BRPI0916095B1 - Composição de procatalisador, composição catalítica e processo para produzir um polímero a base de olefinas - Google Patents

Composição de procatalisador, composição catalítica e processo para produzir um polímero a base de olefinas Download PDF

Info

Publication number
BRPI0916095B1
BRPI0916095B1 BRPI0916095-7A BRPI0916095A BRPI0916095B1 BR PI0916095 B1 BRPI0916095 B1 BR PI0916095B1 BR PI0916095 A BRPI0916095 A BR PI0916095A BR PI0916095 B1 BRPI0916095 B1 BR PI0916095B1
Authority
BR
Brazil
Prior art keywords
procatalyst
group
electron donor
composition
silyl
Prior art date
Application number
BRPI0916095-7A
Other languages
English (en)
Portuguese (pt)
Inventor
Linfeng Chen
Tak W. Leung
Tao Tao
Original Assignee
W. R. Grace & Co.-Conn
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by W. R. Grace & Co.-Conn filed Critical W. R. Grace & Co.-Conn
Publication of BRPI0916095A2 publication Critical patent/BRPI0916095A2/pt
Publication of BRPI0916095A8 publication Critical patent/BRPI0916095A8/pt
Publication of BRPI0916095B1 publication Critical patent/BRPI0916095B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
BRPI0916095-7A 2008-11-25 2009-11-23 Composição de procatalisador, composição catalítica e processo para produzir um polímero a base de olefinas BRPI0916095B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11782008P 2008-11-25 2008-11-25
US61/117,820 2008-11-25
PCT/US2009/065471 WO2010065361A1 (en) 2008-11-25 2009-11-23 Procatalyst composition including silyl ester internal donor and method

Publications (3)

Publication Number Publication Date
BRPI0916095A2 BRPI0916095A2 (pt) 2015-11-17
BRPI0916095A8 BRPI0916095A8 (pt) 2017-09-19
BRPI0916095B1 true BRPI0916095B1 (pt) 2019-05-07

Family

ID=41718309

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0916095-7A BRPI0916095B1 (pt) 2008-11-25 2009-11-23 Composição de procatalisador, composição catalítica e processo para produzir um polímero a base de olefinas

Country Status (10)

Country Link
US (1) US8088872B2 (enExample)
EP (1) EP2350144B1 (enExample)
JP (2) JP6081700B2 (enExample)
KR (1) KR101589780B1 (enExample)
CN (2) CN104059095A (enExample)
BR (1) BRPI0916095B1 (enExample)
MX (1) MX2011005542A (enExample)
RU (1) RU2505548C2 (enExample)
SG (1) SG171799A1 (enExample)
WO (1) WO2010065361A1 (enExample)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2497834C2 (ru) * 2008-11-25 2013-11-10 Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Ллс Композиция прокатализатора с многокомпонентным внутренним донором, содержащим сложный эфир, и способ
US8088872B2 (en) * 2008-11-25 2012-01-03 Dow Global Technologies Llc Procatalyst composition including silyl ester internal donor and method
WO2012118883A1 (en) * 2011-03-01 2012-09-07 Dow Global Technologies Llc Process for improving bulk density with multi-contact procatalyst and product
CN102746426A (zh) * 2011-04-22 2012-10-24 中国石油天然气股份有限公司 一种烯烃聚合催化剂及其制备和应用
US20140316084A1 (en) * 2011-05-13 2014-10-23 Reliance Industries Limited Catalyst system for polymerization of propylene
US9790291B2 (en) 2013-03-14 2017-10-17 Formosa Plastics Corporation, Usa Non-phthalate compounds as electron donors for polyolefin catalysts
US9701773B2 (en) 2013-08-12 2017-07-11 Sabic Global Technologies, B.V. Catalyst system for polymerisation of an OLEFIN
WO2015091940A1 (en) 2013-12-20 2015-06-25 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
EP3083724B1 (en) 2013-12-20 2018-07-25 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
EA034562B1 (ru) 2013-12-20 2020-02-20 Сауди Бейсик Индастриз Корпорейшн Композиция катализатора для полимеризации олефинов
CN105940019B (zh) 2013-12-20 2018-05-18 沙特基础工业公司 用于烯烃聚合的催化剂体系
EP3083722B1 (en) 2013-12-20 2021-11-10 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
WO2015091984A1 (en) 2013-12-20 2015-06-25 Saudi Basic Industries Corporation Procatalyst for polymerization of olefins
MX2016008041A (es) 2013-12-20 2017-03-03 Saudi Basic Ind Corp Sistema catalizador para polimerizacion de una olefina.
US9593184B2 (en) 2014-10-28 2017-03-14 Formosa Plastics Corporation, Usa Oxalic acid diamides as modifiers for polyolefin catalysts
EP3050906B1 (en) * 2015-01-27 2020-07-22 Indian Oil Corporation Limited Catalyst process modification and polymerization thereof
WO2016150996A1 (en) 2015-03-25 2016-09-29 Basell Polyolefine Gmbh Continuous gas-phase polymerization processes
WO2016168108A1 (en) * 2015-04-13 2016-10-20 Basf Corporation Olefin polymerization catalyst component with auxiliary internal electron donor
CN107922694B (zh) 2015-06-12 2023-08-15 Sabic环球技术有限责任公司 用于制造低排放聚丙烯的方法
EP3181625A1 (en) 2015-12-18 2017-06-21 SABIC Global Technologies B.V. Composition comprising heterophasic propylene copolymer
US9777084B2 (en) 2016-02-19 2017-10-03 Formosa Plastics Corporation, Usa Catalyst system for olefin polymerization and method for producing olefin polymer
US11427660B2 (en) 2016-08-17 2022-08-30 Formosa Plastics Corporation, Usa Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same
US9815920B1 (en) 2016-10-14 2017-11-14 Formosa Plastics Corporation, Usa Olefin polymerization catalyst components and process for the production of olefin polymers therewith
BR112019018488B1 (pt) * 2017-03-06 2022-08-09 W.R. Grace & Co.-Conn Componente pré-catalisador sólido e sistema catalisador para uso na polimerização olefínica e processo para polimerização ou copolimerização de um ou mais monômeros de olefina
WO2018167155A1 (en) 2017-03-17 2018-09-20 Sabic Global Technologies B.V. Process of making polyolefins
CN110382555B (zh) 2017-03-17 2022-01-25 Sabic环球技术有限责任公司 用于聚烯烃聚合的方法
US10124324B1 (en) 2017-05-09 2018-11-13 Formosa Plastics Corporation, Usa Olefin polymerization catalyst components and process for the production of olefin polymers therewith
US10822438B2 (en) 2017-05-09 2020-11-03 Formosa Plastics Corporation Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer
CN108440692B (zh) * 2018-04-20 2019-08-27 天津科技大学 催化乙烯聚合Ziegler-Natta催化剂内给电子体、催化剂组分及制备方法
US20210403691A1 (en) 2018-11-19 2021-12-30 Sabic Global Technologies B.V. Food packaging comprising a polymer composition and use of said polymer composition for manufacturing of food packaging
US12479864B2 (en) 2019-03-31 2025-11-25 Dow Global Technologies Llc Methods for preparing catalyst precursor materials
US20220315746A1 (en) 2019-09-06 2022-10-06 Sabic Global Technologies B.V. Healthcare article comprising a random propylene-ethylene copolymer
CN114426603B (zh) * 2020-10-16 2023-11-14 中国石油化工股份有限公司 乙烯聚合的方法及聚乙烯
CN115433296B (zh) * 2021-06-03 2024-04-05 中国科学院化学研究所 一种催化剂组合物及其在烯烃聚合中的应用
US20250066513A1 (en) 2023-08-23 2025-02-27 Formosa Plastics Corporation, U.S.A. Catalyst System For Enhanced Stereo-Specificity Of Olefin Polymerization
US20250066514A1 (en) 2023-08-24 2025-02-27 Formosa Plastics Corporation, U.S.A. Catalysts component and process for the production of polypropylene having high melt flow rate with high isotacticity
US20250109218A1 (en) 2023-09-29 2025-04-03 Formosa Plastics Corporation, U.S.A. Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors
US20250115687A1 (en) 2023-10-06 2025-04-10 Formosa Plastics Corporation, U.S.A. Production method for solid catalyst component for polymerizing olefins, and catalyst for polymerizaing olefins
US20250115686A1 (en) 2023-10-09 2025-04-10 Formosa Plastics Corporation, U.S.A. Olefin polymerization catalyst components containing silane and process for the production of polypropylene having high isotacticity at high melt flow rate
US20250297039A1 (en) 2024-03-19 2025-09-25 Formosa Plastics Corporation, U.S.A. Olefin polymerization catalyst components containing diglycidylester components and its use for the production of polypropylene having high isotacticity at high melt flow rate

Family Cites Families (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB630951A (en) 1947-08-26 1949-10-24 Dow Corning Improvements in or relating to the manufacture of organo silicon esters
US5066737A (en) 1990-10-22 1991-11-19 Shell Oil Company Olefin polymerization catalyst
US5151399A (en) 1990-10-18 1992-09-29 Shell Oil Company Olefin polymerization catalyst
US5082907A (en) 1990-10-18 1992-01-21 Shell Oil Company Olefin polymerization catalyst
US5106806A (en) 1990-10-18 1992-04-21 Shell Oil Company Olefin polymerization catalyst
US5077357A (en) 1990-10-22 1991-12-31 Shell Oil Company Olefin polymerization catalyst
NL160286C (enExample) 1971-06-25
IT1209255B (it) 1980-08-13 1989-07-16 Montedison Spa Catalizzatori per la polimerizzazione di olefine.
JPS5883006A (ja) * 1981-11-13 1983-05-18 Mitsui Petrochem Ind Ltd オレフインの重合方法
IT1190683B (it) * 1982-02-12 1988-02-24 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
IT1190681B (it) * 1982-02-12 1988-02-24 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
US4442276A (en) 1982-02-12 1984-04-10 Mitsui Petrochemical Industries, Ltd. Process for polymerizing or copolymerizing olefins
JPS5991107A (ja) 1982-11-17 1984-05-25 Toho Titanium Co Ltd オレフイン類重合用触媒成分の製造方法
US4458027A (en) * 1983-03-18 1984-07-03 E. I. Du Pont De Nemours And Company Olefin polymerization catalysts
JPS6023404A (ja) 1983-07-20 1985-02-06 Toho Titanium Co Ltd オレフィン類重合用触媒成分
US4540679A (en) 1984-03-23 1985-09-10 Amoco Corporation Magnesium hydrocarbyl carbonate supports
JPH06104693B2 (ja) 1986-01-06 1994-12-21 東邦チタニウム株式会社 オレフイン類重合用触媒
EP0268685B2 (en) 1986-05-06 1996-08-07 Toho Titanium Co. Ltd. Catalyst for polymerizing olefins
CA1310955C (en) 1987-03-13 1992-12-01 Mamoru Kioka Process for polymerization of olefins and polymerization catalyst
US4927797A (en) 1987-04-09 1990-05-22 Fina Technology, Inc. Catalyst system for the polymerization of olefins
US5066738A (en) 1987-04-09 1991-11-19 Fina Technology, Inc. Polymerization of olefins with an improved catalyst system using a new electron donor
JP2536531B2 (ja) * 1987-06-19 1996-09-18 東ソー株式会社 立体規則性ポリオレフィンの製造方法
ES2052004T5 (es) 1988-06-17 2002-05-16 Mitsui Chemicals Inc Procedimiento de preparacion de poliolefinas y catalizador de polimerizacion.
US5247031A (en) 1988-09-13 1993-09-21 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, process for production thereof, olefin polymerization catalyst, and process for polymerizing olefins
IT1227258B (it) 1988-09-30 1991-03-28 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
US5247032A (en) 1989-12-29 1993-09-21 Mitsui Petrochemical Industries, Ltd. Solid catalyst components for olefin polymerization and processes for the polymerization of olefin using same
JP2940684B2 (ja) 1989-12-29 1999-08-25 三井化学株式会社 オレフィン重合用固体状触媒成分およびこの触媒成分を用いたオレフィンの重合方法
IT1241062B (it) 1990-01-10 1993-12-29 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
US5034361A (en) 1990-05-24 1991-07-23 Shell Oil Company Catalyst precursor production
US5146028A (en) 1990-10-18 1992-09-08 Shell Oil Company Olefin polymerization catalyst and process of polymerization
US5229342A (en) 1990-10-18 1993-07-20 Shell Oil Company Olefin polymerization catalyst
US5432244A (en) 1990-12-12 1995-07-11 Union Carbide Chemicals & Plastics Technology Corporation Process for the production of polypropylene
FI88047C (fi) * 1991-05-09 1993-03-25 Neste Oy Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner
GB9300318D0 (en) 1993-01-08 1993-03-03 Oxford Analytical Instr Ltd Improvements relating to sample monitoring
ID24448A (id) * 1997-09-05 2000-07-20 Bp Chemical Ltd Katalis-katalis polimerisasi
AU6342099A (en) 1998-11-04 2000-05-22 Montell Technology Company B.V. Components and catalysts for the polymerization of olefins
WO2000063261A1 (en) 1999-04-15 2000-10-26 Basell Technology Company B.V. Components and catalysts for the polymerization of olefins
CA2369170A1 (en) * 1999-06-30 2001-01-04 Robert Charles Job Magnesium/titanium alkoxide complexes and polymerization catalysts made therefrom
US6391985B1 (en) 1999-10-21 2002-05-21 Union Carbide Chemicals & Plastics Technology Corporation High condensing mode polyolefin production under turbulent conditions in a fluidized bed
US6657025B2 (en) 2001-01-12 2003-12-02 Fina Technology, Inc. Production of ultra high melt flow polypropylene resins
US6825146B2 (en) * 2001-05-29 2004-11-30 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization catalyst compositions and method of preparation
JP2004527636A (ja) * 2001-05-29 2004-09-09 ユニオン・カーバイド・ケミカルズ・アンド・プラスチックス・テクノロジー・コーポレーション オレフィン重合触媒組成物及びその製造方法
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
CN1169845C (zh) * 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
CN100441561C (zh) 2002-02-07 2008-12-10 中国石油化工股份有限公司 用于制备烯烃聚合催化剂的多酯化合物
CN1297534C (zh) 2003-08-06 2007-01-31 中国石油化工股份有限公司 用于制备烯烃聚合催化剂的二醇酯化合物
RU2345094C2 (ru) * 2003-09-23 2009-01-27 Дау Глобал Текнолоджиз Инк. Композиция катализатора с самоограничением реакции, включающая внутренний донор в виде сложного эфира дикарбоновой кислоты, и способ полимеризации пропилена
WO2005103094A1 (en) * 2004-04-07 2005-11-03 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization procatalyst compositions and method of preparation
CN1282670C (zh) * 2004-04-30 2006-11-01 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂
US7351778B2 (en) * 2004-04-30 2008-04-01 China Petroleum & Chemical Corporation Catalyst component for olefin polymerization and catalyst comprising the same
WO2009080497A2 (en) * 2007-12-20 2009-07-02 Basell Poliolefine Italia S.R.L. Highly stereoregular polypropylene with improved properties
RU2497834C2 (ru) * 2008-11-25 2013-11-10 Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Ллс Композиция прокатализатора с многокомпонентным внутренним донором, содержащим сложный эфир, и способ
US8088872B2 (en) * 2008-11-25 2012-01-03 Dow Global Technologies Llc Procatalyst composition including silyl ester internal donor and method

Also Published As

Publication number Publication date
CN102282181A (zh) 2011-12-14
KR101589780B1 (ko) 2016-01-28
US8088872B2 (en) 2012-01-03
KR20110094087A (ko) 2011-08-19
MX2011005542A (es) 2011-06-21
WO2010065361A1 (en) 2010-06-10
RU2505548C2 (ru) 2014-01-27
US20100130709A1 (en) 2010-05-27
JP2012509890A (ja) 2012-04-26
CN104059095A (zh) 2014-09-24
EP2350144A1 (en) 2011-08-03
BRPI0916095A8 (pt) 2017-09-19
SG171799A1 (en) 2011-07-28
BRPI0916095A2 (pt) 2015-11-17
EP2350144B1 (en) 2015-07-15
JP2015155558A (ja) 2015-08-27
CN102282181B (zh) 2014-06-25
RU2011126139A (ru) 2013-01-10
JP6081700B2 (ja) 2017-02-15

Similar Documents

Publication Publication Date Title
BRPI0916095B1 (pt) Composição de procatalisador, composição catalítica e processo para produzir um polímero a base de olefinas
JP6130436B2 (ja) オレフィン重合用触媒組成物
US11254756B2 (en) Process for production of high melt flow propylene-based polymer and product from same
KR101745738B1 (ko) 아다만탄 함유 전촉매 조성물 및 방법
BR112012013285B1 (pt) Componente catalisador sólido insolúvel em hidrocarboneto, método para polimerizar uma olefina e composto
US20100267911A1 (en) Procatalyst Composition with Silyl Glutarate and Method
BR112012013286B1 (pt) Componente catalisador sólido insolúvel em hidrocarboneto e método para polimerizar uma olefina
KR20110110279A (ko) 치환된 1,2-페닐렌 방향족 디에스테르 내부 공여체를 갖는 전촉매 조성물 및 방법
BRPI0819539B1 (pt) composição de catalisador
KR20130132551A (ko) 알콕시알킬 에스테르 내부 전자 공여체를 가진 촉매 조성물 및 이로부터의 중합체
WO2010078330A2 (en) Catalyst composition with phosphorus-based donor and method
KR20140004136A (ko) 알콕시알킬 2-프로페노에이트 내부 전자 공여체를 가진 전촉매 조성물 및 이로부터의 중합체
JP6012623B2 (ja) アルコキシプロピルエステル内部電子供与体を有するプロ触媒組成物およびそれに由来するポリマー
BRPI0918698B1 (pt) Composição de procatalisador e processo para produzir um polímero baseado em olefina
BRPI0815246B1 (pt) Composição de catalisador

Legal Events

Date Code Title Description
B25C Requirement related to requested transfer of rights

Owner name: DOW GLOBAL TECHNOLOGIES LLC (US)

B25A Requested transfer of rights approved

Owner name: W. R. GRACE AND CO. -CONN. (US)

B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06T Formal requirements before examination [chapter 6.20 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 23/11/2009, OBSERVADAS AS CONDICOES LEGAIS. (CO) 20 (VINTE) ANOS CONTADOS A PARTIR DE 23/11/2009, OBSERVADAS AS CONDICOES LEGAIS

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 16A ANUIDADE.