CN104271362B - 用于制备具有高含量的1,4‑顺式单元的支链聚丁二烯的方法 - Google Patents

用于制备具有高含量的1,4‑顺式单元的支链聚丁二烯的方法 Download PDF

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CN104271362B
CN104271362B CN201380024130.2A CN201380024130A CN104271362B CN 104271362 B CN104271362 B CN 104271362B CN 201380024130 A CN201380024130 A CN 201380024130A CN 104271362 B CN104271362 B CN 104271362B
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side chain
cis units
preparation
load
polybutadiene
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CN104271362A (zh
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安德里亚·瓦莱利
玛丽安娜·津纳
康斯坦丁诺·佩雷塔
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Versalis SpA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/14—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen
    • C08F236/16—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201380024130.2A 2012-05-11 2013-04-24 用于制备具有高含量的1,4‑顺式单元的支链聚丁二烯的方法 Active CN104271362B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT000808A ITMI20120808A1 (it) 2012-05-11 2012-05-11 "procedimento per la preparazione di polibutadiene ramificato ad alto contenuto in unita' 1,4-cis"
ITMI2012A000808 2012-05-11
PCT/IB2013/053230 WO2013168039A1 (en) 2012-05-11 2013-04-24 Process for the preparation of branched polybutadiene having a high content of 1,4-cis units

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CN104271362A CN104271362A (zh) 2015-01-07
CN104271362B true CN104271362B (zh) 2017-02-22

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US (1) US9822198B2 (enExample)
EP (1) EP2847006B1 (enExample)
JP (1) JP6154891B2 (enExample)
KR (1) KR102013895B1 (enExample)
CN (1) CN104271362B (enExample)
BR (1) BR112014026242B1 (enExample)
HU (1) HUE030225T2 (enExample)
IN (1) IN2014DN09018A (enExample)
IT (1) ITMI20120808A1 (enExample)
MY (1) MY170891A (enExample)
RU (1) RU2618531C2 (enExample)
TW (1) TWI614274B (enExample)
WO (1) WO2013168039A1 (enExample)
ZA (1) ZA201407010B (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016057985A1 (en) * 2014-10-10 2016-04-14 Bridgestone Corporation Polymerization catalyst composition and method of employing same
CN105906751B (zh) * 2016-05-24 2018-04-10 中国科学院长春应用化学研究所 一种含有不饱和长链烷基的烷基铝的制备方法
IT201800005841A1 (it) * 2018-05-30 2019-11-30 Procedimento per la preparazione di copolimeri random butadiene-isoprene ad elevato contenuto di unita’ 1,4-cis
KR102161967B1 (ko) * 2018-10-02 2020-10-06 금호석유화학 주식회사 다기능화 고시스 1,4-폴리부타디엔의 제조방법
CN113880975B (zh) * 2021-11-11 2023-06-20 中国科学院长春应用化学研究所 一种磷脂类化合物改性聚丁二烯橡胶及其制备方法和硫化橡胶
CN114853948A (zh) * 2022-03-09 2022-08-05 青岛科技大学 一种支化高顺式稀土共轭二烯烃橡胶及其制备方法和应用

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0863165A1 (en) * 1997-03-05 1998-09-09 JSR Corporation Method of producing conjugated diene polymers
EP1431318A1 (en) * 2002-12-20 2004-06-23 Polimeri Europa S.p.A. Process for the preparation of branched polydienes in the presence of catalysts based on rare-earth
US20050182213A1 (en) * 2004-01-22 2005-08-18 Polimeri Europa S.P.A. Process for the preparation of polybutadiene with a low branching degree
EP1650227A2 (en) * 2004-10-25 2006-04-26 Polimeri Europa S.p.A. A process for the preparation of low branch content Polybutadiene
EP1975200A1 (en) * 2006-01-20 2008-10-01 Bridgestone Corporation Rubber composition containing modified polybutadiene rubber and tire
CN102037027A (zh) * 2008-04-02 2011-04-27 波利玛利欧洲股份公司 具有高1,4-顺式单元含量的支化聚丁二烯的制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9119234D0 (en) * 1991-09-09 1991-10-23 Enichem Elastomers Ltd Conjugated diene polymerisation
RU2099357C1 (ru) * 1995-02-10 1997-12-20 Акционерное общество открытого типа "Ефремовский завод синтетического каучука" Способ получения 1,4-цис-полибутадиена
JP4038916B2 (ja) * 1999-02-03 2008-01-30 Ｊｓｒ株式会社 共役ジエン系重合体の製造方法
US6437205B1 (en) * 1999-05-19 2002-08-20 Bridgestone Corporation Low molecular weight high-cis polybutadienes and their use in high molecular weight-low molecular weight high-cis polybutadiene blends
EP1337563B1 (en) * 2000-10-06 2006-12-20 Carnegie-Mellon University Polymerization process for ionic monomers
KR100416409B1 (ko) * 2001-01-22 2004-01-31 금호석유화학 주식회사 실록산 화합물로 말단 변성된 고 1,4-시스 폴리부타디엔의제조방법
KR100472649B1 (ko) * 2002-11-22 2005-03-11 금호석유화학 주식회사 조절된 저온흐름성을 갖는 고 1,4-시스 폴리부타디엔의제조방법
CN100448898C (zh) * 2005-03-30 2009-01-07 中国石油化工股份有限公司 一种稀土催化剂及共轭二烯烃的聚合方法
RU2569673C2 (ru) * 2010-09-23 2015-11-27 Бриджстоун Корпорейшн Способ получения полидиенов

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0863165A1 (en) * 1997-03-05 1998-09-09 JSR Corporation Method of producing conjugated diene polymers
EP1431318A1 (en) * 2002-12-20 2004-06-23 Polimeri Europa S.p.A. Process for the preparation of branched polydienes in the presence of catalysts based on rare-earth
US20050182213A1 (en) * 2004-01-22 2005-08-18 Polimeri Europa S.P.A. Process for the preparation of polybutadiene with a low branching degree
EP1650227A2 (en) * 2004-10-25 2006-04-26 Polimeri Europa S.p.A. A process for the preparation of low branch content Polybutadiene
EP1975200A1 (en) * 2006-01-20 2008-10-01 Bridgestone Corporation Rubber composition containing modified polybutadiene rubber and tire
CN102037027A (zh) * 2008-04-02 2011-04-27 波利玛利欧洲股份公司 具有高1,4-顺式单元含量的支化聚丁二烯的制备方法

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ZA201407010B (en) 2015-12-23
TW201350515A (zh) 2013-12-16
RU2618531C2 (ru) 2017-05-04
WO2013168039A1 (en) 2013-11-14
JP2015516020A (ja) 2015-06-04
BR112014026242B1 (pt) 2020-11-24
CN104271362A (zh) 2015-01-07
IN2014DN09018A (enExample) 2015-05-22
EP2847006B1 (en) 2016-04-13
BR112014026242A2 (pt) 2017-06-27
JP6154891B2 (ja) 2017-06-28
RU2014138950A (ru) 2016-07-10
MY170891A (en) 2019-09-12
HUE030225T2 (en) 2017-04-28
EP2847006A1 (en) 2015-03-18
US20150080526A1 (en) 2015-03-19
US9822198B2 (en) 2017-11-21
KR102013895B1 (ko) 2019-08-23
ITMI20120808A1 (it) 2013-11-12
TWI614274B (zh) 2018-02-11
KR20150013504A (ko) 2015-02-05

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