JP6081700B2 - シリルエステル内部供与体を含むプロ触媒組成物および方法 - Google Patents
シリルエステル内部供与体を含むプロ触媒組成物および方法 Download PDFInfo
- Publication number
- JP6081700B2 JP6081700B2 JP2011537674A JP2011537674A JP6081700B2 JP 6081700 B2 JP6081700 B2 JP 6081700B2 JP 2011537674 A JP2011537674 A JP 2011537674A JP 2011537674 A JP2011537674 A JP 2011537674A JP 6081700 B2 JP6081700 B2 JP 6081700B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- procatalyst
- electron donor
- butyl
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 0 CC=CC(C(OC(*)(*)C(*)(*)*(*)(*)O*(c1ccccc1)=O)=O)=CC Chemical compound CC=CC(C(OC(*)(*)C(*)(*)*(*)(*)O*(c1ccccc1)=O)=O)=CC 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11782008P | 2008-11-25 | 2008-11-25 | |
| US61/117,820 | 2008-11-25 | ||
| PCT/US2009/065471 WO2010065361A1 (en) | 2008-11-25 | 2009-11-23 | Procatalyst composition including silyl ester internal donor and method |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015114161A Division JP2015155558A (ja) | 2008-11-25 | 2015-06-04 | シリルエステル内部供与体を含むプロ触媒組成物 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012509890A JP2012509890A (ja) | 2012-04-26 |
| JP2012509890A5 JP2012509890A5 (enExample) | 2013-01-10 |
| JP6081700B2 true JP6081700B2 (ja) | 2017-02-15 |
Family
ID=41718309
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011537674A Expired - Fee Related JP6081700B2 (ja) | 2008-11-25 | 2009-11-23 | シリルエステル内部供与体を含むプロ触媒組成物および方法 |
| JP2015114161A Pending JP2015155558A (ja) | 2008-11-25 | 2015-06-04 | シリルエステル内部供与体を含むプロ触媒組成物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015114161A Pending JP2015155558A (ja) | 2008-11-25 | 2015-06-04 | シリルエステル内部供与体を含むプロ触媒組成物 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8088872B2 (enExample) |
| EP (1) | EP2350144B1 (enExample) |
| JP (2) | JP6081700B2 (enExample) |
| KR (1) | KR101589780B1 (enExample) |
| CN (2) | CN102282181B (enExample) |
| BR (1) | BRPI0916095B1 (enExample) |
| MX (1) | MX2011005542A (enExample) |
| RU (1) | RU2505548C2 (enExample) |
| SG (1) | SG171799A1 (enExample) |
| WO (1) | WO2010065361A1 (enExample) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8088872B2 (en) * | 2008-11-25 | 2012-01-03 | Dow Global Technologies Llc | Procatalyst composition including silyl ester internal donor and method |
| BRPI0916175A8 (pt) * | 2008-11-25 | 2017-09-19 | Union Carbide Chem Plastic | Composição de procatalisador, composição de catalisador e processo para produzir um polímero baseado em olefina |
| WO2012118883A1 (en) * | 2011-03-01 | 2012-09-07 | Dow Global Technologies Llc | Process for improving bulk density with multi-contact procatalyst and product |
| CN102746426A (zh) * | 2011-04-22 | 2012-10-24 | 中国石油天然气股份有限公司 | 一种烯烃聚合催化剂及其制备和应用 |
| EP2707400A1 (en) * | 2011-05-13 | 2014-03-19 | Reliance Industries Limited | Catalyst system for polymerization of propylene |
| US9790291B2 (en) | 2013-03-14 | 2017-10-17 | Formosa Plastics Corporation, Usa | Non-phthalate compounds as electron donors for polyolefin catalysts |
| EP3033348B1 (en) | 2013-08-12 | 2017-11-29 | Saudi Basic Industries Corporation | Catalyst system for polymerisation of an olefin |
| WO2015091982A1 (en) | 2013-12-20 | 2015-06-25 | Saudi Basic Industries Corporation | Catalyst system for polymerisation of an olefin |
| EP3083724B1 (en) | 2013-12-20 | 2018-07-25 | Saudi Basic Industries Corporation | Catalyst system for polymerization of an olefin |
| US9944731B2 (en) | 2013-12-20 | 2018-04-17 | Saudi Basic Industries Corporation | Catalyst system for polymerization of an olefin |
| MX2016008022A (es) | 2013-12-20 | 2017-05-10 | Saudi Basic Ind Corp | Sistema catalizador para polimerizacion de una olefina. |
| EA028922B1 (ru) | 2013-12-20 | 2018-01-31 | Сауди Бейсик Индастриз Корпорейшн | Прокатализатор для полимеризации олефинов |
| US10000591B2 (en) | 2013-12-20 | 2018-06-19 | Saudi Basic Industries Corporation | Catalyst system for polymerization of an olefin |
| US9926391B2 (en) | 2013-12-20 | 2018-03-27 | Saudi Basic Industries Corporation | Catalyst system for polymerization of an olefin |
| US9593184B2 (en) | 2014-10-28 | 2017-03-14 | Formosa Plastics Corporation, Usa | Oxalic acid diamides as modifiers for polyolefin catalysts |
| EP3050906B1 (en) * | 2015-01-27 | 2020-07-22 | Indian Oil Corporation Limited | Catalyst process modification and polymerization thereof |
| CN107406539B (zh) | 2015-03-25 | 2020-04-07 | 巴塞尔聚烯烃股份有限公司 | 连续气相聚合方法 |
| WO2016168108A1 (en) * | 2015-04-13 | 2016-10-20 | Basf Corporation | Olefin polymerization catalyst component with auxiliary internal electron donor |
| EP3307820B1 (en) | 2015-06-12 | 2019-10-02 | SABIC Global Technologies B.V. | Process for manufacture of low emission polypropylene |
| EP3181625A1 (en) | 2015-12-18 | 2017-06-21 | SABIC Global Technologies B.V. | Composition comprising heterophasic propylene copolymer |
| US9777084B2 (en) | 2016-02-19 | 2017-10-03 | Formosa Plastics Corporation, Usa | Catalyst system for olefin polymerization and method for producing olefin polymer |
| US11427660B2 (en) | 2016-08-17 | 2022-08-30 | Formosa Plastics Corporation, Usa | Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same |
| US9815920B1 (en) | 2016-10-14 | 2017-11-14 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| BR112019018488B1 (pt) * | 2017-03-06 | 2022-08-09 | W.R. Grace & Co.-Conn | Componente pré-catalisador sólido e sistema catalisador para uso na polimerização olefínica e processo para polimerização ou copolimerização de um ou mais monômeros de olefina |
| CN110234663B (zh) | 2017-03-17 | 2022-03-08 | Sabic环球技术有限责任公司 | 制造聚烯烃的方法 |
| WO2018167301A1 (en) | 2017-03-17 | 2018-09-20 | Sabic Global Technologies B.V. | Process for the polymerization of a polyolefin |
| US10124324B1 (en) | 2017-05-09 | 2018-11-13 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| US10822438B2 (en) | 2017-05-09 | 2020-11-03 | Formosa Plastics Corporation | Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer |
| CN108440692B (zh) * | 2018-04-20 | 2019-08-27 | 天津科技大学 | 催化乙烯聚合Ziegler-Natta催化剂内给电子体、催化剂组分及制备方法 |
| CN113056515A (zh) | 2018-11-19 | 2021-06-29 | Sabic环球技术有限责任公司 | 包含聚合物组合物的食品包装和所述聚合物组合物用于制造食品包装的用途 |
| CN113710678A (zh) * | 2019-03-31 | 2021-11-26 | 陶氏环球技术有限责任公司 | 用于制备催化剂前体材料的方法 |
| US20220315746A1 (en) | 2019-09-06 | 2022-10-06 | Sabic Global Technologies B.V. | Healthcare article comprising a random propylene-ethylene copolymer |
| CN114426603B (zh) * | 2020-10-16 | 2023-11-14 | 中国石油化工股份有限公司 | 乙烯聚合的方法及聚乙烯 |
| CN115433296B (zh) * | 2021-06-03 | 2024-04-05 | 中国科学院化学研究所 | 一种催化剂组合物及其在烯烃聚合中的应用 |
| US20250066513A1 (en) | 2023-08-23 | 2025-02-27 | Formosa Plastics Corporation, U.S.A. | Catalyst System For Enhanced Stereo-Specificity Of Olefin Polymerization |
| US20250066514A1 (en) | 2023-08-24 | 2025-02-27 | Formosa Plastics Corporation, U.S.A. | Catalysts component and process for the production of polypropylene having high melt flow rate with high isotacticity |
| US20250109218A1 (en) | 2023-09-29 | 2025-04-03 | Formosa Plastics Corporation, U.S.A. | Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors |
| US20250115687A1 (en) | 2023-10-06 | 2025-04-10 | Formosa Plastics Corporation, U.S.A. | Production method for solid catalyst component for polymerizing olefins, and catalyst for polymerizaing olefins |
| US20250115686A1 (en) | 2023-10-09 | 2025-04-10 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing silane and process for the production of polypropylene having high isotacticity at high melt flow rate |
| US20250297039A1 (en) | 2024-03-19 | 2025-09-25 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing diglycidylester components and its use for the production of polypropylene having high isotacticity at high melt flow rate |
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|---|---|---|---|---|
| GB630951A (en) | 1947-08-26 | 1949-10-24 | Dow Corning | Improvements in or relating to the manufacture of organo silicon esters |
| US5151399A (en) * | 1990-10-18 | 1992-09-29 | Shell Oil Company | Olefin polymerization catalyst |
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| US5082907A (en) * | 1990-10-18 | 1992-01-21 | Shell Oil Company | Olefin polymerization catalyst |
| NL160286C (enExample) * | 1971-06-25 | |||
| IT1209255B (it) * | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| JPS5883006A (ja) * | 1981-11-13 | 1983-05-18 | Mitsui Petrochem Ind Ltd | オレフインの重合方法 |
| IT1190681B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| US4442276A (en) * | 1982-02-12 | 1984-04-10 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing or copolymerizing olefins |
| IT1190683B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| JPS5991107A (ja) * | 1982-11-17 | 1984-05-25 | Toho Titanium Co Ltd | オレフイン類重合用触媒成分の製造方法 |
| US4458027A (en) * | 1983-03-18 | 1984-07-03 | E. I. Du Pont De Nemours And Company | Olefin polymerization catalysts |
| JPS6023404A (ja) * | 1983-07-20 | 1985-02-06 | Toho Titanium Co Ltd | オレフィン類重合用触媒成分 |
| US4540679A (en) * | 1984-03-23 | 1985-09-10 | Amoco Corporation | Magnesium hydrocarbyl carbonate supports |
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| DE3777339D1 (de) * | 1986-05-06 | 1992-04-16 | Toho Titanium Co Ltd | Katalysator zur polymerisation von olefinen. |
| CA1310955C (en) * | 1987-03-13 | 1992-12-01 | Mamoru Kioka | Process for polymerization of olefins and polymerization catalyst |
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| IT1227258B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| JP2940684B2 (ja) * | 1989-12-29 | 1999-08-25 | 三井化学株式会社 | オレフィン重合用固体状触媒成分およびこの触媒成分を用いたオレフィンの重合方法 |
| US5247032A (en) * | 1989-12-29 | 1993-09-21 | Mitsui Petrochemical Industries, Ltd. | Solid catalyst components for olefin polymerization and processes for the polymerization of olefin using same |
| IT1241062B (it) * | 1990-01-10 | 1993-12-29 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| US5034361A (en) * | 1990-05-24 | 1991-07-23 | Shell Oil Company | Catalyst precursor production |
| US5146028A (en) * | 1990-10-18 | 1992-09-08 | Shell Oil Company | Olefin polymerization catalyst and process of polymerization |
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| US5432244A (en) * | 1990-12-12 | 1995-07-11 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of polypropylene |
| FI88047C (fi) * | 1991-05-09 | 1993-03-25 | Neste Oy | Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner |
| GB9300318D0 (en) * | 1993-01-08 | 1993-03-03 | Oxford Analytical Instr Ltd | Improvements relating to sample monitoring |
| SK2712000A3 (en) * | 1997-09-05 | 2001-07-10 | Bp Chem Int Ltd | Polymerisation catalysts |
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| HUP0103083A3 (en) | 1999-04-15 | 2003-01-28 | Basell Technology Co Bv | Components and catalysts for the polymerization of olefins |
| TR200103803T2 (tr) * | 1999-06-30 | 2002-05-21 | Union Carbide Chemicals & Plastics Technology Corporation | Magnezyum/titanyum alkoksit kompleksleri ve bu komplekslerden yapılan polimerizasyon katalizörleri |
| US6391985B1 (en) * | 1999-10-21 | 2002-05-21 | Union Carbide Chemicals & Plastics Technology Corporation | High condensing mode polyolefin production under turbulent conditions in a fluidized bed |
| MXPA02000431A (es) * | 2001-01-12 | 2005-06-06 | Fina Technology | Produccion de resinas de polipropileno de flujo de fundicion ultra rapido. |
| US6825146B2 (en) * | 2001-05-29 | 2004-11-30 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst compositions and method of preparation |
| JP2004527636A (ja) * | 2001-05-29 | 2004-09-09 | ユニオン・カーバイド・ケミカルズ・アンド・プラスチックス・テクノロジー・コーポレーション | オレフィン重合触媒組成物及びその製造方法 |
| US6960635B2 (en) * | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
| CN100441561C (zh) * | 2002-02-07 | 2008-12-10 | 中国石油化工股份有限公司 | 用于制备烯烃聚合催化剂的多酯化合物 |
| CN1169845C (zh) * | 2002-02-07 | 2004-10-06 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用 |
| CN1297534C (zh) | 2003-08-06 | 2007-01-31 | 中国石油化工股份有限公司 | 用于制备烯烃聚合催化剂的二醇酯化合物 |
| EP1668044B1 (en) * | 2003-09-23 | 2014-05-07 | W.R. Grace & CO. - CONN. | Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process |
| EP1735353A1 (en) * | 2004-04-07 | 2006-12-27 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization procatalyst compositions and method of preparation |
| US7351778B2 (en) * | 2004-04-30 | 2008-04-01 | China Petroleum & Chemical Corporation | Catalyst component for olefin polymerization and catalyst comprising the same |
| CN1282670C (zh) * | 2004-04-30 | 2006-11-01 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的催化剂组分及其催化剂 |
| JP2011506718A (ja) * | 2007-12-20 | 2011-03-03 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 改良された特性を有する高立体規則性ポリプロピレン |
| US8088872B2 (en) * | 2008-11-25 | 2012-01-03 | Dow Global Technologies Llc | Procatalyst composition including silyl ester internal donor and method |
| BRPI0916175A8 (pt) * | 2008-11-25 | 2017-09-19 | Union Carbide Chem Plastic | Composição de procatalisador, composição de catalisador e processo para produzir um polímero baseado em olefina |
-
2009
- 2009-11-20 US US12/622,889 patent/US8088872B2/en active Active
- 2009-11-23 EP EP09760417.7A patent/EP2350144B1/en not_active Not-in-force
- 2009-11-23 WO PCT/US2009/065471 patent/WO2010065361A1/en not_active Ceased
- 2009-11-23 BR BRPI0916095-7A patent/BRPI0916095B1/pt not_active IP Right Cessation
- 2009-11-23 CN CN200980155007.8A patent/CN102282181B/zh active Active
- 2009-11-23 JP JP2011537674A patent/JP6081700B2/ja not_active Expired - Fee Related
- 2009-11-23 KR KR1020117014608A patent/KR101589780B1/ko not_active Expired - Fee Related
- 2009-11-23 CN CN201410216442.XA patent/CN104059095A/zh active Pending
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Also Published As
| Publication number | Publication date |
|---|---|
| KR101589780B1 (ko) | 2016-01-28 |
| SG171799A1 (en) | 2011-07-28 |
| WO2010065361A1 (en) | 2010-06-10 |
| US20100130709A1 (en) | 2010-05-27 |
| BRPI0916095A8 (pt) | 2017-09-19 |
| CN102282181B (zh) | 2014-06-25 |
| KR20110094087A (ko) | 2011-08-19 |
| US8088872B2 (en) | 2012-01-03 |
| BRPI0916095B1 (pt) | 2019-05-07 |
| JP2015155558A (ja) | 2015-08-27 |
| BRPI0916095A2 (pt) | 2015-11-17 |
| EP2350144B1 (en) | 2015-07-15 |
| MX2011005542A (es) | 2011-06-21 |
| EP2350144A1 (en) | 2011-08-03 |
| RU2505548C2 (ru) | 2014-01-27 |
| JP2012509890A (ja) | 2012-04-26 |
| CN102282181A (zh) | 2011-12-14 |
| CN104059095A (zh) | 2014-09-24 |
| RU2011126139A (ru) | 2013-01-10 |
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