醇的聚乙二醇醚、叔胺、或长链烯丙基酸硫酸酯、烷基磺酸酯和烷基芳基磺酸的链烷醇胺盐、及其组合。
表面活性剂例如NIAXTM L-6900或DABCOTM DC5598的含量可以为0至6份范围内的任何量。(NIAXTM L-6900购自Momentive,DABCOTM DC5598购自Air Products)。
表面活性物质也包括乳化剂,例如,蓖麻油硫酸酯的钠盐或脂肪酸的钠盐以及脂肪酸的胺盐,例如,二乙胺油酸盐,二乙醇胺硬脂酸盐,二乙醇胺蓖麻油酸盐;磺酸的盐,例如,十二烷基苯二磺酸和蓖麻油酸或二萘基甲烷二磺酸和蓖麻油酸的碱金属盐或铵盐。其它泡沫体乳化剂包括,例如,乙氧基化烷基酚,乙氧基化脂肪醇,石蜡油,蓖麻油或蓖麻油酸酯。
乳化剂物质的用量通常为0.01至5重量份每100份多元醇制剂,优选为1至5重量份每100份多元醇制剂。
试剂例如全氟烷烃在硬质泡沫体的领域是重要的添加剂,因为它们有助于调节泡沫体泡孔结构,因此它们可用于本发明。
填料的实例包括滑石,粘土,硅石,碳酸钙,石墨,玻璃,炭黑,玻璃纤维或其它陶瓷,或粉末状聚合物例如聚酰胺、丙烯、ABS或回收的聚氨酯泡沫体。填料的用量可以为多元醇制剂的至多20重量%。
本发明的方法在物理发泡剂的存在下进行。用于本发明适宜的物理发泡剂是沸点高于结冰(0℃)的那些。优选地,至少一种发泡剂的沸点高于10℃,更优选为15℃或更高。
发泡剂组合物包括至少一种物理发泡剂,其为烃,氢氟烃(HFC),氟烃,二烷基醚或氟取代的二烷基醚,氢氯氟烯烃(HCFO),氢氟烯烃(HFO),或其两种或更多种的混合物。这些类型的发泡剂包括,例如,丙烷,异戊烷,正戊烷,正丁烷,异丁烷,异丁烯,环戊烷,二甲醚,1,1,1,2-四氟乙烷(HFC-134a),1,1,1,3,3-五氟丁烷(HFC-365mfc),1,1-二氟乙烷(HFC-152a),1,1,1,2,3,3,3-七氟丙烷(HFC-227ea),和1,1,1,3,3-五氟丙烷(HFC-245fa)。HFO和HCFO发泡剂的实例包括:五氟丙烯,例如HFO-1225yez和HFO-1225ye;四氟丙烯,例如HFO-1234yf(2,3,3,3-四氟丙烯)和HFO-1234ze(1,3,3,3-四氟丙烯);氯氟丙烯,例如,HCFO-1233zd(1,1,1-三氟-3-氯丙烯),HCFO-1223二氯三氟丙烯);HCFO-1233xf(2-氯-3,3,3-三氟丙烯);和1,1,1,4,4,4-六氟-2-丁烯(FEA-1100)。这样的发泡剂公开于众多公开,例如,公开WO2008121785A1WO2008121790A1;US 2008/0125506;US 2011/0031436;US2009/0099272;US2010/0105788和US2011/0210289。甲酸甲酯和二甲氧基甲烷是可用的物理发泡剂的另外的实例。烃和氢氟烃发泡剂是优选的。在进一步的实施方式中,使用的烃发泡剂是环戊烷。
由于模内的减压,具有高沸点(即,高于50℃)的发泡剂例如环己烷或甲基-环己烷可以用于本发明。任选地,沸点低于0℃的产品例如异丁烯可以与之前列出的其它发泡剂组合。
可以与这些化合物组合使用的其它发泡剂是稀有气体,例如氩气、氪气或氙气。
所有上述物理发泡剂可以作为纯组分以及作为这些各种物理发泡剂的混合物使用。
本发明的方法也使用至少一种化学发泡剂,例如水或甲酸。化学发泡剂的总存在量为0.1wt%至5wt%,基于多元醇制剂的总重量。优选地,化学发泡剂的量为0.5至4wt%。
过高的化学发泡剂含量可能导致脆性增加(由于聚脲连接基的含量增加)和热导率增加(由于在泡孔气体组合物中,二氧化碳与物理发泡剂的摩尔比较高)。
本发明的聚异氰脲酸酯泡沫体如下制备:将多元醇制剂和异氰酸酯组分在约20℃在物理发泡剂的存在下混合,并将其注射进闭合的模具空腔内,所述模具空腔具有的内部气压低于大气压力并且处于使得多元醇和多异氰酸酯反应和固化的条件下。
通常没必要的是,将各组分预加热或将热量施加于反应混合物,以便获得良好的反应和固化,但是如果期望可以加热。但是,通常将模内空腔优选在30至60℃、更优选在40至50℃加热,从而提供适当的表面固化并且将泡沫体有效粘合于塑料和/或金属衬垫。
根据本发明,模具具有内部压力,其足以用所用的发泡组合物进行良好的填充。内部模具压力可以为300至950毫巴,优选为400至950毫巴,更优选为500至900毫巴。控制内部气压,使得可以在具有填充时间相对于胶凝时间的恰好平衡的情况下获得模塑密度。
可替换地,可以在刚注射完发泡组合物之后就施加真空,但是这不是优选的选择。通过在降低的模内压力下注射、或在刚注射完就施加真空可使发泡组合物较快和较有效地流动和填充空腔,与用常规法在大气压进行的相比,因此可在本发明使用较为粘性或反应性较高的泡沫体制剂。向模具空腔施加局部真空的技术是本领域已知的,例如参见美国专利5,454,582和5,972,260。当可燃的发泡剂用于泡沫体制剂时,在减压下注射进闭合的模具空腔之前,为了安全可以用惰性气体例如氮气吹洗空腔。
泡沫体的模塑密度通常为30至75kg/m3,优选为35至70kg/m3,更优选为35至65kg/m3。为在使用的局部真空下获得所需密度范围内的泡沫体以及确保适当填充整个模具空腔,通常将模具填充至大于1.03但不高于1.9的填料因子(packing factor)。优选地,填料因子设置为1.06至1.6,更优选为1.1至1.5。
有利地,本发明制备的聚异氰脲酸酯泡沫体可以表现出改善的阻燃性能,与使用常规制剂和在大气压进行的常规方法按类似密度制备的常规泡沫体相比。
本申请使用的术语"改善的阻燃性能"是指泡沫体具有不高于15厘米的火焰高度的能力,当根据EN ISO 11925/2测试时。在某些实施方式中,本发明可用于满足建筑产品的对火的反应(reaction-to-fire)要求,基于新的Euroclasses规定(欧洲标准EN 13501)。
由本发明方法制备的聚异氰脲酸酯夹芯板优选用于组装用于冷储存和运输的结构体,例如冷库,冷藏车皮(refrigerated trucks),冷藏车(refrigeratedrail cars)等。
给出以下实施例以说明本发明,但不应以任何方式认为其限制本发明。
除非明确指出,否则工作实施例中的数值都是重量份。对用于实施例的原料的描述如下:
多元醇1是芳族聚酯多元醇;羟值为215,基于31.5%的TPA(对苯二甲酸)、8.5%的DEG(二甘醇)和60%的PEG200(聚乙二醇,200 MW)。
多元醇2是芳族树脂引发的环氧丙烷-环氧乙烷聚醚多元醇;羟值为约200,平均官能度为约3.3;其中该树脂是苯酚和甲醛的缩合产物。
多元醇3是蔗糖/甘油引发的聚醚多元醇,官能度为约7,当量为约200,和羟值为280,以商品名VORANOLTM280购自The Dow Chemical Company。
多元醇4是甘油引发的聚环氧乙烷/聚环氧丙烷聚醚多元醇;羟值为32-35;1,675当量;作为VORANOLTMCP-1421购自The Dow ChemicalCompany。
添加剂1:己二酸二甲酯
阻燃剂1(FR 1):磷酸三乙酯(TEP)
阻燃剂2(FR 2):乙基膦酸二乙基酯(DEEP)
阻燃剂3(FR 3):磷酸三(氯异丙基)酯(TCPP)
表面活性剂DABCOTMDC-5598,有机硅表面活性剂;购自Air Products
催化剂1:在乙二醇中的醋酸钾(32%);Dabco K2097,购自Air Products
催化剂2:N,N-二甲基环己基胺(DMCHA)
异氰酸酯VORANATETMM-220(聚亚甲基聚苯基异氰酸酯,其总异氰酸酯含量为约31%,平均官能度为2.7)。
所有泡沫体使用装备有连接于模具注射孔的混合头的高压Cannon机器在其中大气压为约1,000毫巴(或hPa)的实验室中制备。将预混合物(多元醇制剂连同发泡剂)和异氰酸酯在混合头中在90巴或更高的压力进行冲击,并将其注射进模具中。模具由铝制成,尺寸为194x35x6cm,没有通风口使得在发泡过程中在模具中产生减压,因此不会挤出发泡的物质。模具的内部压力通过连接于500升缓冲罐的管子控制,该缓冲罐连接于中等容量真空泵(15001/min)。用控制阀可保持缓冲罐中的真空,由此保持模具气压。在该模具中制得的泡沫体可用于测量模塑密度,密度分布,压缩强度,热导率和对火的反应。模具的温度为约50℃。施涂于模具的脱模剂是由Acmos供应的ACMOS 37-7900。
乳白时间是以秒计的从混合过程开始直到发生反应物的视觉变化(颜色变化和/或起发开始)的时间
胶凝时间是以秒计的从混合过程开始直到可以使用探头如压舌板从起发的泡沫体拉出线丝的一段时间。
以kg/m3计的自由起发密度(FRD)是从100x100x100mm块料测得的密度,该块料得自由200克或更大的总体系制剂重量制备的自由起发泡沫体(在环境气压)的中心。FRD以kg/m3报告。
最小填充密度(MFD)是由完全填充模具(填料因子=100%)所需的最小重量和该模具的体积确定的密度。MFD以kg/m3报告。
流动指数是最小填充密度/自由起发密度的比率,后者在大气压测量。
平均密度方差(density deviation)是基于在不同试样(最少17个样品)上测得的密度的变化计算的数值,该试样为35X10x6cm,从模塑面板194X35X6cm切割的。
应用密度是由模内空腔中注射的重量和该模内空腔的体积确定的密度。应用密度以kg/m3报告。
以kPa计的泡沫体压缩强度垂直于模塑面板的主面根据EN ISO 844(2009)测量。
以mW.m°K计的在10℃的热导率是根据欧洲标准EN12667测得的垂直于模塑面板的主面的热流。
以cm计的火焰高度根据EN ISO 11925-2测量。
以MJ/m2计的总热释放量;以kW/m2计的峰值热释放量;和以m2/m2计的总烟雾产生量使用锥形量热仪设备根据(ISO-5660-1)测量。
实施例
基于卤素阻燃剂的制剂根据表1中的组分制备。
表1
体系编号 | 1 | 2 | 3 | 4 |
多元醇1 | 25.43 | 25.43 | 25.43 | 25.43 |
多元醇2 | 22.1 | 22.1 | 22.1 | 22.1 |
多元醇3 | ||||
多元醇4 | ||||
添加剂1 | ||||
FR 1 | ||||
FR 2 | 8.51 | 8.51 | 8.51 | 8.51 |
FR 3 | 33.81 | 33.81 | 33.81 | 33.81 |
表面活性剂 | 4 | 4 | 4 | 4 |
催化剂1 | 2.05 | 2.05 | 2.05 | 2.05 |
催化剂2 | 0.25 | 0.25 | 0.25 | 0.25 |
甲酸 | 3.4 | 3.4 | 3.4 | 3.4 |
水 | 0.45 | 0.45 | 0.45 | 0.45 |
总计 | 100 | 100 | 100 | 100 |
指数 | 400 | 300 | 400 | 300 |
环戊烷/异戊烷* | 6 | 6 | 10 | 10 |
异氰酸酯 | 216 | 162 | 216 | 162 |
*是环戊烷/异戊烷的70/30wt/wt共混物。
将多元醇制剂/发泡剂与异氰酸酯混合,将其在约1000毫巴的环境压力注射进模具从而制备标准泡沫体(对比实施例1-4),将其注射进保持在900毫巴的模具从而制备泡沫体(实施例1-4)。制得的泡沫体的性质显示于表2。制剂3和4(对比实施例3和4)利用较高含量的烃发泡剂,以获得与在实施例1和2中获得的那些相当的密度。
表2
无卤素阻燃剂制剂根据表3中的组分制备。
表3
将多元醇制剂/发泡剂与异氰酸酯混合,将其在约1000毫巴的环境压力注射进模具从而制备标准泡沫体(对比实施例5和对比实施例8),将其注射进保持在900毫巴的模具从而制备泡沫体(实施例3-6以及对比实施例10和12)。对比实施例6、7、9、11通过将反应性混合物倒入袋状物中并测量反应性和FRD来制备。
表4
表5
为确定本发明方法的多用途,体系5用于在各种压力制备泡沫体以确定应用密度和视觉上观察制得的绝缘面板的美观性质。所得结果显示于以上表5。美观是指对空隙的数目和尺寸的视觉观察。
表2和4的结果表明,本发明的泡沫体(实施例1-6)根据EN ISO 11925-2标准满足对火的反应Euroclass E的要求(火焰高度小于15cm)并且表现出良好的反应概况。
从表2中的实施例1和2可见,本发明的泡沫体(在900毫巴模塑)显示出降低的火焰高度性质,与在标准压力条件下制备的相同制剂的泡沫体相比。例如,在1000毫巴模塑的体系1的火焰高度为6cm,而在900毫巴模塑的体系1的火焰高度仅为5cm。
实施例1和2也证明了,由在900毫巴模塑的泡沫体产生的热释放量峰值低于在1000毫巴模塑的泡沫体的该值。
从表4可以看出,在900毫巴模塑的实施例3和6的无卤素制剂也具有显著改善的阻燃性能,与在1000毫巴模塑的相同制剂的泡沫体的该性能相比。模具气压降低10%连同降低的应用密度共同导致EN ISO 11925-2火焰高度降低、总热释放量减少、以及产生的总烟雾显著减少。
体系9和10未落入本发明的范围内。体系9不包括含有至少35wt%芳族聚酯多元醇的多元醇混合物。类似地,体系10也不包括含有至少35wt%芳族聚酯多元醇的多元醇混合物并且异氰酸酯指数也不是大于250。
从表4可以看出,当在900毫巴模塑时,本发明的体系(即,实施例3-6,其包含至少35wt%芳族聚酯多元醇构成的多元醇混合物且异氰酸酯指数大于250)得到的泡沫体具有改善的阻燃性能,与体系9和10的泡沫体相比。例如,在900毫巴模塑的体系10的火焰高度为10cm,而在900毫巴模塑的实施例3-6的火焰高度全部小于或等于7.5cm。而且,由在900毫巴模塑的体系9产生的总烟雾显著大于由在900毫巴模塑的实施例3-6任一项产生的总烟雾。
从表4和5可以看出,本发明的方法可以生产特征在于优越的热绝缘性的PIR泡沫体。此外,如表5所示,该方法可通过调节模具空腔中的绝压而容易控制空腔填充和物料分布(密度方差)。
已经参考优选实施方式描述了本发明,但是应该理解本发明范围内的各种修改形式也是可行的。
在本说明书中,除非明确地相反指出,否则措辞‘或’在运算符的情况下使用中,当满足所述条件任一种或两者时归还真值,这与运算符‘排他的或’相反,其仅需满足条件之一。措辞‘包括’的使用意义是‘包含’而不是表示‘由…组成’。以上公知的所有现有技术教导通常参考并入本申请。不应认为本申请任何现有技术公开的文件承认或表示其教导是在其申请日的澳大利亚或别处的公知常识。
Claims (12)
1.制备聚异氰脲酸酯(PIR)泡沫体的方法,其包括:
A)将反应混合物注射进闭合的模具空腔,其中所述模具空腔处于300至950毫巴的绝压下,所述反应混合物包含以下组分:
a)有机多异氰酸酯;
b)多元醇混合物,其中所述多元醇混合物包含芳族聚酯多元醇,其中所述芳族聚酯多元醇占多元醇总量的至少35wt%;
c)三聚催化剂;
d)至少一种阻燃剂;
e)任选的辅助物质;和
f)发泡剂组分,
其中所述反应混合物的异氰酸酯指数大于250;和
B)固化以形成聚异氰脲酸酯泡沫体。
2.制备具有两个外壳和一个中间的聚异氰脲酸酯(PIR)结构泡沫体芯的夹芯板的方法,包括进行权利要求1的方法,其中所述闭合的模具空腔由所述两个外壳和一个环形框架限定。
3.根据权利要求1或2的方法,其中所述芳族聚酯多元醇占多元醇总量的至少50wt%。
4.根据前述权利要求任一项的方法,其中所述反应混合物的异氰酸酯指数大于350。
5.根据前述权利要求任一项的方法,其中所述模具空腔绝压为800至950毫巴。
6.根据前述权利要求任一项的方法,其中所述发泡剂组分包括物理发泡剂和化学发泡剂。
7.根据权利要求6的方法,其中所述化学发泡剂是水、甲酸或其组合。
8.根据权利要求6或7的方法,其中所述物理发泡剂是戊烷。
9.根据前述权利要求任一项的方法,其中所述泡沫体的应用密度为30至75kg/m3。
10.根据前述权利要求任一项的方法,其中所述反应混合物另外包含有机硅表面活性剂。
11.根据前述权利要求任一项的方法,其中所述阻燃剂是无卤素阻燃剂。
12.包括两个外壳和一个中间的聚异氰脲酸酯(PIR)结构泡沫体芯的夹芯板,其中所述PIR泡沫体芯由包含以下组分的反应混合物制备:
a)有机多异氰酸酯;
b)多元醇混合物,其中所述多元醇混合物包含大于35重量%的芳族聚酯多元醇和10至65重量%线型酚醛清漆引发的多元醇,基于多元醇的总重量;
c)至少一种固化和/或发泡催化剂;
d)至少一种三聚催化剂;
e)至少一种阻燃剂;
f)任选的至少一种有机硅表面活性剂;
g)至少一种选自水和甲酸的化学发泡剂;和
h)戊烷,
其中所述反应混合物的异氰酸酯指数大于250。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12425099.4 | 2012-05-25 | ||
EP12425099 | 2012-05-25 | ||
PCT/EP2013/060465 WO2013174844A1 (en) | 2012-05-25 | 2013-05-22 | Production of polyisocyanurate foam panels |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104334599A true CN104334599A (zh) | 2015-02-04 |
CN104334599B CN104334599B (zh) | 2019-04-05 |
Family
ID=48539113
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201380027444.8A Active CN104334599B (zh) | 2012-05-25 | 2013-05-22 | 聚异氰脲酸酯泡沫面板的制造 |
Country Status (9)
Country | Link |
---|---|
US (2) | US20150118476A1 (zh) |
EP (1) | EP2855549B1 (zh) |
JP (1) | JP6507095B2 (zh) |
CN (1) | CN104334599B (zh) |
ES (1) | ES2651388T3 (zh) |
MX (1) | MX2014014397A (zh) |
PL (1) | PL2855549T3 (zh) |
RU (1) | RU2639871C2 (zh) |
WO (1) | WO2013174844A1 (zh) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109415481A (zh) * | 2016-05-30 | 2019-03-01 | 巴斯夫欧洲公司 | 制造夹芯组件的方法 |
CN109476814A (zh) * | 2016-07-21 | 2019-03-15 | 科思创德国股份有限公司 | 高温稳定的聚异氰脲酸酯泡沫材料 |
CN109898343A (zh) * | 2019-02-26 | 2019-06-18 | 合肥安利聚氨酯新材料有限公司 | 一种超柔软合成革用无溶剂聚氨酯中间层树脂及其制备方法 |
CN110405998A (zh) * | 2019-07-25 | 2019-11-05 | 力王新材料(惠州)有限公司 | 三聚氰胺隔热材料的制备工艺 |
CN110606268A (zh) * | 2019-09-03 | 2019-12-24 | 海宁市方圣包装材料有限公司 | 一种多层复合包装袋及其加工工艺 |
TWI791656B (zh) * | 2018-01-16 | 2023-02-11 | 美商亨茲曼國際公司 | 具有長乳稠時間及快速固化行為之包含聚異三聚氰酸酯之發泡體 |
EP4177288A1 (en) | 2021-11-03 | 2023-05-10 | Covestro Deutschland AG | Method for preparing a rigid polyurethane foam |
CN117343276A (zh) * | 2023-12-04 | 2024-01-05 | 烟台万华聚氨酯合成材料有限公司 | 阻燃双组份聚氨酯灌封胶的制备方法 |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103758252A (zh) * | 2013-12-06 | 2014-04-30 | 嘉善东祥木胶贸易有限公司 | 一种节能阻燃装饰板 |
EP3059064B1 (en) * | 2013-12-19 | 2019-02-06 | Toyo Seikan Group Holdings, Ltd. | Plastic molding method |
EP2993195A1 (en) * | 2014-09-05 | 2016-03-09 | Huntsman International Llc | A method for improving fracture toughness of polyisocyanurate comprising reaction products |
JP6480775B2 (ja) * | 2015-03-26 | 2019-03-13 | 積水化学工業株式会社 | ウレタン樹脂組成物、建材の耐火補強方法、および建材の耐火補強構造 |
US10301236B2 (en) | 2015-05-21 | 2019-05-28 | The Chemours Company Fc, Llc | Hydrofluorination of a halogenated olefin with SbF5 in the liquid phase |
JP2017105188A (ja) * | 2015-12-01 | 2017-06-15 | 積水化学工業株式会社 | 難燃断熱パネルの製造方法 |
CA3019617A1 (en) * | 2016-05-04 | 2017-11-09 | Covestro Deutschland Ag | Method for producing a polyisocyanurate composite material |
EP3458491A1 (en) * | 2016-05-18 | 2019-03-27 | Basf Se | Process for preparing polyisocyanurate rigid foams |
IT201700020023A1 (it) * | 2017-02-22 | 2018-08-22 | Doors & More S R L | Preparazione di poliisocianurato espanso |
IT201700020006A1 (it) * | 2017-02-22 | 2018-08-22 | Doors & More S R L | Uso di poliisocianurato ad esempio per la realizzazione di serramenti o compartimentazioni di sicurezza |
EP3371408B1 (en) * | 2016-07-22 | 2022-09-07 | Doors & More S.R.L. | High fire-resistant polyisocyanurate, and use thereof to manufacture fire door or window frames and/or profiles therefor |
CA3034242C (en) * | 2016-08-19 | 2021-04-06 | Firestone Building Products Company, Llc | Process for producing isocyanate-based foam construction boards |
WO2018111750A1 (en) * | 2016-12-15 | 2018-06-21 | Dow Global Technologies Llc | Polyurethane product with sulfur-containing polyester polyol |
KR20190142414A (ko) * | 2017-05-11 | 2019-12-26 | 바스프 에스이 | 낮은 가공 온도 및 향상된 접착성을 갖는 샌드위치 패널용 폴리이소시아누레이트 폼 |
JP7144135B2 (ja) * | 2017-10-14 | 2022-09-29 | 株式会社エフコンサルタント | 硬化性組成物 |
US11279809B2 (en) * | 2018-08-08 | 2022-03-22 | Covestro Intellectual Property Gmbh & Co. Kg | Phosphinate as flame-proofing additive for PUR/PIR hard foam material |
US10968327B2 (en) * | 2018-08-27 | 2021-04-06 | Covestro Llc | Methods for formulating polyisocyanurate foam-forming compositions, related polyisocyanurate foam-forming compositions, and foams produced thereby |
US11299882B2 (en) * | 2018-12-03 | 2022-04-12 | Johns Manville | Foam insulation with improved low temperature properties using polyol additives |
WO2020157063A1 (en) | 2019-02-01 | 2020-08-06 | Basf Se | Method for preparing polyurethane foams |
JP2021054884A (ja) * | 2019-09-27 | 2021-04-08 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | ポリイソシアヌレートフォーム形成用組成物及びポリイソシアヌレートフォーム |
EP4055073A1 (en) * | 2019-11-06 | 2022-09-14 | Basf Se | Rigid polyurethane based foam with compression strength and fire resistance |
WO2024079004A1 (en) * | 2022-10-13 | 2024-04-18 | Covestro Deutschland Ag | Solid surface materials based on reaction mixtures with two kind of blowing agents |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2838473A (en) | 1953-09-28 | 1958-06-10 | Dow Chemical Co | Rapid method for producing stable novolaks |
BE536296A (zh) | 1954-03-22 | |||
BE538608A (zh) | 1954-06-10 | |||
US2846458A (en) | 1956-05-23 | 1958-08-05 | Dow Corning | Organosiloxane ethers |
US2938884A (en) | 1956-11-20 | 1960-05-31 | Dow Chemical Co | Oxypropylation of phenolic resins |
GB1123727A (en) | 1965-06-14 | 1968-08-14 | Dow Chemical Co | Polyurethanes and a method of making the same |
US3470118A (en) | 1966-05-20 | 1969-09-30 | Reichhold Chemicals Inc | Flame-resistant polyol urethane foam composition and process of producing the same |
US4046721A (en) | 1976-07-30 | 1977-09-06 | Texaco Development Corporation | Low friability polyisocyanurate foams |
US4871612A (en) | 1986-09-05 | 1989-10-03 | Inoue Mtp Kabushiki Kaisha | Interior member for vehicles and method for its manufacture |
US4883826A (en) | 1988-07-27 | 1989-11-28 | The Dow Chemical Company | Tertiary amine-containing polyols prepared in a mannich condensation reaction using a mixture of alkanolamines |
US4939182A (en) | 1988-07-27 | 1990-07-03 | The Dow Chemical Company | Melamine-alkanolamine condensates and polyurethanes prepared therefrom |
US5120815A (en) | 1989-06-29 | 1992-06-09 | The Dow Chemical Company | Tertiary amine-containing polyols prepared in a mannich condensation reaction using a mixture of alkanolamines |
US5308881A (en) | 1993-10-25 | 1994-05-03 | The Celotex Corporation | Surfactant for polyisocyanurate foams made with alternative blowing agents |
US5600019A (en) | 1993-12-17 | 1997-02-04 | The Dow Chemical Company | Polyisocyanate based polymers perpared from formulations including non-silicone surfactants and method for the preparation thereof |
US5454582A (en) | 1994-04-08 | 1995-10-03 | Rines; Hubert M. | Apparatus for hitching a trailer coupler to a hitch ball |
IT1289472B1 (it) | 1996-12-19 | 1998-10-15 | Manni S P A | Procedimento ed apparecchiatura per la schiumatura sottovuoto di pannelli isolanti,con insufflaggio di gas inerte |
HUP0004077A3 (en) | 1997-07-25 | 2001-04-28 | Huntsman Ici Chemicals Llc Sal | Flame resistant rigid polyurethane foams blown with hydrofluorocarbons |
US9796848B2 (en) | 2002-10-25 | 2017-10-24 | Honeywell International Inc. | Foaming agents and compositions containing fluorine substituted olefins and methods of foaming |
ATE404603T1 (de) * | 2003-01-03 | 2008-08-15 | Dow Global Technologies Inc | Polyisocyanuratschaum und verfahren zu seiner herstellung |
EP1577332A1 (en) * | 2004-03-15 | 2005-09-21 | Huntsman International Llc | Process for making rigid polyurethane foams |
RU2418810C2 (ru) | 2005-11-14 | 2011-05-20 | Дау Глобал Текнолоджиз Инк. | Способ формования жестких пенополиуретанов с улучшенной теплопроводностью |
US8034251B2 (en) | 2007-01-03 | 2011-10-11 | Honeywell International Inc. | Azeotropic compositions of 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf), 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb), and hydrogen fluoride (HF) |
PL2129709T5 (pl) | 2007-03-29 | 2021-11-15 | Arkema, Inc. | Sposób wytwarzania pianek termoutwardzalnych |
US9279039B2 (en) | 2007-03-29 | 2016-03-08 | Arkema Inc. | Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin |
US9453115B2 (en) | 2007-10-12 | 2016-09-27 | Honeywell International Inc. | Stabilization of polyurethane foam polyol premixes containing halogenated olefin blowing agents |
CA3008518C (en) | 2008-05-07 | 2020-06-16 | E. I. Du Pont De Nemours And Company | Compositions comprising 2,3-dichloro-1,1,1-trifluoropropane, 2-chloro-1,1,1-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane or 2,3,3,3-tetrafluoropropene |
WO2010004636A1 (ja) | 2008-07-10 | 2010-01-14 | 川崎重工業株式会社 | ロボット及びその教示方法 |
ITMI20081480A1 (it) | 2008-08-06 | 2010-02-06 | Dow Global Technologies Inc | Poliesteri aromatici, miscele palioliche che li comprendono e prodotti risultanti |
ITMI20081867A1 (it) * | 2008-10-22 | 2010-04-22 | Dow Global Technologies Inc | Processo per lapreparazione di schiume poliuretaniche rigide a celle chiuse |
BRPI1006449B1 (pt) * | 2009-04-01 | 2019-10-29 | Dow Global Technologies Llc | composição de poliol estável em armazenamento, formulação para o preparo de uma espuma de poliisocianurato e método para o preparo de uma espuma de poliisocianurato |
RU2653540C2 (ru) * | 2009-04-01 | 2018-05-11 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Полиуретановые и полиизоциануратные пены с улучшенными характеристиками затвердевания и огнестойкости |
ES2741589T3 (es) * | 2010-08-13 | 2020-02-11 | Dow Global Technologies Llc | Composición de poliisocianurato |
JP5876492B2 (ja) * | 2010-09-29 | 2016-03-02 | ダウ グローバル テクノロジーズ エルエルシー | 高官能価芳香族ポリエステル、高官能価芳香族ポリエステルを含むポリオールブレンド、およびそれから得られる生成物 |
-
2013
- 2013-05-22 EP EP13726145.9A patent/EP2855549B1/en active Active
- 2013-05-22 WO PCT/EP2013/060465 patent/WO2013174844A1/en active Application Filing
- 2013-05-22 PL PL13726145T patent/PL2855549T3/pl unknown
- 2013-05-22 CN CN201380027444.8A patent/CN104334599B/zh active Active
- 2013-05-22 JP JP2015513148A patent/JP6507095B2/ja active Active
- 2013-05-22 RU RU2014152834A patent/RU2639871C2/ru active
- 2013-05-22 MX MX2014014397A patent/MX2014014397A/es active IP Right Grant
- 2013-05-22 ES ES13726145.9T patent/ES2651388T3/es active Active
- 2013-05-22 US US14/396,531 patent/US20150118476A1/en not_active Abandoned
-
2016
- 2016-06-24 US US15/191,675 patent/US9987775B2/en active Active
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109415481A (zh) * | 2016-05-30 | 2019-03-01 | 巴斯夫欧洲公司 | 制造夹芯组件的方法 |
CN109476814A (zh) * | 2016-07-21 | 2019-03-15 | 科思创德国股份有限公司 | 高温稳定的聚异氰脲酸酯泡沫材料 |
TWI791656B (zh) * | 2018-01-16 | 2023-02-11 | 美商亨茲曼國際公司 | 具有長乳稠時間及快速固化行為之包含聚異三聚氰酸酯之發泡體 |
CN109898343A (zh) * | 2019-02-26 | 2019-06-18 | 合肥安利聚氨酯新材料有限公司 | 一种超柔软合成革用无溶剂聚氨酯中间层树脂及其制备方法 |
CN109898343B (zh) * | 2019-02-26 | 2021-09-10 | 合肥安利聚氨酯新材料有限公司 | 一种超柔软合成革用无溶剂聚氨酯中间层树脂及其制备方法 |
CN110405998A (zh) * | 2019-07-25 | 2019-11-05 | 力王新材料(惠州)有限公司 | 三聚氰胺隔热材料的制备工艺 |
CN110405998B (zh) * | 2019-07-25 | 2021-07-27 | 力王新材料(惠州)有限公司 | 三聚氰胺隔热材料的制备工艺 |
CN110606268A (zh) * | 2019-09-03 | 2019-12-24 | 海宁市方圣包装材料有限公司 | 一种多层复合包装袋及其加工工艺 |
EP4177288A1 (en) | 2021-11-03 | 2023-05-10 | Covestro Deutschland AG | Method for preparing a rigid polyurethane foam |
CN117343276A (zh) * | 2023-12-04 | 2024-01-05 | 烟台万华聚氨酯合成材料有限公司 | 阻燃双组份聚氨酯灌封胶的制备方法 |
CN117343276B (zh) * | 2023-12-04 | 2024-02-06 | 烟台万华聚氨酯合成材料有限公司 | 阻燃双组份聚氨酯灌封胶的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
US20160303778A1 (en) | 2016-10-20 |
EP2855549B1 (en) | 2017-10-04 |
PL2855549T3 (pl) | 2018-03-30 |
MX2014014397A (es) | 2015-02-05 |
RU2639871C2 (ru) | 2017-12-25 |
ES2651388T3 (es) | 2018-01-26 |
JP6507095B2 (ja) | 2019-04-24 |
WO2013174844A1 (en) | 2013-11-28 |
EP2855549A1 (en) | 2015-04-08 |
RU2014152834A (ru) | 2016-07-20 |
US20150118476A1 (en) | 2015-04-30 |
US9987775B2 (en) | 2018-06-05 |
JP2015520260A (ja) | 2015-07-16 |
CN104334599B (zh) | 2019-04-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104334599A (zh) | 聚异氰脲酸酯泡沫面板的制造 | |
CN101351484B (zh) | 导热性增强的硬质聚氨酯泡沫的模制法 | |
CN102203156B (zh) | 闭孔刚性聚氨酯泡沫体的制备方法 | |
EP2414423B1 (en) | Polyurethane and polyisocyanurate foams having improved curing performance and fire behavior | |
JP5931913B2 (ja) | 硬質ポリウレタンフォームの改善された低温スキン硬化のためのポリオール配合物 | |
JP5876492B2 (ja) | 高官能価芳香族ポリエステル、高官能価芳香族ポリエステルを含むポリオールブレンド、およびそれから得られる生成物 | |
EP2652000B1 (en) | Polyurethane and polyisocyanurate foams | |
WO2010111021A1 (en) | Production of rigid polyurethane foams and the use thereof | |
CN107849215B (zh) | 聚氨酯泡沫的制备 | |
JPWO2013058341A1 (ja) | 硬質発泡合成樹脂の製造方法 | |
MX2015000241A (es) | Produccion de espumas que tienen mejores propiedades. | |
US20220403096A1 (en) | Hcfo-containing isocyanate-reactive compositions, related foam-forming compositions and polyurethane foams | |
CN103619904A (zh) | 用于改进聚异氰脲酸酯刚性泡沫体的原始强度的多元醇制剂 | |
CN110582522B (zh) | 制造硬质的聚氨酯改性的聚异氰脲酸酯泡沫的方法 | |
JP2014141595A (ja) | 硬質発泡合成樹脂の製造方法 | |
JP2012107214A (ja) | 硬質発泡合成樹脂の製造方法 | |
WO2017198747A1 (en) | Process for preparing polyisocyanurate rigid foams |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |