CN103998126B - 可用于烷烃脱氢的锌的和/或锰的铝酸盐催化剂 - Google Patents

可用于烷烃脱氢的锌的和/或锰的铝酸盐催化剂 Download PDF

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Publication number
CN103998126B
CN103998126B CN201280062907.XA CN201280062907A CN103998126B CN 103998126 B CN103998126 B CN 103998126B CN 201280062907 A CN201280062907 A CN 201280062907A CN 103998126 B CN103998126 B CN 103998126B
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zinc
manganese
catalyst composition
catalyst
aluminate
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Expired - Fee Related
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CN201280062907.XA
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English (en)
Chinese (zh)
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CN103998126A (zh
Inventor
安东尼萨米·塞尔瓦纳坦
钱德拉·拉哈·苏布哈希
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Saudi Basic Industries Corp
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Saudi Basic Industries Corp
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/322—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/34—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with zinc, cadmium or mercury

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201280062907.XA 2011-12-22 2012-12-17 可用于烷烃脱氢的锌的和/或锰的铝酸盐催化剂 Expired - Fee Related CN103998126B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11010141 2011-12-22
EP11010141.7 2011-12-22
PCT/EP2012/005211 WO2013091822A1 (en) 2011-12-22 2012-12-17 Zinc and/or manganese aluminate catalyst useful for alkane dehdyrogenation

Publications (2)

Publication Number Publication Date
CN103998126A CN103998126A (zh) 2014-08-20
CN103998126B true CN103998126B (zh) 2016-09-07

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CN201280062907.XA Expired - Fee Related CN103998126B (zh) 2011-12-22 2012-12-17 可用于烷烃脱氢的锌的和/或锰的铝酸盐催化剂

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US (1) US20130165729A1 (enExample)
EP (1) EP2794093B1 (enExample)
JP (1) JP6029682B2 (enExample)
KR (1) KR20140108264A (enExample)
CN (1) CN103998126B (enExample)
EA (1) EA023714B1 (enExample)
WO (1) WO2013091822A1 (enExample)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101425985B1 (ko) * 2012-04-10 2014-08-14 한국생산기술연구원 글리세롤로부터 글리세롤 카보네이트를 제조하기 위한 촉매, 이의 제조방법 및 이를 이용한 글리세롤로부터 글리세롤 카보네이트를 제조하는 방법
WO2014118194A2 (fr) 2013-01-29 2014-08-07 IFP Energies Nouvelles Catalyseur comprenant des oxydes mixtes des éléments aluminium, zinc et manganèse et son utilisation en déshydrogenation
CN105363455B (zh) * 2014-08-27 2018-10-23 中国石油化工股份有限公司 低碳烷烃脱氢制低碳烯烃催化剂及其应用
CN105435856B (zh) * 2014-08-27 2018-07-17 中国石油化工股份有限公司 低碳烷烃脱氢制低碳烯烃催化剂载体及其用途
CN105363472B (zh) * 2014-08-27 2018-04-06 中国石油化工股份有限公司 低碳烷烃脱氢制低碳烯烃催化剂及其使用方法
CN106365939A (zh) * 2016-08-28 2017-02-01 山东成泰化工有限公司 一种异丁烯的制备方法
CN106622357A (zh) * 2016-08-28 2017-05-10 山东成泰化工有限公司 一种异丁烯制备用催化剂
CN109647433B (zh) * 2017-10-12 2021-11-30 中国石油化工股份有限公司 异丁烷脱氢的催化剂
US11033880B2 (en) 2018-09-28 2021-06-15 Exelus, Inc. Mixed metal oxide catalyst useful for paraffin dehydrogenation
CN113365727B (zh) * 2018-09-28 2024-03-08 艾克瑟路斯股份有限公司 可用于链烷烃脱氢的改进的混合金属氧化物催化剂
US11364482B2 (en) 2019-05-17 2022-06-21 Exelus, Inc. Mixed metal oxide catalyst useful for paraffin dehydrogenation
US11168039B2 (en) 2019-05-17 2021-11-09 Exelus, Inc. Mixed metal oxide catalyst useful for paraffin dehydrogenation
WO2020236738A1 (en) 2019-05-17 2020-11-26 Exelus, Inc. Improved mixed metal oxide catalyst useful for paraffin dehydrogenation
WO2020236707A1 (en) 2019-05-17 2020-11-26 Exelus, Inc. Improved mixed metal oxide catalyst useful for paraffin dehydrogenation
KR102628005B1 (ko) * 2019-11-27 2024-01-19 에스케이가스 주식회사 알칸족 가스로부터 올레핀 제조용 탈수소촉매 및 그 제조방법
CN111013563B (zh) * 2019-12-15 2022-08-19 复旦大学 用于二氧化碳气氛下乙烷脱氢制乙烯的尖晶石催化剂及其制备方法
CN113967472B (zh) * 2020-07-24 2024-11-12 中国石油化工股份有限公司 丙烷脱氢催化剂的制备方法
CN114425388B (zh) * 2020-10-15 2023-08-29 中国石油化工股份有限公司 低碳烷烃脱氢制备低碳烯烃催化剂及其制备方法和应用
CN114425316B (zh) * 2020-10-15 2024-01-30 中国石油化工股份有限公司 载体及其制备方法和烷烃脱氢催化剂及其制备方法和应用
CN114618463B (zh) * 2020-12-10 2023-11-17 中国科学院大连化学物理研究所 一种复合型催化剂及其制备方法和应用
CN114950401A (zh) * 2022-07-07 2022-08-30 润和科华催化剂(上海)有限公司 改性铝酸锌载体、低碳烷烃脱氢催化剂及其制备方法和应用
CN114984946A (zh) * 2022-07-08 2022-09-02 润和科华催化剂(上海)有限公司 一种镓基低碳烷烃脱氢催化剂及其制备方法和应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85101105A (zh) * 1984-06-19 1987-01-10 飞力士石油公司 催化脱氢工艺中副产物丁二烯的重复利用
CN1044646A (zh) * 1989-02-06 1990-08-15 菲利蒲石油公司 脱氢方法
EP0557982A2 (en) * 1992-02-26 1993-09-01 Phillips Petroleum Company Alkane dehydrogenation
EP0623383A1 (en) * 1993-05-03 1994-11-09 Phillips Petroleum Company Platinum and tin-containing catalyst and use thereof in alkane dehydrogenation

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5016322B1 (enExample) * 1967-02-10 1975-06-12
US3626021A (en) * 1968-07-01 1971-12-07 Atlantic Richfield Co Dehydrogenation of aliphatics over alkali metal oxide-chromia-zinc aluminate spinel catalyst
US3880776A (en) * 1971-06-10 1975-04-29 Phillips Petroleum Co Highly calcined support for catalytic dehydrogenation
US3763255A (en) 1972-02-01 1973-10-02 Universal Oil Prod Co Dehydrogenation method and multicomponent catalyst for use therein
US3948808A (en) * 1973-03-02 1976-04-06 Phillips Petroleum Company Zinc aluminate catalyst compositions
US4191846A (en) * 1973-11-15 1980-03-04 Phillips Petroleum Company Catalytic dehydrogenation process
US4229609A (en) * 1979-03-08 1980-10-21 Phillips Petroleum Company Process for dehydrogenating hydrocarbons
AU562124B2 (en) * 1984-06-19 1987-05-28 Phillips Petroleum Co. Dehydrogenation of butanes
CA2050146C (en) * 1990-11-19 1998-10-27 Paul F. Schubert Catalyst preparation
FR2718371B1 (fr) * 1994-04-08 1996-05-03 Rhone Poulenc Chimie Catalyseurs de réduction des oxydes d'azote à base de spinelles.
JP3889467B2 (ja) * 1996-09-25 2007-03-07 日本特殊陶業株式会社 窒素酸化物除去用触媒材料及び該材料を用いた窒素酸化物処理装置並びに窒素酸化物除去方法
US6127310A (en) * 1997-02-27 2000-10-03 Phillips Petroleum Company Palladium containing hydrogenation catalysts
JP4054116B2 (ja) * 1998-07-24 2008-02-27 千代田化工建設株式会社 脱水素触媒
JP2000037629A (ja) * 1998-07-24 2000-02-08 Chiyoda Corp 脱水素触媒
JP2004196638A (ja) * 2002-12-20 2004-07-15 Chiyoda Corp 水素の製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85101105A (zh) * 1984-06-19 1987-01-10 飞力士石油公司 催化脱氢工艺中副产物丁二烯的重复利用
CN1044646A (zh) * 1989-02-06 1990-08-15 菲利蒲石油公司 脱氢方法
EP0557982A2 (en) * 1992-02-26 1993-09-01 Phillips Petroleum Company Alkane dehydrogenation
EP0623383A1 (en) * 1993-05-03 1994-11-09 Phillips Petroleum Company Platinum and tin-containing catalyst and use thereof in alkane dehydrogenation

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
尖晶石的性质_制备及在催化中的应用;董文生，等;《石油化工高等学校学报》;19961231;第9卷(第4期);全文 *

Also Published As

Publication number Publication date
CN103998126A (zh) 2014-08-20
EA023714B1 (ru) 2016-07-29
WO2013091822A1 (en) 2013-06-27
EA201491210A1 (ru) 2014-09-30
JP6029682B2 (ja) 2016-11-24
EP2794093B1 (en) 2019-11-06
JP2015507528A (ja) 2015-03-12
EP2794093A1 (en) 2014-10-29
US20130165729A1 (en) 2013-06-27
KR20140108264A (ko) 2014-09-05

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