CN102264775B - 使用原位制备的氟化离聚物的分散颗粒通过含水聚合制备含氟聚合物 - Google Patents

使用原位制备的氟化离聚物的分散颗粒通过含水聚合制备含氟聚合物 Download PDF

Info

Publication number
CN102264775B
CN102264775B CN200980152388.4A CN200980152388A CN102264775B CN 102264775 B CN102264775 B CN 102264775B CN 200980152388 A CN200980152388 A CN 200980152388A CN 102264775 B CN102264775 B CN 102264775B
Authority
CN
China
Prior art keywords
fluorinated
polymerization
weight
ionomer
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN200980152388.4A
Other languages
English (en)
Chinese (zh)
Other versions
CN102264775A (zh
Inventor
R·M·阿滕
K·W·莱夫尤
R·B·劳埃德
C·J·内尔克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CN102264775A publication Critical patent/CN102264775A/zh
Application granted granted Critical
Publication of CN102264775B publication Critical patent/CN102264775B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18Monomers containing fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F259/00Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
    • C08F259/08Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN200980152388.4A 2008-12-23 2009-12-23 使用原位制备的氟化离聚物的分散颗粒通过含水聚合制备含氟聚合物 Expired - Fee Related CN102264775B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14011808P 2008-12-23 2008-12-23
US61/140,118 2008-12-23
PCT/US2009/069370 WO2010075496A1 (en) 2008-12-23 2009-12-23 Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer produced in situ

Publications (2)

Publication Number Publication Date
CN102264775A CN102264775A (zh) 2011-11-30
CN102264775B true CN102264775B (zh) 2014-05-07

Family

ID=42026728

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200980152388.4A Expired - Fee Related CN102264775B (zh) 2008-12-23 2009-12-23 使用原位制备的氟化离聚物的分散颗粒通过含水聚合制备含氟聚合物

Country Status (5)

Country Link
US (1) US8058376B2 (https=)
EP (1) EP2367861B1 (https=)
JP (1) JP5703233B2 (https=)
CN (1) CN102264775B (https=)
WO (1) WO2010075496A1 (https=)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100036053A1 (en) * 2008-08-08 2010-02-11 E.I. Du Pont De Nemours And Company Aqueous Polymerization Process for the Manufacture of Fluoropolymer Comprising Repeating Units Arising from a Perfluoromonomer and a Monomer Having a Functional Group and a Polymerizable Carbon-Carbon Double Bond
US8153738B2 (en) * 2008-12-23 2012-04-10 E I Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
US9012025B2 (en) * 2012-04-05 2015-04-21 Xerox Corporation Fuser member
JP5665800B2 (ja) 2012-06-22 2015-02-04 三井・デュポンフロロケミカル株式会社 テトラフルオロエチレン/パーフルオロ(アルキルビニルエーテル)共重合体
EP2882705B1 (en) 2012-08-10 2018-02-21 Solvay Specialty Polymers Italy S.p.A. Allyl-bearing fluorinated ionomers
WO2014084400A1 (ja) * 2012-11-30 2014-06-05 ダイキン工業株式会社 ポリテトラフルオロエチレン水性分散液の製造方法
EP2935370A1 (en) * 2012-12-18 2015-10-28 E. I. du Pont de Nemours and Company Process for producing fluoroelastomers
US20160177079A1 (en) * 2013-07-30 2016-06-23 Solvay Specialty Polymers Italy S.P.A. Fluorine-containing thermoplastic elastomer composition
US10688448B2 (en) 2013-11-29 2020-06-23 Daikin Industries, Ltd. Porous body, polymer electrolyte membrane, filter material for filter, and filter unit
JP5849148B2 (ja) 2013-11-29 2016-01-27 旭化成イーマテリアルズ株式会社 高分子電解質膜
CN110233277A (zh) * 2013-11-29 2019-09-13 旭化成株式会社 高分子电解质膜
CN105793300B (zh) 2013-11-29 2018-01-05 大金工业株式会社 改性聚四氟乙烯细粉和单向拉伸多孔质体
JP6395411B2 (ja) * 2014-03-25 2018-09-26 三井・ケマーズ フロロプロダクツ株式会社 テトラフルオロエチレンとパーフルオロ(エチルビニルエーテル)との共重合体を含む複合成形体
EP3681948A4 (en) 2017-09-14 2021-07-14 3M Innovative Properties Company FLUORINATED COPOLYMER WITH SULFONYL SIDE GROUPS AS WELL AS COMPOSITIONS AND ARTICLES THEREFORE
JP6974784B2 (ja) 2018-03-01 2021-12-01 ダイキン工業株式会社 フルオロポリマーの製造方法
CN117417612A (zh) * 2018-11-19 2024-01-19 大金工业株式会社 组合物和拉伸体
JP7174272B2 (ja) 2018-11-19 2022-11-17 ダイキン工業株式会社 変性ポリテトラフルオロエチレンの製造方法及び組成物
EP3960713A4 (en) 2019-04-26 2023-01-18 Daikin Industries, Ltd. Water treatment method and composition
CN113728014B (zh) 2019-04-26 2024-07-26 大金工业株式会社 含氟聚合物水性分散液的制造方法、排水的处理方法和含氟聚合物水性分散液
EP4026856A4 (en) * 2019-09-05 2023-09-27 Daikin Industries, Ltd. METHOD FOR MANUFACTURING PERFLUOROELASTOMER, AND COMPOSITION
CN114269840A (zh) 2019-09-05 2022-04-01 大金工业株式会社 组合物及其制造方法
CN114651018A (zh) 2019-11-19 2022-06-21 大金工业株式会社 含氟聚合物的制造方法、聚四氟乙烯的制造方法、全氟弹性体的制造方法和组合物
CN111114836B (zh) * 2019-12-31 2021-07-06 上海空间推进研究所 大尺寸高基频轻量化表面张力贮箱
CN111690092B (zh) * 2020-06-03 2022-04-19 乳源东阳光氟树脂有限公司 一种聚偏氟乙烯表面改性的核壳结构锂电池粘结剂及其制备方法和应用
CN112409528B (zh) * 2020-10-21 2021-11-16 浙江巨化技术中心有限公司 一种核壳结构ptfe分散树脂的制备方法
WO2022107894A1 (ja) 2020-11-19 2022-05-27 ダイキン工業株式会社 ポリテトラフルオロエチレンの製造方法およびポリテトラフルオロエチレンを含有する組成物
WO2022107891A1 (ja) 2020-11-19 2022-05-27 ダイキン工業株式会社 含フッ素エラストマー水性分散液の製造方法および組成物
JP7549257B2 (ja) 2020-11-19 2024-09-11 ダイキン工業株式会社 パーフルオロエラストマー水性分散液の製造方法、組成物、架橋性組成物および架橋物
EP4306553A4 (en) 2021-03-10 2025-04-30 Daikin Industries, Ltd. COATING COMPOSITION, COATING FILM, COATED PRODUCT AND COATED ARTICLE
EP4342921A4 (en) 2021-05-19 2025-04-23 Daikin Industries, Ltd. Process for producing a fluoropolymer, process for producing polytetrafluoroethylene and composition
EP4353759A4 (en) 2021-06-11 2025-06-18 Daikin Industries, Ltd. Manufacturing process for aqueous fluorinated elastomer dispersion, composition and aqueous dispersion
WO2023277139A1 (ja) 2021-06-30 2023-01-05 ダイキン工業株式会社 フルオロポリマー組成物の製造方法およびフルオロポリマー組成物
EP4365211A4 (en) 2021-06-30 2025-07-16 Daikin Ind Ltd METHOD FOR PRODUCING A COMPOSITION CONTAINING A HIGH-PURITY FLUOROPOLYMER, AND COMPOSITION CONTAINING A HIGH-PURITY FLUOROPOLYMER
CN113549168B (zh) * 2021-08-19 2023-01-20 常熟三爱富中昊化工新材料有限公司 聚三氟苯乙烯的制备方法
JP7791483B2 (ja) 2022-03-23 2025-12-24 ダイキン工業株式会社 フルオロポリマーの製造方法および組成物
CN119072500A (zh) * 2022-04-28 2024-12-03 大金工业株式会社 含有氟树脂的组合物的制造方法和含有氟树脂的组合物
WO2023210818A1 (ja) 2022-04-28 2023-11-02 ダイキン工業株式会社 フッ素ゴムを含有する組成物
EP4516819A1 (en) 2022-04-28 2025-03-05 Daikin Industries, Ltd. Method for producing fluoropolymer
JP7492186B1 (ja) 2023-01-18 2024-05-29 ダイキン工業株式会社 電気化学デバイス用合剤、電気化学デバイス用合剤シート、電極、及び、電気化学デバイス
JP7653042B2 (ja) 2023-01-18 2025-03-28 ダイキン工業株式会社 テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池
CN121712810A (zh) 2023-08-14 2026-03-20 大金工业株式会社 含氟聚合物水性分散液的制造方法和含氟聚合物水性分散液
CN121752344A (zh) 2023-08-28 2026-03-27 大金工业株式会社 水溶性含氟聚合物的回收方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1886433A (zh) * 2003-10-30 2006-12-27 3M创新有限公司 功能化含氟单体的水乳浊液聚合
CN101193923A (zh) * 2005-06-10 2008-06-04 3M创新有限公司 在存在有部分氟化的低聚物作为乳化剂的条件下进行的氟化单体的水乳液聚合

Family Cites Families (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2559752A (en) * 1951-03-06 1951-07-10 Du Pont Aqueous colloidal dispersions of polymers
US2713593A (en) * 1953-12-21 1955-07-19 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US3037953A (en) * 1961-04-26 1962-06-05 Du Pont Concentration of aqueous colloidal dispersions of polytetrafluoroethylene
US3271341A (en) * 1961-08-07 1966-09-06 Du Pont Aqueous colloidal dispersions of polymer
US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3291843A (en) * 1963-10-08 1966-12-13 Du Pont Fluorinated vinyl ethers and their preparation
US3391099A (en) * 1966-04-25 1968-07-02 Du Pont Polymerization process
GB1292268A (en) 1970-02-16 1972-10-11 Bitterfeld Chemie Process for the dimerisation of hexafluoropropene epoxide
US3704272A (en) * 1970-09-15 1972-11-28 Du Pont Concentration of polytetrafluoroethylene aqueous dispersion
US4358545A (en) * 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
JPS5816622U (ja) * 1981-07-23 1983-02-01 株式会社リコー カメラシステムにおける信号伝達装置
US4380618A (en) * 1981-08-21 1983-04-19 E. I. Du Pont De Nemours And Company Batch polymerization process
US4552631A (en) * 1983-03-10 1985-11-12 E. I. Du Pont De Nemours And Company Reinforced membrane, electrochemical cell and electrolysis process
DE3486428T2 (de) 1983-12-26 1996-10-10 Daikin Ind Ltd Halogen enthaltendes Polyether
US4621116A (en) * 1984-12-07 1986-11-04 E. I. Du Pont De Nemours And Company Process for copolymerization of tetrafluoroethylene in the presence of a dispersing agent comprising a perfluoroalkoxybenzene sulfonic acid or salt
US4743658A (en) * 1985-10-21 1988-05-10 E. I. Du Pont De Nemours And Company Stable tetrafluoroethylene copolymers
US4940525A (en) * 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US4952630A (en) * 1987-12-31 1990-08-28 E. I. Du Pont De Nemours And Company Modified polytetrafluoroethylene resins and blends thereof
JP3172983B2 (ja) * 1993-09-20 2001-06-04 ダイキン工業株式会社 ビニリデンフルオライド系重合体の水性分散液およびその製法
US5422411A (en) * 1993-09-21 1995-06-06 Ballard Power Systems Inc. Trifluorostyrene and substituted trifluorostyrene copolymeric compositions and ion-exchange membranes formed therefrom
US5637748A (en) * 1995-03-01 1997-06-10 E. I. Du Pont De Nemours And Company Process for synthesizing fluorinated nitrile compounds
JP3346090B2 (ja) * 1995-03-31 2002-11-18 ダイキン工業株式会社 ポリテトラフルオロエチレン水性分散液組成物及びその用途
US5789508A (en) * 1995-08-31 1998-08-04 E. I. Du Pont De Nemours And Company Polymerization process
US5688884A (en) * 1995-08-31 1997-11-18 E. I. Du Pont De Nemours And Company Polymerization process
US5763552A (en) * 1996-07-26 1998-06-09 E. I. Du Pont De Nemours And Company Hydrogen-containing flourosurfacant and its use in polymerization
US5969067A (en) * 1996-09-13 1999-10-19 E.I. Dupont De Nemours And Company Phosphorus-containing fluoromonomers and polymers thereof
US5866711A (en) * 1996-09-13 1999-02-02 E. I. Du Pont De Nemours And Company Fluorocyanate and fluorocarbamate monomers and polymers thereof
WO1998016581A1 (en) * 1996-10-15 1998-04-23 E.I. Du Pont De Nemours And Company Compositions containing particles of highly fluorinated ion exchange polymer
DE69835366T2 (de) * 1997-03-31 2007-07-19 Daikin Industries, Ltd. Verfahren zur herstellung von perfluorvinylethersulfonsäure-derivaten
US6395848B1 (en) * 1999-05-20 2002-05-28 E. I. Du Pont De Nemours And Company Polymerization of fluoromonomers
US6482979B1 (en) 1999-12-22 2002-11-19 Dyneon Llc Perfluorinated acid fluorides and preparation thereof
DE60119307T2 (de) 2000-02-16 2007-04-12 Daikin Industries, Ltd. Verfahren zur herstellung eines fluorionomers, verfahren zur reinigung und konzentrierung von ionomeren und verfahren zur filmbildung
US7045571B2 (en) * 2001-05-21 2006-05-16 3M Innovative Properties Company Emulsion polymerization of fluorinated monomers
US6956078B2 (en) 2002-01-04 2005-10-18 E.I. Du Pont De Nemours And Company Concentrated fluoropolymer dispersions
US6902839B2 (en) * 2002-05-31 2005-06-07 Korea Advanced Institute Of Science And Technology Polymer electrolyte membrane for fuel cell and method for producing the same
JP4096764B2 (ja) 2002-06-17 2008-06-04 ダイキン工業株式会社 含フッ素結晶性ポリマー分散体製造方法
US6841616B2 (en) * 2003-03-28 2005-01-11 Arkema Inc. Polymerization of halogen-containing monomers using siloxane surfactant
JP2004359870A (ja) 2003-06-05 2004-12-24 Daikin Ind Ltd 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
JP2004358397A (ja) 2003-06-05 2004-12-24 Daikin Ind Ltd 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
WO2005003075A1 (ja) * 2003-07-02 2005-01-13 Daikin Industries, Ltd. フルオロアルキルカルボン酸誘導体、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
WO2005020363A2 (en) * 2003-08-19 2005-03-03 E.I. Dupont De Nemours And Company Membranes of fluorinated ionomer blended with nonionomeric fluoropolymers for electrochemical cells
US20050090613A1 (en) * 2003-10-22 2005-04-28 Daikin Industries, Ltd. Process for preparing fluorine-containing polymer latex
DE10352692A1 (de) 2003-11-12 2005-06-23 Sanguibiotech Gmbh Verwendung hypo-onkotischer Lösungen in das Blut addierbarer, hyperpolymerer Hämoglobine zur Behandlung eines Lungenödems
EP1533325B1 (en) * 2003-11-17 2011-10-19 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant
JP2005320501A (ja) * 2004-04-07 2005-11-17 Daikin Ind Ltd 含フッ素エラストマー重合体の製造方法
US20060014887A1 (en) * 2004-07-19 2006-01-19 3M Innovative Properties Company Method of hydrolyzing a dispersion of ionic fluoropolymer
GB0514387D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
US7671112B2 (en) * 2005-07-15 2010-03-02 3M Innovative Properties Company Method of making fluoropolymer dispersion
GB0514398D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
EP1939222B2 (en) 2005-10-17 2019-09-04 AGC Inc. Process for producing an AQUEOUS POLYTETRAFLUOROETHYLENE EMULSION, AND POLYTETRAFLUOROETHYLENE FINE POWDER AND POROUS MATERIAL PRODUCED FROM THE SAME
WO2007046377A1 (ja) 2005-10-20 2007-04-26 Asahi Glass Company, Limited 溶融成形可能なフッ素樹脂の製造方法
JP5141256B2 (ja) 2005-10-20 2013-02-13 旭硝子株式会社 ポリテトラフルオロエチレン水性分散液およびその製品
WO2007049517A1 (ja) 2005-10-26 2007-05-03 Asahi Glass Company, Limited 含フッ素乳化剤の残留量が少ないフッ素樹脂およびその製造方法
EP2084195B1 (en) 2006-11-09 2011-06-08 E.I. Du Pont De Nemours And Company Aqueous polymerization of fluorinated monomers using polymerization agent comprising fluoropolyether acid or salt and hydrocarbon surfactant
US7999049B2 (en) 2008-01-22 2011-08-16 Dupont Performance Elastomers L.L.C. Process for producing fluoroelastomers

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1886433A (zh) * 2003-10-30 2006-12-27 3M创新有限公司 功能化含氟单体的水乳浊液聚合
CN101193923A (zh) * 2005-06-10 2008-06-04 3M创新有限公司 在存在有部分氟化的低聚物作为乳化剂的条件下进行的氟化单体的水乳液聚合

Also Published As

Publication number Publication date
WO2010075496A1 (en) 2010-07-01
EP2367861B1 (en) 2015-02-25
JP2012513534A (ja) 2012-06-14
JP5703233B2 (ja) 2015-04-15
US20100160510A1 (en) 2010-06-24
CN102264775A (zh) 2011-11-30
EP2367861A1 (en) 2011-09-28
US8058376B2 (en) 2011-11-15

Similar Documents

Publication Publication Date Title
CN102264775B (zh) 使用原位制备的氟化离聚物的分散颗粒通过含水聚合制备含氟聚合物
CN102264777B (zh) 使用氟化离聚物的分散颗粒通过含水聚合制备含氟聚合物
CN102264779B (zh) 具有氟化离聚物核心的含氟聚合物颗粒
CN102264776B (zh) 使用原位制备的氟化离聚物的分散颗粒通过含水聚合制备氟化离聚物
CN102027023B (zh) 使用氟聚醚酸或盐的混合物的氟化单体含水聚合反应
CN101616939A (zh) 使用包含高分子量氟聚醚酸或盐以及氟聚醚酸或盐表面活性剂的聚合剂进行的氟化单体的含水聚合反应
EP2367862B1 (en) Aqueous polymerization of fluorinated monomer using hydrogen containing branched fluoroether surfactant
CN102264774A (zh) 使用氟化离聚物的分散颗粒通过含水聚合制备的氟化离聚物
US8436053B2 (en) Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140507

Termination date: 20161223