Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
  • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
  • C08F214/18—Monomers containing fluorine
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
  • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
  • C08F14/18—Monomers containing fluorine

Definitions

• This invention relates to a process for the dispersion polymerization of fluorinated monomer in an aqueous polymerization medium and fiuoropolymer particles and aqueous dispersions made thereby,
• Fluorinated ionomers are used commercially in the manufacture of ion exchange membranes for electrochemical applications.
• One industrial application is the chloralkali process for the electrolysis of sodium chloride to produce sodium hydroxide and chlorine.
• Polymer electrolyte membrane (PEM) fuel cells typically employ fluorinated ionom ⁇ r membranes. Fluorinated ionomer is also useful as a solid acid catalyst for various chemical processes.
• Patent 7,071 ,271 teaches a process which employs the step of making a pre-emulsion of the SO;F-comonomer using a microfluidizer prior to the start of the polymerization process.
• the pre-emulsion is not stable over time, i.e., has a "pot life" of at least 1 hour.
• the copolymerization of tetrafluoroethylene with a fluorinated vinyl ether monomer with a sulfonyl fluoride group does not produce an ionomer directly and instead produce a fiuorinated ionomer precursor.
• the sulfonyl fluoride precursor is useful for fabrication of articles such as membranes by melt processing, the fiuorinated ionomer precursor must be subjected to a subsequent process step to hydrolyze the s ⁇ lfonyl fluoride groups of the polymer sulfonate groups to form the ionomer.
• ionomer is desired is sulfonic acid form, the ionomer must be further treated to convert it to acid form.
• a process is desired for the manufacture of fiuorinated ionomer which directly produces fiuorinated ionomer, especially as a dispersion of fiuorinated ionomer particles in an aqueous medium.
• the invention is based on the discovery that a process for making an aqueous dispersion of fiuorinated ionomer particles is effectively carried out by polymerizing in a first polymerization step at least one fiuorinated monomer having an ionic group in an aqueous polymerization medium in the presence of initiator, the polymerizing providing dispersed paniculate of fiuorinated ionomer, polymerizing in a second polymerization step at least one fiuorinated monomer having an ionic group in the aqueous polymerization medium in the presence of the dispersed particulate of fiuorinated ionomer and initiator to form the aqueous dispersion of particles of fiuorinated ionomer, and suspending the first polymerization step prior to beginning the second polymerization step.
• the amount of dispersed particulate of fiuorinated ionomer present in the aqueous polymerization medium in the second polymerization step comprises less than about 15 wt% of the fluoropolymer solids produced in the aqueous dispersion.
• the dispersed particulate of fiuorinated ionomer has a weight average particle size of about 2 nm to about 100 nm.
• the fiuorinated ionomer preferably has an ion exchange ratio of about 3 to about 53.
• the fiuorinated ionomer is highly fiuorinated. more preferably, perfluorinated,
• the process further comprises providing surfactant in the polymerization medium.
• the surfactant comprises fluoros ⁇ rfactant, more preferably, fiuoroether surfactant.
• fluorinated ionomer is polymerized in the first polymerization step process in accordance with the present invention.
• "Fluorinated lonomer” means a fl ⁇ oropoiymer having sufficient ionic groups to provide an ion exchange ratio of no greater than about 53.
• ion exchange ratio or "IXR” is defined as number of carbon atoms in the polymer backbone in relation to the ionic groups.
• Precursor groups such as -SCbF which upon hydrolysis become ionic are not treated as ionic groups for the purposes of determining IXR.
• the fluorinated ionomer employed in the process of the invention preferably has an ion exchange ratio of about 3 to about 53.
• the IXR is about 3 to about 43, even more preferably about 3 to about 33, still more preferably about 8 to about 33, most preferably 8 to about 23.
• the fluorinated ionomer is highly fluorinated. "Highly fluorinated 1* in reference to ionomer means that at least 90% of the total number of univalent atoms bonded to carbon atoms in the polymer are fluorine atoms. Most preferably, the ionomer is perfluorinated.
• the ionic groups are typically distributed along the polymer backbone.
• the fluorinated ionomer comprises a polymer backbone with recurring side chains attached to the backbone with the side chains carrying the ionic groups.
• Preferred fluorinated ionomer comprises ionic groups having a pKa less than about 10, more preferably, less than about 7.
• Ionic groups of the polymer are preferably selected from the group consisting of sulfonate, carboxylate, phosphonate, phosphate, and mixtures thereof,
• the tenms "sulfonate, carboxylate, phosphonate and phosphate" are intended to refer to either the respective salts or respective acids from which salts can be formed,
• the salts are alkali metal or ammonium saits.
• Preferred ionic groups are sulfonate groups.
• Sulfonate groups in preferred fluorinated ionomers used in the process of the invention have a pKa of about 1.9 as measured on the fl ⁇ orinated ionomer in aqueous dispersion form having 10 wt% solids at room temperature.
• the dispersed fl ⁇ orinated ionomer particulate can be polymerized in situ
• various known fluorinated ionomers can be used including polymers and copolymers of trifluoroethyfene, tetrafluoroethylene (TFE), ⁇ , ⁇ , ⁇ -trifluorostyrene, etc., which contain ionic groups.
• Possible polymers include homopolymers or copolymers of two or more monomers. Copolymers are typically formed from one monomer which is a nonfunctional monomer and which provides carbon atoms for the polymer backbone.
• a second monomer provides both carbon atoms for the polymer backbone and also contributes the side chain carrying the ionic group, e.g., a sulfonate functional group.
• copolymers of a first fluorinated vinyl monomer together with a second fluorinated vinyl monomer having a sulfonate functional group can be used.
• Possible first monomers include tetrafluoroethylene (TFE) 1 hexafluoropropylene, vinyl fluoride, vinylidine fluoride, triffuoroethylene, chlorotrifluoroethylene. perfluoro (alKyl vinyl ether), and mixtures thereof.
• Possible second monomers include a variety of fluorinated vinyl ethers with ionic groups which can provide the desired side chain in the polymer.
• the first monomer may also have a side chain. Additional monomers can also be incorporated into these polymers if desired.
• the preferred ionomers include, for example, polymers disclosed in U.S. Patent 3,282,875 and in U.S.
• One preferred ionomer comprises a perfluorocarbon backbone and the side chain is represented by the formula -0-CF 2 CF(CFs)-O-CFsCF 2 SOaX, wherein X is as defined above, ionomers of this type are disclosed in U.S. Patent 3,282.875.
• TFE tetrafl ⁇ oroethylene
• POMOS perffuormated vinyl ether
• POM perf!uoro(3,6-d ⁇ oxa-4 ⁇ methy!-7-octenesulfonate
• One preferred ionomer of the type disclosed in U S Patents 4,358,545 and 4,940,525 has the side chain O CF 2 CF 2 SO 3 X.
• EW equivalent weight
• the equivalent weight is somewhat lower because of the lower molecular weight of the monomer unit containing the ionic group
• the corresponding equivalent weight range is about 575 EW to about 1325 EW.
• the molecular weight of the fluonnated ionomer particulate produced in the first polymerization step can generally be in the same range as the resin which is used in ion exchange polymer membranes used in the chloralkafi process for the electrolytic production of chlorine and sodium hydroxide from sodium chlonde and in fuel cells
• Such fluonnated ionomer resin has a molecular weight which preferably provides solid fluorinated ionomer particulate at room temperature.
• melt flow rate is preferably in the range of 1 to about 500, more preferably about 5 to about 50, most preferably about 10 to about 35 g/10 min.
• the fluorinated ionomer particulate of the dispersion produced in the first polymerization step of the process of the invention preferably has a weight average particle size of about 2 nm to about 100 nm. More preferably, such particulate has a weight average particle size of about 2 to about 50 nm, even more preferably about 2 to about 30, still more preferably about 2 to about 10 nm.
• the weight average particle size in a liquid dispersion of fluorinated ionomer particulate used in accordance with the invention can be measured by a dynamic light scattering (DLS) technique as described below in the Test Methods. Additional detail concerning the first polymerization step to produce in situ dispersed fluorinated ionomer particulate possessing properties desirable for use in accordance with the invention is provided in the description of the process below.
• DLS dynamic light scattering
• the fluorinated ionomer of the fluorinated ionomer particles produced by the process of the invention can be of the same type as described above for the fluorinated ionomer of the fluorinated tonomer particulate with the fluorinated ionomer being produced directly due to the fluorinated monomer being employed with the ionic group in ionic form during polymerization, i.e., as the acid or salt.
• the type of monomers employed, the types ionic groups, whether in the ionic groups are in acid or salt form, IXR, melt flow, dispersion concentration, weight average particle size and other properties are selected based on the desired end use properties and the selected conditions employed in the polymerization process of the invention employed as will be described in more detail hereinafter.
• the aqueous polymerization medium used to form the aqueous dispersion of particles of fluoropolymers may further comprise surfactant
• the surfactant can be selected from a large group of suitable surfactants including hydrocarbon surfactants, siloxane surfactants, and fluorosurfactants Suitable hydrocarbon surfactants have been disclosed in U S Patent 5.925,705 to Araki et al, and JP Patent Publications 2004/358397 and 2004/359870 to Tsuda et al Suitable siioxane surfactants have been descnbed in U S. Patent 6,841 616 to WiMe et ai
• the surfactant is a fluorosurfactant and more preferably is a fluoroether surfactant
• fluorosurfactants that may be a component of the polymerization agent are descnbed in U S. Patent 6,395 848 to Morgan et al as fiuoroalky! having at most one ether oxygen, preferably perfluoroalkyl, carboxylic acids and salts thereof having 6-20 carbon atoms, preferably 6-12 carbon atoms, such as ammonium perfluorooctanoate and ammonium perfluorononanoate (see Berry, U S. Patent 2,559,752).
• Perfluoroalkyl sulfonic acids and salt may also be used in a preferred embodiment of the invention, perfluoroalkyl ethane sulfonic acids and salts thereof are employed, preferably a compound or a mixture of compounds of the formula F- ⁇ CFs-CFc- ⁇ -CHsCHs-SOaM, wherein n is 2-8 and M is a cation having a valence of 1 as described in Khan & Morgan, U S Patent 4,380,618 More preferably, such perfluoroalkyl ethane sulfonic acid surfactant compnses a compound of the formula C 6 F 13 -CH 2 CH 2 -SO 3 M wherein M is a catjon having a valence of 1 as described in Baker & Zipfel, U S Patents 5,688,884 and 5,789,508 Preferably, M in the above formula is NH 4 +
• fluorosurfactants include perfluoroalkoxy benzene sulfonic acids and salts thereof wherein the perfluoroalkyl component of the perfluoroalkoxy has 4-12 carbon atoms, preferably 7-12 carbon atoms (as described in Morgan, U S Patent 4,621 ,1 16) Additional examples of such surfactants also include partiaily- fluonnated surfactants having internal methylene groups and having the formula Rr(CH ; .) n -R'rCOOM wherein m is 1-3, R, is perfluoroalkyi or perfl ⁇ oroalkoxy containing 3-8 carbon atoms, R'» is linear or branched perfluoroalkylene containing 1-4 carbon atoms, and M is NK 1 , Li 1 Na, K 1 or H (as described in Feiring et al., U.S.
• Patent 5,763,552 Examples of suitable fiuoroether surfactants have been described in U.S. Patent 3,271 ,341 to Garrison: U.S. Patent Publications 2007/0015864. 2007/0015865, and 2007/0015866 to Hintzer et al.; U.S. Patent Publications 2005/0090613 to Maruya et al. and 2006/0281946 to Morita et al.: PCT Patent Publications WO 2007046345 to Higuchi et a!., 2007046377 to F ⁇ naki et aL 2007046482 to Hoshikawa et al.. and 2007/049517 to Matsuoka et al.
• the aqueous medium comprises less than about 300 ppm of perfluoroalkane carboxylic acid or salt fiuorosurfactants having 8 or more carbon atoms, based on the weight of water in the aqueous medium.
• Perfluoroalkane acid or salt fiuorosurfactants having 8 or more carbon atoms include such surfactants having for example 8-14 carbon atoms, e.g., perfluorooctanoic acid and salts and perfluorononanoic acid and salts.
• the aqueous medium comprises less than about 100 ppm of perfluoroalkane carboxylic acid or salt fiuorosurfactants having 8 or more carbon atoms, more preferably less than 50 ppm.
• the aqueous medium is substantially free of perfluoroalkane carboxylic acid or salt fiuorosurfactants having 8 or more carbon atoms.
• Substantially free of perfluoroalkane carboxylic acid or salt fiuorosurfactants having 8 or more carbon atoms means that aqueous medium contains no more than about 10 ppm of such fiuorosurfactants.
• the aqueous polymerization medium contains a short chain fluorosurfactant having the formula:
• R 1 is a linear or branched partially or fully fiuorinated aliphatic group which may contain ether linkages; n is O or 1 ;
• L is a linear or branched alkylene group which may be nonfi ⁇ orinated, partially fluorinated or fully fluorinated and which may contain ether linkages;
• A- is an anionic group selected from the group consisting of carboxylate, sulfonate, sulfonamide anion, and phosphonate; and
• Y + is hydrogen, ammonium or alkali metal cation; with the proviso that the chain length of R 1 -O n -L- is not greater than 6 atoms.
• Chain length refers to the number of atoms in the longest linear chain in the hydrophobic tail of the fluorosurfactant employed in the process of this invention.
• Chain length includes atoms such as oxygen atoms in addition to carbon in the chain of the hydrophobic tail of the surfactant but does not include branches off of the longest linear chain or include atoms of the anionic group, e.g. , does not include the carbon in carboxylate.
• Short chain as used in this application refers to a chain length of not greater than 6.
• Long chain refers to a chain length of greater than 6, e.g., fluorosurfactants having a chain length of 7 to 14 atoms.
• the chain length of R 1 -O n -L- is 3 to 6 atoms.
• the chain length of R 1 -O n -L- is 4 to 6 atoms
• the chain length of R 1 O n -L- is 3 to 5 atoms.
• the chain length of R 1 -O n -L- is 4 to 5 atoms
• a preferred class of fluorosurfactants is short chain fluoroether acids or salts, i.e., wherein n is 1 in Formula (I) above.
• Preferred fluoroether acids or salts in accordance with the invention are fluorosurfactants according to Formula (I) wherein:
• R 1 is a linear or branched partially or fully fluorinated alkyl group having 1 to 3 carbon atoms which may contain ether linkages; and L is an alkylene group selected from -CX(R 2 )-, wherein R 2 is fluorine or perfluoromethyl and X is hydrogen or fluorine, and -CZ 1 Z 2 CZ 3 Z 4 -, wherein Z 1 , Z 2 , Z 3 , and Z 4 are independently selected from hydrogen or fluorine. Fluoroether acids and salts of this type are known.
• L is an alkylene group selected from -CX(R 2 )-, wherein R 2 is fluorine or perfluoromethyl and X is hydrogen or fluorine
• the compound can be made, for example, by hydrolysis of perfiuoro-2-alkoxypropiony! fluoride intermediates prepared by reacting aikanoic acid fluorides with hexafluoropropylene oxide as disclosed in U, S. Patent 3.291 ,843 to Fritz and Selman for use in perfluoro(alkyi vinyl ether) manufacture.
• L is -CZ 2 CZ 2 -, wherein Z is independently selected from hydrogen or fluorine
• routes to making such compounds are generally described In U.
• L in Formula (I) is an alkylene group selected from -CF(CF 3 )-, -CF 2 -, -CF 2 CF 2 -, -CHFCF 2 -. and -CF 2 CHF-.
• the fluorosurfactant used in accordance with the invention may be a diether if R1 or L contains ether linkages.
• R1 or L contains ether linkages.
• Such compounds are made, for example, by the teachings in WO 01/461 16 A1 (Hintzer et al.).
• Preferred fluoroether acids or salts are fluoromonoethers where R 1 and L do not contain ether linkages.
• R 1 in Formula (I) is a linear partially or fully fluorinated alky! group having 2 to 3 carbon atoms.
• R 1 is fully fluorinated.
• the fluorosurfactant is highly fluorinated. "Highly fluorinated" in reference to fluorosurfactant means that at least about 50% of the total number of univalent atoms bonded to carbon in the fluorosurfactant are fluorine atoms. More preferably, at least about 75% of the total number of univalent atoms bonded to carbon in the fl ⁇ orosurfactant are fluorine atoms, most preferably at least about 90%. Perfluorinated surfactants are also preferred for use in accordance with the invention.
• the fluorosurfactant is a compound of the formula:
• Y + is hydrogen, ammonium, or alkali metal cation.
• This compound is represented by Formula (I) wherein R 1 is CF 3 CF 2 CF 2 -; L is -CF(CF 3 )-; A ' is carboxylate; and Y + is hydrogen, ammonium or alkali metal cation.
• Y + is hydrogen or ammonium.
• a compound of this formula can be obtained from the perfluoro-2-propoxypropionyl fluoride intermediate prepared according to U.S.
• Y* is hydrogen, ammonium, or alkali metai cation.
• a compound of this formula can be obtained from the perfluoro-2-ethoxypropionyl fluoride intermediate prepared according to U.S. Patent 3,291 ,843 and subsequent hydrolysis of the resulting acid fluoride to carboxylic acid in the case of the acid and, in the case of the salt, by simultaneous or subsequent reaction with the appropriate base to produce the desired salt.
• the fluorosurfactant is a compound of the formula:
• Y + is hydrogen, ammonium, or alkali metai cation.
• the fluoros ⁇ rfactant is a compound of Formula (I) wherein n is O; R 1 and L collectively comprises a perfiuoroalkyi group having 4-6 carbons; and A * is sulfonate and sulfonamide anion.
• a ' is sulfonamide anion, the sulfonamide compound of Formula (VIII) below:
• Y + is hydrogen, ammonium, or alkali metal cation.
• a surfactant of this formula as the ammonium salt is available commercially from 3M under the trademark N0VEC M 4200.
• the fluorosurfactant is a compound of the formula:
• Y + is hydrogen, ammonium, or alkali metal cation.
• the surfactant can be added to the aqueous polymerization medium prior to, simultaneously with and/or subsequently to the addition of the dispersion of fluorinated ionomer particulate.
• the surfactant is supplied in salt form. If the surfactant is supplied as the corresponding acid, conversion to salt can be accomplished by adding ammonium hydroxide or alkali metai hydroxide, preferably ammonium hydroxide, to a solution of the acid in a quantity sufficient to substantially completely convert the acid to salt form prior to adding the surfactant to the aqueous polymerization medium. Alternatively the surfactant supplied in acid form can be added to the aqueous polymerization medium and subsequently converted to salt form.
• initiators capable of generating radicals under the conditions of polymerization.
• initiators for use in accordance with the invention are selected based on the type of fiuoropolymer and the desired properties to be obtained, e.g., end group type, molecular weight, etc.
• Water-soluble salts of inorganic peracids are suitably employed which produce anionic end groups in the polymer.
• Preferred initiators of this type have a relatively long half-life at the temperature of polymerization, preferably persulfate salts, e.g., ammonium persulfate or potassium persulfate.
• reducing agents such as ammonium bisulfite or sodium metabisulfite. with or without metal catalyst salts such as iron, can be used.
• Preferred persulfate initiators are substantially free of metal ions and most preferably are ammonium salts.
• the initiator is added to the aqueous polymerization medium in an amount sufficient to initiate and maintain the polymerization reaction at a desired reaction rate. At least a portion of the initiator is preferably added at the beginning of the polymerization. A variety of modes of addition may be used including continuously throughout the polymerization, or in doses or intervals at predetermined times during the polymerization.
• a particularly preferred mode of operation is for initiator to be precharged to the reactor and additional initiator to be continuously fed into the reactor as the polymerization proceeds.
• total amounts of ammonium persulfate and/or potassium persulfate employed during the course of polymerization are about 25 ppm to about 250 ppm based on the weight of the aqueous medium.
• Other types of initiators for example, potassium permanganate/oxalic acid initiators, can be employed in amounts and in accordance with procedures as known in the art.
• Chain-transfer agents may be used in a process in accordance with the invention to decrease molecular weight for the purposes of controlling melt viscosity. If used, chain-transfer agents are primarily used in the second polymerization step of the process. Chain transfer agents useful for this purpose are well-known for use in the polymerization of fluorinated monomers. Preferred chain transfer agents include hydrogen, aliphatic hydrocarbons, halocarbons, hydrohalocarbons or alcohol having 1 to 20 carbon atoms, more preferably 1 to 8 carbon atoms. Representative preferred examples of such chain transfer agents are alkanes such as ethane, chloroform, 1 ,4-diiodoperfluorobutane and methanol.
• the amount of a chain transfer agent and the mode of addition depend on the activity of the particular chain transfer agent and on the desired molecular weight of the polymer product. A variety of modes of addition may be used including a single addition before the start of polymerization, continuously throughout the polymerization, or in doses or intervals at predetermined times during the polymerization.
• the amount of chain train transfer agent supplied to the polymerization reactor is preferably about 0.005 to about 5 wt%, more preferably from about 0.01 to about 2 wt% based upon the weight of the resulting fluorinated ionomer.
• the first step of the polymerization process can be carried out as a batch process in a pressured reactor of the type known for use in the dispersion polymerization of fluoropolymers.
• Suitable vertical or horizontal reactors for carrying first step of the process of the invention are equipped with stirrers for the aqueous medium to provide sufficient contact of gas phase monomers such as TFE for desirable reaction rates and uniform incorporation of the comonomer with the ionic group.
• the reactor preferably includes a cooling jacket surrounding the reactor so that the reaction temperature may be conveniently controlled by circulation of a controlled temperature heat exchange medium.
• the reactor is first charged with deionized and deaerated water of the polymerization medium and, if used, some or ali of the surfactant to be employed may be added although surfactant may be added for the first polymenzation step surfactant is typically not needed because the ionic character of the fluonnated ionomer particulate stabilizes the particulate as it is formed in the dispersion
• the comonomer having the ionic group e g PDMOS can be precharged and-'or fed into the reactor as the polymerization proceeds
• the reactor is pressurized with TFE and free-radical initiator solution such as ammonium persulfate solution is then added
• the temperature is increased and, once polymerization begins, additional TFE is added to maintain the pressure
• the start of poiymenzation in the first polymerization step is referred to as the first kick-off and is defined as the point at which gaseous monomer feed pressure is observed to drop substantially, for example about 10 psi (about
• the process includes suspending the first polymerization step prior to beginning of the second polymerization step, Suspending the process effectively separate the first and second steps of the process so that fluoropolymer formed in the second step does not incorporate significant quantities of residual monomers from the first.
• suspending the process can be carried out by stopping the TFE and initiator feeds, stopping agitation, and venting the reactor.
• Suspending the process prior to the beginning of the first and second steps also allows the dispersed ionomer particular to be analyzed for particle size, concentration, or other properties which may be needed or useful for control of or operation of the second polymerization step. For example, it may be desirable to adjust the concentration and/or remove some of the dispersed ionomer particulate for the potposes of controlling the number of particles formed in the second polymerization step.
• the suspending of the process includes storing the dispersed particulate of fluorinated ionomer made in the first polymerization step in a separate vessel.
• the first polymerization step it is often preferable for the first polymerization step to produce sufficient dispersed fluorinated ionomer particulate to carry out the second polymerization step multiple times, i.e., a batch of dispersed fluorinated ionomer is made which is sufficiently large that it can be used for multiple fl ⁇ oropolymer polymerizations
• different batch sizes and/or different pressurized reactors can be used which match the volume of dispersions to be produced in the first and second steps.
• the term in situ in connection with polymerization of the fluorinated ionomer means that the dispersed particulate of fluorinated ionomer formed in the first polymerization step is employed in the second polymerization step of the process.
• the same aqueous medium from dispersed particulate from the first polymerization step will form at least part of the aqueous medium employed in the second polymerization step.
• the use of the term in situ is not intended to mean that the first and second polymerization steps are necessarily carried out in the same reactor or to place any time limits on the suspension between the first and second polymerization steps.
• the second polymerization step of the process can be carried out in the same type of reactor as discussed for the first step of the process.
• the aqueous polymerization medium may be partially or entirely provided by the aqueous dispersion of fluorinated ionomer particulate, if not already present and if desired for use in the process, surfactant may be added. Additional deionized and deaerated water may all be added.
• reactor may be charged with a dispersion of fluorinated ionomer particulate from a previously made batch of aqueous dispersion of fiuorinated ionomer particulate and deionized and deaerated water and surfactant added (if used) to provide the desired concentration of fluorinated ionomer particulate in the polymerization medium.
• the reactor is first charged with deionized and deaerated water of the polymerization medium and the fluorinated ionomer particulate is dispersed in the medium. If used, surfactant is suitable precharged and/or fed to the reactor as the reaction proceeds.
• a suitable procedure for a copolymer of TFE and perfluoro(3,6-dioxa- 4-methyl-7-octenesulfonate (PDMOS) monomer includes first pressurizing the reactor with TFE. The comonomer PDMOS is then added, A free-radical initiator solution such as ammonium persulfate solution is then added.
• the temperature is increased and, once polymerization begins, additional TFE is added to maintain the pressure.
• the beginning of polymerization in the second polymerization step is referred to as the second kick-off and is defined as the point at which gaseous monomer feed pressure is observed to drop substantially, for example, about 5-10 psi (about 35-70 kPa).
• Comonomer and/or chain transfer agent can also be added as the polymerization proceeds.
• additional monomers., surfactant and/or initiator may be added during the polymerization.
• Batch dispersion polymerizations can be described as proceeding in two phases.
• the initial period of the reaction can be said to be a nucleation phase during which a given number of particles are established.
• a growth phase occurs in which the predominant action is polymerization of monomer on established particles with little or no formation of new particles.
• the transition from the nucleation to the growth phase of polymerization occurs smoothly, typically between about 4 and about 10 percent solids in the polymerization of TFE.
• the use of fluorinated ionomer produced in the first polymerization step in accordance with the invention generally provides sufficient nucleatfon for the polymerization process and additional nucleating agents are not required.
• the number of dispersed ffuorinated tonomer particles in the particulate introduced into the polymerization medium is preferably selected to control the number of particles formed during the second step of the process.
• the fluorinated ionomer particulate in the aqueous polymerization medium provides a number of dispersed fluorinated ionomer particles within about 15% of the number of fluoropolymer particles produced by polymerizing the fluorinated monomer.
• the number of dispersed fluorinated ionomer particles is within about 10% of the number of fluoropolymer particles produced by polymerizing, more preferably, the number of dispersed fluorinated ionomer particles is within about 5% of the number of fluoropolymer particles produced by polymerizing. Most preferably, the number of dispersed fluorinated ionomer particles is approximately equal to the number of fluoropolymer particles produced by polymerizing.
• the amount of fiuoropoiymer particulate to be employed in a process in accordance with the invention may be determined by estimating the number of fluoropolymer particles to be produced in the process based on particle size and solids content and employing an amount of fluorinated ionomer particulate which provides approximately the same number of particles. If other nucleating agents are also employed in the polymerization, it may be desirable to employ a smaller number of particles of fluorinated ionomer particulate. Typical concentrations of dispersed fluorinated ionomer particulate are about 1 x 10 1 ⁇ particles per liter to about 1 x 10 20 particles per liter.
• the amount of fluorinated ionomer particulate provided in the aqueous polymerization medium comprises less than about 15 weight % of the fluoropolymer solids to be produced in the process, in more preferred embodiments the amount of fluorinated ionomer particulate provided in the aqueous polymerization medium comprises less than about 10 wt%.
• the amount of surfactant employed is dependent upon the desired solids content for the polymerization, the type of surfactant, the type of fluoropolymer being produced, reactor design, etc.
• the amounts employed can be similar to the amounts employed in conventional polymerizations which do not employ fluorinated ionomer particulate. Typical amounts are about 0.01 wt% to about 1 wt% based on the weight of water in the polymerization medium.
• the solids content of the dispersion upon completion of polymerization can be varied depending upon the intended use for the dispersion
• the solids content of fluoropolymer dispersion produced by the process of the invention is preferably at least about 10 wt% More preferably, the fl ⁇ oropoiymer solids content is at least about 20 wt%
• a preferred range for fluoropolymer solids content produced by the process is about 20 wt% to about 65 wt%, even more preferably about 20 wt% to about 55 wt%, most preferably, about 35 wt% to about 55 wt%
• polymerizing produces less than about 13 wt%, more preferably less than about 10 wt% still more preferably less than 3 wt%, even more preferably less than 1 wt% most preferably less that about 0 5 wt% of undispersed fluoropolymer (coagulum) based on the total weight of fluoropolymer produced
• the aqueous dispersion of fluoropolymer particles has a raw dispersion particle size (RPDS) of from about 10 to about 400 nm preferably 100 to 350 nm.
• RPDS raw dispersion particle size
• the aqueous dispersions of fluorinated ionomer particles produced m accordance with the invention typically are stable as produced but can be further stabilized with anionic, cationic, or nonionic surfactant for certain uses
• the fluorinated ionomer can also be isolated from the dispersion by coagulation and removal of the aqueous medium Sulfonate polymers in acid form can be melt-processed for some applications For this use the fluorinated ionomer is dned then processed into a convenient form such as flake, chip or pellet for use in subsequent melt-processing operations
• the process of the invention may also be carried out as a continuous process in a pressurized reactor
• the fluorinated ionomer comprises a polymer backbone with recurring side chains attached to the polymer backbone with the side chains carrying ionic groups.
• Ionic groups are preferably selected from the group consisting of sulfonate, carboxyiate, phosphonate, phosphate and mixtures thereof.
• the fluorinated ionomer of the particulate comprises ionic groups having a pKa less than about 10. Sulfonate groups are most preferred.
• fluorinated ionomer produced by the process has a melt flow in thermoplastic form at 27O°C using a 5 kg weight of about 1 to about 500.
• the fluorinated ionomer particles made using the process of the invention can be employed generally in the same manner as fluorinated ionomer made conventionally except that hydrolysis is not required to convert the as-polymerized polymer to ionomer.
• Aqueous dispersions of the fiuorinated ionomer particles can be used for to produce coatings on a variety of substrates and cast to make films useful as ion exchange membranes useful in electrochemical processes and devices, for example, as membranes in the chloralkaii process and in fuel cells. Melt processable fl ⁇ orinated ionomer coagulated from the dispersion can be melt extruded into films for similar uses in the chloralkaii process and in fuel cells.
• the aqueous dispersions of fluorinated ionomer particles, as well as coating and articles produced, are also useful for acid catalyst applications. Test Methods
• Melt Fiow Rate (MFR) of the Fluorinated lonomer is measured on the polymer in thermoplastic form, e.g., the sulfonyl fluoride or sulfonic acid form for sulfonate ionomers, according to the method of ASTM D- 1238-04C at 27O°C with a 21 10 gram weight.
• the diluted dispersion was filtered through a 1.0 urn graded density glass micro fiber syringe filter (Whatman PURADISC® #6783- 2510) into a disposable polystyrene cuvette.
• Dynamic light scattering (DLS) was measured at 25 * C using a Malvern Instruments Nano S, which measures scattered light from a HeNe laser at 633 nm at a scattered angle of 173° (close to backscattered).
• the automated instrument chooses how many 10 s runs make up each measurement (generally 12 to 16), and for each sample ten measurements were performed, the entire process taking usually ⁇ 30 min.
• z-average particle diameter calculated from the z-average diffusion coefficient made by a cumuiants fit to the autocorrelation function.
• the name z-average has been used in analogy to the z-average molecular weight Mz , in that the DLS z-average particle size is derived from a distribution of diffusion coefficients weighted by the square of the particle mass Mj 5 .
• Half of the scattered light Intensity is produced by particles with diameters larger than D(i)50.
• the software uses a Mie calculation to convert the intensity distribution to a weight distribution.
• the weight average diameter is that diameter at which half of the mass of the particies in the sampie have a larger diameter and half have a smaller diameter.
• Dry coaguiurn amount is measured by physically collecting the wet polymer that coagulates during the course of the polymerization and then drying this coagulum overnight at 80"C and a vacuum of 30 mm Hg (4 kPa). The dried coaguium is weighed and the Weight Percentage of Undispersed Polymer (Coaq. wt%) is determined based on the total weight of fluoropolymer in the dispersion.
• Transition Temperatures of Fluorooolvmers by Differential Scanning Calorimetry is measured according to ASTM D 3418-03.
• Comonomer Content is measured by FTIR according to the method disclosed in U.S. Patent No. 4,743,658, col. 5, fines 9-23.
• Fluorinated lonomer Particle Size i.e., raw dispersion particle size (RDPS) of the fluorinated ionomer produced in the process is determined by laser diffraction techniques that measure the particle size distributions (PSD) of materials using a Microtrac Uitrafine Particle Analyzer (UPA).
• the UPA uses dynamic light scattering principle for measuring PSD with size range of 0.003 micron to 6.54 micron. The samples were analyzed after collecting the background with water. The measurements were repeated three times and averaged.
• Perfluoroalkane Carboxylic Acid Or Salt Fiuorosurfactant Content is measured by a GC technique in which the fiuorosurfactant is esterified with acidic methanol. Perfluoroheptanoic acid is used as an internal standard. Upon addition of electrolyte and hexane the ester is extracted into the upper hexane layer. The hexane iayer is analyzed by injection onto a glass GC column of 20 ft. x 2mm LD. packed with 10% OV-210 on 70/80 mech Chromos ⁇ rb W.AW.DMCS. held at 120 C. The detector is ECD and the carrier gas of 95% argon/5% methane has a flow rate of 20 to 30 ml/min.
• the surfactant C 3 F 7 OCF(CF 3 )COONH 4 (HFPO dimer acid salt, DAS), 20 Wt % , is prepared by dropwise addition of 128 g of concentrated ammonium hydroxide solution to 500 g of C 3 F 7 OCF(CF 3 )COOH and subsequent dilution with deionized water to 20 wt%.
• This example demonstrates the polymerization of fiuorinated ionomer (sulfonic acid form) in the presence of dispersed fluorinated ionomer particulate (sulfonate salt form) prepared in situ and short chain surfactant (DAS).
• fiuorinated ionomer sulfonic acid form
• dispersed fluorinated ionomer particulate sulfonate salt form
• a cylindrical, horizontal, water-jacketed, paddle-stirred, stainless steel reactor having a length to diameter ratio of about 1.5 and a water capacity of 1 gallon (3.8 liter) is charged with 1750 grams of demineralized water, 0.6 grams of a 30 wt% aqueous solution of ammonium perfluoro(3,6-dioxa-4-methyl ⁇ 7-octene) sulfonate (PDMOS), and 20 grams of a 20 wt% aqueous solution of DAS.
• PDMOS ammonium perfluoro(3,6-dioxa-4-methyl ⁇ 7-octene) sulfonate
• TFE tetrafluoroethylene
• the reactor temperature is increased to 65°C, and is pressured to 30 psig (0.31 MPa) with TFE. Then 40 ml of freshly prepared aqueous initiator solution containing 0.2% ammonium persulfate (APS) is injected. Then, this same initiator solution is pumped into the reactor at 0.1 ml/min. After polymerization has begun as indicated by a 5 psi (35 KPa) drop in reactor pressure (kickoff). additional TFE is fed into the reactor at a rate of 0, 1 gram/minute. After 2 grams of TFE have been consumed after kickoff. the process is suspended by stopping the TFE and initiator feeds slowly venting the reactor. After stopping agitation, the reactor vapor space is evacuated.
• APS ammonium persulfate
• a sample of the reaction medium is taken.
• the sample is a clear dispersion of fluorinated ionomer particulate (sulfonate salt form) with a solids content of 0.01%.
• Weight average particle size of the fluorinated ionomer particulate is approximately 11 nm in diameter.
• IXR is approximately 15 (EW -1100).
• the dispersion is coagulated by freezing and thawing. After coagulation, the polymer is isolated by filtering and then drying in a 15O°C convection air oven.

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