KR101769275B1 - 내충격성 프로필렌 중합체 조성물의 제조 방법 - Google Patents

내충격성 프로필렌 중합체 조성물의 제조 방법 Download PDF

Info

Publication number
KR101769275B1
KR101769275B1 KR1020117030298A KR20117030298A KR101769275B1 KR 101769275 B1 KR101769275 B1 KR 101769275B1 KR 1020117030298 A KR1020117030298 A KR 1020117030298A KR 20117030298 A KR20117030298 A KR 20117030298A KR 101769275 B1 KR101769275 B1 KR 101769275B1
Authority
KR
South Korea
Prior art keywords
delete delete
propylene
polymer
bis
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020117030298A
Other languages
English (en)
Korean (ko)
Other versions
KR20120042763A (ko
Inventor
잔니 콜리나
마르코 치아라포니
오펠리아 푸스코
베네데타 자디
모니카 갈반
잠피에로 모리니
로베르토 판타레오니
프란체스카 베로치오
Original Assignee
바셀 폴리올레핀 이탈리아 에스.알.엘
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 바셀 폴리올레핀 이탈리아 에스.알.엘 filed Critical 바셀 폴리올레핀 이탈리아 에스.알.엘
Publication of KR20120042763A publication Critical patent/KR20120042763A/ko
Application granted granted Critical
Publication of KR101769275B1 publication Critical patent/KR101769275B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
  • Emergency Medicine (AREA)
KR1020117030298A 2009-06-19 2010-06-16 내충격성 프로필렌 중합체 조성물의 제조 방법 Active KR101769275B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP09163192.9 2009-06-19
EP09163192 2009-06-19
US26963509P 2009-06-26 2009-06-26
US61/269,635 2009-06-26
PCT/EP2010/058437 WO2010146074A1 (en) 2009-06-19 2010-06-16 Process for the preparation of impact resistant propylene polymer compositions

Publications (2)

Publication Number Publication Date
KR20120042763A KR20120042763A (ko) 2012-05-03
KR101769275B1 true KR101769275B1 (ko) 2017-08-18

Family

ID=43355907

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020117030298A Active KR101769275B1 (ko) 2009-06-19 2010-06-16 내충격성 프로필렌 중합체 조성물의 제조 방법

Country Status (9)

Country Link
US (1) US9068028B2 (enExample)
EP (1) EP2443159B1 (enExample)
JP (1) JP5676586B2 (enExample)
KR (1) KR101769275B1 (enExample)
CN (2) CN102803310A (enExample)
BR (1) BRPI1014019B1 (enExample)
ES (1) ES2672731T3 (enExample)
RU (1) RU2536682C2 (enExample)
WO (1) WO2010146074A1 (enExample)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011036021A1 (en) 2009-09-22 2011-03-31 Basell Poliolefine Italia S.R.L. Propylene polymer compositions
US8569419B2 (en) 2009-09-22 2013-10-29 Basell Poliolefine Italia, s.r.l. Propylene polymer compositions
US9068029B2 (en) 2009-11-19 2015-06-30 Basell Poliolefine Italia S.R.L. Process for the preparation of impact resistant propylene polymer compositions
BR112013018569B1 (pt) * 2011-01-19 2020-04-22 Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp componente catalisador sólido, catalisador para a polimerização de olefina e processo para polimerização de olefina
CN103476806B (zh) * 2011-04-12 2016-12-07 巴塞尔聚烯烃意大利有限责任公司 用于烯烃聚合的催化剂组分
WO2012152802A1 (en) * 2011-05-11 2012-11-15 Basell Poliolefine Italia S.R.L. Soft polyolefin compositions and highly filled compounds thereof
WO2013004507A1 (en) * 2011-07-01 2013-01-10 Basell Poliolefine Italia S.R.L. Polypropylene films and sheets
US20140249264A1 (en) * 2011-10-07 2014-09-04 Total Research & Technology Feluy High-fluidity heterophasic propylene copolymer with improved rigidity
EP2594593A1 (en) 2011-11-17 2013-05-22 Basell Poliolefine Italia S.r.l. Process for the preparation of heterophasic propylene polymer compositions
EP2682505A1 (en) * 2012-07-06 2014-01-08 Basell Poliolefine Italia S.r.l. Polypropylene fiber
EP2722348A1 (en) * 2012-10-16 2014-04-23 Basell Poliolefine Italia S.r.l. Process for the preparation of propylene random copolymers
KR101768846B1 (ko) * 2013-03-15 2017-08-17 바셀 폴리올레핀 이탈리아 에스.알.엘 프로필렌 삼원중합체의 제조 공정, 및 그에 의해 얻은 프로필렌 삼원중합체
EP2829557A1 (en) * 2013-07-22 2015-01-28 Basell Poliolefine Italia S.r.l. Sterilisable article made of propylene copolymer
TWI639626B (zh) * 2013-09-30 2018-11-01 中國石油化工科技開發有限公司 Catalyst composition for olefin polymerization and application thereof
WO2015059117A1 (en) 2013-10-24 2015-04-30 Basell Poliolefine Italia S.R.L. Process for the preparation of porous propylene polymers
WO2017021122A1 (en) * 2015-08-04 2017-02-09 Basell Poliolefine Italia S.R.L. Prepolymerized catalyst components for the polymerization of olefins
US10155828B2 (en) * 2015-11-17 2018-12-18 Borealis Ag High flow TPO composition with excellent low temperature impact
EP3170864B1 (en) * 2015-11-17 2018-10-17 Borealis AG High flow tpo composition with excellent balance in mechanical properties for automotive interior
US9777084B2 (en) 2016-02-19 2017-10-03 Formosa Plastics Corporation, Usa Catalyst system for olefin polymerization and method for producing olefin polymer
JP6860326B2 (ja) * 2016-11-07 2021-04-14 サンアロマー株式会社 ポリプロピレン組成物およびこれを成形してなるマット調フィルム
WO2020114837A1 (en) * 2018-12-04 2020-06-11 Basell Poliolefine Italia S.R.L. Process for the preparation of a colored polypropylene
CN114058113B (zh) * 2020-08-10 2023-09-26 中国石油天然气股份有限公司 高抗冲透明聚丙烯树脂及其制备方法
WO2022084033A1 (en) * 2020-10-19 2022-04-28 Basell Poliolefine Italia S.R.L. Polypropylene composition
WO2022269364A1 (en) 2021-06-25 2022-12-29 Braskem S.A. Propylene preliminary polymerization

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000063261A1 (en) 1999-04-15 2000-10-26 Basell Technology Company B.V. Components and catalysts for the polymerization of olefins
WO2004087807A1 (en) 2003-04-03 2004-10-14 Basell Poliolefine Italia S.R.L. Impact resistant polyolefin compositions

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL162661B (nl) 1968-11-21 1980-01-15 Montedison Spa Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1.
YU35844B (en) 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
IT1098272B (it) * 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
IL117114A (en) 1995-02-21 2000-02-17 Montell North America Inc Components and catalysts for the polymerization ofolefins
FI952175A7 (fi) 1995-05-05 1996-11-06 Borealis As Menetelmä ja katalysaattorikomponentti olefiinien homo- tai kopolymeroimiseksi
JP4644352B2 (ja) 2000-10-19 2011-03-02 日本ポリプロ株式会社 プロピレン−エチレンブロック共重合体の製造方法
TWI268939B (en) 2001-12-12 2006-12-21 Basell Poliolefine Spa Process for the polymerization of olefins
US7005487B2 (en) 2002-07-02 2006-02-28 Basell Poliolefine Italia S.R.L. Catalyst system for the polymerization of olefins
DE60317903T2 (de) 2002-07-02 2008-11-13 Basell Poliolefine Italia S.R.L. Katalysatorsystem für die polymerisation von olefinen
CA2492939A1 (en) 2002-08-01 2004-02-12 Basell Poliolefine Italia S.P.A. Highly stereoregular polypropylene with improved properties
CN1274724C (zh) * 2003-09-18 2006-09-13 中国石油化工股份有限公司 一种生产烯烃聚合物的方法及其聚合物
US7772324B2 (en) * 2004-10-04 2010-08-10 Basell Poliolefine Italia S.R.L. Elastomeric polyolefin compositions
CN101035816B (zh) 2004-10-14 2010-11-03 巴塞尔聚烯烃意大利有限责任公司 烯烃气相聚合的方法
EP2013249B1 (en) 2006-04-24 2015-06-03 Total Research & Technology Feluy Use of a ziegler-natta catalyst to make a polypropylene random copolymer having a high melt flow rate
EP1849807A1 (en) 2006-04-24 2007-10-31 Total Petrochemicals Research Feluy Catalyst composition for the copolymerization of propylene
WO2007147864A2 (en) 2006-06-21 2007-12-27 Total Petrochemicals Research Feluy Catalyst composition for the (co)polymerization of propylene.
KR20090102802A (ko) 2006-12-20 2009-09-30 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀의 중합을 위한 촉매 성분 및 이로부터 수득된 촉매
EP2121773B1 (en) 2006-12-22 2016-11-23 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins and catalysts therefrom obtained
RU2471811C2 (ru) 2007-10-15 2013-01-10 Базелль Полиолефин Италия С.Р.Л. Способ получения полимеров пропилена с высокой текучестью
CN101918457B (zh) * 2007-12-20 2013-05-22 巴塞尔聚烯烃意大利有限责任公司 具有改进的性能的高度有规立构的聚丙烯
US20100273641A1 (en) 2007-12-21 2010-10-28 Linfeng Chen Self-Limiting Catalyst Composition with Non-Phthalate Internal Donor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000063261A1 (en) 1999-04-15 2000-10-26 Basell Technology Company B.V. Components and catalysts for the polymerization of olefins
WO2004087807A1 (en) 2003-04-03 2004-10-14 Basell Poliolefine Italia S.R.L. Impact resistant polyolefin compositions
US20070010625A1 (en) 2003-04-03 2007-01-11 Bassell Polioefine Italia S.R.L. Impact resistant polyolefin compositions

Also Published As

Publication number Publication date
WO2010146074A1 (en) 2010-12-23
CN107043491A (zh) 2017-08-15
RU2012101804A (ru) 2013-07-27
CN102803310A (zh) 2012-11-28
JP2012530170A (ja) 2012-11-29
ES2672731T3 (es) 2018-06-15
BRPI1014019A2 (pt) 2016-04-12
EP2443159B1 (en) 2018-04-25
BRPI1014019B1 (pt) 2019-10-22
RU2536682C2 (ru) 2014-12-27
KR20120042763A (ko) 2012-05-03
JP5676586B2 (ja) 2015-02-25
US9068028B2 (en) 2015-06-30
EP2443159A1 (en) 2012-04-25
US20120083576A1 (en) 2012-04-05

Similar Documents

Publication Publication Date Title
KR101769275B1 (ko) 내충격성 프로필렌 중합체 조성물의 제조 방법
CN102597022B (zh) 用于制备耐冲击丙烯聚合物组合物的方法
US8829113B2 (en) Automotive interior element
US9752023B2 (en) Process for the preparation of heterophasic propylene polymer compositions
US8063160B2 (en) Propylene-ethylene copolymers and process for their preparation
CN105636994A (zh) 多孔丙烯聚合物的制备方法
EP2909244B1 (en) Process for the preparation of propylene random copolymers
EP2986652A1 (en) Nucleated propylene-based polyolefin compositions
EP4031588B1 (en) Catalyst components for the polymerization of olefins
JP2025529403A (ja) 高延性で高弾性率のフタレートフリー耐衝撃性プロピレンコポリマー

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20111216

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20150522

Comment text: Request for Examination of Application

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20160928

Patent event code: PE09021S01D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20170510

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20170811

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20170814

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
PR1001 Payment of annual fee

Payment date: 20200624

Start annual number: 4

End annual number: 4

PR1001 Payment of annual fee

Payment date: 20210702

Start annual number: 5

End annual number: 5

PR1001 Payment of annual fee

Payment date: 20220622

Start annual number: 6

End annual number: 6

PR1001 Payment of annual fee

Payment date: 20230626

Start annual number: 7

End annual number: 7

PR1001 Payment of annual fee

Payment date: 20240624

Start annual number: 8

End annual number: 8

PR1001 Payment of annual fee

Payment date: 20250625

Start annual number: 9

End annual number: 9