CN103874576A - 装饰板 - Google Patents

装饰板 Download PDF

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Publication number
CN103874576A
CN103874576A CN201280049874.5A CN201280049874A CN103874576A CN 103874576 A CN103874576 A CN 103874576A CN 201280049874 A CN201280049874 A CN 201280049874A CN 103874576 A CN103874576 A CN 103874576A
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resin
decorative panel
manufacture
decorative
noninflammability
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CN103874576B (zh
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安井元隆
香山和辉
荻野智也
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Eike Kogyo K K
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Eike Kogyo K K
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

一种装饰板(5)，其特征在于，将含有(a)粘合剂成分以及(b)吸热性金属氢氧化物的预浸料(2)和热固性树脂浸渍装饰纸(1)层叠并使其一体化，其中在所述(a)粘合剂成分中，(a1)选自玻璃化转变温度Tg超过0℃的丙烯酸树脂、玻璃化转变温度Tg超过0℃的氯乙烯树脂、丙烯酸氨基甲酸酯树脂、以及水性聚氨酯树脂中的至少一种热塑性树脂与(a2)热固性树脂的配合比例以固体成分的比例计为1∶0-0.5。

Description

装饰板
相关申请的交叉引用
本申请要求2011年10月13日在日本专利局提交的日本发明专利申请第2011-225419号的优先权，所述日本发明专利中请的全部内容通过引用而并入本文。
技术领域
本发明涉及一种装饰板。
背景技术
以往，已知有热固性树脂装饰板。在热固性树脂装饰板中，特别是符合JIS K6902“热固性树脂高压装饰板试验方法”的三聚氰胺装饰板由于具有优良的耐热性、抗冲击性、耐磨性以及尺寸稳定性，而被广泛地用于住宅器具、内部装饰材料(例如顶板、台面等)等。
近几年，已知使用无机纤维无纺布来替代牛皮纸作为构成芯层的纤维质基材的同时，使用配合了含有热固性树脂的粘合剂成分和无机填充剂的浆料制造的不燃性装饰板(专利文献1)。另外，还公开了使用浸渍了含有热固性树脂且含有合成树脂乳液或橡胶胶乳等热塑性树脂的浆料的预浸料来制造不燃性装饰板的技术(专利文献2、3、4)。
现有技术文献
专利文献
专利文献1：日本特开第2008-290444号公报
专利文献2：日本特开第2005-103769号公报
专利文献3：日本特开第2005-199532号公报
专利文献4：日本特开平第3-253342号公报
发明内容
发明要解决的问题
但是，以往的不燃性装饰板的板厚为3mm左右，因其较厚，所以当粘合加工于桌子、台子的顶板时，由于截面显眼而没有整体感。另外，因为以往的不燃性装饰板厚且重，所以在家具加工工序中，与板厚0.8-1.6mm的一般的三聚氰胺装饰板相比难以操作。解决上述问题为本发明的一个方面。
解决问是的技术方案
本发明的装饰板的特征在于，将含有(a)粘合剂成分以及(b)吸热性金属氢氧化物的预浸料和热固性树脂浸渍装饰纸层叠并使其一体化，其中在所述(a)粘合剂成分中，(a1)选自玻璃化转变温度Tg超过0℃的丙烯酸树脂、玻璃化转变温度Tg超过0℃的氯乙烯树脂、丙烯酸氨基甲酸酯树脂、以及水性聚氨酯树脂中的至少一种热塑性树脂与(a2)热固性树脂的配合比例以固体成分的比例计为1∶0-0.5。
即使本发明的装饰板的板厚较薄(例如即使为0.6-0.8mm)也具有不燃性。此外，本发明的装饰板易于加工，翘曲也小，便于处理。
附图说明
图1是表示不燃性装饰板5的结构的截面图。
图2是表示不燃性装饰板5’的结构的截面图。
附图标记的说明
1…三聚氰胺树脂浸渍装饰纸
2…预浸料
3…三聚氰胺树脂浸渍平衡纸
5、5’…不燃性装饰板
具体实施方式
在本发明中，(a1)热塑性树脂与(a2)热固性树脂的配合比例以固体成分的比例(重量比)计为1∶0-0.5。在此范围之内可使装饰板的挠性得以提高。
(a1)热塑性树脂为选自玻璃化转变温度Tg超过0℃的丙烯酸树脂、玻璃化转变温度Tg超过0℃的氯乙烯树脂、内烯酸氨基甲酸酯树脂、以及水性聚氨酯树脂中的至少一种。不特别限定丙烯酸氨基甲酸酯树脂以及水性聚氨酯树脂的玻璃化转变温度Tg。
另外，作为(a1)热塑性树脂，如果使用平均粒径为150-300nm的丙烯酸树脂乳液，则可以进一步提高预浸料的粘结力、以及装饰板的弯曲加工性或平滑性。平滑性提高的原因可以推测为由于丙烯酸树脂乳液是微颗粒。而且，平均粒径为使用激光衍射散射式粒径测定装置(大塚电子株式会社制ELS-8000)且基于在激光照射时测定得到的散射光而计算出的值。
作为所述(a2)热固性树脂可列举例如三聚氰胺-甲醛树脂、苯酚-甲醛树脂、不饱和聚酯树脂等。在此之中，如果使用玻璃化转变温度超过0℃的丙烯酸树脂，则能够使弯曲性、密合性、成形性进一步得以提高。(a2)热固性树脂为任意成分，也可以不配合。
(b)吸热性金属氢氧化物含有结晶水，在高温时分解、吸热、释放结合水，因此，提高了本发明的装饰板的不燃性。作为吸热性金属氢氧化物可列举例如氢氧化铝、氢氧化镁、氢氧化钙等。
(b)吸热性金属氢氧化物可以与例如(a)粘合剂成分等一起作为浆料的配合成分。可以将该浆料浸渍到例如纤维质基材中，来制造预浸料。吸热性金属氢氧化物的平均粒径可以在例如1-50μm的范围内。该平均粒径为基于通过激光衍射散射法(Microtrack法)测定得到的粒度分布(体积分布)而算出的算术平均粒径。通过使吸热性金属氢氧化物的平均粒径在上述范围内来提高浆料中的(b)吸热性金属氢氧化物的分散性，并提高浆料对纤维质基材的浸渍性。另外，通过使吸热性金属氢氧化物的平均粒径在上述范围内，最终的装饰板的表面成平滑表面。
所述预浸料除(b)吸热性金属氢氧化物外，还可含有例如无水无机填充剂。作为无水无机填充剂可列举例如碳酸钙、碳酸镁、碳酸锌等的碳酸盐、二氧化硅、滑石、粉煤灰等。无水无机填充剂的平均粒径(基于通过激光衍射散射法(Microtrack法)测定得到的粒度分布(体积分布)算出的算术平均粒径)可在例如0.0520μm的范围内。在这种情况下，浆料对纤维质基材的浸渍性进一步得以提高。
在无水无机填充剂中，特别可以选择碳酸盐(例如碳酸钙)。在这种情况下，在装饰板的制造工序中的操作性、切削性进一步得以提高。作为碳酸钙可以使用例如重质碳酸钙、轻质碳酸钙(沉淀性碳酸钙)等。碳酸钙的平均粒径可为例如0.05-10μn、更可优选为1-5μn。平均粒径为0.05μm以上可使得在浆料中不易产生碳酸钙的凝集，浆料对纤维质基材的浸渍性得以提高。另外，通过使平均粒径在10μm以下，装饰板的表面变得更加平滑，并且外观得以改善。
并且，轻质碳酸钙是指通过将石灰石煅烧化学制造的碳酸钙，重质碳酸钙是指通过将白色结晶石灰石进行干式或湿式粉碎而制造的细粉碳酸钙。
在预浸料所含的全部无机填充剂中(b)吸热性金属氢氧化物所占的配合比例可为例如50-100重量％。在这种情况下，装饰板的不燃性进一步得以提高。
在本发明的装饰板中，预浸料可含有例如(c)硅烷偶联剂。在这种情况下，与不含(c)硅烷偶联剂时相比，在JIS K-6902“热固性树脂高压装饰板试验方法”的耐蒸煮性方面，重量增加率变得更小，另外，预浸料和热固性树脂浸渍装饰纸的密合性进一步增强。
(c)成分的配合比例可为例如(a)+(b)+(c)的全部成分中的0.7-0.9重量％。在这种情况下，在JIS K-6902“热固性树脂高压装饰板试验方法”的耐蒸煮性方面，重量增加率变得更小，另外，预浸料和热固性树脂浸渍装饰纸的密合性进一步增强。
作为硅烷偶联剂可列举例如3-(甲基)丙烯酰氧基丙基三甲氧基硅烷、3-(甲基)丙烯酰氧基丙基三乙氧基硅烷等含有(甲基)丙烯酰氧基的硅烷、乙烯基三甲氧基硅烷、乙烯基三乙氧基硅烷等含有乙烯基的硅烷、3-缩水甘油醚氧丙基三甲氧基硅烷、3-缩水甘油醚氧丙基三乙氧基硅烷等含有环氧基的硅烷、p-苯乙烯基三甲氧基硅烷等含有苯乙烯基的硅烷、3-氨基丙基三甲氧基硅烷、3-氨基丙基三乙氧基硅烷等含有氨基的硅烷、3-巯基丙基三甲氧基硅烷等含有巯基的硅烷等。尤其是如果使用含有环氧基的硅烷或含有氨基的硅烷，则预浸料中的交联密度进一步得以提高。
全体组合物(a+b+c)中的(a)粘合剂成分的比例可为例如按固体成分计9-15重量％。通过使粘合剂成分的比例在15重量％以下，不燃性进一步得以提高，同时在热压成形时合成树脂不易发生渗出。另外，通过使粘合剂成分的比例在9重量％以上，预浸料彼此间的密合性进一步得以提高，同时对纤维质基材的浆料浸渍量的控制变得更加容易。
本发明的装饰板中的预浸料可通过将含有例如(a)粘合剂成分以及(b)吸热性金属氢氧化物的浆料浸渍到纤维质基材中而制造。作为该纤维质基材可列举例如有机纤维基材或无机纤维基材等。
作为有机纤维基材可列举例如包含聚乙烯、聚丙烯、维尼纶、聚氯乙烯、聚偏二氯乙烯、聚丙烯腈、聚酰胺、聚酯、聚氨酯等、这些物质的改性物、乙烯-乙酸乙烯酯共聚物等所代表的各种共聚物的纤维、包含这些物质的混合物的复合纤维、以及包含这些物质的聚合物复合纤维等。
作为无机纤维基材可列举例如由玻璃纤维、岩棉、碳纤维等的无机纤维形成的无纺布、织布等。无机纤维基材的基量可在例如10-200g／m2的范围内。使用无机纤维基材时，与使用有机纤维基材时相比，进一步提高了装饰板的不燃性。在无机纤维基材中，当使用玻璃纤维无纺布时，进一步提高了耐热性、耐燃性、浆料的浸渍性。
使用式1所表示的算出方法算出的对于纤维质基材的浆料固体成分浸渍率(％)优选在700-1200％的范围内。通过使浆料固体成分浸渍率在1200％以下，从预浸料脱落的浆料固体成分减少，并易于操作预浸料。通过使浆料固体成分浸渍率在700％以上，不易发生预浸料的层间剥离。
[式1]
Figure BDA0000489338600000051
在本发明的装饰板中，例如可以在包含将浆料浸渍到纤维质基材中的预浸料的芯层的至少单面上形成装饰层。作为装饰层的形成方法可列举例如实施涂装的方法或者使用树脂浸渍的装饰纸的方法或者使用转印箔转印装饰层的方法等。当使用树脂浸渍的装饰纸时，装饰板的生产率、芯层和装饰层的密合性、以及装饰层的耐磨性进一步得以提高。
使用树脂浸渍装饰纸的方法为，例如，首先，将以热固性树脂为主要成分的树脂液浸渍到热固性树脂装饰板用原纸中，其次，层叠干燥的树脂浸渍装饰纸，并进行热压成形的方法。在热压成形中可使用例如平板压机、连续压机等压力机。
树脂浸渍装饰纸可以通过例如将包含氨基-甲醛树脂、邻苯二甲酸二烯丙酯树脂、不饱和聚酯树脂等的热固性树脂的树脂液浸渍到热固性树脂装饰板用的30-140g／m2的装饰纸中，并使得式1所表示的浸渍率为80-300％来制造。在树脂浸渍装饰纸中，氨基-甲醛树脂浸渍装饰纸在耐热性、耐磨性方面更优良。
本发明的装饰板可以在其单面或双面上形成装饰层。只在单面上形成装饰层(例如由树脂浸渍装饰纸形成的装饰层)时，在另一个面上可以配置例如平衡纸。当配置了平衡纸时，可以进一步抑制装饰板的翘曲或破损。
作为平衡纸可列举，例如用树脂液对基量为18-40g／m2的装饰板用表面纸以按照式1所表示的算出方法算出的浸渍率260-320％进行浸渍，并进行干燥的树脂浸渍平衡纸，上述树脂液以热固性树脂(例如，三聚氰胺树脂、尿素树脂、胍胺树脂、邻苯二甲酸二烯丙酯树脂、丙烯酸树脂等)为主要成分，通过使用水、有机溶剂来稀释以调整粘度。
(实施例1)
(1)浆料的制造
制造含有以下成分的浆料。
玻璃化转变温度Tg为47℃，以丙烯酸乙酯和甲基丙烯酸甲酯作为主要单体的丙烯酸树脂乳液(型号AXN-150，爱克工业株式会社制造，平均粒径225nm)：36重量份(固体成分)
平均粒径8μm的氢氧化铝(吸热性金属氢氧化物)：200重量份
平均粒径1μm的重质碳酸钙(无水无机填充剂)：40重量份
另外，所述丙烯酸树脂乳液是(a1)成分的一个实施方式。
(2)预浸料的制造
将上述(1)中制造的浆料浸渍到50g／m2的玻璃纤维无纺布(纤维质基材)中且使得由式1所定义的算出方法算出的浸渍率为800％，并进行干燥从而制造预浸料。
(3)三聚氰胺树脂浸渍装饰纸的制造
将以三聚氰胺-甲醛树脂作为主要成分的树脂液浸渍到基量为100g／m2的白色的热固性树脂装饰板用装饰纸中且使得由式1所定义的算出方法算出的浸渍率为130％，并进行干燥从而制造三聚氰胺树脂浸渍装饰纸。
(4)三聚氰胺树脂浸渍平衡纸的制造
将以三聚氰胺-甲醛树脂作为主要成分的树脂液浸渍到基量为23g／m2的热固性树脂装饰板用表面纸中且使得由式1所定义的算出方法算出的浸渍率为280％，并进行干燥从而制造三聚氰胺树脂浸渍平衡纸。
(5)不燃性装饰板的制造
从下向上依次层叠上述(4)中制造的三聚氰胺树脂浸渍平衡纸1张、上述(2)中制造的预浸料2张、以及上述(3)中制造的三聚氰胺树脂浸渍装饰纸1张，使用平面加工板，在130℃、70kg／cm2、60分钟的条件下通过热压成形使其一体化，从而制造不燃性装饰板。如图1所示，所制造的不燃性装饰板5具有层叠了1张三聚氰胺树脂浸渍装饰纸1、2张预浸料2、以及1张三聚氰胺树脂浸渍平衡纸3的结构。
另外，在表1至表3中示出了基于本实施例以及后述的各实施例以及各比较例制造的不燃性装饰板的组成。组成的单位是重量份。
[表1]
Figure BDA0000489338600000071
[表2]
Figure BDA0000489338600000081
[表3]
(实施例2)
以基本上与上述实施例1相同的方式制造不燃性装饰板。但是，在浆料的制造中，丙烯酸树脂乳液的配合量为30重量份。
(实施例3)
以基本上与上述实施例1相同的方式制造不燃性装饰板。但是，在浆料的制造中，添加3-缩水甘油醚氧丙基三甲氧基硅烷((c)硅烷偶联剂)2.4重量份，其为一种含有环氧基的硅烷。
(实施例4)
以基本上与上述实施例3相同的方式制造不燃性装饰板。但是，在浆料的制造中，丙烯酸树脂乳液的配合量为26重量份，此外，3-缩水甘油醚氧丙基三甲氧基硅烷((c)硅烷偶联剂)的配合量为2.2重量份。
(实施例5)
以基本上与上述实施例3相同的方式制造不燃性装饰板。但是，在浆料的制造中，丙烯酸树脂乳液的配合量为32重量份，此外，3缩水甘油醚氧丙基三甲氧基硅烷((c)硅烷偶联剂)的配合量为2.2重量份。
(实施例6)
以基本上与上述实施例3相同的方式制造不燃性装饰板。但是，在浆料的制造中，丙烯酸树脂乳液的配合量为26重量份，此外，3-缩水甘油醚氧丙基三甲氧基硅烷((c)硅烷偶联剂)的配合量为1.9重量份。
(实施例7)
以基本上与上述实施例3相同的方式制造不燃性装饰板。但是，在浆料的制造中，丙烯酸树脂乳液的配合量为34重量份，氢氧化铝的配合量为120重量份，重质碳酸钙的配合量为120重量份，3-缩水甘油醚氧丙基三甲氧基硅烷((c)硅烷偶联剂)的配合量为2.2重量份。
(实施例8)
以基本上与上述实施例3相同的方式制造不燃性装饰板。但是，在浆料的制造中，丙烯酸树脂乳液的配合量为34重量份，氢氧化铝的配合量为240重量份，3-缩水甘油醚氧丙基三甲氧基硅烷((c)硅烷偶联剂)的配合量为2.2重量份。
(实施例9)
以基本上与上述实施例3相同的方式制造不燃性装饰板。但是，在浆料的制造中，3-缩水甘油醚氧丙基三甲氧基硅烷((c)硅烷偶联剂)的配合量为2.2重量份。此外，不使用三聚氰胺树脂浸渍平衡纸制造不燃性装饰板。如图2所示，所制造的不燃性装饰板5’具有层叠了1张三聚氰胺树脂浸渍装饰纸1以及2张预浸料2的结构。
本实施例中制造的不燃性装饰板与上述实施例1-8中制造的不燃性装饰板相比，弯曲强度稍弱，翘曲稍大。
(实施例10)
以基本上与上述实施例3相同的方式制造不燃性装饰板。但是，在浆料的制造中，使用3-(2-氨乙基)氨基丙基三甲氧基硅烷(商品名称：SH-6020、东丽道康宁株式会社制造(東レ·ゲゥコ-ニンゲ株式会社製))2.2重量份来替代3-缩水甘油醚氧丙基三甲氧基硅烷。3-(2-氨乙基)氨基丙基三甲氧基硅烷是(c)硅烷偶联剂的一个实施方式。
(实施例11)
以基本上与上述实施例3相同的方式制造不燃性装饰板。但是，在浆料的制造中，使用等量的丙烯酸氨基甲酸酯乳液(商品名称：WEM-3008、大成精细化工株式会社制造(大成ファイソケミ力ル株式会社製))来替代丙烯酸树脂乳液(型号AXN-150、爱克工业株式会社制造、平均粒径225nm)，另外，3-缩水甘油醚氧丙基三甲氧基硅烷的配合量为2.2重量份。
(实施例12)
以基本上与上述实施例11相同的方式制造不燃性装饰板。但是，在浆料的制造中，使用等量的使高分子量的热塑性氨基甲酸酯树脂稳定地分散在水中的非离子性的水性聚氨酯树脂(HYDRAN(注册商标)WLI-602、DIC株式会社制造)来替代丙烯酸氨基甲酸酯乳液(商品名称：WEM-3008、大成精细化工株式会社制造(大成ファイソケミ力ル株式会社製))。
(实施例13)
以基本上与上述实施例11相同的方式制造不燃性装饰板。但是，在浆料的制造中，使用等量的以氯乙烯系聚合物为主要成分的氯乙烯系水溶液(Vinyblan(注册商标)711、玻璃化转变温度30℃、日信化学工业株式会社制造)来替代丙烯酸氨基甲酸酯乳液(商品名称：WEM-3008、大成精细化工株式会社制造(大成ファイソケミ力ル株式会社製))。
(实施例14)
以基本上与上述实施例4相同的方式制造不燃性装饰板。但是，在浆料的制造中，丙烯酸树脂乳液的配合量为24重量份，并且配合三聚氰胺-甲醛树脂12重量份。
(比较例1)
(浆料的制造)
制造含有以下成分的浆料。
苯酚-甲醛树脂：36重量份(固体成分)
平均粒径8μm的氢氧化铝：200重量份
平均粒径1μm的重质碳酸钙：40重量份
3-缩水甘油醚氧丙基三甲氧基硅烷：2.2重量份
(2)预浸料的制造
将上述(1)中制造的浆料浸渍到50g／m2的玻璃纤维无纺布(纤维质基材)中且使得由式1所定义的算出方法算出浸渍率为760％，并进行干燥从而制造预浸料。
(3)三聚氰胺树脂浸渍装饰纸的制造
以与上述实施例1相同的方式制造三聚氰胺树脂浸渍装饰纸。
(4)三聚氰胺树脂浸渍平衡纸的制造
以与上述实施例1相同的方式制造三聚氰胺树脂浸渍平衡纸。
(5)不燃性装饰板的制造
从下向上依次层叠上述(4)中制造的三聚氰胺树脂浸渍平衡纸1张、上述(2)中制造的预浸料2张、以及上述(3)中制造的三聚氰胺树脂浸渍装饰纸1张，并使用平面加工板，在130℃、70kg／cm2、60分钟的条件下通过热压成形使其一体化，从而制造不燃性装饰板。
(比较例2)
以基本上与上述比较例1相同的方式制造不燃性装饰板。但是，在浆料的制造中，使用等量的三聚氰胺-甲醛树脂来替代苯酚-甲醛树脂。
(比较例3)
以基本上与上述比较例1相同的方式制造不燃性装饰板。但是，在浆料的制造中，使用热塑性树脂中玻璃化转变温度(Tg)为47℃的丙烯酸树脂乳液(型号AXN-150、爱克工业株式会社制造、平均粒径225nm)18重量份(固体成分)和三聚氰胺-甲醛树脂18重量份(固体成分)来替代苯酚-甲醛树脂。
(比较例4)
以基本上与上述比较例1相同的方式制造不燃性装饰板。但是，在浆料的制造中，使用热塑性树脂中玻璃化转变温度(Tg)为47℃的丙烯酸树脂乳液(型号AXN-150、爱克工业株式会社制造、平均粒径225nm)12重量份(固体成分)和三聚氰胺-甲醛树脂24重量份(固体成分)来替代苯酚-甲醛树脂。
(比较例5)
以基本上与上述比较例1相同的方式制造不燃性装饰板。但是，在浆料的制造中，使用热塑性树脂中玻璃化转变温度(Tg)为47℃的丙烯酸树脂乳液(型号AXN-150、爱克工业株式会社制造、平均粒径225nm)18重量份(固体成分)和苯酚-甲醛树脂18重量份(固体成分)来替代苯酚-甲醛树脂。
在本比较例中，丙烯酸树脂乳液和苯酚-甲醛树脂的互溶性差，不能制造不燃性装饰板。
(比较例6)
以基本上与上述实施例1相同的方式制造不燃性装饰板。但是，在浆料的制造中，使用苯酚-甲醛树脂11.5重量份(固体成分)和三聚氰胺-甲醛树脂9.5重量份(固体成分)来替代丙烯酸树脂乳液。
(比较例7)
以基本上与上述实施例1相同的方式制造不燃性装饰板。但是，在浆料的制造中，使用玻璃化转变温度为-21℃的丙烯酸树脂乳液(型号CMX-43、爱克工业株式会社制造)36重量份(固体成分)来替代玻璃化转变温度Tg为47℃的丙烯酸树脂乳液(型号AXN-150、爱克工业株式会社制造、平均粒径225nm)。
(比较例8)
层叠苯酚-甲醛树脂浸渍芯纸5张和三聚氰胺-甲醛树脂浸渍图案纸1张，在130℃、70kg／cm2、60分钟的条件下热压成形，获得厚度为1.2mm的三聚氰胺装饰板(公知的三聚氰胺装饰板)。
<装饰板的评价>
对各实施例以及各比较例的装饰板进行不燃性、弯曲强度、弹性模量、尺寸变化率、装饰板的翘曲、弯曲加工性、以及重量增加率的评价试验。试验方法如下
(i)不燃性
实施采用基于IS05660的锥形量热计测试20分钟的发热性试验。以下α-γ全部被满足时评价为○，除此之外评价为×。
α：总发热量在8MJ／m2以下。
β：最大发热速度连续10秒以上不超过200KW／m2。
γ：在试验开始后20分钟内不出现贯穿至背面的龟裂以及孔洞。
(ii)弯曲强度
基于JIS K7171“塑料弯曲特性的试验方法”进行测定。
(iii)弹性模量
基于JIS K7171“塑料弯曲特性的试验方法”进行测定。
(iv)尺寸变化率
基于JIS K6902“热固性树脂高压装饰板试验方法”的尺寸稳定性试验进行测定。
(v)装饰板翘曲
将纤维方向为短边方向的50mm×300mm的样品在室温40℃、湿度30％的环境下养护24小时。之后，测定当将样品放置在水平面上时的、自水平面翘曲的高度。
(vi)弯曲加工性
切出宽度为150mm的样品，通过使样品接触具有规定的半径的弯曲棒并使得装饰板的纤维方向和弯曲棒相平行从而进行弯曲加工，通过目视确认是否产生了裂纹。没有产生裂纹的最小曲率为测定值。
(vii)重量增加率
基于JIS K6902“热固性树脂高压装饰板试验方法”的耐蒸煮性进行测定。并且，标准值为17％以下。
评价试验的结果在上述表1-表3中示出。根据该结果可知，实施例1-14的装饰板即使板厚较薄也具有不燃性，而且，弯曲强度、弹性模量、尺寸变化率、装饰板翘曲、弯曲加工性、重量增加率的每个项目皆优，易于加工，便于处理。
与上述结果相比，比较例1-8的装饰板在至少一个评价项目上次劣。特别在比较例1-4的装饰板中装饰板翘曲的评价结果次劣。另外，在比较例6的装饰板中，弯曲加工性次劣。另外，比较例7的装饰板的弹性模量小，难以处理。

Claims (5)

1.一种装饰板，其特征在于，将含有(a)粘合剂成分以及(b)吸热性金属氢氧化物的预浸料和热固性树脂浸渍装饰纸层叠并使其一体化，其中在所述(a)粘合剂成分中，(a1)选自玻璃化转变温度Tg超过0℃的丙烯酸树脂、玻璃化转变温度Tg超过0℃的氯乙烯树脂、丙烯酸氨基甲酸酯树脂、以及水性聚氨酯树脂中的至少一种热塑性树脂与(a2)热固性树脂的配合比例以固体成分的比例计为1∶0-0.5。
2.根据权利要求1所述的装饰板，其特征在于，所述预浸料还含有(c)硅烷偶联剂。
3.根据权利要求1或2所述的装饰板，其特征在于，所述(b)吸热性金属氢氧化物为氢氧化铝。
4.根据权利要求1至3中任一项所述的装饰板，其特征在于，所述热塑性树脂为丙烯酸树脂乳液。
5.根据权利要求1至4中任一项所述的装饰板，其特征在于，所述预浸料以玻璃纤维无纺布作为基材。
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107848263A (zh) * 2015-07-10 2018-03-27 爱克工业株式会社 装饰片材

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI631013B (zh) * 2014-03-31 2018-08-01 愛克工業股份有限公司 裝飾板
CN104260160B (zh) * 2014-09-18 2017-01-11 湖南德易森环保科技有限公司 一种芯板一分为三取代中板的三聚氰胺生态板及制作工艺
CN104314259A (zh) * 2014-10-21 2015-01-28 王铁石 一种净化板板芯、净化板及净化板板芯和净化板的制造方法
JP6243995B2 (ja) * 2015-11-17 2017-12-06 イビデン株式会社 化粧板
NL2016241B1 (en) * 2016-02-09 2017-08-15 Trespa Int Bv A decorative panel
JP6671049B2 (ja) * 2016-03-10 2020-03-25 パナソニックＩｐマネジメント株式会社 表面化粧パネル、これを備えた化粧パネル及びパネル製造方法
US10933608B2 (en) 2016-08-19 2021-03-02 Wilsonart Llc Surfacing materials and method of manufacture
US11745475B2 (en) 2016-08-19 2023-09-05 Wilsonart Llc Surfacing materials and method of manufacture
US11504955B2 (en) 2016-08-19 2022-11-22 Wilsonart Llc Decorative laminate with matte finish and method of manufacture
US11077639B2 (en) 2016-08-19 2021-08-03 Wilsonart Llc Surfacing materials and method of manufacture
WO2019067983A1 (en) 2017-09-28 2019-04-04 Wilsonart Llc HIGH PRESSURE DECORATIVE LAMINATE HAVING A SUPERIOR LAYER OF ENERGY-PROVIDED CURRENT ACRYLIC URETHANE POLYMER
KR102437756B1 (ko) * 2018-09-12 2022-08-29 아이카고교 가부시키가이샤 장식용 적층판
CN113906067A (zh) * 2019-06-10 2022-01-07 3M创新有限公司 散热片材
SG10202008197RA (en) * 2020-03-10 2021-10-28 Aica Kogyo Co Ltd Attachment configuration of and method for applying decorative laminates
FR3115229A1 (fr) 2020-10-20 2022-04-22 Ahlstrom-Munksjö Oyj Papier de cœur imprégné pour stratifié décoratif

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007245548A (ja) * 2006-03-16 2007-09-27 Aica Kogyo Co Ltd 熱硬化性樹脂化粧板
CN101175634A (zh) * 2005-04-18 2008-05-07 欧文斯科宁知识产权资产有限公司 阻燃层压板
JP2008173773A (ja) * 2007-01-16 2008-07-31 Aica Kogyo Co Ltd 可撓性不燃化粧板
CN101668632A (zh) * 2007-04-26 2010-03-10 爱克工业株式会社 装饰板

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4514462A (en) * 1983-04-14 1985-04-30 Westinghouse Electric Corp. Warp resistant laminates having a core impregnated with a mixture of phenolix resin and alkyl substituted phenol
US4828910A (en) * 1987-12-16 1989-05-09 Reinhold Haussling Sound absorbing laminate
JPH0624822B2 (ja) 1990-03-05 1994-04-06 アイカ工業株式会社 化粧材
JP2002166516A (ja) 2000-09-22 2002-06-11 Ibiden Co Ltd 化粧材
US6846528B2 (en) * 2000-03-24 2005-01-25 Ibiden Co., Ltd. Translucent decorative board
KR100495220B1 (ko) * 2003-06-25 2005-06-14 삼성전기주식회사 고차모드 흡수층을 갖는 반도체 레이저 다이오드
JP2005103769A (ja) 2003-09-26 2005-04-21 Aica Kogyo Co Ltd 不燃化粧板
JP3844135B2 (ja) 2004-01-15 2006-11-08 アイカ工業株式会社 化粧板
JP2006095743A (ja) * 2004-09-28 2006-04-13 Aica Kogyo Co Ltd 不燃化粧板
US20070048504A1 (en) * 2005-08-25 2007-03-01 Dimario Joseph Methods for applying sound dampening and/or aesthetic coatings and articles made thereby
US20070193683A1 (en) * 2006-02-17 2007-08-23 Halo Lsi, Inc. Continuous pressed laminates
JP2008303378A (ja) * 2007-05-08 2008-12-18 Sekisui Chem Co Ltd タンニン系接着剤、それを用いた木質系複合材料およびこの木質系複合材料の製造方法
CN102203184B (zh) * 2008-11-05 2013-03-27 帝人化成株式会社 聚乳酸组合物及其成形品
DE102009034767A1 (de) * 2009-07-25 2011-01-27 Lanxess Deutschland Gmbh & Co. Kg Organoblechstrukturbauteil
TWM403523U (en) * 2010-09-15 2011-05-11 Sheng-Chi Chen Decoration board
TWM403439U (en) * 2010-12-08 2011-05-11 jin-yong Huang Improved structure of decorative board
JP2017003773A (ja) * 2015-06-10 2017-01-05 オリンパス株式会社 レンズの接着固定構造

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101175634A (zh) * 2005-04-18 2008-05-07 欧文斯科宁知识产权资产有限公司 阻燃层压板
JP2007245548A (ja) * 2006-03-16 2007-09-27 Aica Kogyo Co Ltd 熱硬化性樹脂化粧板
JP2008173773A (ja) * 2007-01-16 2008-07-31 Aica Kogyo Co Ltd 可撓性不燃化粧板
CN101668632A (zh) * 2007-04-26 2010-03-10 爱克工业株式会社 装饰板

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107848263A (zh) * 2015-07-10 2018-03-27 爱克工业株式会社 装饰片材
CN107848263B (zh) * 2015-07-10 2020-10-09 爱克工业株式会社 装饰片材

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