CN102782197B - 碳纤维的制造方法 - Google Patents

碳纤维的制造方法 Download PDF

Info

Publication number
CN102782197B
CN102782197B CN201180011873.7A CN201180011873A CN102782197B CN 102782197 B CN102782197 B CN 102782197B CN 201180011873 A CN201180011873 A CN 201180011873A CN 102782197 B CN102782197 B CN 102782197B
Authority
CN
China
Prior art keywords
catalyst
intensity
colloid
peak
carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201180011873.7A
Other languages
English (en)
Chinese (zh)
Other versions
CN102782197A (zh
Inventor
宫本大辅
神原英二
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Holdings Corp
Original Assignee
Showa Denko KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Denko KK filed Critical Showa Denko KK
Publication of CN102782197A publication Critical patent/CN102782197A/zh
Application granted granted Critical
Publication of CN102782197B publication Critical patent/CN102782197B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10Magnesium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/745Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/20Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45Nanoparticles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/009Preparation by separation, e.g. by filtration, decantation, screening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0211Impregnation using a colloidal suspension
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/158Carbon nanotubes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00Compounds of iron
    • C01G49/02Oxides; Hydroxides
    • C01G49/08Ferroso-ferric oxide [Fe3O4]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15X-ray diffraction
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00Structure or properties of carbon nanotubes
    • C01B2202/04Nanotubes with a specific amount of walls
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00Structure or properties of carbon nanotubes
    • C01B2202/20Nanotubes characterized by their properties
    • C01B2202/36Diameter
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/74Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/84Manufacture, treatment, or detection of nanostructure
    • Y10S977/842Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/902Specified use of nanostructure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Catalysts (AREA)
  • Inorganic Fibers (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Dispersion Chemistry (AREA)
CN201180011873.7A 2010-03-02 2011-03-02 碳纤维的制造方法 Expired - Fee Related CN102782197B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2010-044963 2010-03-02
JP2010044963 2010-03-02
PCT/JP2011/001233 WO2011108269A1 (ja) 2010-03-02 2011-03-02 炭素繊維の製造方法

Publications (2)

Publication Number Publication Date
CN102782197A CN102782197A (zh) 2012-11-14
CN102782197B true CN102782197B (zh) 2015-05-20

Family

ID=44541938

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201180011873.7A Expired - Fee Related CN102782197B (zh) 2010-03-02 2011-03-02 碳纤维的制造方法

Country Status (6)

Country Link
US (1) US8992879B2 (enExample)
EP (1) EP2543756A4 (enExample)
JP (2) JP4852671B2 (enExample)
KR (1) KR101543682B1 (enExample)
CN (1) CN102782197B (enExample)
WO (1) WO2011108269A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5649269B2 (ja) * 2008-06-18 2015-01-07 昭和電工株式会社 カーボンナノファイバー、その製造方法及び用途
JP5585275B2 (ja) * 2010-07-30 2014-09-10 東レ株式会社 カーボンナノチューブ製造法
JP5852531B2 (ja) * 2012-09-12 2016-02-03 東芝環境ソリューション株式会社 金属微粒子の回収方法および回収装置
KR20150082495A (ko) * 2013-05-13 2015-07-15 이구루코교 가부시기가이샤 Ptfe 수지 조성물
JP2015044718A (ja) * 2013-08-29 2015-03-12 デュポン株式会社 熱伝導性粒子の製造方法
CN105939834B (zh) * 2013-12-13 2019-03-29 伍德韦尔丁公司 用于加强和/或加衬材料的方法
CN105980301B (zh) * 2014-02-05 2018-03-06 电化株式会社 碳纳米纤维的制造方法以及碳纳米纤维
CN104445140A (zh) * 2014-11-05 2015-03-25 华文蔚 一种碳纳米管的制造方法
JP6673337B2 (ja) * 2015-03-25 2020-03-25 日本ゼオン株式会社 炭素ナノ構造体の製造方法
EP4035775A4 (en) * 2019-09-27 2023-11-01 Zeon Corporation METHOD FOR PRODUCING CATALYST SUPPORT AND METHOD FOR PRODUCING CARBON FIBROUS NANOSTRUCTURE
CN120394010A (zh) * 2025-04-23 2025-08-01 中国石油大学(北京) 碳纤维负载Fe3O4复合材料及其制备方法和应用、电芬顿氧化降解有机污染物的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1535246A (zh) * 2001-07-20 2004-10-06 KH��ѧ���޹�˾ 纳米碳管的制备
WO2008075766A1 (ja) * 2006-12-21 2008-06-26 Showa Denko K.K. 炭素繊維および炭素繊維製造用触媒

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57127449A (en) * 1981-01-29 1982-08-07 Agency Of Ind Science & Technol Manufacture of solid catalyst carried in a colloidal form
JPH0196342A (ja) 1987-10-08 1989-04-14 Agency Of Ind Science & Technol 過共晶Al−Si合金複合材料の連続製造方法
JP3618492B2 (ja) 1996-11-29 2005-02-09 昭和電工株式会社 電池用電極材および二次電池
JP3722965B2 (ja) 1997-10-22 2005-11-30 昭和電工株式会社 電気二重層コンデンサ用炭素材料
JP3438041B2 (ja) 1999-08-31 2003-08-18 独立行政法人産業技術総合研究所 カーボンナノチューブ合成用触媒液
EP1154050A1 (en) * 2000-05-13 2001-11-14 Korean Carbon Black Co., Ltd., Degussa Group Carbon fibrils and method for producing same
JP3960973B2 (ja) 2001-01-16 2007-08-15 昭和電工株式会社 電池用触媒組成物、ガス拡散層及びこれらを備えた燃料電池
JP4778645B2 (ja) 2001-08-31 2011-09-21 昭和電工株式会社 微細炭素繊維及びその製造方法
JP2003171832A (ja) 2001-12-11 2003-06-20 Showa Denko Kk 炭素繊維の合成用原料組成物、それを用いた炭素繊維の製造方法および炭素繊維
GB0216654D0 (en) * 2002-07-17 2002-08-28 Univ Cambridge Tech CVD Synthesis of carbon nanoutubes
JP4761346B2 (ja) * 2005-03-28 2011-08-31 国立大学法人名古屋大学 2層カーボンナノチューブ含有組成物
JP4834818B2 (ja) * 2005-05-10 2011-12-14 国立大学法人名古屋大学 カーボンナノチューブ集合体の製造方法
JP4872042B2 (ja) * 2005-05-10 2012-02-08 国立大学法人名古屋大学 高密度カーボンナノチューブ集合体及びその製造方法
EP1977997A4 (en) * 2005-12-29 2013-06-05 Toray Industries PROCESS FOR PRODUCING CARBON NANOTUBES AND CATALYST FOR THE PRODUCTION OF CARBON NANOTUBES
JP4730707B2 (ja) 2006-03-08 2011-07-20 株式会社豊田中央研究所 カーボンナノチューブ合成用触媒及びその製造方法、触媒分散液、並びに、カーボンナノチューブの製造方法
JP5192774B2 (ja) * 2006-10-26 2013-05-08 黒崎播磨株式会社 ナノカーボン被覆耐火原料とその製造方法、およびそれを使用した耐火物とその製造方法
DE102006055106C5 (de) * 2006-11-14 2018-08-23 Byk-Chemie Gmbh Dispergierverfahren
JP4873413B2 (ja) * 2006-11-15 2012-02-08 ニッタ株式会社 多層カーボンナノチューブの集合構造
JP2008169092A (ja) 2007-01-12 2008-07-24 National Institute Of Advanced Industrial & Technology カーボンナノチューブの製造方法
ATE456691T1 (de) * 2007-07-02 2010-02-15 Centre Nat Rech Scient Verfahren zur herstellung von wasserstoffgas und kohlenstoffnanoröhrchen aus dem katalytischen abbau von ethanol
TW201012749A (en) * 2008-08-19 2010-04-01 Univ Rice William M Methods for preparation of graphene nanoribbons from carbon nanotubes and compositions, thin films and devices derived therefrom

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1535246A (zh) * 2001-07-20 2004-10-06 KH��ѧ���޹�˾ 纳米碳管的制备
JP2004534715A (ja) * 2001-07-20 2004-11-18 ケイエイチ ケミカルズ カンパニー、リミテッド カーボンナノチューブの製造方法
WO2008075766A1 (ja) * 2006-12-21 2008-06-26 Showa Denko K.K. 炭素繊維および炭素繊維製造用触媒

Also Published As

Publication number Publication date
EP2543756A1 (en) 2013-01-09
JPWO2011108269A1 (ja) 2013-06-20
CN102782197A (zh) 2012-11-14
KR20130004469A (ko) 2013-01-10
US20120321543A1 (en) 2012-12-20
JP2012052282A (ja) 2012-03-15
EP2543756A4 (en) 2013-12-18
WO2011108269A1 (ja) 2011-09-09
JP4852671B2 (ja) 2012-01-11
KR101543682B1 (ko) 2015-08-11
US8992879B2 (en) 2015-03-31

Similar Documents

Publication Publication Date Title
CN102782197B (zh) 碳纤维的制造方法
CN102781828B (zh) 碳纳米管取向集合体的制造方法
KR101446116B1 (ko) 탄소나노튜브 제조용 금속촉매의 제조방법 및 이를 이용한 탄소나노튜브의 제조방법
CN103201215B (zh) 新型碳纳米管及其制造方法
CN101600824B (zh) 碳纳米纤维、其制造方法和用途
KR101414560B1 (ko) 전도성 필름의 제조방법
KR101350690B1 (ko) 초저밀도 특성을 지닌 번들 구조의 고전도성 탄소나노튜브 및 이의 제조방법
US7879261B2 (en) Carbon nanofiber, production process and use
JP5653696B2 (ja) 炭素繊維凝集体
JP5649901B2 (ja) 多層カーボンナノチューブ集合体及びその製造方法
CN104918881A (zh) 控制碳纳米管聚集体的堆积密度的方法
Tran et al. Electroconductive performance of polypyrrole/reduced graphene oxide/carbon nanotube composites synthesized via in situ oxidative polymerization
CN105517707A (zh) 制造具有可控堆密度的碳纳米管团聚体的方法
JP7556170B1 (ja) カーボンナノチューブ集合体、カーボンナノチューブ分散液、導電材料、電極、二次電池、平面状集合体、フィルター、電磁波シールド及び極端紫外線用ペリクル
KR101327812B1 (ko) 초저밀도 배향성 번들 구조를 지닌 고전도성 탄소나노튜브 및 이를 이용한 고전도성 고분자 나노복합재 조성물
KR101608477B1 (ko) 탄소나노튜브 제조용 금속촉매의 제조방법 및 이를 이용한 탄소나노튜브의 제조방법
KR20120093458A (ko) 수직 배향된 번들 구조를 지닌 고전도성 탄소나노튜브 및 이를 이용한 고전도성 고분자 나노복합재 조성물
Cao et al. Decorating Mg/Fe oxide nanotubes with nitrogen-doped carbon nanotubes

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150520

Termination date: 20160302

CF01 Termination of patent right due to non-payment of annual fee