CN104271674B - 苯并噁嗪树脂组合物、预浸料坯和纤维增强复合材料 - Google Patents

苯并噁嗪树脂组合物、预浸料坯和纤维增强复合材料 Download PDF

Info

Publication number
CN104271674B
CN104271674B CN201380023507.2A CN201380023507A CN104271674B CN 104271674 B CN104271674 B CN 104271674B CN 201380023507 A CN201380023507 A CN 201380023507A CN 104271674 B CN104271674 B CN 104271674B
Authority
CN
China
Prior art keywords
resin composition
benzoxazine
benzoxazine resin
resin
prepreg
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201380023507.2A
Other languages
English (en)
Chinese (zh)
Other versions
CN104271674A (zh
Inventor
新井厚仁
J·A·萨特怀特
J·C·休斯
坂田宏明
吉冈健
吉冈健一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Publication of CN104271674A publication Critical patent/CN104271674A/zh
Application granted granted Critical
Publication of CN104271674B publication Critical patent/CN104271674B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0233—Polyamines derived from (poly)oxazolines, (poly)oxazines or having pendant acyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/06—Elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/02—Polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02—Polythioethers; Polythioether-ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/04—Polysulfides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
    • C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/06—Polysulfones; Polyethersulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2481/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2481/06—Polysulfones; Polyethersulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/12—Applications used for fibers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/05—Polymer mixtures characterised by other features containing polymer components which can react with one another
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/04—Thermoplastic elastomer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Reinforced Plastic Materials (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201380023507.2A 2012-06-27 2013-06-27 苯并噁嗪树脂组合物、预浸料坯和纤维增强复合材料 Expired - Fee Related CN104271674B (zh)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US201261664803P 2012-06-27 2012-06-27
US61/664,803 2012-06-27
US201261681834P 2012-08-10 2012-08-10
US61/681,834 2012-08-10
US201361825259P 2013-05-20 2013-05-20
US61/825,259 2013-05-20
PCT/US2013/048305 WO2014004900A2 (en) 2012-06-27 2013-06-27 Benzoxazine resin composition, prepreg, and fiber-reinforced composite material

Publications (2)

Publication Number Publication Date
CN104271674A CN104271674A (zh) 2015-01-07
CN104271674B true CN104271674B (zh) 2016-12-07

Family

ID=49784024

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380023507.2A Expired - Fee Related CN104271674B (zh) 2012-06-27 2013-06-27 苯并噁嗪树脂组合物、预浸料坯和纤维增强复合材料

Country Status (5)

Country Link
US (1) US9777155B2 (enExample)
EP (1) EP2834308B1 (enExample)
JP (1) JP6187586B2 (enExample)
CN (1) CN104271674B (enExample)
WO (1) WO2014004900A2 (enExample)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5912920B2 (ja) * 2012-06-29 2016-04-27 Ｊｘエネルギー株式会社 繊維強化複合材料
CN105164192B (zh) * 2012-09-26 2018-11-09 帝人株式会社 预浸料及其制造方法
KR102123710B1 (ko) * 2012-12-14 2020-06-16 블루 큐브 아이피 엘엘씨 개질된 에폭시 수지
CN105612198B (zh) * 2013-10-16 2017-10-13 3M创新有限公司 苯并噁嗪聚合
US20150204274A1 (en) * 2014-01-21 2015-07-23 Raytheon Company Resin transfer molded rocket motor nozzle
JPWO2016136052A1 (ja) * 2015-02-27 2017-11-30 東レ株式会社 エポキシ樹脂組成物、エポキシ樹脂硬化物、プリプレグおよび繊維強化複合材料
CN105086367B (zh) * 2015-08-21 2017-03-01 成都鲁晨新材料科技有限公司 一种基于耐高温复合材料树脂的预浸料及其制备方法
CN105199386B (zh) * 2015-09-21 2017-11-03 四川天策聚材科技有限公司 一种增韧型苯并噁嗪复合材料及其制备方法
US10125231B2 (en) * 2015-10-05 2018-11-13 Raytheon Company Benzoxazine cyanate ester resin for pyrolisis densification of carbon-carbon composites
JP6799376B2 (ja) * 2016-02-12 2020-12-16 日鉄ケミカル＆マテリアル株式会社 オキサジン樹脂組成物及びその硬化物
CN107541061A (zh) * 2016-06-24 2018-01-05 洛阳尖端技术研究院 一种苯并噁嗪/环氧树脂/碳纤维复合材料及其制备方法
CN107541062A (zh) * 2016-06-24 2018-01-05 洛阳尖端技术研究院 一种改性碳纤维/苯并噁嗪复合材料及其制备方法
JP6570038B2 (ja) 2016-07-26 2019-09-04 Ｊｆｅケミカル株式会社 熱硬化性組成物、そのワニスおよび熱硬化物
FR3069187B1 (fr) * 2017-07-24 2019-08-02 Saint-Gobain Glass France Polymere hybride pour intercalaire plastique viscoelastique
JP7279319B2 (ja) * 2017-09-04 2023-05-23 味の素株式会社 樹脂組成物
US11897998B2 (en) * 2017-10-27 2024-02-13 Eneos Corporation Composition for curable resin, cured product of said composition, production method for said composition and said cured product, and semiconductor device
KR20200139131A (ko) * 2018-03-30 2020-12-11 도레이 카부시키가이샤 벤족사진 수지 조성물, 프리프레그 및 섬유 강화 복합 재료
CN112313078A (zh) * 2018-06-26 2021-02-02 东丽株式会社 预浸料坯及其制造方法、分切带预浸料坯、碳纤维增强复合材料
WO2020109721A1 (fr) * 2018-11-30 2020-06-04 Compagnie Generale Des Etablissements Michelin Matériau multi-composite à base de composite verre-résine
FR3089217A3 (fr) 2018-11-30 2020-06-05 Michelin & Cie Matériau multi-composite à base de composite verre-résine
WO2020109723A1 (fr) * 2018-11-30 2020-06-04 Compagnie Generale Des Etablissements Michelin Collage d'un monobrin en composite verre-résine à une matrice thermoplastique
FR3089228A3 (fr) * 2018-11-30 2020-06-05 Michelin & Cie Collage d’un monobrin en composite verre-résine à une matrice thermoplastique
FR3089218A3 (fr) * 2018-11-30 2020-06-05 Michelin & Cie Matériau multi-composite à base de composite verre-résine
WO2020109722A1 (fr) * 2018-11-30 2020-06-04 Compagnie Generale Des Etablissements Michelin Matériau multi-composite à base de composite verre-résine
JP7410052B2 (ja) 2018-12-10 2024-01-09 Ｅｎｅｏｓ株式会社 硬化樹脂用組成物、該組成物の硬化物、該組成物および該硬化物の製造方法、ならびに半導体装置
CN113728032A (zh) 2019-04-26 2021-11-30 引能仕株式会社 固化树脂用组合物、该组合物的固化物、该组合物及该固化物的制造方法、以及半导体装置
CN112210106B (zh) * 2019-07-12 2023-04-14 航天材料及工艺研究所 一种可中温固化的热熔苯并噁嗪组合物制备方法
ES2982344T3 (es) * 2019-10-02 2024-10-15 Toray Industries Composición de resina de benzoxazina, producto preimpregnado y material compuesto reforzado con fibra
CN110982222A (zh) * 2019-10-31 2020-04-10 长沙新材料产业研究院有限公司 一种苯并噁嗪复合材料及其制备方法
JP7719786B2 (ja) * 2020-02-21 2025-08-06 ハンツマン・アドバンスド・マテリアルズ・アメリカズ・エルエルシー 高靭化熱硬化性樹脂組成物
WO2021261391A1 (ja) * 2020-06-23 2021-12-30 住友化学株式会社 樹脂組成物、硬化物、プリプレグ、樹脂組成物の製造方法、及び芳香族ポリスルホン樹脂
CN113235303B (zh) * 2021-06-08 2023-08-18 青岛大学 一种聚苯并噁嗪改性聚苯硫醚材料及其制备方法
CN115725110B (zh) * 2022-11-16 2024-03-26 航天特种材料及工艺技术研究所 一种硅树脂改性聚苯并噁嗪气凝胶及其制备方法
CN116728914B (zh) * 2023-05-30 2025-11-14 洛阳船舶材料研究所(中国船舶集团有限公司第七二五研究所) 一种防火型电磁屏蔽复合材料及其制备方法
CN117247654B (zh) * 2023-11-17 2024-02-09 西南石油大学 一种水溶性苯并噁嗪和无机纤维复合气凝胶及其制备方法
CN118084521A (zh) * 2024-02-23 2024-05-28 陕西天策新材料科技有限公司 预包覆纤维光固化浆料和碳化硅陶瓷基复合材料
CN118620264B (zh) * 2024-06-26 2025-08-29 北京玻钢院复合材料有限公司 高强高韧隔热用苯并噁嗪树脂基热熔预浸料及其制备方法、苯并噁嗪树脂基复合材料及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006233188A (ja) * 2005-01-31 2006-09-07 Toray Ind Inc 複合材料用プリプレグ、および複合材料
US20120088864A1 (en) * 2010-10-12 2012-04-12 Hexcel Corporation Solvent resistance of epoxy resins toughened with polyethersulfone

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4734729B2 (ja) * 2000-02-23 2011-07-27 東レ株式会社 複合材料成形用中間体及び繊維強化複合材料
US6437026B1 (en) * 2001-01-05 2002-08-20 Cookson Singapore Pte Ltd. Hardener for epoxy molding compounds
JP3894035B2 (ja) * 2001-07-04 2007-03-14 東レ株式会社 炭素繊維強化基材、それからなるプリフォームおよび複合材料
JP2003147273A (ja) * 2001-11-12 2003-05-21 Sumitomo Chem Co Ltd 熱硬化性樹脂ワニスの製造方法
US6699545B2 (en) 2001-12-21 2004-03-02 E. I. Du Pont De Nemours And Company Method for increasing solid state polymerization rate of polyester polymers
JP2007016121A (ja) * 2005-07-07 2007-01-25 Toray Ind Inc 複合材料用プリプレグおよび複合材料
JP2008094961A (ja) * 2006-10-12 2008-04-24 Toray Ind Inc ベンゾオキサジン樹脂組成物
US7537827B1 (en) * 2006-12-13 2009-05-26 Henkel Corporation Prepreg laminates
BRPI0820687B1 (pt) 2007-12-06 2019-11-26 Henkel Ag & Co Kgaa composições curáveis, adesivas, selantes ou de revestimento contendo enrijecedores baseados em isocianato
KR20110120314A (ko) * 2009-02-12 2011-11-03 제이엑스 닛코닛세키에너지주식회사 벤조옥사진 수지 조성물
CN102421824B (zh) 2009-05-14 2014-06-25 亨斯迈先进材料美国有限责任公司 基于液体单苯并噁嗪的树脂体系
WO2010150714A1 (ja) 2009-06-23 2010-12-29 住友化学株式会社 芳香族ポリマーの製造方法
EP2481777B1 (en) * 2009-09-25 2017-10-25 The Yokohama Rubber Co., Ltd. Thermosetting resin composition, thermosetting resin composition for fiber-reinforced composite material, prepreg using the same, and honeycomb sandwich panel
WO2011047939A1 (en) * 2009-10-22 2011-04-28 Henkel Ag & Co. Kgaa Curable composition comprising a benzoxazine compound and a sulfonic acid ester having a cyclic structure as a heat-activatable catalyst
KR20170097233A (ko) 2010-03-05 2017-08-25 헌츠만 어드밴스드 머티리얼스 아메리카스 엘엘씨 전기 부품에 사용하기 위한, 고주파에서 낮은 유전 손실을 갖는 열경화성 수지 시스템
JP5691538B2 (ja) * 2010-04-02 2015-04-01 Jsr株式会社 仮固定用組成物、仮固定材、基材の処理方法、および半導体素子
WO2012015604A1 (en) 2010-07-28 2012-02-02 Huntsman Advanced Materials Americas Llc Solvent-free benzoxazine based thermosetting resin composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006233188A (ja) * 2005-01-31 2006-09-07 Toray Ind Inc 複合材料用プリプレグ、および複合材料
US20120088864A1 (en) * 2010-10-12 2012-04-12 Hexcel Corporation Solvent resistance of epoxy resins toughened with polyethersulfone

Also Published As

Publication number Publication date
JP6187586B2 (ja) 2017-08-30
EP2834308A2 (en) 2015-02-11
JP2015522092A (ja) 2015-08-03
US20150141583A1 (en) 2015-05-21
US9777155B2 (en) 2017-10-03
WO2014004900A3 (en) 2014-04-03
EP2834308B1 (en) 2018-04-18
WO2014004900A2 (en) 2014-01-03
CN104271674A (zh) 2015-01-07
EP2834308A4 (en) 2015-03-18

Similar Documents

Publication Publication Date Title
CN104271674B (zh) 苯并噁嗪树脂组合物、预浸料坯和纤维增强复合材料
CN102348735B (zh) 纤维增强复合材料用环氧树脂组合物、预浸料坯及纤维增强复合材料
CN102822227B (zh) 碳纤维增强复合材料用环氧树脂组合物、预浸料以及碳纤维增强复合材料
JP5780367B2 (ja) エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
KR101766624B1 (ko) 에폭시 수지 조성물, 수지 경화물, 프리프레그 및 섬유 강화 복합 재료
KR20130118302A (ko) 섬유 강화 복합 재료용 에폭시 수지 조성물, 프리프레그 및 섬유 강화 복합 재료
KR20100133963A (ko) 에폭시 수지 조성물, 프리프레그 및 섬유 강화 복합 재료
KR20100019428A (ko) 에폭시 수지 조성물, 프리프레그, 섬유 강화 복합 재료
JP6497027B2 (ja) エポキシ樹脂組成物、樹脂硬化物、プリプレグおよび繊維強化複合材料
KR20130108351A (ko) 에폭시 수지 조성물, 프리프레그 및 섬유 강화 복합 재료
WO2014112180A1 (ja) エポキシ樹脂組成物、プリプレグおよび炭素繊維強化複合材料
US20140212658A1 (en) Benzoxazine resin composition, and fiber-reinforced composite material
JP2011079983A (ja) 炭素繊維強化複合材料用エポキシ樹脂組成物、プリプレグおよび炭素繊維強化複合材料
JP6555006B2 (ja) エポキシ樹脂組成物、樹脂硬化物、プリプレグおよび繊維強化複合材料
JP2016132709A (ja) エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
JP2016132708A (ja) エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
US20150132553A1 (en) Fiber-reinforced composite material
JPWO2018131580A1 (ja) エポキシ樹脂組成物、エポキシ樹脂硬化物、プリプレグ、繊維強化複合材料、ブロック共重合体およびその製造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20161207

CF01 Termination of patent right due to non-payment of annual fee