CN102803310A - 制备抗冲击性丙烯聚合物组合物的方法 - Google Patents

制备抗冲击性丙烯聚合物组合物的方法 Download PDF

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Publication number
CN102803310A
CN102803310A CN2010800272561A CN201080027256A CN102803310A CN 102803310 A CN102803310 A CN 102803310A CN 2010800272561 A CN2010800272561 A CN 2010800272561A CN 201080027256 A CN201080027256 A CN 201080027256A CN 102803310 A CN102803310 A CN 102803310A
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Prior art keywords
propylene
weight
polymer
xylene
electron donor
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Chinese (zh)
Inventor
G.科利纳
M.蔡拉福尼
O.富斯科
B.加迪
M.卡尔文
G.莫里尼
R.潘塔利奥尼
F.弗罗基奥
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Basell Poliolefine Italia SRL
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Basell Poliolefine Italia SRL
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Priority to CN201710041292.7A priority Critical patent/CN107043491A/zh
Publication of CN102803310A publication Critical patent/CN102803310A/zh
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/06Organic solvent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/02Carriers therefor
    • C08F4/022Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/06Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
  • Emergency Medicine (AREA)
CN2010800272561A 2009-06-19 2010-06-16 制备抗冲击性丙烯聚合物组合物的方法 Pending CN102803310A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710041292.7A CN107043491A (zh) 2009-06-19 2010-06-16 制备抗冲击性丙烯聚合物组合物的方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09163192.9 2009-06-19
EP09163192 2009-06-19
PCT/EP2010/058437 WO2010146074A1 (en) 2009-06-19 2010-06-16 Process for the preparation of impact resistant propylene polymer compositions

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CN201710041292.7A Pending CN107043491A (zh) 2009-06-19 2010-06-16 制备抗冲击性丙烯聚合物组合物的方法

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US (1) US9068028B2 (enExample)
EP (1) EP2443159B1 (enExample)
JP (1) JP5676586B2 (enExample)
KR (1) KR101769275B1 (enExample)
CN (2) CN102803310A (enExample)
BR (1) BRPI1014019B1 (enExample)
ES (1) ES2672731T3 (enExample)
RU (1) RU2536682C2 (enExample)
WO (1) WO2010146074A1 (enExample)

Cited By (6)

* Cited by examiner, † Cited by third party
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CN107873037A (zh) * 2015-08-04 2018-04-03 巴塞尔聚烯烃意大利有限公司 用于聚合丙烯的气相工艺
CN108350240A (zh) * 2015-11-17 2018-07-31 博里利斯股份公司 用于汽车内饰的具有力学性能间的优异平衡的高流动性tpo组合物
CN108350241A (zh) * 2015-11-17 2018-07-31 博里利斯股份公司 具有优异的低温冲击的高流动性tpo组合物
CN112969727A (zh) * 2018-12-04 2021-06-15 巴塞尔聚烯烃意大利有限公司 制备彩色聚丙烯的方法
CN114058113A (zh) * 2020-08-10 2022-02-18 中国石油天然气股份有限公司 高抗冲透明聚丙烯树脂及其制备方法
CN116209686A (zh) * 2020-10-19 2023-06-02 巴塞尔聚烯烃意大利有限公司 聚丙烯组合物

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WO2011036021A1 (en) 2009-09-22 2011-03-31 Basell Poliolefine Italia S.R.L. Propylene polymer compositions
US8569419B2 (en) 2009-09-22 2013-10-29 Basell Poliolefine Italia, s.r.l. Propylene polymer compositions
US9068029B2 (en) 2009-11-19 2015-06-30 Basell Poliolefine Italia S.R.L. Process for the preparation of impact resistant propylene polymer compositions
BR112013018569B1 (pt) * 2011-01-19 2020-04-22 Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp componente catalisador sólido, catalisador para a polimerização de olefina e processo para polimerização de olefina
CN103476806B (zh) * 2011-04-12 2016-12-07 巴塞尔聚烯烃意大利有限责任公司 用于烯烃聚合的催化剂组分
WO2012152802A1 (en) * 2011-05-11 2012-11-15 Basell Poliolefine Italia S.R.L. Soft polyolefin compositions and highly filled compounds thereof
WO2013004507A1 (en) * 2011-07-01 2013-01-10 Basell Poliolefine Italia S.R.L. Polypropylene films and sheets
US20140249264A1 (en) * 2011-10-07 2014-09-04 Total Research & Technology Feluy High-fluidity heterophasic propylene copolymer with improved rigidity
EP2594593A1 (en) 2011-11-17 2013-05-22 Basell Poliolefine Italia S.r.l. Process for the preparation of heterophasic propylene polymer compositions
EP2682505A1 (en) * 2012-07-06 2014-01-08 Basell Poliolefine Italia S.r.l. Polypropylene fiber
EP2722348A1 (en) * 2012-10-16 2014-04-23 Basell Poliolefine Italia S.r.l. Process for the preparation of propylene random copolymers
KR101768846B1 (ko) * 2013-03-15 2017-08-17 바셀 폴리올레핀 이탈리아 에스.알.엘 프로필렌 삼원중합체의 제조 공정, 및 그에 의해 얻은 프로필렌 삼원중합체
EP2829557A1 (en) * 2013-07-22 2015-01-28 Basell Poliolefine Italia S.r.l. Sterilisable article made of propylene copolymer
TWI639626B (zh) * 2013-09-30 2018-11-01 中國石油化工科技開發有限公司 Catalyst composition for olefin polymerization and application thereof
WO2015059117A1 (en) 2013-10-24 2015-04-30 Basell Poliolefine Italia S.R.L. Process for the preparation of porous propylene polymers
US9777084B2 (en) 2016-02-19 2017-10-03 Formosa Plastics Corporation, Usa Catalyst system for olefin polymerization and method for producing olefin polymer
JP6860326B2 (ja) * 2016-11-07 2021-04-14 サンアロマー株式会社 ポリプロピレン組成物およびこれを成形してなるマット調フィルム
WO2022269364A1 (en) 2021-06-25 2022-12-29 Braskem S.A. Propylene preliminary polymerization

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CN1313869A (zh) * 1999-04-15 2001-09-19 巴塞尔技术有限公司 用于烯烃聚合的组分和催化剂
CN1768108A (zh) * 2003-04-03 2006-05-03 巴塞尔聚烯烃意大利有限责任公司 耐冲击的聚烯烃组合物
CN101065437A (zh) * 2004-10-04 2007-10-31 巴塞尔聚烯烃意大利有限责任公司 弹性体聚烯烃组合物
WO2007147865A2 (en) * 2006-06-21 2007-12-27 Total Petrochemicals Research Feluy Catalyst composition for the copolymerization of propylene.

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CN1313869A (zh) * 1999-04-15 2001-09-19 巴塞尔技术有限公司 用于烯烃聚合的组分和催化剂
CN1768108A (zh) * 2003-04-03 2006-05-03 巴塞尔聚烯烃意大利有限责任公司 耐冲击的聚烯烃组合物
CN101065437A (zh) * 2004-10-04 2007-10-31 巴塞尔聚烯烃意大利有限责任公司 弹性体聚烯烃组合物
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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107873037A (zh) * 2015-08-04 2018-04-03 巴塞尔聚烯烃意大利有限公司 用于聚合丙烯的气相工艺
CN107873036A (zh) * 2015-08-04 2018-04-03 巴塞尔聚烯烃意大利有限公司 用于聚合烯烃的预聚合催化剂组分
CN107873036B (zh) * 2015-08-04 2021-03-30 巴塞尔聚烯烃意大利有限公司 用于聚合烯烃的预聚合催化剂组分
CN108350241A (zh) * 2015-11-17 2018-07-31 博里利斯股份公司 具有优异的低温冲击的高流动性tpo组合物
CN108350240B (zh) * 2015-11-17 2020-06-30 博里利斯股份公司 用于汽车内饰的具有力学性能间的优异平衡的高流动性tpo组合物
CN108350241B (zh) * 2015-11-17 2020-12-04 博里利斯股份公司 具有优异的低温冲击的高流动性tpo组合物
CN108350240A (zh) * 2015-11-17 2018-07-31 博里利斯股份公司 用于汽车内饰的具有力学性能间的优异平衡的高流动性tpo组合物
CN112969727A (zh) * 2018-12-04 2021-06-15 巴塞尔聚烯烃意大利有限公司 制备彩色聚丙烯的方法
CN112969727B (zh) * 2018-12-04 2022-11-11 巴塞尔聚烯烃意大利有限公司 制备彩色聚丙烯的方法
CN114058113A (zh) * 2020-08-10 2022-02-18 中国石油天然气股份有限公司 高抗冲透明聚丙烯树脂及其制备方法
CN114058113B (zh) * 2020-08-10 2023-09-26 中国石油天然气股份有限公司 高抗冲透明聚丙烯树脂及其制备方法
CN116209686A (zh) * 2020-10-19 2023-06-02 巴塞尔聚烯烃意大利有限公司 聚丙烯组合物
CN116209686B (zh) * 2020-10-19 2024-01-26 巴塞尔聚烯烃意大利有限公司 聚丙烯组合物

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WO2010146074A1 (en) 2010-12-23
CN107043491A (zh) 2017-08-15
RU2012101804A (ru) 2013-07-27
KR101769275B1 (ko) 2017-08-18
JP2012530170A (ja) 2012-11-29
ES2672731T3 (es) 2018-06-15
BRPI1014019A2 (pt) 2016-04-12
EP2443159B1 (en) 2018-04-25
BRPI1014019B1 (pt) 2019-10-22
RU2536682C2 (ru) 2014-12-27
KR20120042763A (ko) 2012-05-03
JP5676586B2 (ja) 2015-02-25
US9068028B2 (en) 2015-06-30
EP2443159A1 (en) 2012-04-25
US20120083576A1 (en) 2012-04-05

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