CN102264776B - 使用原位制备的氟化离聚物的分散颗粒通过含水聚合制备氟化离聚物 - Google Patents

使用原位制备的氟化离聚物的分散颗粒通过含水聚合制备氟化离聚物 Download PDF

Info

Publication number
CN102264776B
CN102264776B CN200980152389.9A CN200980152389A CN102264776B CN 102264776 B CN102264776 B CN 102264776B CN 200980152389 A CN200980152389 A CN 200980152389A CN 102264776 B CN102264776 B CN 102264776B
Authority
CN
China
Prior art keywords
fluorinated
fluorinated ionomer
polymerization
particles
ionomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN200980152389.9A
Other languages
English (en)
Chinese (zh)
Other versions
CN102264776A (zh
Inventor
R·M·阿滕
K·W·莱夫尤
R·B·劳埃德
C·J·内尔克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CN102264776A publication Critical patent/CN102264776A/zh
Application granted granted Critical
Publication of CN102264776B publication Critical patent/CN102264776B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
CN200980152389.9A 2008-12-23 2009-12-23 使用原位制备的氟化离聚物的分散颗粒通过含水聚合制备氟化离聚物 Expired - Fee Related CN102264776B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14012208P 2008-12-23 2008-12-23
US61/140,122 2008-12-23
PCT/US2009/069377 WO2010075497A1 (en) 2008-12-23 2009-12-23 Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer produced in situ

Publications (2)

Publication Number Publication Date
CN102264776A CN102264776A (zh) 2011-11-30
CN102264776B true CN102264776B (zh) 2014-04-30

Family

ID=41611328

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200980152389.9A Expired - Fee Related CN102264776B (zh) 2008-12-23 2009-12-23 使用原位制备的氟化离聚物的分散颗粒通过含水聚合制备氟化离聚物

Country Status (5)

Country Link
US (1) US8436054B2 (enExample)
EP (1) EP2367860B1 (enExample)
JP (1) JP5758810B2 (enExample)
CN (1) CN102264776B (enExample)
WO (1) WO2010075497A1 (enExample)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104812781B (zh) * 2012-11-30 2018-10-16 大金工业株式会社 聚四氟乙烯水性分散液的制造方法
CN111040058B (zh) 2012-11-30 2022-10-25 大金工业株式会社 聚四氟乙烯水性分散液的制造方法
US9527980B2 (en) 2012-11-30 2016-12-27 Daikin Industries, Ltd. Polytetrafluoroethylene aqueous dispersion, and polytetrafluoroethylene fine powder
JP6225683B2 (ja) * 2013-05-17 2017-11-08 ダイキン工業株式会社 フルオロポリマー水性分散液の製造方法
WO2016175502A1 (ko) * 2015-04-28 2016-11-03 단국대학교 천안캠퍼스 산학협력단 과불소계 이오노머 나노입자 분산액 및 이의 제조방법
WO2019168183A1 (ja) 2018-03-01 2019-09-06 ダイキン工業株式会社 フルオロポリマーの製造方法
WO2019181435A1 (ja) 2018-03-22 2019-09-26 富士フイルム株式会社 ろ過装置、精製装置、薬液の製造方法
JP7174272B2 (ja) 2018-11-19 2022-11-17 ダイキン工業株式会社 変性ポリテトラフルオロエチレンの製造方法及び組成物
US12195617B2 (en) 2018-11-19 2025-01-14 Daikin Industries, Ltd. Composition and stretched body
JP7417129B2 (ja) 2019-04-26 2024-01-18 ダイキン工業株式会社 水の処理方法および組成物
EP3960773B1 (en) 2019-04-26 2025-07-16 Daikin Industries, Ltd. Method for producing aqueous fluoropolymer dispersion, drainage treatment method, and aqueous fluoropolymer dispersion
CN114364710B (zh) 2019-09-05 2024-02-09 大金工业株式会社 全氟弹性体的制造方法和组合物
CN114269840A (zh) 2019-09-05 2022-04-01 大金工业株式会社 组合物及其制造方法
JP7352110B2 (ja) 2019-11-19 2023-09-28 ダイキン工業株式会社 フルオロポリマーの製造方法、ポリテトラフルオロエチレンの製造方法、パーフルオロエラストマーの製造方法および組成物
JP7606110B2 (ja) 2020-11-19 2024-12-25 ダイキン工業株式会社 ポリテトラフルオロエチレンの製造方法およびポリテトラフルオロエチレンを含有する組成物
WO2022107890A1 (ja) 2020-11-19 2022-05-27 ダイキン工業株式会社 パーフルオロエラストマー水性分散液の製造方法、組成物、架橋性組成物および架橋物
EP4249517A4 (en) 2020-11-19 2024-10-16 Daikin Industries, Ltd. PROCESS FOR PRODUCING AN AQUEOUS DISPERSION OF FLUORINE-CONTAINING ELASTOMER, AND COMPOSITION
KR20230150868A (ko) 2021-03-10 2023-10-31 다이킨 고교 가부시키가이샤 도료 조성물, 도포막, 적층체 및 도장 물품
WO2022244784A1 (ja) 2021-05-19 2022-11-24 ダイキン工業株式会社 フルオロポリマーの製造方法、ポリテトラフルオロエチレンの製造方法および組成物
JP7741413B2 (ja) 2021-06-11 2025-09-18 ダイキン工業株式会社 含フッ素エラストマー水性分散液の製造方法、組成物および水性分散液
JP7747987B2 (ja) 2021-06-30 2025-10-02 ダイキン工業株式会社 フルオロポリマー組成物の製造方法およびフルオロポリマー組成物
CN117500847A (zh) 2021-06-30 2024-02-02 大金工业株式会社 含有高纯度含氟聚合物的组合物的制造方法和含有高纯度含氟聚合物的组合物
WO2023182229A1 (ja) 2022-03-23 2023-09-28 ダイキン工業株式会社 フルオロポリマーの製造方法および組成物
EP4516820A4 (en) 2022-04-28 2026-04-22 Daikin Ind Ltd PROCESS FOR PRODUCING A COMPOSITION CONTAINING A FLUORIDE RESIN, AND COMPOSITION CONTAINING A FLUORIDE RESIN
EP4516819A4 (en) 2022-04-28 2026-05-06 Daikin Ind Ltd FLUORIDE POLYMER MANUFACTURING PROCESS
EP4516855A4 (en) 2022-04-28 2026-06-03 Daikin Ind Ltd COMPOSITION INCLUDES FLUORIDE RUBBER
JP7653042B2 (ja) 2023-01-18 2025-03-28 ダイキン工業株式会社 テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池
JP7492186B1 (ja) 2023-01-18 2024-05-29 ダイキン工業株式会社 電気化学デバイス用合剤、電気化学デバイス用合剤シート、電極、及び、電気化学デバイス
CN121712810A (zh) 2023-08-14 2026-03-20 大金工业株式会社 含氟聚合物水性分散液的制造方法和含氟聚合物水性分散液
JP7689278B2 (ja) 2023-08-28 2025-06-06 ダイキン工業株式会社 水溶性含フッ素ポリマーの回収方法
WO2025126950A1 (ja) 2023-12-12 2025-06-19 ダイキン工業株式会社 フルオロポリマー水性分散液
JP2025093905A (ja) 2023-12-12 2025-06-24 ダイキン工業株式会社 テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池
CN122349673A (zh) 2023-12-12 2026-07-07 大金工业株式会社 四氟乙烯系聚合物组合物、电化学器件用粘结剂、电极合剂、电极和二次电池
WO2025127124A1 (ja) 2023-12-12 2025-06-19 ダイキン工業株式会社 テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池
WO2025127120A1 (ja) 2023-12-12 2025-06-19 ダイキン工業株式会社 テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池

Family Cites Families (71)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2559752A (en) 1951-03-06 1951-07-10 Du Pont Aqueous colloidal dispersions of polymers
US2713593A (en) 1953-12-21 1955-07-19 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US3037953A (en) 1961-04-26 1962-06-05 Du Pont Concentration of aqueous colloidal dispersions of polytetrafluoroethylene
US3271341A (en) 1961-08-07 1966-09-06 Du Pont Aqueous colloidal dispersions of polymer
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3291843A (en) 1963-10-08 1966-12-13 Du Pont Fluorinated vinyl ethers and their preparation
US3391099A (en) 1966-04-25 1968-07-02 Du Pont Polymerization process
GB1292268A (en) 1970-02-16 1972-10-11 Bitterfeld Chemie Process for the dimerisation of hexafluoropropene epoxide
US3704272A (en) 1970-09-15 1972-11-28 Du Pont Concentration of polytetrafluoroethylene aqueous dispersion
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
JPS5816622U (ja) 1981-07-23 1983-02-01 株式会社リコー カメラシステムにおける信号伝達装置
US4380618A (en) 1981-08-21 1983-04-19 E. I. Du Pont De Nemours And Company Batch polymerization process
US4552631A (en) 1983-03-10 1985-11-12 E. I. Du Pont De Nemours And Company Reinforced membrane, electrochemical cell and electrolysis process
EP0148482B1 (en) 1983-12-26 1992-03-25 Daikin Industries, Limited Process for preparing halogen-containing polyether
US4621116A (en) 1984-12-07 1986-11-04 E. I. Du Pont De Nemours And Company Process for copolymerization of tetrafluoroethylene in the presence of a dispersing agent comprising a perfluoroalkoxybenzene sulfonic acid or salt
US4743658A (en) 1985-10-21 1988-05-10 E. I. Du Pont De Nemours And Company Stable tetrafluoroethylene copolymers
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US4952630A (en) 1987-12-31 1990-08-28 E. I. Du Pont De Nemours And Company Modified polytetrafluoroethylene resins and blends thereof
JP3172983B2 (ja) 1993-09-20 2001-06-04 ダイキン工業株式会社 ビニリデンフルオライド系重合体の水性分散液およびその製法
US5422411A (en) 1993-09-21 1995-06-06 Ballard Power Systems Inc. Trifluorostyrene and substituted trifluorostyrene copolymeric compositions and ion-exchange membranes formed therefrom
US5637748A (en) 1995-03-01 1997-06-10 E. I. Du Pont De Nemours And Company Process for synthesizing fluorinated nitrile compounds
JP3346090B2 (ja) 1995-03-31 2002-11-18 ダイキン工業株式会社 ポリテトラフルオロエチレン水性分散液組成物及びその用途
US5688884A (en) 1995-08-31 1997-11-18 E. I. Du Pont De Nemours And Company Polymerization process
US5789508A (en) 1995-08-31 1998-08-04 E. I. Du Pont De Nemours And Company Polymerization process
US5763552A (en) 1996-07-26 1998-06-09 E. I. Du Pont De Nemours And Company Hydrogen-containing flourosurfacant and its use in polymerization
US5969067A (en) 1996-09-13 1999-10-19 E.I. Dupont De Nemours And Company Phosphorus-containing fluoromonomers and polymers thereof
US5866711A (en) 1996-09-13 1999-02-02 E. I. Du Pont De Nemours And Company Fluorocyanate and fluorocarbamate monomers and polymers thereof
WO1998016581A1 (en) 1996-10-15 1998-04-23 E.I. Du Pont De Nemours And Company Compositions containing particles of highly fluorinated ion exchange polymer
WO1998043952A1 (en) 1997-03-31 1998-10-08 Daikin Industries, Ltd. Process for producing perfluorovinyl ethersulfonic acid derivatives and copolymer of the same
JP4150867B2 (ja) * 1998-05-13 2008-09-17 ダイキン工業株式会社 燃料電池に使用するのに適した固体高分子電解質用材料
US6395848B1 (en) 1999-05-20 2002-05-28 E. I. Du Pont De Nemours And Company Polymerization of fluoromonomers
US6482979B1 (en) 1999-12-22 2002-11-19 Dyneon Llc Perfluorinated acid fluorides and preparation thereof
JP4759782B2 (ja) * 2000-02-16 2011-08-31 ダイキン工業株式会社 フッ素系アイオノマーの精製・濃縮方法
DE60119307T2 (de) 2000-02-16 2007-04-12 Daikin Industries, Ltd. Verfahren zur herstellung eines fluorionomers, verfahren zur reinigung und konzentrierung von ionomeren und verfahren zur filmbildung
JP4779184B2 (ja) * 2000-02-16 2011-09-28 ダイキン工業株式会社 フッ素系アイオノマー共重合体の製造法
US6737489B2 (en) 2001-05-21 2004-05-18 3M Innovative Properties Company Polymers containing perfluorovinyl ethers and applications for such polymers
US7045571B2 (en) 2001-05-21 2006-05-16 3M Innovative Properties Company Emulsion polymerization of fluorinated monomers
US7094851B2 (en) * 2001-12-06 2006-08-22 Gore Enterprise Holdings, Inc. Low equivalent weight ionomer
MXPA04006460A (es) 2002-01-04 2004-10-04 Du Pont Dispersiones de fluoropolimeros concentradas.
US6822059B2 (en) 2002-04-05 2004-11-23 3M Innovative Properties Company Dispersions containing bicomponent fluoropolymer particles and use thereof
US6833418B2 (en) 2002-04-05 2004-12-21 3M Innovative Properties Company Dispersions containing perfluorovinyl ether homopolymers and use thereof
US6902839B2 (en) 2002-05-31 2005-06-07 Korea Advanced Institute Of Science And Technology Polymer electrolyte membrane for fuel cell and method for producing the same
JP4096764B2 (ja) 2002-06-17 2008-06-04 ダイキン工業株式会社 含フッ素結晶性ポリマー分散体製造方法
DE10228103A1 (de) 2002-06-24 2004-01-15 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
US6841616B2 (en) 2003-03-28 2005-01-11 Arkema Inc. Polymerization of halogen-containing monomers using siloxane surfactant
JP2004359870A (ja) 2003-06-05 2004-12-24 Daikin Ind Ltd 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
JP2004358397A (ja) 2003-06-05 2004-12-24 Daikin Ind Ltd 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
WO2005003075A1 (ja) 2003-07-02 2005-01-13 Daikin Industries, Ltd. フルオロアルキルカルボン酸誘導体、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
EP1661198A2 (en) 2003-08-19 2006-05-31 E.I. Dupont De Nemours And Company Membranes of fluorinated ionomer blended with nonionomeric fluoropolymers for electrochemical cells
US20050090613A1 (en) 2003-10-22 2005-04-28 Daikin Industries, Ltd. Process for preparing fluorine-containing polymer latex
US7071271B2 (en) 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
EP1533325B1 (en) 2003-11-17 2011-10-19 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant
JP2005320501A (ja) 2004-04-07 2005-11-17 Daikin Ind Ltd 含フッ素エラストマー重合体の製造方法
EP1769092A4 (en) 2004-06-29 2008-08-06 Europ Nickel Plc IMPROVED LIXIVIATION OF BASE METALS
US20060014887A1 (en) 2004-07-19 2006-01-19 3M Innovative Properties Company Method of hydrolyzing a dispersion of ionic fluoropolymer
GB0511779D0 (en) * 2005-06-10 2005-07-20 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers in the presence of a partially fluorinated oligomer as an emulsifier
ATE498358T1 (de) 2005-06-29 2011-03-15 Compumedics Ltd Sensoranordnung mit leitfähiger brücke
US20070015937A1 (en) 2005-07-15 2007-01-18 3M Innovative Properties Company Process for recovery of fluorinated carboxylic acid surfactants from exhaust gas
GB0514398D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
GB0514387D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
WO2007046345A1 (ja) 2005-10-17 2007-04-26 Asahi Glass Company, Limited ポリテトラフルオロエチレン水性乳化液、それから得られるポリテトラフルオロエチレンファインパウダーおよび多孔体
EP1939223B1 (en) 2005-10-20 2011-07-13 Asahi Glass Company, Limited Method for producing melt-moldable fluororesin
JP5141256B2 (ja) 2005-10-20 2013-02-13 旭硝子株式会社 ポリテトラフルオロエチレン水性分散液およびその製品
JP5343355B2 (ja) 2005-10-26 2013-11-13 旭硝子株式会社 含フッ素乳化剤の残留量が少ないフッ素樹脂およびその製造方法
TW200801513A (en) 2006-06-29 2008-01-01 Fermiscan Australia Pty Ltd Improved process
WO2008001894A1 (fr) * 2006-06-30 2008-01-03 Daikin Industries, Ltd. Procédé de production de polymère contenant du fluor
ATE512165T1 (de) 2006-11-09 2011-06-15 Du Pont Wässrige polymerisation von fluorierten monomeren unter verwendung eines polymerisationsmittels, das fluorpolyethersäure oder -salz und kohlenwasserstofftensid umfasst
JP5588679B2 (ja) 2006-11-09 2014-09-10 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フルオロポリエーテル酸または塩および短鎖フッ素系界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合
US7989566B2 (en) 2008-01-22 2011-08-02 Dupont Performance Elastomers Llc Process for producing fluoropolymers
US8153738B2 (en) 2008-12-23 2012-04-10 E I Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
JP2012513533A (ja) 2008-12-23 2012-06-14 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フッ素化イオノマーの分散した微粒子を使用する水性重合によって製造されるフッ素化イオノマー

Also Published As

Publication number Publication date
EP2367860A1 (en) 2011-09-28
EP2367860B1 (en) 2016-04-27
JP2012513535A (ja) 2012-06-14
US20100160465A1 (en) 2010-06-24
JP5758810B2 (ja) 2015-08-05
US8436054B2 (en) 2013-05-07
CN102264776A (zh) 2011-11-30
WO2010075497A1 (en) 2010-07-01

Similar Documents

Publication Publication Date Title
US8436054B2 (en) Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer produced in situ
CN102264775B (zh) 使用原位制备的氟化离聚物的分散颗粒通过含水聚合制备含氟聚合物
EP3091039B1 (en) Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
US8835547B2 (en) Fluoropolymer particles having a nucleus of fluorinated ionomer
CN102027023B (zh) 使用氟聚醚酸或盐的混合物的氟化单体含水聚合反应
US20120077931A1 (en) Aqueous polymerization of fluorinated monomer using polymerization agent comprising fluoropolyether acid or salt and short chain fluorosurfactant
CN102264774A (zh) 使用氟化离聚物的分散颗粒通过含水聚合制备的氟化离聚物
CN111247176B (zh) 合成氟聚合物的方法
US8436053B2 (en) Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140430

Termination date: 20161223

CF01 Termination of patent right due to non-payment of annual fee