CN103998131A - 从热处理的杂原子胺前体衍生的用于燃料电池应用的非-pgm阴极催化剂 - Google Patents

从热处理的杂原子胺前体衍生的用于燃料电池应用的非-pgm阴极催化剂 Download PDF

Info

Publication number
CN103998131A
CN103998131A CN201280039823.4A CN201280039823A CN103998131A CN 103998131 A CN103998131 A CN 103998131A CN 201280039823 A CN201280039823 A CN 201280039823A CN 103998131 A CN103998131 A CN 103998131A
Authority
CN
China
Prior art keywords
aapyr
silica
precursors
population
pores
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201280039823.4A
Other languages
English (en)
Chinese (zh)
Inventor
A.塞罗夫
B.哈列维
K.阿特于什科瓦
P.B.阿塔纳索夫
U.A.马丁内斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UNM Rainforest Innovations
Original Assignee
STC UNM
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by STC UNM filed Critical STC UNM
Publication of CN103998131A publication Critical patent/CN103998131A/zh
Pending legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • H01M4/8652—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/33—Electric or magnetic properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/084—Decomposition of carbon-containing compounds into carbon
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H01M4/8882—Heat treatment, e.g. drying, baking
    • H01M4/8885—Sintering or firing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9041—Metals or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
    • H01M4/9083—Catalytic material supported on carriers, e.g. powder carriers on carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9091—Unsupported catalytic particles; loose particulate catalytic materials, e.g. in fluidised state
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
    • H01M2004/8689—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Composite Materials (AREA)
  • Catalysts (AREA)
  • Inert Electrodes (AREA)
CN201280039823.4A 2011-06-15 2012-06-15 从热处理的杂原子胺前体衍生的用于燃料电池应用的非-pgm阴极催化剂 Pending CN103998131A (zh)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US201161497444P 2011-06-15 2011-06-15
US61/497444 2011-06-15
US201261606109P 2012-03-02 2012-03-02
US61/606109 2012-03-02
US201261621084P 2012-04-06 2012-04-06
US201261621095P 2012-04-06 2012-04-06
US61/621095 2012-04-06
US61/621084 2012-04-06
PCT/US2012/042609 WO2012174344A2 (en) 2011-06-15 2012-06-15 Non-pgm cathode catalysts for fuel cell application derived from heat treated heteroatomic amines precursors

Publications (1)

Publication Number Publication Date
CN103998131A true CN103998131A (zh) 2014-08-20

Family

ID=47357757

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280039823.4A Pending CN103998131A (zh) 2011-06-15 2012-06-15 从热处理的杂原子胺前体衍生的用于燃料电池应用的非-pgm阴极催化剂

Country Status (11)

Country Link
US (1) US9634331B2 (enExample)
EP (1) EP2720793B1 (enExample)
JP (1) JP6202629B2 (enExample)
KR (1) KR20140035492A (enExample)
CN (1) CN103998131A (enExample)
AU (1) AU2012271494B2 (enExample)
CA (1) CA2838267C (enExample)
DK (1) DK2720793T3 (enExample)
HK (1) HK1201228A1 (enExample)
IL (1) IL229855B (enExample)
WO (1) WO2012174344A2 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114388802A (zh) * 2021-12-24 2022-04-22 合肥国轩高科动力能源有限公司 一种单原子负载氮磷共掺杂碳复合材料包覆的磷酸铁锂及其制备方法和应用
CN116093388A (zh) * 2015-03-13 2023-05-09 Stc.Unm 公司 用于大功率燃料电池的智能mea的设计
CN118949986A (zh) * 2024-07-26 2024-11-15 北京工业大学 一种原子间距可调的铁原子催化剂及其制备方法和应用

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014011831A1 (en) * 2012-07-11 2014-01-16 Stc.Unm Carbendazim-based catalytic materials
WO2014113525A1 (en) * 2013-01-16 2014-07-24 Stc.Unm Non-pgm catalysts for orr based on charge transfer organic complexes
CN103326041B (zh) * 2013-06-19 2015-03-25 厦门大学 一种氧还原电催化剂及其制备方法
DE102013219937A1 (de) * 2013-10-01 2015-04-02 Volkswagen Aktiengesellschaft Edemetallfreies Katalysatorsystem für eine Brennstoffzelle
US10619256B2 (en) 2015-02-16 2020-04-14 Stc.Unm Materials with atomically dispersed chemical moieties
CN105789644B (zh) * 2016-03-02 2018-08-21 中南大学 一种Fe-N/C氧还原反应复合电催化剂的制备方法
WO2018159622A1 (en) * 2017-02-28 2018-09-07 Okinawa Institute Of Science And Technology School Corporation Process for preparing a supported catalytic material, and supported catalytic material
CN108889300A (zh) * 2018-06-04 2018-11-27 中国科学院生态环境研究中心 一种新型水热炭负载纳米双金属催化剂的制备方法及其应用
CN113097515A (zh) * 2019-12-23 2021-07-09 罗伯特·博世有限公司 导电抗腐蚀镁钛氧化物催化剂载体材料
US20250329754A1 (en) 2023-03-29 2025-10-23 GM Global Technology Operations LLC Fuel Cell Electrode and Fuel Cell System Including Zirconium-Based Dopants

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005035841A2 (en) * 2003-10-10 2005-04-21 Board Of Regents, The University Of Texas System Carbon nanostructure-based electrocatalytic electrodes
CN1635654A (zh) * 2003-12-31 2005-07-06 山东理工大学 活性炭表面用卟啉、酞菁化学修饰的产品在燃料电池中的应用
CN101657921A (zh) * 2007-04-12 2010-02-24 3M创新有限公司 高性能、高耐用非贵重金属燃料电池催化剂
US20100167106A1 (en) * 2008-12-31 2010-07-01 Samsung Electronics Co., Ltd. Ordered mesoporous carbon composite catalyst, method of manufacturing the same, and fuel cell using the same

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5240893A (en) 1992-06-05 1993-08-31 General Motors Corporation Method of preparing metal-heterocarbon-nitrogen catalyst for electrochemical cells
DE10132490B4 (de) * 2001-07-03 2007-04-12 Hahn-Meitner-Institut Berlin Gmbh Platinfreies Chelat-Katalysatormaterial für die selektive Sauerstoffreduktion und Verfahren zu seiner Herstellung
US7718155B2 (en) * 2005-10-06 2010-05-18 Headwaters Technology Innovation, Llc Carbon nanostructures manufactured from catalytic templating nanoparticles
JP4893918B2 (ja) 2005-11-15 2012-03-07 株式会社豊田中央研究所 含窒素炭素系電極触媒
US7618915B2 (en) 2006-05-08 2009-11-17 University Of South Carolina Composite catalysts supported on modified carbon substrates and methods of making the same
US7678728B2 (en) * 2006-10-16 2010-03-16 Stc.Unm Self supporting structurally engineered non-platinum electrocatalyst for oxygen reduction in fuel cells
KR101473319B1 (ko) 2007-10-16 2014-12-16 삼성에스디아이 주식회사 복합 중형 다공성 탄소, 그 제조방법 및 이를 이용한연료전지
WO2009075038A1 (en) 2007-12-12 2009-06-18 Toyota Jidosha Kabushiki Kaisha Electrode catalyst for fuel cells, a method of preparing an electrode catalyst for fuel cells, and a polymer electrolyte fuel cell
US20100048380A1 (en) 2008-08-21 2010-02-25 Board Of Trustees Of Michigan State University Novel catalyst for oxygen reduction reaction in fuel cells
JP5507099B2 (ja) * 2009-03-11 2014-05-28 花王株式会社 メソポーラスシリカ粒子の製造方法
CN102348641B (zh) * 2009-03-12 2014-03-19 三井化学株式会社 新型金属氧化物多孔质体、其制造方法及用途
JP5636171B2 (ja) 2009-06-19 2014-12-03 東洋炭素株式会社 多孔質炭素及びその製造方法
US20140349843A1 (en) * 2011-09-16 2014-11-27 Stc.Unm Structured Cathode Catalysts for Fuel Cell Application Derived From Metal-Nitrogen-Carbon Precursors, Using Hierarchically Structured Silica as a Sacrificial Support
WO2013187976A1 (en) * 2012-06-13 2013-12-19 Stc.Unm Bi-functional catalysts for oxygen reduction and oxygen evolution
WO2014011831A1 (en) * 2012-07-11 2014-01-16 Stc.Unm Carbendazim-based catalytic materials
US9359681B1 (en) * 2013-03-11 2016-06-07 Alexey Serov CO2 electroreduction on metals and metal alloys prepared by a sacrificial support-based method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005035841A2 (en) * 2003-10-10 2005-04-21 Board Of Regents, The University Of Texas System Carbon nanostructure-based electrocatalytic electrodes
CN1635654A (zh) * 2003-12-31 2005-07-06 山东理工大学 活性炭表面用卟啉、酞菁化学修饰的产品在燃料电池中的应用
CN101657921A (zh) * 2007-04-12 2010-02-24 3M创新有限公司 高性能、高耐用非贵重金属燃料电池催化剂
US20100167106A1 (en) * 2008-12-31 2010-07-01 Samsung Electronics Co., Ltd. Ordered mesoporous carbon composite catalyst, method of manufacturing the same, and fuel cell using the same

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ARND GARSUCH等: "Fuel Cell Studies on a Non-Noble Metal Catalyst Prepared by a Template-Assisted Synthesis Route", 《JOURNAL OF THE ELECTROCHEMICAL SOCIETY》 *
S. HWANG等: "Preparation of Bimodal Porous Carbon Supported PtRu Catalysts for Fuel Cells", 《FUEL CELLS》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116093388A (zh) * 2015-03-13 2023-05-09 Stc.Unm 公司 用于大功率燃料电池的智能mea的设计
CN114388802A (zh) * 2021-12-24 2022-04-22 合肥国轩高科动力能源有限公司 一种单原子负载氮磷共掺杂碳复合材料包覆的磷酸铁锂及其制备方法和应用
CN114388802B (zh) * 2021-12-24 2023-03-10 合肥国轩高科动力能源有限公司 一种单原子负载氮磷共掺杂碳复合材料包覆的磷酸铁锂及其制备方法和应用
CN118949986A (zh) * 2024-07-26 2024-11-15 北京工业大学 一种原子间距可调的铁原子催化剂及其制备方法和应用

Also Published As

Publication number Publication date
HK1201228A1 (en) 2015-08-28
JP6202629B2 (ja) 2017-09-27
EP2720793A2 (en) 2014-04-23
WO2012174344A3 (en) 2013-05-02
EP2720793A4 (en) 2015-01-14
US20160181621A1 (en) 2016-06-23
AU2012271494B2 (en) 2017-03-09
KR20140035492A (ko) 2014-03-21
CA2838267A1 (en) 2012-12-20
JP2014523065A (ja) 2014-09-08
EP2720793B1 (en) 2018-03-07
IL229855B (en) 2018-01-31
WO2012174344A2 (en) 2012-12-20
DK2720793T3 (en) 2018-05-07
CA2838267C (en) 2018-10-02
AU2012271494A1 (en) 2013-12-19
US9634331B2 (en) 2017-04-25

Similar Documents

Publication Publication Date Title
AU2012271494B2 (en) Non-PGM cathode catalysts for fuel cell application derived from heat treated heteroatomic amines precursors
US9502719B2 (en) Cathode catalysts for fuel cell application derived from polymer precursors
US9647275B2 (en) Bi-functional catalysts for oxygen reduction and oxygen evolution
EP3269003B1 (en) Design of smart-meas for high power fuel cells
US9515323B2 (en) Cathode catalysts for fuel cells
CN104812488B (zh) 基于贝芬替的催化材料
Cao et al. Enhanced electrocatalytic activity of platinum nanoparticles supported on nitrogen-modified mesoporous carbons for methanol electrooxidation
US10038196B2 (en) Active support for cathode catalysts
CN104812489A (zh) 基于热解的聚-复合物,用于氧还原反应的非铂族金属催化剂
CN105188922A (zh) 基于电荷转移有机络合物的用于氧化还原反应的非pgm催化剂
Serov et al. Cathode catalysts for fuel cell application derived from polymer precursors
Geng et al. Functionalization of Chemically Derived Graphene as Electrode Materials for Fuel Cells
HK1212945B (en) Carbendazim-based catalytic materials
HK1219074B (zh) 基於电荷转移有机复合物的用於氧化还原反应的非pgm催化剂
HK1208399B (en) Non-pgm catalyst for orr based on pyrolysed poly-complexes

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1201228

Country of ref document: HK

RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20140820