CN102766032B - 一种环己烷氧化的方法 - Google Patents

一种环己烷氧化的方法 Download PDF

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Publication number
CN102766032B
CN102766032B CN201110117354.0A CN201110117354A CN102766032B CN 102766032 B CN102766032 B CN 102766032B CN 201110117354 A CN201110117354 A CN 201110117354A CN 102766032 B CN102766032 B CN 102766032B
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China
Prior art keywords
rectifying tower
hts
tower
organic solvent
molecular sieve
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CN201110117354.0A
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English (en)
Chinese (zh)
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CN102766032A (zh
Inventor
林民
史春风
朱斌
汝迎春
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sinopec Research Institute of Petroleum Processing
China Petroleum and Chemical Corp
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Sinopec Research Institute of Petroleum Processing
China Petroleum and Chemical Corp
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Application filed by Sinopec Research Institute of Petroleum Processing , China Petroleum and Chemical Corp filed Critical Sinopec Research Institute of Petroleum Processing
Priority to CN201110117354.0A priority Critical patent/CN102766032B/zh
Priority to PCT/CN2012/000578 priority patent/WO2012149827A1/zh
Priority to US14/115,754 priority patent/US8940939B2/en
Priority to EP12780008.4A priority patent/EP2706051B1/en
Priority to JP2014508673A priority patent/JP6339498B2/ja
Publication of CN102766032A publication Critical patent/CN102766032A/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C07C27/10—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
    • C07C27/16—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with other oxidising agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201110117354.0A 2011-05-05 2011-05-05 一种环己烷氧化的方法 Active CN102766032B (zh)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN201110117354.0A CN102766032B (zh) 2011-05-05 2011-05-05 一种环己烷氧化的方法
PCT/CN2012/000578 WO2012149827A1 (zh) 2011-05-05 2012-05-02 一种氧化环己烷的方法
US14/115,754 US8940939B2 (en) 2011-05-05 2012-05-02 Process of oxidizing cyclohexane
EP12780008.4A EP2706051B1 (en) 2011-05-05 2012-05-02 Method for oxidating cyclohexane
JP2014508673A JP6339498B2 (ja) 2011-05-05 2012-05-02 シクロヘキサンのエポキシ化方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201110117354.0A CN102766032B (zh) 2011-05-05 2011-05-05 一种环己烷氧化的方法

Publications (2)

Publication Number Publication Date
CN102766032A CN102766032A (zh) 2012-11-07
CN102766032B true CN102766032B (zh) 2014-10-01

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CN201110117354.0A Active CN102766032B (zh) 2011-05-05 2011-05-05 一种环己烷氧化的方法

Country Status (5)

Country Link
US (1) US8940939B2 (enExample)
EP (1) EP2706051B1 (enExample)
JP (1) JP6339498B2 (enExample)
CN (1) CN102766032B (enExample)
WO (1) WO2012149827A1 (enExample)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103965015B (zh) * 2013-01-30 2016-01-20 中国石油化工股份有限公司 一种环己酮和环己醇的制备方法
KR101518009B1 (ko) * 2013-12-16 2015-05-06 김호진 콘센트 어셈블리
CN105524019B (zh) * 2014-09-29 2017-12-22 中国石油化工股份有限公司 一种氧化烯烃的制备方法
CN105327717B (zh) * 2015-12-03 2017-09-15 湖南科技大学 SiO2‑介孔TiO2空心微球封装纳米金环己烷氧化催化剂及其制备和应用
CN108329191B (zh) * 2018-01-28 2020-03-27 江西科因润滑材料有限公司 一种环己烷氧化液加工的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1301599A (zh) * 1999-12-24 2001-07-04 中国石油化工集团公司 一种钛硅分子筛及其制备方法
CN1678389A (zh) * 2002-08-30 2005-10-05 巴斯福股份公司 氧化法

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IT1187661B (it) * 1985-04-23 1987-12-23 Enichem Sintesi Catalizzatore a base di silicio e titanio ad elevata resistenza meccanica
KR0151712B1 (ko) * 1988-11-08 1998-10-15 피터 챨스 보우덴 포화탄화수소 사슬의 산화
IT1231779B (it) * 1989-08-09 1991-12-21 Eniricerche Spa Procedimento per l'ossidazione di composti paraffinici.
JPH03220142A (ja) * 1990-01-25 1991-09-27 Tosoh Corp パラフィンの酸化方法
IN190356B (enExample) * 1994-12-30 2003-07-19 Council Scient Ind Res
WO1999026936A2 (en) * 1997-11-24 1999-06-03 E.I. Du Pont De Nemours And Company Process for the selective oxidation of organic compounds
US7837977B2 (en) 2005-09-13 2010-11-23 Chevron U.S.A. Inc. Preparation of titanosilicate zeolite TS-1
CN101279959B (zh) 2008-05-21 2010-12-01 湖南长岭石化科技开发有限公司 一种合成环氧丙烷的方法
CN102079695B (zh) 2009-11-27 2014-01-15 中国石油化工股份有限公司 一种催化氧化环己烷的方法
CN102206147B (zh) 2010-03-31 2013-09-04 中国石油化工股份有限公司 一种环己烷氧化的方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1301599A (zh) * 1999-12-24 2001-07-04 中国石油化工集团公司 一种钛硅分子筛及其制备方法
CN1678389A (zh) * 2002-08-30 2005-10-05 巴斯福股份公司 氧化法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CYCLOHEXANE OXIDATION CATALYZED BY TITANIUM SILICALITE(TS-1) WITH HYDROGEN PEROXIDE;Tao Jialin et al.;《Journal of Natural Gas Chemistry》;20011228;第10卷(第4期);第295-307页 *
Tao Jialin et al..CYCLOHEXANE OXIDATION CATALYZED BY TITANIUM SILICALITE(TS-1) WITH HYDROGEN PEROXIDE.《Journal of Natural Gas Chemistry》.2001,第10卷(第4期),第295-307页.

Also Published As

Publication number Publication date
JP2014523860A (ja) 2014-09-18
EP2706051A1 (en) 2014-03-12
US20140088327A1 (en) 2014-03-27
EP2706051B1 (en) 2019-01-09
CN102766032A (zh) 2012-11-07
WO2012149827A1 (zh) 2012-11-08
EP2706051A4 (en) 2014-09-17
US8940939B2 (en) 2015-01-27
JP6339498B2 (ja) 2018-06-06

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