CN102179024A - 通过高温进行组分间发生化学反应产生灭火物质的灭火组合物 - Google Patents
通过高温进行组分间发生化学反应产生灭火物质的灭火组合物 Download PDFInfo
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- CN102179024A CN102179024A CN2010102854978A CN201010285497A CN102179024A CN 102179024 A CN102179024 A CN 102179024A CN 2010102854978 A CN2010102854978 A CN 2010102854978A CN 201010285497 A CN201010285497 A CN 201010285497A CN 102179024 A CN102179024 A CN 102179024A
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- Prior art keywords
- carbonate
- fire
- phosphate
- acid
- ammonium
- Prior art date
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- 238000006243 chemical reaction Methods 0.000 title claims abstract description 9
- 239000000203 mixture Substances 0.000 title abstract description 10
- 239000000126 substance Substances 0.000 title abstract description 4
- 239000003063 flame retardant Substances 0.000 claims abstract description 25
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 11
- 239000007800 oxidant agent Substances 0.000 claims abstract description 11
- 230000001590 oxidative effect Effects 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000000443 aerosol Substances 0.000 claims abstract description 6
- 238000002485 combustion reaction Methods 0.000 claims abstract description 4
- -1 bromo trimethylphenyl Chemical group 0.000 claims description 34
- 239000002131 composite material Substances 0.000 claims description 29
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 229910001868 water Inorganic materials 0.000 claims description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 claims description 12
- 229920000877 Melamine resin Polymers 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- 235000011007 phosphoric acid Nutrition 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 8
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 8
- 239000003814 drug Substances 0.000 claims description 8
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical group C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 claims description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- KZTYYGOKRVBIMI-UHFFFAOYSA-N S-phenyl benzenesulfonothioate Natural products C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 239000001095 magnesium carbonate Substances 0.000 claims description 6
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 6
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 6
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- 239000011574 phosphorus Substances 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 4
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- QHWKHLYUUZGSCW-UHFFFAOYSA-N Tetrabromophthalic anhydride Chemical compound BrC1=C(Br)C(Br)=C2C(=O)OC(=O)C2=C1Br QHWKHLYUUZGSCW-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 4
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 4
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical compound NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims description 4
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 4
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 4
- 239000000347 magnesium hydroxide Substances 0.000 claims description 4
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
- 150000007974 melamines Chemical class 0.000 claims description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 4
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 claims description 4
- QZRNTVPRGQDWRA-UHFFFAOYSA-N strontium;boron;oxygen(2-) Chemical compound [B].[O-2].[Sr+2] QZRNTVPRGQDWRA-UHFFFAOYSA-N 0.000 claims description 4
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(II) oxide Inorganic materials [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 claims description 4
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 4
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 claims description 4
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 claims description 4
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 239000011149 active material Substances 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- UIPNVCZMXRSSMM-UHFFFAOYSA-N strontium;oxido(oxo)borane Chemical compound [Sr+2].[O-]B=O.[O-]B=O UIPNVCZMXRSSMM-UHFFFAOYSA-N 0.000 claims description 3
- GRKDVZMVHOLESV-UHFFFAOYSA-N (2,3,4,5,6-pentabromophenyl)methyl prop-2-enoate Chemical compound BrC1=C(Br)C(Br)=C(COC(=O)C=C)C(Br)=C1Br GRKDVZMVHOLESV-UHFFFAOYSA-N 0.000 claims description 2
- CHLNHIVUNRZION-UHFFFAOYSA-N (2,3-dibromophenyl) dihydrogen phosphate Chemical compound OP(O)(=O)OC1=CC=CC(Br)=C1Br CHLNHIVUNRZION-UHFFFAOYSA-N 0.000 claims description 2
- LPKCJFLRJWWIDI-UHFFFAOYSA-N (diaminomethylideneamino)phosphonic acid Chemical compound NC(N)=NP(O)(O)=O LPKCJFLRJWWIDI-UHFFFAOYSA-N 0.000 claims description 2
- FIAXCDIQXHJNIX-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-ethylbenzene Chemical compound CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br FIAXCDIQXHJNIX-UHFFFAOYSA-N 0.000 claims description 2
- OZHJEQVYCBTHJT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-methylbenzene Chemical compound CC1=C(Br)C(Br)=C(Br)C(Br)=C1Br OZHJEQVYCBTHJT-UHFFFAOYSA-N 0.000 claims description 2
- MRHCTSJVGDQROS-UHFFFAOYSA-N 1,2,3-tribromo-4-ethoxybenzene Chemical compound CCOC1=CC=C(Br)C(Br)=C1Br MRHCTSJVGDQROS-UHFFFAOYSA-N 0.000 claims description 2
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 claims description 2
- ZXSQEZNORDWBGZ-UHFFFAOYSA-N 1,3-dihydropyrrolo[2,3-b]pyridin-2-one Chemical compound C1=CN=C2NC(=O)CC2=C1 ZXSQEZNORDWBGZ-UHFFFAOYSA-N 0.000 claims description 2
- OOSZCNKVJAVHJI-UHFFFAOYSA-N 1-[(4-fluorophenyl)methyl]piperazine Chemical compound C1=CC(F)=CC=C1CN1CCNCC1 OOSZCNKVJAVHJI-UHFFFAOYSA-N 0.000 claims description 2
- IDCPFAYURAQKDZ-UHFFFAOYSA-N 1-nitroguanidine Chemical compound NC(=N)N[N+]([O-])=O IDCPFAYURAQKDZ-UHFFFAOYSA-N 0.000 claims description 2
- CHUGKEQJSLOLHL-UHFFFAOYSA-N 2,2-Bis(bromomethyl)propane-1,3-diol Chemical compound OCC(CO)(CBr)CBr CHUGKEQJSLOLHL-UHFFFAOYSA-N 0.000 claims description 2
- NXJGWHGJPITYOJ-UHFFFAOYSA-N 2-[(2,4,6-tribromophenoxy)methyl]oxirane Chemical compound BrC1=CC(Br)=CC(Br)=C1OCC1OC1 NXJGWHGJPITYOJ-UHFFFAOYSA-N 0.000 claims description 2
- OAVRWNUUOUXDFH-UHFFFAOYSA-H 2-hydroxypropane-1,2,3-tricarboxylate;manganese(2+) Chemical compound [Mn+2].[Mn+2].[Mn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O OAVRWNUUOUXDFH-UHFFFAOYSA-H 0.000 claims description 2
- ULRPISSMEBPJLN-UHFFFAOYSA-N 2h-tetrazol-5-amine Chemical compound NC1=NN=NN1 ULRPISSMEBPJLN-UHFFFAOYSA-N 0.000 claims description 2
- XDVOLDOITVSJGL-UHFFFAOYSA-N 3,7-dihydroxy-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B(O)OB2OB(O)OB1O2 XDVOLDOITVSJGL-UHFFFAOYSA-N 0.000 claims description 2
- QGBLCIBATKETJC-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;manganese(2+) Chemical compound [Mn+2].O1B([O-])OB2OB([O-])OB1O2 QGBLCIBATKETJC-UHFFFAOYSA-N 0.000 claims description 2
- JBMFDCVHPFKUIX-UHFFFAOYSA-N 3-(2,4,6-tribromophenyl)pyrrole-2,5-dione Chemical compound BrC1=CC(Br)=CC(Br)=C1C1=CC(=O)NC1=O JBMFDCVHPFKUIX-UHFFFAOYSA-N 0.000 claims description 2
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 claims description 2
- NBOCQTNZUPTTEI-UHFFFAOYSA-N 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide Chemical compound C1=CC(S(=O)(=O)NN)=CC=C1OC1=CC=C(S(=O)(=O)NN)C=C1 NBOCQTNZUPTTEI-UHFFFAOYSA-N 0.000 claims description 2
- WZUKKIPWIPZMAS-UHFFFAOYSA-K Ammonium alum Chemical compound [NH4+].O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O WZUKKIPWIPZMAS-UHFFFAOYSA-K 0.000 claims description 2
- 239000004254 Ammonium phosphate Substances 0.000 claims description 2
- OJRHBOVEJOQQOA-UHFFFAOYSA-N BrBr(CC1=CC=CC=C1)(Br)(Br)(Br)Br Chemical compound BrBr(CC1=CC=CC=C1)(Br)(Br)(Br)Br OJRHBOVEJOQQOA-UHFFFAOYSA-N 0.000 claims description 2
- VXNRLQNRDGVMAJ-UHFFFAOYSA-N BrC(C(C(Cl)(Br)Br)(Br)Br)CCC Chemical compound BrC(C(C(Cl)(Br)Br)(Br)Br)CCC VXNRLQNRDGVMAJ-UHFFFAOYSA-N 0.000 claims description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
- NWCOUGMDAPWVOK-UHFFFAOYSA-N CC.BrC=1C(=C(C(=C2C1C(=O)NC2=O)Br)Br)Br Chemical compound CC.BrC=1C(=C(C(=C2C1C(=O)NC2=O)Br)Br)Br NWCOUGMDAPWVOK-UHFFFAOYSA-N 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 claims description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000004277 Ferrous carbonate Substances 0.000 claims description 2
- 229910017569 La2(CO3)3 Inorganic materials 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 2
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 2
- KPQIKRADSQBNSN-UHFFFAOYSA-N N1=C(N)N=C(N)N=C1N.P(=O)(OO)(O)O Chemical compound N1=C(N)N=C(N)N=C1N.P(=O)(OO)(O)O KPQIKRADSQBNSN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004677 Nylon Substances 0.000 claims description 2
- DQMUQFUTDWISTM-UHFFFAOYSA-N O.[O-2].[Fe+2].[Fe+2].[O-2] Chemical compound O.[O-2].[Fe+2].[Fe+2].[O-2] DQMUQFUTDWISTM-UHFFFAOYSA-N 0.000 claims description 2
- OTRAYOBSWCVTIN-UHFFFAOYSA-N OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N Chemical compound OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N OTRAYOBSWCVTIN-UHFFFAOYSA-N 0.000 claims description 2
- YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical class NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 229920001800 Shellac Polymers 0.000 claims description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- KYPYTERUKNKOLP-UHFFFAOYSA-N Tetrachlorobisphenol A Chemical compound C=1C(Cl)=C(O)C(Cl)=CC=1C(C)(C)C1=CC(Cl)=C(O)C(Cl)=C1 KYPYTERUKNKOLP-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 239000005083 Zinc sulfide Substances 0.000 claims description 2
- FZQSLXQPHPOTHG-UHFFFAOYSA-N [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 Chemical compound [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 FZQSLXQPHPOTHG-UHFFFAOYSA-N 0.000 claims description 2
- ZLXPLDLEBORRPT-UHFFFAOYSA-M [NH4+].[Fe+].[O-]S([O-])(=O)=O Chemical compound [NH4+].[Fe+].[O-]S([O-])(=O)=O ZLXPLDLEBORRPT-UHFFFAOYSA-M 0.000 claims description 2
- DZHMRSPXDUUJER-UHFFFAOYSA-N [amino(hydroxy)methylidene]azanium;dihydrogen phosphate Chemical compound NC(N)=O.OP(O)(O)=O DZHMRSPXDUUJER-UHFFFAOYSA-N 0.000 claims description 2
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 claims description 2
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 2
- 150000008065 acid anhydrides Chemical class 0.000 claims description 2
- GJYJYFHBOBUTBY-UHFFFAOYSA-N alpha-camphorene Chemical compound CC(C)=CCCC(=C)C1CCC(CCC=C(C)C)=CC1 GJYJYFHBOBUTBY-UHFFFAOYSA-N 0.000 claims description 2
- 229940037003 alum Drugs 0.000 claims description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 2
- 229940010048 aluminum sulfate Drugs 0.000 claims description 2
- OJMOMXZKOWKUTA-UHFFFAOYSA-N aluminum;borate Chemical compound [Al+3].[O-]B([O-])[O-] OJMOMXZKOWKUTA-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 claims description 2
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 claims description 2
- MXZRMHIULZDAKC-UHFFFAOYSA-L ammonium magnesium phosphate Chemical compound [NH4+].[Mg+2].[O-]P([O-])([O-])=O MXZRMHIULZDAKC-UHFFFAOYSA-L 0.000 claims description 2
- 239000011609 ammonium molybdate Substances 0.000 claims description 2
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- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 2
- 229940010552 ammonium molybdate Drugs 0.000 claims description 2
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 claims description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 2
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- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
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- 229910000410 antimony oxide Inorganic materials 0.000 claims description 2
- NDGSBJSAXJUQTE-UHFFFAOYSA-N azane;phosphorous acid Chemical compound N.OP(O)O NDGSBJSAXJUQTE-UHFFFAOYSA-N 0.000 claims description 2
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 claims description 2
- ZBUQRSWEONVBES-UHFFFAOYSA-L beryllium carbonate Chemical compound [Be+2].[O-]C([O-])=O ZBUQRSWEONVBES-UHFFFAOYSA-L 0.000 claims description 2
- 229910000023 beryllium carbonate Inorganic materials 0.000 claims description 2
- XWTXZJITNNRDLC-UHFFFAOYSA-K bis[(2-hydroxyacetyl)oxy]alumanyl 2-hydroxyacetate Chemical compound [Al+3].OCC([O-])=O.OCC([O-])=O.OCC([O-])=O XWTXZJITNNRDLC-UHFFFAOYSA-K 0.000 claims description 2
- 229940049676 bismuth hydroxide Drugs 0.000 claims description 2
- TZSXPYWRDWEXHG-UHFFFAOYSA-K bismuth;trihydroxide Chemical compound [OH-].[OH-].[OH-].[Bi+3] TZSXPYWRDWEXHG-UHFFFAOYSA-K 0.000 claims description 2
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- IUTYMBRQELGIRS-UHFFFAOYSA-N boric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OB(O)O.NC1=NC(N)=NC(N)=N1 IUTYMBRQELGIRS-UHFFFAOYSA-N 0.000 claims description 2
- YZYDPPZYDIRSJT-UHFFFAOYSA-K boron phosphate Chemical compound [B+3].[O-]P([O-])([O-])=O YZYDPPZYDIRSJT-UHFFFAOYSA-K 0.000 claims description 2
- 229910000149 boron phosphate Inorganic materials 0.000 claims description 2
- 150000001649 bromium compounds Chemical group 0.000 claims description 2
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 2
- 239000001639 calcium acetate Substances 0.000 claims description 2
- 235000011092 calcium acetate Nutrition 0.000 claims description 2
- 229960005147 calcium acetate Drugs 0.000 claims description 2
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 claims description 2
- 229940062672 calcium dihydrogen phosphate Drugs 0.000 claims description 2
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 claims description 2
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- LNEUSAPFBRDCPM-UHFFFAOYSA-N carbamimidoylazanium;sulfamate Chemical compound NC(N)=N.NS(O)(=O)=O LNEUSAPFBRDCPM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- AWNIPGYSDJLJRJ-UHFFFAOYSA-N carbonic acid erbium Chemical compound [Er].OC(O)=O AWNIPGYSDJLJRJ-UHFFFAOYSA-N 0.000 claims description 2
- CTTLHHPBBQUMJT-UHFFFAOYSA-N carbonic acid;holmium Chemical compound [Ho].OC(O)=O CTTLHHPBBQUMJT-UHFFFAOYSA-N 0.000 claims description 2
- NAPFHXCBNVVCGD-UHFFFAOYSA-N carbonic acid;lutetium Chemical compound [Lu].OC(O)=O NAPFHXCBNVVCGD-UHFFFAOYSA-N 0.000 claims description 2
- UHNYFORPCMZIEW-UHFFFAOYSA-N carbonic acid;vanadium Chemical compound [V].OC(O)=O UHNYFORPCMZIEW-UHFFFAOYSA-N 0.000 claims description 2
- GHLITDDQOMIBFS-UHFFFAOYSA-H cerium(3+);tricarbonate Chemical compound [Ce+3].[Ce+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O GHLITDDQOMIBFS-UHFFFAOYSA-H 0.000 claims description 2
- UNJPQTDTZAKTFK-UHFFFAOYSA-K cerium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Ce+3] UNJPQTDTZAKTFK-UHFFFAOYSA-K 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- XHFVDZNDZCNTLT-UHFFFAOYSA-H chromium(3+);tricarbonate Chemical compound [Cr+3].[Cr+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O XHFVDZNDZCNTLT-UHFFFAOYSA-H 0.000 claims description 2
- 229910021446 cobalt carbonate Inorganic materials 0.000 claims description 2
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 claims description 2
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 claims description 2
- ILZSSCVGGYJLOG-UHFFFAOYSA-N cobaltocene Chemical compound [Co+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 ILZSSCVGGYJLOG-UHFFFAOYSA-N 0.000 claims description 2
- 229940116318 copper carbonate Drugs 0.000 claims description 2
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 claims description 2
- 239000013078 crystal Substances 0.000 claims description 2
- 125000000950 dibromo group Chemical group Br* 0.000 claims description 2
- 235000019700 dicalcium phosphate Nutrition 0.000 claims description 2
- FWBOFUGDKHMVPI-UHFFFAOYSA-K dicopper;2-oxidopropane-1,2,3-tricarboxylate Chemical compound [Cu+2].[Cu+2].[O-]C(=O)CC([O-])(C([O-])=O)CC([O-])=O FWBOFUGDKHMVPI-UHFFFAOYSA-K 0.000 claims description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 2
- MHJAJDCZWVHCPF-UHFFFAOYSA-L dimagnesium phosphate Chemical compound [Mg+2].OP([O-])([O-])=O MHJAJDCZWVHCPF-UHFFFAOYSA-L 0.000 claims description 2
- GXGAKHNRMVGRPK-UHFFFAOYSA-N dimagnesium;dioxido-bis[[oxido(oxo)silyl]oxy]silane Chemical compound [Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O GXGAKHNRMVGRPK-UHFFFAOYSA-N 0.000 claims description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 2
- RGPUVZXXZFNFBF-UHFFFAOYSA-K diphosphonooxyalumanyl dihydrogen phosphate Chemical compound [Al+3].OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O RGPUVZXXZFNFBF-UHFFFAOYSA-K 0.000 claims description 2
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 claims description 2
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 2
- 229910000397 disodium phosphate Inorganic materials 0.000 claims description 2
- 235000019800 disodium phosphate Nutrition 0.000 claims description 2
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 claims description 2
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 2
- 239000010459 dolomite Substances 0.000 claims description 2
- 229910000514 dolomite Inorganic materials 0.000 claims description 2
- QGXMZGYYAAPYRV-UHFFFAOYSA-H dysprosium(3+);tricarbonate Chemical compound [Dy+3].[Dy+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O QGXMZGYYAAPYRV-UHFFFAOYSA-H 0.000 claims description 2
- SULCVUWEGVSCPF-UHFFFAOYSA-L europium(2+);carbonate Chemical compound [Eu+2].[O-]C([O-])=O SULCVUWEGVSCPF-UHFFFAOYSA-L 0.000 claims description 2
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 2
- 235000019268 ferrous carbonate Nutrition 0.000 claims description 2
- RAQDACVRFCEPDA-UHFFFAOYSA-L ferrous carbonate Chemical compound [Fe+2].[O-]C([O-])=O RAQDACVRFCEPDA-UHFFFAOYSA-L 0.000 claims description 2
- 229960004652 ferrous carbonate Drugs 0.000 claims description 2
- RQXZRSYWGRRGCD-UHFFFAOYSA-H gadolinium(3+);tricarbonate Chemical compound [Gd+3].[Gd+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O RQXZRSYWGRRGCD-UHFFFAOYSA-H 0.000 claims description 2
- NDEMNVPZDAFUKN-UHFFFAOYSA-N guanidine;nitric acid Chemical compound NC(N)=N.O[N+]([O-])=O.O[N+]([O-])=O NDEMNVPZDAFUKN-UHFFFAOYSA-N 0.000 claims description 2
- 150000002357 guanidines Chemical class 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- CKAPSXZOOQJIBF-UHFFFAOYSA-N hexachlorobenzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl CKAPSXZOOQJIBF-UHFFFAOYSA-N 0.000 claims description 2
- 238000005984 hydrogenation reaction Methods 0.000 claims description 2
- CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 claims description 2
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims description 2
- 150000002469 indenes Chemical class 0.000 claims description 2
- 235000014413 iron hydroxide Nutrition 0.000 claims description 2
- 229910001337 iron nitride Inorganic materials 0.000 claims description 2
- 229910000015 iron(II) carbonate Inorganic materials 0.000 claims description 2
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 claims description 2
- RTQMYJXQIDQHMH-UHFFFAOYSA-N iron;propan-2-one Chemical compound [Fe].CC(C)=O RTQMYJXQIDQHMH-UHFFFAOYSA-N 0.000 claims description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 2
- NZPIUJUFIFZSPW-UHFFFAOYSA-H lanthanum carbonate Chemical compound [La+3].[La+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O NZPIUJUFIFZSPW-UHFFFAOYSA-H 0.000 claims description 2
- 229960001633 lanthanum carbonate Drugs 0.000 claims description 2
- YXEUGTSPQFTXTR-UHFFFAOYSA-K lanthanum(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[La+3] YXEUGTSPQFTXTR-UHFFFAOYSA-K 0.000 claims description 2
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 2
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 2
- 229940018564 m-phenylenediamine Drugs 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229960001708 magnesium carbonate Drugs 0.000 claims description 2
- 239000004337 magnesium citrate Substances 0.000 claims description 2
- 229960005336 magnesium citrate Drugs 0.000 claims description 2
- 235000002538 magnesium citrate Nutrition 0.000 claims description 2
- 239000000391 magnesium silicate Substances 0.000 claims description 2
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- 229940099273 magnesium trisilicate Drugs 0.000 claims description 2
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- QQFLQYOOQVLGTQ-UHFFFAOYSA-L magnesium;dihydrogen phosphate Chemical compound [Mg+2].OP(O)([O-])=O.OP(O)([O-])=O QQFLQYOOQVLGTQ-UHFFFAOYSA-L 0.000 claims description 2
- LOCZQLKNTOXJDV-UHFFFAOYSA-N magnesium;oxido(oxo)borane Chemical compound [Mg+2].[O-]B=O.[O-]B=O LOCZQLKNTOXJDV-UHFFFAOYSA-N 0.000 claims description 2
- 239000011656 manganese carbonate Substances 0.000 claims description 2
- 235000006748 manganese carbonate Nutrition 0.000 claims description 2
- 229940093474 manganese carbonate Drugs 0.000 claims description 2
- 239000011564 manganese citrate Substances 0.000 claims description 2
- 235000014872 manganese citrate Nutrition 0.000 claims description 2
- 229940097206 manganese citrate Drugs 0.000 claims description 2
- VOEZDMCKEMNFOS-UHFFFAOYSA-N manganese oxalic acid dihydrate Chemical compound O.O.[Mn].OC(=O)C(O)=O VOEZDMCKEMNFOS-UHFFFAOYSA-N 0.000 claims description 2
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 claims description 2
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 claims description 2
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 2
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 claims description 2
- GVYLCNUFSHDAAW-UHFFFAOYSA-N mirex Chemical compound ClC12C(Cl)(Cl)C3(Cl)C4(Cl)C1(Cl)C1(Cl)C2(Cl)C3(Cl)C4(Cl)C1(Cl)Cl GVYLCNUFSHDAAW-UHFFFAOYSA-N 0.000 claims description 2
- GDXTWKJNMJAERW-UHFFFAOYSA-J molybdenum(4+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Mo+4] GDXTWKJNMJAERW-UHFFFAOYSA-J 0.000 claims description 2
- 235000019691 monocalcium phosphate Nutrition 0.000 claims description 2
- 229910000401 monomagnesium phosphate Inorganic materials 0.000 claims description 2
- 235000019785 monomagnesium phosphate Nutrition 0.000 claims description 2
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 2
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 2
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims description 2
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 2
- UTWHRPIUNFLOBE-UHFFFAOYSA-H neodymium(3+);tricarbonate Chemical compound [Nd+3].[Nd+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O UTWHRPIUNFLOBE-UHFFFAOYSA-H 0.000 claims description 2
- 229940078494 nickel acetate Drugs 0.000 claims description 2
- DOLZKNFSRCEOFV-UHFFFAOYSA-L nickel(2+);oxalate Chemical compound [Ni+2].[O-]C(=O)C([O-])=O DOLZKNFSRCEOFV-UHFFFAOYSA-L 0.000 claims description 2
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 claims description 2
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 claims description 2
- 229920001778 nylon Polymers 0.000 claims description 2
- FXADMRZICBQPQY-UHFFFAOYSA-N orthotelluric acid Chemical compound O[Te](O)(O)(O)(O)O FXADMRZICBQPQY-UHFFFAOYSA-N 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 2
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229960003975 potassium Drugs 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 235000011056 potassium acetate Nutrition 0.000 claims description 2
- 239000001508 potassium citrate Substances 0.000 claims description 2
- 229960002635 potassium citrate Drugs 0.000 claims description 2
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 2
- 235000011082 potassium citrates Nutrition 0.000 claims description 2
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 claims description 2
- 229940099402 potassium metaphosphate Drugs 0.000 claims description 2
- 239000004323 potassium nitrate Substances 0.000 claims description 2
- 235000010333 potassium nitrate Nutrition 0.000 claims description 2
- 235000019353 potassium silicate Nutrition 0.000 claims description 2
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Classifications
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/06—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components
Abstract
一种通过高温进行组分间发生化学反应产生灭火物质的灭火组合物，其特征在于：所述的灭火组合物包括阻燃剂、氧化剂、还原剂及黏合剂；各组分的含量为：阻燃剂：50质量％～90质量％；氧化剂：5质量％～30质量％；还原剂：5质量％～10质量％；黏合剂：0％～10质量％。在使用时，以烟火类药剂为热力源和动力源，通过点燃烟火类药剂，利用烟火类药剂燃烧的高温，使灭火组合物中氧化剂与还原剂反应产生灭火活性物质而灭火。与传统气溶胶发生剂不同的是，没有外界热源，该组合物本身并不燃烧。本发明的灭火组合物比传统气溶胶发生剂更高效、更安全。
Description
技术领域
本发明属消防领域，涉及灭火组合物，化学灭火物质的使用，特别指通过高温进行化学反应产生灭火物质的灭火组合物。
背景技术
自从人们发现了哈龙灭火剂对地球大气臭氧层严重的破坏作用后，国际社会及我国政府开始了淘汰哈龙灭火剂的行动，气体灭火系统，干粉灭火系统及水系灭火系统等对环境无害的灭火剂作为哈龙灭火器的替代品得到了广泛使用。
二氧化碳，IG541等惰性气体灭火的机理为物理灭火，是通过降低着火区的氧气浓度窒息灭火，这种灭火方式容易对人员的人身安全造成威胁，干粉灭火系统是通过在加压气体作用下喷出的粉末与火焰接触，发生物理化学抑制作用而灭火，水雾灭火系统是通过细水雾的冷却，窒息和隔绝热辐射的三重作用下达到控制火灾，抑制火灾和扑灭火灾的目的。
然而，这些灭火系统都需要高压贮存，不仅体积较大，在贮存过程中还存在物理爆炸的危险，文献“气体灭火系统的安全性分析”(消防科学与技术200221(5))分析了气体灭火系统所存在的危险，并列举了贮压气体灭火系统在使用中所引发的安全事故。
气溶胶灭火技术，因为具有无毒、无腐蚀、容积效率高、贮存周期长、全淹没、全方位灭火等特点而备受瞩目，从上世纪末到目前的十多年见，气溶胶技术得到了迅猛的发展，相关专利层出不穷。如俄罗斯专利RU2230726、RU2184587、RU2214848、RU2150310、RU2108124、RU2091106、RU2076761及国内专利CN1739820A、CN1150952C、CN1222331C。
现有的气溶胶灭火也有不足之处：自身产生的灭火活性在经过冷却层过滤后，衰减严重，大大影响灭火效能。
发明内容
针对上述研究状况，本发明将在高温下进行化学反应产生灭火物质的组合物用于灭火器中。本发明的目的在于，提供一种不需要压力贮存，更安全，对环境友好，具有高效灭火效能的灭火组合物。
本发明所涉及一种通过高温进行组分间发生化学反应产生灭火物质的组合物，其特征在于：所述的灭火组合物包括阻燃剂、氧化剂、还原剂及黏合剂。各组分的质量百分含量为：阻燃剂：50％～90％；氧化剂：5％～30％；还原剂：5％～10％；黏合剂：0％～10％。在使用时，以烟火类药剂为热力源和动力源，通过点燃烟火类药剂，利用烟火类药剂燃烧的高温，使灭火组合物中氧化剂与还原剂反应产生灭火活性物质而灭火。
所述的阻燃剂为溴系阻燃剂，氯系阻燃剂，有机磷系阻燃剂，磷-卤系阻燃剂，氮系及磷-氮系阻燃剂，无机阻燃剂的一种或多种。
所述的溴系阻燃剂为四溴双酚A，四溴双酚A醚，1，2-双(三溴苯氧基)乙烷，2，4，6-三溴苯基缩水甘油醚，四溴邻苯二甲酸酐，1，2-双(四溴邻苯二甲酰亚胺)乙烷，四溴邻苯二甲酸二甲酯，四溴邻苯二甲酸二钠，十溴二苯醚，十四溴二(苯氧基)苯，1，2-双(五溴苯基)乙烷，溴代三甲基苯基氢化茚，丙烯酸五溴苄酯，五溴苄基溴，六溴苯，五溴甲苯，2，4，6-三溴苯基顺丁烯二酰亚胺，六溴环十二烷，N，N’-1，2-双(二溴降冰片基二碳酰亚胺)乙烷，五溴氯环己烷，三(2，3-二溴丙基)异三聚氰酸酯，溴代苯乙烯共聚物，四溴双酚A碳酸酯低聚物，聚丙烯酸五溴苄酯，聚二溴亚苯基醚。
所述的氯系阻燃剂为海特酸酐，全氯五环癸烷，四氯双酚A，四氯邻苯二甲酸酐，六氯苯，氯化聚丙烯，氯化聚率乙烯，氯乙烯-偏二氯乙烯共聚物，氯化聚醚，六氯乙烷。
所述的有机磷系阻燃剂为1-氧代-4-羟甲基-2，6，7-三氧杂-1-磷杂双环[2，2，2]辛烷，2，2-二甲基-1，3-丙二醇-二(新戊二醇)双磷酸酯，9，10-二氢-9-氧杂-10-磷杂菲-10氧化物，双(4-羧苯基)苯基氧化磷，双(4-羟苯基)苯基氧化磷，磷酸苯基二苯砜酯齐聚物。
所述的磷-卤系阻燃剂为三(2，2-二(溴甲基)-3-溴丙基)磷酸酯，三(二溴苯基)磷酸酯，3，9-双(三溴苯氧基)-2，4，8，10，-四氧杂-3，9-二磷杂螺环[5，5]-3，9-二氧十一烷，3，9-双(五溴苯氧基)-2，4，8，10，-四氧杂-3，9-二磷杂螺环[5，5]-3，9-二氧十一烷，1-氧代-4-三溴苯氧羰基-2，6，7-三氧杂-1-磷杂双环[2，2，2]辛烷，对亚苯基四(2，4，6-三溴苯基)双磷酸酯，2，2-二(氯甲基)-1，3-丙二醇-二(新戊二醇)双磷酸酯，2，9-二(三溴新戊氧基)-2，4，8，10-四氧杂-3，9-二磷杂螺环[5.5]-3，9-二氧十一烷。
所述的氮系及磷-氮系阻燃剂为氰尿酸三聚氰胺，磷酸密胺盐，正磷酸二三聚氰胺，聚磷酸三聚氰胺，硼酸三聚氰胺，八钼酸三聚氰胺，三聚氰酸，三羟乙基异氰尿酸酯，2，4-二氨基-6-(3，3，3-三氯丙基)-1，3，5-三嗪，2，4-二(N-羟甲基氨基)-6-(3，3，3-三氯丙基-1，3，5-三嗪)，磷酸氢二胍，磷酸二氢胍，碳酸胍，氨基磺酸胍，脲，磷酸二氢脲，双氰胺，双(2，6，7-三氧杂-1-磷杂-双环[2.2.2]辛烷-1-氧-4-甲基)羟基磷酸酯三聚氰胺，3，9-二羟基-3，9-二氧-2，4，8，10-四氧杂-3，9-二磷杂螺环[5.5]十一烷-3，9-二三聚氰胺，1，2-二(2-氧-5，5-二甲基-1，3-二氧杂-2-磷杂环己基-2-氨基)乙烷，N，N’-双(2-氧-5，5-二甲基-1，3-二氧杂-2-磷杂换己基)-2，2’-间苯二胺，三(2-氧-5，5-二甲基-1，3-二氧杂-2-杂环己基-2-甲基)胺，六氯环三磷腈。
所述的无机灭火材料为聚磷酸铵，磷酸氢二铵，磷酸二氢铵，磷酸锌，磷酸铝，磷酸硼，三氧化二锑，氢氧化铝，氢氧化镁，水菱镁石，碱性草酸铝，硼酸锌，偏硼酸钡，氧化锌，硫化锌，七水硫酸锌，硼酸铝晶须，八钼酸铵，七钼酸铵，锡酸锌，一氧化锡，二氧化锡，二茂铁，丙酮铁，三氧化二铁，四氧化三铁，溴化铵，钨酸钠，六氟钛酸钾，六氟锆酸价，钛白粉，碳酸钙，硫酸钡，碳酸氢钠，碳酸氢钾，碳酸钴，碳酸锌，碱式碳酸锌，重质碳酸镁，碱式碳酸镁，碳酸锰，碳酸亚铁，碳酸锶，碳酸钠钾·6水，碳酸镁，碳酸钙，白云岩，碱式碳酸铜，碳酸锆，碳酸铍，倍半碳酸钠，碳酸铈，碳酸镧，碳酸胍，碳酸锂，碳酸钪，碳酸钒，碳酸铬，碳酸镍，碳酸钇，碳酸银，碳酸镨，碳酸钕，碳酸钐，碳酸铕，碳酸钆，碳酸铽，碳酸镝，碳 酸钬，碳酸铒，碳酸铥，碳酸镱，碳酸镥，二醋酸铝，乙酸钙，酒石酸氢钠，醋酸钠，醋酸钾，醋酸锌，醋酸锶，醋酸镍，醋酸铜，草酸钠，草酸钾，草酸铵，草酸镍，二水草酸锰，一氮化二铁，硝酸锆，磷酸二氢钙，磷酸二氢钠，二水磷酸二氢钠，磷酸二氢钾，磷酸二氢铝，磷酸二氢铵，磷酸二氢锌，磷酸二氢锰，磷酸二氢镁，磷酸氢二钠，磷酸氢二铵，磷酸氢钙，磷酸氢镁，磷酸铵，磷酸铵镁，聚磷酸铵，偏磷酸钾，三聚磷酸钾，三偏磷酸钠，次磷酸铵，亚磷酸二氢铵，磷酸锰，磷酸氢二锌，磷酸氢二锰，磷酸胍，磷酸蜜胺盐，磷酸脲，磷酸氢二偏硼酸锶，钾，硼酸，五硼酸铵，四硼酸钾·8水，偏硼酸镁·8水，四硼酸铵·4水，偏硼酸锶，四硼酸锶，四硼酸锶·4水，四硼酸钠·10水，硼酸锰，硼酸锌，氟硼酸铵，硫酸亚铁铵，硫酸铝，硫酸铝钾，硫酸铝铵，硫酸铵，硫酸氢镁，氢氧化铝，氢氧化镁，氢氧化铁，氢氧化钴，氢氧化铋，氢氧化锶，氢氧化铈，氢氧化镧，氢氧化钼，钼酸铵，锡酸锌，三硅酸镁，碲酸，钨酸锰，水锰矿，二茂钴。
所述的灭火材料还可为5-氨基四唑，偶氮二甲酰胺，尼龙粉，草酰胺，缩二脲，季戊四醇，十溴联苯醚，四溴邻苯二甲酸酐，二溴新戊二醇，柠檬酸钾，柠檬酸钠，柠檬酸锰，柠檬酸镁，柠檬酸铜，柠檬酸铵。
所述的氧化剂为硝酸钠、硝酸镁、氧化铁、硝酸钡、硝酸锶、硝酸钾一种或多种。
所述的还原剂为镁、碳、铝、铁、硝酸胍、硝基胍、三聚氰胺一种或多种。
所述的黏合剂为水玻璃、酚醛树脂、虫胶、淀粉中的一种或多种。
本发明的灭火组合物可在制作时加工成所需要的形状，如球状，片状，条状，块状，蜂窝状，并且可经过表面包覆处理。
灭火组合物灭火机理如下：烟火类药剂点燃后，释放出大量的热，这样，灭火组合物中的氧化剂和还原剂发生氧化还原反应，产生大量的灭火活性物质而灭火。但与传统气溶胶发生剂不同的是，由于大量阻燃剂的存在，如没有外界热源，该组合物本身并不能燃烧。本发明可提供一种比传统气溶胶发 生剂更高效、更安全的灭火组合物。
具体实施方式
将制得的片状灭火组合物30g分别加入装有20gK型热气溶胶发生剂的灭火装置中，分别在1.0m3试验箱中实施分布火灭火试验；试验测试结果见表1。对比例选择为20g市售K型热气溶胶发生剂。
表1各种组分成分比较和试验结果对比
通过上表试验数据可以看出，本发明的实施例1-7的灭火组合物在1.0m3试验箱中实施分布火灭火试验时灭火性能优于20g市售K型热气溶胶发生剂。
实验方法是按照GA 499-2004中7.13的浓度分布试验方法，在1m3的实 验箱中进行灭火试验，试验箱中共放置5个试验罐，四个燃料为放置在实验空间的四角，两上两下交错放置，另外在挡板后实验空间底部再放置一燃料罐。燃料罐中加入正庚烷。
Claims (13)
1.一种通过高温进行组分间发生化学反应产生灭火物质的灭火组合物，其特征在于：所述的灭火组合物包括阻燃剂、氧化剂、还原剂及黏合剂；
所述的灭火组合物各组分的含量为：
阻燃剂：约50质量％～90质量％
氧化剂：约5质量％～30质量％
还原剂：约5质量％～10质量％
黏合剂：约0％～10质量％
在使用时，以烟火类药剂为热力源和动力源，通过点燃烟火类药剂，利用烟火类药剂燃烧的高温，使灭火组合物中氧化剂与还原剂反应产生灭火活性物质而灭火。
2.根据权利要求1所述的灭火组合物，其特征在于：所述的灭火组合物中阻燃剂为溴系阻燃剂、氯系阻燃剂、有机磷系阻燃剂、磷-卤系阻燃剂、氮系及磷-氮系阻燃剂或无机阻燃剂。
3.根据权利要求2所述的灭火组合物，其特征在于：所述的溴系阻燃剂为四溴双酚A、四溴双酚A醚、1，2-双(三溴苯氧基)乙烷、2，4，6-三溴苯基缩水甘油醚、四溴邻苯二甲酸酐、1，2-双(四溴邻苯二甲酰亚胺)乙烷、四溴邻苯二甲酸二甲酯、四溴邻苯二甲酸二钠、十溴二苯醚、十四溴二(苯氧基)苯、1，2-双(五溴苯基)乙烷、溴代三甲基苯基氢化茚、丙烯酸五溴苄酯、五溴苄基溴、六溴苯、五溴甲苯、2，4，6-三溴苯基顺丁烯二酰亚胺、六溴环十二烷、N，N’-1，2-双(二溴降冰片基二碳酰亚胺)乙烷、五溴氯环己烷、三(2，3-二溴丙基)异三聚氰酸酯、溴代苯乙烯共聚物、四溴双酚A碳酸酯低聚物、聚丙烯酸五溴苄酯或聚二溴亚苯基醚。
4.根据权利要求2所述的灭火组合物，其特征在于：所述的氯系阻燃剂为得克隆、海特酸酐、全氯五环癸烷、四氯双酚A、四氯邻苯二甲酸酐、六氯苯、氯化聚丙烯、氯化聚率乙烯、氯乙烯-偏二氯乙烯共聚物、氯化聚醚或六氯乙烷。
5.根据权利要求2所述的灭火组合物，其特征在于：所述的有机磷系阻燃剂为1-氧代-4-羟甲基-2，6，7-三氧杂-1-磷杂双环[2，2，2]辛烷、2，2-二甲基-1，3-丙二醇-二(新戊二醇)双磷酸酯、9，10-二氢-9-氧杂-10-磷杂菲-10氧化物、双(4-羧苯基)苯基氧化磷、双(4-羟苯基)苯基氧化磷或磷酸苯基二苯砜酯齐聚物。
6.根据权利要求2所述的灭火组合物，其特征在于：所述的磷-卤系阻燃剂为三(2，2-二(溴甲基)-3-溴丙基)磷酸酯、三(二溴苯基)磷酸酯、3，9-双(三溴苯氧基)-2，4，8，10，-四氧杂-3，9-二磷杂螺环[5，5]-3，9-二氧十一烷、3，9-双(五溴苯氧基)-2，4，8，10，-四氧杂-3，9-二磷杂螺环[5，5]-3，9-二氧十一烷、1-氧代-4-三溴苯氧羰基-2，6，7-三氧杂-1-磷杂双环[2，2，2]辛烷、对亚苯基四(2，4，6-三溴苯基)双磷酸酯、2，2-二(氯甲基)-1，3-丙二醇-二(新戊二醇)双磷酸酯或2，9-二(三溴新戊氧基)-2，4，8，10-四氧杂-3，9-二磷杂螺环[5.5]-3，9-二氧十一烷。
7.根据权利要求2所述的灭火组合物，其特征在于：所述的氮系及磷-氮系阻燃剂为氰尿酸三聚氰胺、磷酸密胺盐、正磷酸二三聚氰胺、聚磷酸三聚氰胺、硼酸三聚氰胺、八钼酸三聚氰胺、三聚氰酸、三羟乙基异氰尿酸酯、2，4-二氨基-6-(3，3，3-三氯丙基)-1，3，5-三嗪、2，4-二(N-羟甲基氨基)-6-(3，3，3-三氯丙基-1，3，5-三嗪)、磷酸氢二胍、磷酸二氢胍、碳酸胍、氨基磺酸胍、脲、磷酸二氢脲、双氰胺、双(2，6，7-三氧杂-1-磷杂-双环[2.2.2]辛烷-1-氧-4-甲基)羟基磷酸酯三聚氰胺、3，9-二羟基-3，9-二氧-2，4，8，10-四氧杂-3，9-二磷杂螺环[5.5]十一烷-3，9-二三聚氰胺、1，2-二(2-氧-5，5-二甲基-1，3-二氧杂-2-磷杂环己基-2-氨基)乙烷、N，N’-双(2-氧-5，5-二甲基-1，3-二氧杂-2-磷杂换己基)-2，2’-间苯二胺、三(2-氧-5，5-二甲基-1，3-二氧杂-2-杂环己基-2-甲基)胺或六氯环三磷腈。
8.根据权利要求2所述的灭火组合物，其特征在于：所述的无机阻燃剂为聚磷酸铵、磷酸氢二铵、磷酸二氢铵、磷酸锌、磷酸铝、磷酸硼、三氧化二锑、氢氧化铝、氢氧化镁、水菱镁石、碱性草酸铝、硼酸锌、偏硼酸钡、氧化锌、硫化锌、七水硫酸锌、硼酸铝晶须、八钼酸铵、七钼酸铵、锡酸锌、一氧化锡、二氧化锡、二茂铁、丙酮铁、三氧化二铁、四氧化三铁、溴化铵、钨酸钠、六氟钛酸钾、六氟锆酸价、钛白粉、碳酸钙、硫酸钡、碳酸氢钠、碳酸氢钾、碳酸钴、碳酸锌、碱式碳酸锌、重质碳酸镁、碱式碳酸镁、碳酸锰、碳酸亚铁、碳酸锶、碳酸钠钾·6水、碳酸镁、碳酸钙、白云岩、碱式碳酸铜、碳酸锆、碳酸铍、倍半碳酸钠、碳酸铈、碳酸镧、碳酸胍、碳酸锂、碳酸钪、碳酸钒、碳酸铬、碳酸镍、碳酸钇、碳酸银、碳酸镨、碳酸钕、碳酸钐、碳酸铕、碳酸钆、碳酸铽、碳酸镝、碳酸钬、碳酸铒、碳酸铥、碳酸镱、碳酸镥、二醋酸铝、乙酸钙、酒石酸氢钠、醋酸钠、醋酸钾、醋酸锌、醋酸锶、醋酸镍、醋酸铜、草酸钠、草酸钾、草酸铵、草酸镍、二水草酸锰、一氮化二铁、硝酸锆、磷酸二氢钙、磷酸二氢钠、二水磷酸二氢钠、磷酸二氢钾、磷酸二氢铝、磷酸二氢铵、磷酸二氢锌、磷酸二氢锰、磷酸二氢镁、磷酸氢二钠、磷酸氢二铵、磷酸氢钙、磷酸氢镁、磷酸铵、磷酸铵镁、聚磷酸铵、偏磷酸钾、三聚磷酸钾、三偏磷酸钠、次磷酸铵、亚磷酸二氢铵、磷酸锰、磷酸氢二锌、磷酸氢二锰、磷酸胍、磷酸蜜胺盐、磷酸脲、磷酸氢二偏硼酸锶、磷酸氢二偏硼酸锶钾、硼酸、五硼酸铵、四硼酸钾·8水、偏硼酸镁·8水、四硼酸铵·4水、偏硼酸锶、四硼酸锶、四硼酸锶·4水、四硼酸钠·10水、硼酸锰、硼酸锌、氟硼酸铵、硫酸亚铁铵、硫酸铝、硫酸铝钾、硫酸铝铵、硫酸铵、硫酸氢镁、氢氧化铝、氢氧化镁、氢氧化铁、氢氧化钴、氢氧化铋、氢氧化锶、氢氧化铈、氢氧化镧、氢氧化钼、钼酸铵、锡酸锌、三硅酸镁、碲酸、钨酸锰、水锰矿、二茂钴或其组合。
9.根据权利要求2所述的灭火组合物，其特征在于：所述的阻燃剂还可为5-氨基四唑、偶氮二甲酰胺、尼龙粉、草酰胺、缩二脲、季戊四醇、十溴联苯醚、四溴邻苯二甲酸酐、二溴新戊二醇、柠檬酸钾、柠檬酸钠、柠檬酸锰、柠檬酸镁、柠檬酸铜或檬酸铵。
10.根据权利要求1或2所述的灭火组合物，其特征在于：所述的灭火组合物中氧化剂为硝酸钠、硝酸镁、氧化铁、硝酸钡、硝酸锶、硝酸钾一种或多种。
11.根据权利要求1或2所述的灭火组合物，其特征在于：所述的灭火组合物中还原剂为镁、碳、铝、铁、硝酸胍、硝基胍、三聚氰胺一种或多种。
12.根据权利要求1或2所述的灭火组合物，其特征在于：所述的黏合剂为水玻璃、酚醛树脂、虫胶、淀粉中的一种或多种。
13.根据上述任一权利要求所述的灭火组合物，其特征在于：所述的烟火类药剂为烟火类气溶胶灭火剂。
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| CN2010102854978A CN102179024B (zh) | 2010-09-16 | 2010-09-16 | 通过高温进行组分间发生化学反应产生灭火物质的灭火组合物 |
| KR1020137009263A KR101504474B1 (ko) | 2010-09-16 | 2011-09-07 | 고온에서 성분간 화학 반응을 통하여 소화 물질을 생성하는 조성물 |
| BR112013006237-1A BR112013006237B1 (pt) | 2010-09-16 | 2011-09-07 | composição extintora de fogo, que gera substância extintora de fogo através de reação química dos ingredientes em alta temperatura |
| TR2018/10287T TR201810287T4 (tr) | 2010-09-16 | 2011-09-07 | Bileşenlerin yüksek sıcaklıkta kimyasal reaksiyonu yoluyla yangın söndürme maddesi oluşturan bileşim. |
| US13/824,103 US8871110B2 (en) | 2010-09-16 | 2011-09-07 | Composition generating fire extinguishing substance through chemical reaction of ingredients at high temperature |
| MYPI2013000898A MY162645A (en) | 2010-09-16 | 2011-09-07 | Composition generating fire extinguishing substance through chemical reaction of ingredients at high temperature |
| EP11824563.8A EP2617473B1 (en) | 2010-09-16 | 2011-09-07 | Composition generating fire extinguishing substance through chemical reaction of ingredient at high temperature |
| AU2011301573A AU2011301573B2 (en) | 2010-09-16 | 2011-09-07 | Composition generating fire extinguishing substance through chemical reaction of ingredient at high temperature |
| MX2013002994A MX336246B (es) | 2010-09-16 | 2011-09-07 | Composicion generadora de una sustancia extintora a traves de una reaccion quimica de ingredientes de altas temperaturas. |
| RU2013115866/05A RU2554638C2 (ru) | 2010-09-16 | 2011-09-07 | Композиция, образующая огнетушащее вещество вследствие химической реакции ингредиентов при высокой температуре |
| PCT/CN2011/079428 WO2012034493A1 (zh) | 2010-09-16 | 2011-09-07 | 通过高温进行组分间发生化学反应产生灭火物质的组合物 |
| JP2013528505A JP5801894B2 (ja) | 2010-09-16 | 2011-09-07 | 高温で成分間化学反応を行って消火物質を生成する組成物 |
| CA2811459A CA2811459C (en) | 2010-09-16 | 2011-09-07 | Composition generating fire extinguishing substance through chemical reaction of ingredients at high temperature |
| IL225248A IL225248B (en) | 2010-09-16 | 2013-03-14 | A fire suppressant compound that produces a fire suppressant by a chemical reaction of components at a high temperature |
| ZA2013/02694A ZA201302694B (en) | 2010-09-16 | 2013-04-15 | Composition generating fire extinguishing substance through chemical reaction of ingredient at high temperature |
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| Publication number | Publication date |
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| AU2011301573B2 (en) | 2014-08-07 |
| BR112013006237A8 (pt) | 2017-07-11 |
| CN102179024B (zh) | 2012-06-27 |
| ZA201302694B (en) | 2014-06-25 |
| WO2012034493A1 (zh) | 2012-03-22 |
| TR201810287T4 (tr) | 2018-08-27 |
| CA2811459C (en) | 2016-03-01 |
| RU2013115866A (ru) | 2014-10-27 |
| EP2617473A1 (en) | 2013-07-24 |
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| RU2554638C2 (ru) | 2015-06-27 |
| BR112013006237A2 (pt) | 2016-06-07 |
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| EP2617473A4 (en) | 2014-03-12 |
| AU2011301573A1 (en) | 2013-05-09 |
| MX2013002994A (es) | 2013-09-26 |
| JP5801894B2 (ja) | 2015-10-28 |
| IL225248B (en) | 2018-02-28 |
| BR112013006237B1 (pt) | 2020-12-01 |
| JP2013541362A (ja) | 2013-11-14 |
| IL225248A0 (en) | 2013-06-27 |
| US8871110B2 (en) | 2014-10-28 |
| US20130181157A1 (en) | 2013-07-18 |
| KR101504474B1 (ko) | 2015-03-23 |
| MY162645A (en) | 2017-06-30 |
| CA2811459A1 (en) | 2012-03-22 |
| MX336246B (es) | 2016-01-11 |
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