CN102066241B - 制备含锂、铁和磷酸根的结晶材料的方法 - Google Patents

制备含锂、铁和磷酸根的结晶材料的方法 Download PDF

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CN102066241B
CN102066241B CN200980122733XA CN200980122733A CN102066241B CN 102066241 B CN102066241 B CN 102066241B CN 200980122733X A CN200980122733X A CN 200980122733XA CN 200980122733 A CN200980122733 A CN 200980122733A CN 102066241 B CN102066241 B CN 102066241B
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compound
mixture
feooh
general formula
lithium
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CN102066241A (zh
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H·希布施特
B·罗伯茨
J·K·拉姆派尔特
K·布拉姆尼克
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Advanced Lithium Electrochemistry Co Ltd
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BASF SE
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/30—Alkali metal phosphates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/08—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances oxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/02—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
CN200980122733XA 2008-04-17 2009-04-16 制备含锂、铁和磷酸根的结晶材料的方法 Active CN102066241B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US4580208P 2008-04-17 2008-04-17
US61/045,802 2008-04-17
PCT/EP2009/054488 WO2009127674A1 (en) 2008-04-17 2009-04-16 Process for the preparation of crystalline lithium-, iron- and phosphate-comprising materials

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CN102066241A CN102066241A (zh) 2011-05-18
CN102066241B true CN102066241B (zh) 2013-11-13

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US (2) US20110049443A1 (enExample)
EP (1) EP2285740B1 (enExample)
JP (1) JP2011519806A (enExample)
KR (1) KR101592049B1 (enExample)
CN (1) CN102066241B (enExample)
CA (1) CA2721029A1 (enExample)
TW (1) TW201010944A (enExample)
WO (1) WO2009127674A1 (enExample)

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KR101063214B1 (ko) * 2008-11-28 2011-09-07 전자부품연구원 리튬이차전지용 구형 양극 활물질 제조방법
TWI474970B (zh) * 2008-12-29 2015-03-01 Basf Se 於水熱條件下合成鋰－金屬－磷酸鹽
WO2010106035A2 (en) 2009-03-17 2010-09-23 Basf Se Synthesis of lithium-iron-phosphates
WO2010149681A1 (en) 2009-06-24 2010-12-29 Basf Se Process for the preparation of lifepo4-carbon composites
JP5729802B2 (ja) * 2009-12-25 2015-06-03 三菱マテリアル株式会社 Ｌｉイオン電池用正極活物質、およびその製造方法
CN101989653B (zh) * 2010-05-06 2012-10-31 黄兵 超微球颗粒连接的锂离子电池用球形正极材料及其制备方法
FR2978137A1 (fr) * 2011-07-21 2013-01-25 Saint Gobain Ct Recherches Produit fondu a base de lithium
FR2989378B1 (fr) 2012-04-16 2015-10-02 Commissariat Energie Atomique Polymere comme materiau d'electrode pour des batteries secondaires au lithium.
EP2845250B1 (en) * 2012-06-15 2018-05-02 Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. Method of manufacture of an electrode material and an electrode material
US20140328729A1 (en) 2013-05-06 2014-11-06 Liang-Yuh Chen Apparatus for Preparing a Material of a Battery Cell
JP6078650B2 (ja) 2013-08-28 2017-02-08 エルジー・ケム・リミテッド リチウム遷移金属リン酸化物粒子を含む正極活物質、この製造方法、及びこれを含むリチウム二次電池
FR3012450B1 (fr) 2013-10-30 2017-10-13 Commissariat Energie Atomique Materiau d'electrode pour batterie organique
CN103647080A (zh) * 2013-11-15 2014-03-19 成都兴能新材料有限公司 金属离子-LiFePO4-C复合材料的制备方法
CN106684379B (zh) * 2015-11-11 2019-05-10 中国科学院金属研究所 合成具有超高大倍率充放电性能的超薄纳米片状LiFePO4的方法
JP7280722B2 (ja) * 2019-03-15 2023-05-24 積水化学工業株式会社 非水電解質二次電池用正極及びリチウムイオン二次電池
US11121354B2 (en) 2019-06-28 2021-09-14 eJoule, Inc. System with power jet modules and method thereof
CN119657060A (zh) 2019-06-28 2025-03-21 壹久公司 具有辅助气体流的处理系统与方法
US11376559B2 (en) 2019-06-28 2022-07-05 eJoule, Inc. Processing system and method for producing a particulate material
US11673112B2 (en) 2020-06-28 2023-06-13 eJoule, Inc. System and process with assisted gas flow inside a reaction chamber
WO2024038136A1 (en) 2022-08-18 2024-02-22 Integrals Power Improved cathode material for secondary lithium batteries

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KR20110008218A (ko) 2011-01-26
KR101592049B1 (ko) 2016-02-11
JP2011519806A (ja) 2011-07-14
WO2009127674A1 (en) 2009-10-22
CN102066241A (zh) 2011-05-18
EP2285740B1 (en) 2014-05-21
CA2721029A1 (en) 2009-10-22
EP2285740A1 (en) 2011-02-23
US9147877B2 (en) 2015-09-29
US20110049443A1 (en) 2011-03-03
TW201010944A (en) 2010-03-16
US20150090940A1 (en) 2015-04-02

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