CN103237591B - 制备用于制造阳离子交换膜的单体溶液的方法 - Google Patents

制备用于制造阳离子交换膜的单体溶液的方法 Download PDF

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Publication number
CN103237591B
CN103237591B CN201180060474.XA CN201180060474A CN103237591B CN 103237591 B CN103237591 B CN 103237591B CN 201180060474 A CN201180060474 A CN 201180060474A CN 103237591 B CN103237591 B CN 103237591B
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solution
mixture
sulfonic acid
styrene sulfonic
organic solvent
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CN103237591A (zh
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J.R.林
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Evoqua Water Technologies LLC
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Evoqua Water Technologies LLC
Siemens Industry Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2275—Heterogeneous membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0006—Organic membrane manufacture by chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/422—Electrodialysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/106—Membranes in the pores of a support, e.g. polymerized in the pores or voids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/107—Organic support material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/28—Polymers of vinyl aromatic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/34—Use of radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/34—Use of radiation
    • B01D2323/345—UV-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/36—Introduction of specific chemical groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/42—Ion-exchange membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00—Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124—Water desalination
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Urology & Nephrology (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201180060474.XA 2010-10-15 2011-10-17 制备用于制造阳离子交换膜的单体溶液的方法 Active CN103237591B (zh)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US39377010P 2010-10-15 2010-10-15
US39375410P 2010-10-15 2010-10-15
US61/393,754 2010-10-15
US61/393770 2010-10-15
US61/393,770 2010-10-15
US61/393754 2010-10-15
PCT/US2011/056516 WO2012051610A1 (en) 2010-10-15 2011-10-17 Process for making a monomer solution for making cation exchange membranes

Publications (2)

Publication Number Publication Date
CN103237591A CN103237591A (zh) 2013-08-07
CN103237591B true CN103237591B (zh) 2016-04-13

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US (1) US9611368B2 (enExample)
EP (1) EP2627436B1 (enExample)
JP (1) JP5889907B2 (enExample)
CN (1) CN103237591B (enExample)
AU (1) AU2011315854B2 (enExample)
CA (1) CA2814701C (enExample)
EA (1) EA023933B1 (enExample)
IL (1) IL225697A (enExample)
SG (1) SG189894A1 (enExample)
WO (1) WO2012051610A1 (enExample)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5638003B2 (ja) 2009-01-12 2014-12-10 ユニバーシティ オブ マサチューセッツ ローウェル ポリイソブチレン系ポリウレタン
EP2470290B1 (en) 2009-08-26 2019-07-24 Evoqua Water Technologies Pte. Ltd. Ion exchange membranes
CN106110898B (zh) 2010-10-15 2019-03-22 懿华水处理技术有限责任公司 阴离子交换膜及制造方法
CN103237591B (zh) * 2010-10-15 2016-04-13 伊沃夸水处理技术有限责任公司 制备用于制造阳离子交换膜的单体溶液的方法
WO2014055123A1 (en) 2012-10-04 2014-04-10 Evoqua Water Technologies Llc High-performance anion exchange membranes and methods of making same
SG11201502697YA (en) 2012-10-11 2015-05-28 Evoqua Water Technologies Llc Coated ion exchange membranes
CN104028007B (zh) * 2013-03-05 2016-08-17 中国科学院大连化学物理研究所 一种咪唑离子液体毛细管整体柱及其制备和应用
US9459377B2 (en) * 2014-01-15 2016-10-04 Johnson & Johnson Vision Care, Inc. Polymers comprising sulfonic acid groups
US10913809B2 (en) 2016-06-17 2021-02-09 Cornell University Cross-linked polymeric material
CN107204475B (zh) * 2017-05-22 2019-07-16 大连理工大学 一种脂基侧链水解的交联型多孔膜及其制备方法
CN108067102B (zh) * 2017-12-30 2020-08-04 山东天维膜技术有限公司 一种阳离子交换膜及其制备方法
US11472911B2 (en) 2018-01-17 2022-10-18 Cardiac Pacemakers, Inc. End-capped polyisobutylene polyurethane
US12485364B2 (en) 2018-08-10 2025-12-02 Clemson University Research Foundation Multi-modal ion-exchange membranes for rapid separations
EP3856395A4 (en) * 2018-09-25 2022-07-06 Evoqua Water Technologies LLC MONOVALENT SELECTIVE CATION EXCHANGE MEMBRANE
KR102589994B1 (ko) 2018-12-12 2023-10-18 삼성디스플레이 주식회사 표시장치
CN110756060B (zh) * 2019-08-30 2022-08-30 浙江工业大学 一种高侧链密度含氟聚芳醚阴离子交换膜及其制备方法
CN110813386B (zh) * 2019-09-11 2022-04-19 浙江工业大学 一种改性阳离子交换膜的制备方法
JP2022552415A (ja) 2019-10-17 2022-12-15 シー２センス， インコーポレイテッド 感知用発光イメージング
JP2022552414A (ja) 2019-10-17 2022-12-15 シー２センス， インコーポレイテッド 感知および／または認証のための発光イメージング
JP7544523B2 (ja) * 2020-07-29 2024-09-03 東ソー・ファインケム株式会社 自然重合が抑制されたスチレンスルホン酸リチウムの極性有機溶剤溶液及び自然重合を抑制する方法
CN113522042A (zh) * 2021-08-07 2021-10-22 南开大学 含烷基苯磺酸盐的均相阳离子交换膜的制备方法及应用
CN113813792B (zh) * 2021-09-26 2023-12-01 湖北吉星化工集团有限责任公司 一种双极膜电渗析生产次磷酸的工艺
NL2030514B1 (en) * 2022-01-12 2023-07-17 W&F Tech B V Method for assembling a bipolar membrane, bipolar membrane, and use of said bipolar membrane
CN114699935B (zh) * 2022-03-14 2023-11-17 华东理工大学 一种聚阳离子复合结构功能层改性的阳离子交换膜及其制备方法
US11502322B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell with heat pump
US11502323B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell and methods of use thereof
EP4619641A1 (en) 2022-11-15 2025-09-24 Nana, Rahul S. Reverse electrodialysis or pressure-retarded osmosis cell and methods of use thereof
US11855324B1 (en) 2022-11-15 2023-12-26 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell with heat pump
US12040517B2 (en) 2022-11-15 2024-07-16 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell and methods of use thereof
CN116672906B (zh) * 2023-06-19 2024-07-26 绍兴百立盛新材料科技有限公司 一种可水洗全热交换新风膜的制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3737045A (en) * 1969-12-20 1973-06-05 Uivac Corp Membrane for use in dialysis and ultrafiltration and the production of such member
CN1114237A (zh) * 1994-06-20 1996-01-03 中国科学院化学研究所 聚丙烯微孔膜为基膜的离子交换膜及其制法
US6344584B2 (en) * 1998-03-23 2002-02-05 Ionics, Incorporated Process for producing styrene sulfonate cation
US20070272613A1 (en) * 2004-02-06 2007-11-29 Minhas Bhupender S Acid tolerant polymeric membrane and process for the recovery of acid using polymeric membranes
US20080223785A1 (en) * 2007-03-13 2008-09-18 Miller Jeffrey T Ionic Polymer Membranes

Family Cites Families (127)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2780604A (en) 1953-01-22 1957-02-05 Ionics Mono (chloromethyl) styrene, its derivatives, and ion-exchange resins from polymers of aminated compound
US3009895A (en) 1956-12-31 1961-11-21 Monsanto Chemicals Compatible blends of two or more interpolymers that follow the slocombewesp rule of azeotropic line clarity and solutions thereof
NL134681C (enExample) * 1966-04-26
US3926864A (en) 1971-06-21 1975-12-16 Ionics Ion exchange membranes having a macroporous surface area
US4297431A (en) 1978-09-15 1981-10-27 Polaroid Corporation Diffusion control layers in diffusion transfer photographic products
US4231855A (en) 1979-03-02 1980-11-04 Ionics, Incorporated Electrodialysis membranes of high interstitial molality based upon methacrylate ester derivatives
US4585833A (en) 1983-05-26 1986-04-29 Union Carbide Corporation Low shrinkling curable poly(acrylate) molding compositions
US4828772A (en) 1984-10-09 1989-05-09 Millipore Corporation Microporous membranes of ultrahigh molecular weight polyethylene
US4778601A (en) 1984-10-09 1988-10-18 Millipore Corporation Microporous membranes of ultrahigh molecular weight polyethylene
US4704324A (en) * 1985-04-03 1987-11-03 The Dow Chemical Company Semi-permeable membranes prepared via reaction of cationic groups with nucleophilic groups
GB8608430D0 (en) 1986-04-07 1986-05-14 Raychem Ltd Porous polymer article
US4933405A (en) 1986-06-10 1990-06-12 The Dow Chemical Company Homogeneous copolymerization of non-polar monomers with ionic amphiphilic monomers
US4874567A (en) 1987-04-24 1989-10-17 Millipore Corporation Microporous membranes from polypropylene
US5032274A (en) 1988-05-04 1991-07-16 Millipore Corporation Process for producing fluorocarbon membranes and membrane product
US5145618A (en) 1989-09-08 1992-09-08 Ionics, Incorporated Process for manufacturing continuous supported ion selective membranes using non-polymerizable high boiling point solvents
US5264125A (en) 1989-09-08 1993-11-23 Ionics' Incorporated Process for manufacturing continuous supported ion selective membranes using non-polymerizable high boiling point solvents
US5194189A (en) 1989-09-08 1993-03-16 Ionics, Incorporated Process for manufacturing continuous, supported polymeric sheet from polymerizable liquid starting materials
US5118717A (en) 1990-02-13 1992-06-02 Ionics, Incorporated High ion exchange capacity polyelectrolytes having high crosslink densities and caustic stability
US5039420A (en) 1990-08-16 1991-08-13 Elias Klein Hydrophilic semipermeable membranes based on copolymers of acrylonitrile and hydroxyalkyl esters of (meth) acrylic acid
US5120632A (en) 1990-12-28 1992-06-09 Xerox Corporation Pigment passivation via polymer encapsulation
US5510394A (en) 1991-02-19 1996-04-23 Ionics Incorporated High ionic conductance ion exchange membranes and their preparation
EP0600470A3 (en) 1992-12-04 1995-01-04 Asahi Glass Co Ltd Bipolar membrane.
BE1006940A6 (fr) 1993-04-08 1995-01-31 Solvay Procede de fabrication d'une membrane bipolaire et procede de fabrication d'une solution aqueuse d'hydroxyde de metal alcalin.
US5447636A (en) 1993-12-14 1995-09-05 E. I. Du Pont De Nemours And Company Method for making reinforced ion exchange membranes
IL109240A (en) 1994-04-07 1998-02-22 Yeda Res & Dev Ion exchange membranes
US5503729A (en) 1994-04-25 1996-04-02 Ionics Incorporated Electrodialysis including filled cell electrodialysis (electrodeionization)
BE1008471A3 (fr) 1994-07-05 1996-05-07 Solvay Membrane bipolaire et procede de fabrication d'une membrane bipolaire.
IT1269982B (it) 1994-09-20 1997-04-16 Solvay Procedimento di fabbricazione di una membrana bipolare e procedimento di preparazione di una soluzione acquosa di un idrossido di un metalloalcalino mediante elettrodialisi
JPH11502764A (ja) 1995-03-23 1999-03-09 アイオニクス インコーポレイテッド 電気透析を含めた膜処理の改良
US6258276B1 (en) 1996-10-18 2001-07-10 Mcmaster University Microporous membranes and uses thereof
EP0863191A3 (en) 1997-03-05 1999-01-27 Nippon Paint Co., Ltd. Raindrop fouling-resistant paint film, coating composition, film-forming method, and coated article
US5868976A (en) 1997-03-14 1999-02-09 Koch Membrane Systems, Inc. Process of making a dialysis membrane
US5961796A (en) 1997-06-03 1999-10-05 Lynntech, Inc. Bipolar membranes with fluid distribution passages
US6248469B1 (en) 1997-08-29 2001-06-19 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
US6635384B2 (en) 1998-03-06 2003-10-21 Gore Enterprise Holdings, Inc. Solid electrolyte composite for electrochemical reaction apparatus
US6723758B2 (en) 1997-11-12 2004-04-20 Ballard Power Systems Inc. Graft polymeric membranes and ion-exchange membranes formed therefrom
CA2325403C (en) 1998-03-24 2009-09-29 Ebara Corporation Electrical deionization apparatus
US6780327B1 (en) 1999-02-25 2004-08-24 Pall Corporation Positively charged membrane
DE19919881A1 (de) 1999-04-30 2000-11-02 Univ Stuttgart Organisch-Anorganische Komposites und Kompositmembranen aus Ionomeren oder Ionomerblends und aus Schicht- oder Gerätsilicaten
US6277512B1 (en) 1999-06-18 2001-08-21 3M Innovative Properties Company Polymer electrolyte membranes from mixed dispersions
US6410672B1 (en) 1999-07-28 2002-06-25 Ionics, Incorporated Ion exchange and electrochemical methods and devices employing one-step quaternized and polymerized anion selective polymers
JP4398031B2 (ja) 1999-12-03 2010-01-13 株式会社トクヤマ イオン交換膜及びその製造方法
JP4331909B2 (ja) 2000-02-25 2009-09-16 株式会社トクヤマ バイポーラ膜
FR2807950B1 (fr) 2000-04-19 2002-07-19 Solvay Procede de fabrication d'une membrane bipolaire et utilisation de la membrane bipolaire ainsi obtenue
WO2001093361A2 (en) * 2000-05-30 2001-12-06 Genesis Group Inc. A fuel cell incorporating a modified ion exchange membrane
CA2353378C (en) 2000-07-24 2008-09-23 Asahi Glass Company, Limited Anion exchange membrane, process for its production and solution treating apparatus
ES2276731T3 (es) 2000-09-07 2007-07-01 Mitsui Chemicals, Inc. Copolimero de olefina que contiene un grupo polar, procedimiento para preparar el mismo, composicion de resina termoplastica que contiene el copolimero y usos de los mismos.
US7361729B2 (en) 2000-09-20 2008-04-22 Virginia Tech Intellectual Properties, Inc. Ion-conducting sulfonated polymeric materials
KR20090003374A (ko) 2001-04-13 2009-01-09 오르가노 가부시키가이샤 이온교환체
ES2284747T3 (es) 2001-06-29 2007-11-16 Tokuyama Corporation Membrana de intercambio ionico.
DE60212637T2 (de) * 2001-07-20 2007-05-24 Mcmaster University, Hamilton Asymmetrische gelgefüllte mikroporöse membranen
DE60214684T2 (de) 2001-07-30 2007-09-06 Asahi Glass Engineering Co. Ltd., Chiba Anionenaustauscher und Verfahren zur Herstellung einer Anionenaustauschmembran
US7318972B2 (en) 2001-09-07 2008-01-15 Itm Power Ltd. Hydrophilic polymers and their use in electrochemical cells
KR20040041695A (ko) 2001-10-15 2004-05-17 이 아이 듀폰 디 네모아 앤드 캄파니 메탄올 투과율의 감소를 위하여 폴리아민이 흡수된, 연료전지용 고체 중합체 막
US6814865B1 (en) 2001-12-05 2004-11-09 Seventy-Seventh Meridian Corporation Llc Ion exchange membranes, methods and processes for production thereof and uses in specific applications
US20030153708A1 (en) 2002-01-11 2003-08-14 Caneba Gerald Tablada Free radical retrograde precipitation copolymers and process for making same
US6849688B2 (en) 2002-03-26 2005-02-01 Sachem, Inc. Polymer grafted support polymers
US20070261962A1 (en) 2002-04-02 2007-11-15 Ryszard Gajek Separation Systems with Charge Mosaic Membrane
JP3773190B2 (ja) 2002-05-15 2006-05-10 オルガノ株式会社 電気式脱イオン水製造装置
WO2004005380A1 (en) 2002-07-04 2004-01-15 Ben-Gurion University Of The Negev Highly conductive ordered ion exchange membranes
FR2843399B1 (fr) 2002-08-06 2004-09-03 Commissariat Energie Atomique Polymeres de type polyphenylenes, leur procede de preparation, membranes et dispositif de pile a combustible comprenant ces membranes
US6828386B2 (en) 2002-09-20 2004-12-07 Ballard Power Systems Inc. Process for preparing graft copolymers and membranes formed therefrom
AU2003273034A1 (en) 2002-10-17 2004-05-04 Toyo Boseki Kabushiki Kaisha Composite ion-exchange membrane
EP2143481A1 (en) 2003-02-19 2010-01-13 Natrix Separations Inc. Composite materials comprising supported porous gels
US20040175625A1 (en) 2003-03-06 2004-09-09 Lotfi Hedhli Non-perfluorinated resins containing ionic or ionizable groups and products containing the same
US7449111B2 (en) 2003-07-30 2008-11-11 Arkema Inc. Resins containing ionic or ionizable groups with small domain sizes and improved conductivity
US7179847B2 (en) 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7632406B2 (en) 2004-04-20 2009-12-15 Lawrence Livermore National Security, Llc Smart membranes for nitrate removal, water purification, and selective ion transportation
US7604746B2 (en) 2004-04-27 2009-10-20 Mcmaster University Pervaporation composite membranes
JP2005334263A (ja) 2004-05-26 2005-12-08 Tokuyama Corp イオントフォレーシス装置及びイオン交換膜
WO2005123606A1 (ja) 2004-06-18 2005-12-29 Ebara Corporation 液体の処理装置
JP4613528B2 (ja) 2004-06-24 2011-01-19 コニカミノルタホールディングス株式会社 プロトン伝導性電解質膜とその製造方法、及び該プロトン伝導性電解質膜を用いた固体高分子型燃料電池
US7959780B2 (en) 2004-07-26 2011-06-14 Emporia Capital Funding Llc Textured ion exchange membranes
KR100723389B1 (ko) 2005-12-21 2007-05-30 삼성에스디아이 주식회사 폴리머 전해질막 및 이를 채용한 연료전지
US20060045985A1 (en) 2004-09-02 2006-03-02 Kozak Paul D Method and apparatus for electrostatically coating an ion-exchange membrane or fluid diffusion layer with a catalyst layer
US20060062982A1 (en) 2004-09-17 2006-03-23 Massachusetts Institute Of Technology Carbon-polymer electrochemical systems and methods of fabricating them using layer-by-layer technology
FR2876299B1 (fr) 2004-10-12 2007-01-12 Solvay Membranes echangeuses d'ions structurees dans l'epaisseur et procede pour la fabrication de ces membranes
KR20070072530A (ko) 2004-10-27 2007-07-04 아사히 가라스 가부시키가이샤 전해질 재료, 전해질 막 및 고체 고분자형 연료 전지용막전극 접합체
EP1845122B1 (en) 2005-02-04 2011-11-16 JSR Corporation Polyarylene, process for producing the same, solid polyelectrolyte, and proton-conductive film
US7833644B2 (en) 2005-03-17 2010-11-16 Teijin Limited Electrolytic membrane
KR100668339B1 (ko) 2005-06-18 2007-01-12 삼성전자주식회사 이온 교환성 혼합물 및 그의 제조방법
KR101218518B1 (ko) * 2005-07-01 2013-01-03 가부시끼가이샤 도꾸야마 연료 전지용 격막
US20070031716A1 (en) 2005-08-05 2007-02-08 Rajendran Raj G Process for making cation exchange membranes with reduced methanol permeability
BRPI0614646A2 (pt) 2005-08-09 2011-04-12 University Of Sunderland análise de impressão digital usando espectrometria de massa
JP4708133B2 (ja) 2005-09-14 2011-06-22 旭化成ケミカルズ株式会社 電解用フッ素系陽イオン交換膜及びその製造方法
KR20080059265A (ko) 2005-09-30 2008-06-26 일립사, 인코포레이티드 포유동물의 위장관으로부터 칼륨 이온을 선택적으로제거하기 위한 방법 및 조성물
US8367267B2 (en) 2005-10-28 2013-02-05 3M Innovative Properties Company High durability fuel cell components with cerium oxide additives
WO2008048317A1 (en) 2005-12-22 2008-04-24 Ballard Power Systems Inc. Water insoluble additive for improving conductivity of an ion exchange membrane
US7368200B2 (en) 2005-12-30 2008-05-06 Tekion, Inc. Composite polymer electrolyte membranes and electrode assemblies for reducing fuel crossover in direct liquid feed fuel cells
WO2007099808A1 (ja) * 2006-02-23 2007-09-07 Nissan Chemical Industries, Ltd. スルホン酸エステル化合物およびその利用
US7829218B2 (en) 2006-03-09 2010-11-09 Samsung Sdi Co., Ltd Proton conductive electrolyte and fuel cell comprising the same
WO2007114480A1 (en) 2006-03-30 2007-10-11 Fujifilm Corporation Solid electrolyte membrane, method and apparatus for producing the same, membrane electrode assembly and fuel cell
JP5066865B2 (ja) 2006-08-09 2012-11-07 トヨタ自動車株式会社 燃料電池用補強型電解質膜、その製造方法、燃料電池用膜−電極接合体、及びそれを備えた固体高分子型燃料電池
GB0701449D0 (en) 2007-01-26 2007-03-07 Secr Defence Anion Exchange Membranes
JP5050285B2 (ja) 2007-03-14 2012-10-17 財団法人塩事業センター 製塩用陰イオン交換膜及びその製造方法
GB0706634D0 (en) 2007-04-04 2007-05-16 Itm Fuel Cells Ltd Membrane production
EP1982757A1 (de) 2007-04-10 2008-10-22 Stichting Voor De Technische Wetenschappen Ionendurchlässige Membran und ihre Herstellung
US7806275B2 (en) 2007-05-09 2010-10-05 The United States Of America As Represented By The Secretary Of The Interior, The Bureau Of Reclamation Chlorine resistant polyamides and membranes made from the same
JP2008288065A (ja) * 2007-05-18 2008-11-27 Keio Gijuku 電解質膜、膜−電極接合体、燃料電池及び電解質膜の製造方法
JP5579365B2 (ja) 2007-12-13 2014-08-27 公益財団法人 塩事業センター 陰イオン交換膜およびその製造方法
US7968663B2 (en) 2007-12-18 2011-06-28 General Electric Company Anion exchange polymers, methods for making and materials prepared therefrom
JP5196234B2 (ja) 2008-01-25 2013-05-15 財団法人塩事業センター 陰イオン交換膜及びその製造方法
JP5196236B2 (ja) 2008-01-28 2013-05-15 財団法人塩事業センター 陽イオン交換膜及びその製造方法
JP5196241B2 (ja) 2008-03-12 2013-05-15 財団法人塩事業センター 陽イオン交換膜及びその製造方法
JP5196242B2 (ja) 2008-03-12 2013-05-15 財団法人塩事業センター 陰イオン交換膜及びその製造方法
JP5145411B2 (ja) 2008-03-26 2013-02-20 帝人株式会社 固体高分子型燃料電池の電解質膜補強用フィルム
US7888397B1 (en) 2008-04-30 2011-02-15 Sandia Corporation Poly(phenylene)-based anion exchange membrane
KR101000214B1 (ko) 2008-05-28 2010-12-10 주식회사 엘지화학 이온전도성 수지 파이버, 이온전도성 복합막, 막-전극 접합체 및 연료전지
GB0813227D0 (en) 2008-07-18 2008-08-27 Fuji Film Mfg Europ B V Process for preparing membranes
KR100999048B1 (ko) 2008-08-01 2010-12-09 한국화학연구원 스티렌계-비닐벤질계 공중합체가 함유된 음이온교환 복합막의 제조방법
US20110281197A1 (en) 2008-11-14 2011-11-17 Tokuyama Corporation Anion-exchange membrane and method for producing the same
EP2391442A1 (en) 2009-01-19 2011-12-07 Fujifilm Manufacturing Europe BV Process for preparing membranes
CA2751045A1 (en) 2009-02-23 2010-08-26 Asahi Glass Company, Limited Cation exchange membrane, production process thereof and electrolytic cell using the same
GB0904558D0 (en) 2009-03-17 2009-04-29 Fujifilm Mfg Europe Bv Membranes
GB0904560D0 (en) 2009-03-17 2009-04-29 Fujifilm Mfg Europe Bv Process for preparing composite membranes
US8716358B2 (en) 2009-03-25 2014-05-06 Kuraray Co., Ltd. Anion exchange membrane and method for producing same
JP5531267B2 (ja) 2009-04-13 2014-06-25 国立大学法人山口大学 イオン交換膜およびその製造方法
EP2470290B1 (en) 2009-08-26 2019-07-24 Evoqua Water Technologies Pte. Ltd. Ion exchange membranes
US8696882B2 (en) 2009-12-03 2014-04-15 Lawrence Livermore National Security, Llc. Nanoengineered field induced charge separation membranes and methods of manufacture thereof
GB0921949D0 (en) 2009-12-16 2010-02-03 Fujifilm Mfg Europe Bv Curable compositions and membranes
GB0921951D0 (en) 2009-12-16 2010-02-03 Fujifilm Mfg Europe Bv Curable compositions and membranes
US20110147308A1 (en) * 2009-12-21 2011-06-23 Siemens Water Technologies Corp. Charged Porous Polymeric Membranes and Their Preparation
CN103237591B (zh) * 2010-10-15 2016-04-13 伊沃夸水处理技术有限责任公司 制备用于制造阳离子交换膜的单体溶液的方法
CN106110898B (zh) 2010-10-15 2019-03-22 懿华水处理技术有限责任公司 阴离子交换膜及制造方法
US9457318B2 (en) 2010-12-12 2016-10-04 Ben-Gurion University Of The Negev Research And Development Authority Anion exchange membranes, methods of preparation and uses
US9713792B2 (en) 2011-07-25 2017-07-25 Fujifilm Manufacturing Europe Bv Composite membranes
US9073050B2 (en) 2011-10-05 2015-07-07 General Electric Company Ion exchange compositions, methods for making and materials prepared therefrom

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3737045A (en) * 1969-12-20 1973-06-05 Uivac Corp Membrane for use in dialysis and ultrafiltration and the production of such member
CN1114237A (zh) * 1994-06-20 1996-01-03 中国科学院化学研究所 聚丙烯微孔膜为基膜的离子交换膜及其制法
US6344584B2 (en) * 1998-03-23 2002-02-05 Ionics, Incorporated Process for producing styrene sulfonate cation
US20070272613A1 (en) * 2004-02-06 2007-11-29 Minhas Bhupender S Acid tolerant polymeric membrane and process for the recovery of acid using polymeric membranes
US20080223785A1 (en) * 2007-03-13 2008-09-18 Miller Jeffrey T Ionic Polymer Membranes

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