CN102282181B - 包括甲硅烷基酯内给体的前催化剂组合物和方法 - Google Patents

包括甲硅烷基酯内给体的前催化剂组合物和方法 Download PDF

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Publication number
CN102282181B
CN102282181B CN200980155007.8A CN200980155007A CN102282181B CN 102282181 B CN102282181 B CN 102282181B CN 200980155007 A CN200980155007 A CN 200980155007A CN 102282181 B CN102282181 B CN 102282181B
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procatalyst
electron donor
group
silyl
ester
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CN102282181A (zh
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陈林枫
塔克·W·梁
T·陶
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WR Grace and Co
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Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN200980155007.8A 2008-11-25 2009-11-23 包括甲硅烷基酯内给体的前催化剂组合物和方法 Active CN102282181B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11782008P 2008-11-25 2008-11-25
US61/117,820 2008-11-25
PCT/US2009/065471 WO2010065361A1 (en) 2008-11-25 2009-11-23 Procatalyst composition including silyl ester internal donor and method

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CN201410216442.XA Division CN104059095A (zh) 2008-11-25 2009-11-23 包括甲硅烷基酯内给体的前催化剂组合物和方法

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CN102282181A CN102282181A (zh) 2011-12-14
CN102282181B true CN102282181B (zh) 2014-06-25

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US (1) US8088872B2 (enExample)
EP (1) EP2350144B1 (enExample)
JP (2) JP6081700B2 (enExample)
KR (1) KR101589780B1 (enExample)
CN (2) CN102282181B (enExample)
BR (1) BRPI0916095B1 (enExample)
MX (1) MX2011005542A (enExample)
RU (1) RU2505548C2 (enExample)
SG (1) SG171799A1 (enExample)
WO (1) WO2010065361A1 (enExample)

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CN102746426A (zh) * 2011-04-22 2012-10-24 中国石油天然气股份有限公司 一种烯烃聚合催化剂及其制备和应用
KR20140010985A (ko) * 2011-05-13 2014-01-27 릴라이언스 인더스트리즈 리미티드 프로필렌 중합용 촉매 시스템
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CN108440692B (zh) * 2018-04-20 2019-08-27 天津科技大学 催化乙烯聚合Ziegler-Natta催化剂内给电子体、催化剂组分及制备方法
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JP6081700B2 (ja) 2017-02-15
EP2350144B1 (en) 2015-07-15
US8088872B2 (en) 2012-01-03
WO2010065361A1 (en) 2010-06-10
BRPI0916095A8 (pt) 2017-09-19
RU2011126139A (ru) 2013-01-10
KR101589780B1 (ko) 2016-01-28
EP2350144A1 (en) 2011-08-03
BRPI0916095B1 (pt) 2019-05-07
US20100130709A1 (en) 2010-05-27
SG171799A1 (en) 2011-07-28
JP2015155558A (ja) 2015-08-27
MX2011005542A (es) 2011-06-21
KR20110094087A (ko) 2011-08-19
BRPI0916095A2 (pt) 2015-11-17
CN102282181A (zh) 2011-12-14
CN104059095A (zh) 2014-09-24
JP2012509890A (ja) 2012-04-26
RU2505548C2 (ru) 2014-01-27

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