CN101679232B - 自由基引发剂体系和生产低密度聚乙烯聚合物的高压、自由基聚合方法 - Google Patents

自由基引发剂体系和生产低密度聚乙烯聚合物的高压、自由基聚合方法 Download PDF

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Publication number
CN101679232B
CN101679232B CN200880015358.4A CN200880015358A CN101679232B CN 101679232 B CN101679232 B CN 101679232B CN 200880015358 A CN200880015358 A CN 200880015358A CN 101679232 B CN101679232 B CN 101679232B
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free radical
high pressure
solvent
density polyethylene
low density
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CN200880015358.4A
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Chinese (zh)
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CN101679232A (zh
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彼得·埃尔茨
奥托·伯比
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
CN200880015358.4A 2007-03-09 2008-02-12 自由基引发剂体系和生产低密度聚乙烯聚合物的高压、自由基聚合方法 Expired - Fee Related CN101679232B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US90599907P 2007-03-09 2007-03-09
US60/905,999 2007-03-09
PCT/US2008/053677 WO2008112373A1 (en) 2007-03-09 2008-02-12 A free radical initiator system and a high pressure, freeradical polymerization process for producing a low density polyethylene polymer

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CN101679232A CN101679232A (zh) 2010-03-24
CN101679232B true CN101679232B (zh) 2014-02-12

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Country Status (12)

Country Link
US (1) US20100093961A1 (https=)
EP (1) EP2121592B1 (https=)
JP (1) JP5415289B2 (https=)
KR (1) KR20100015430A (https=)
CN (1) CN101679232B (https=)
AR (1) AR065665A1 (https=)
BR (1) BRPI0808310A2 (https=)
CA (1) CA2680577A1 (https=)
MX (1) MX2009009638A (https=)
RU (1) RU2009137375A (https=)
TW (1) TW200902561A (https=)
WO (1) WO2008112373A1 (https=)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011008197A1 (en) * 2009-07-14 2011-01-20 Exxonmobil Chemical Patents Inc. High pressure radical polymerization process
EP2576688B1 (en) * 2010-05-27 2017-01-18 Dow Global Technologies LLC Polymer compositions, methods of making the same, and articles prepared from the same
FR2971510B1 (fr) * 2011-02-10 2013-03-22 Arkema France Polymerisation radicalaire de l'ethylene amorcee par des peroxydes organiques a haute productivite
US9334348B2 (en) 2011-11-23 2016-05-10 Dow Global Technologies Llc Low density ethylene-based polymers with extracts at lower molecular weights
US9228036B2 (en) 2011-11-23 2016-01-05 Dow Global Technologies Llc Low density ethylene-based polymers with broad molecular weight distributions and low extractables
CA2907849C (en) * 2013-04-25 2020-03-31 Infiana Germany Gmbh & Co. Kg Multilayer film resistant to linear tear propagation
MY180980A (en) * 2014-08-05 2020-12-15 Exxonmobil Chemical Patents Inc Process for manufacturing ethylene polymers and using modifiers
EP3317307A1 (en) * 2015-06-30 2018-05-09 Dow Global Technologies LLC High pressure free-radical polymerizations
FR3041645B1 (fr) * 2015-09-29 2017-09-08 Arkema France Polymerisation radicalaire de l'ethylene amorcee par un couple de peroxydes organiques a haute productivite
JP6946331B2 (ja) 2016-04-22 2021-10-06 ダウ グローバル テクノロジーズ エルエルシー 清浄な押出コーティング処理のための低揮発性管状低密度エチレン系ポリマーを製造する方法
TWI648328B (zh) * 2016-07-01 2019-01-21 旭化成股份有限公司 Polyethylene resin composition
CA2960665A1 (en) * 2017-03-14 2018-09-14 Nova Chemicals Corporation Method to control melt elasticity in ldpe
CN110770259B (zh) 2017-06-28 2022-05-27 陶氏环球技术有限责任公司 用于生产基于乙烯的聚合物的高压自由基聚合
KR102410623B1 (ko) 2017-10-19 2022-06-17 주식회사 엘지화학 폴리에틸렌 수지의 제조 방법
US11684904B2 (en) 2021-10-14 2023-06-27 Chevron Phillips Chemical Company Lp Initiator injection into high pressure LDPE reactors

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3775341A (en) * 1971-08-02 1973-11-27 Ppg Industries Inc Liquid dialkyl peroxydicarbonate composition
US3956396A (en) * 1974-04-12 1976-05-11 Pennwalt Corporation Safe diacyl peroxide solution compositions
CN1487958A (zh) * 2001-01-23 2004-04-07 �����ɷ� 通过高压法制备乙烯聚合物

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Publication number Priority date Publication date Assignee Title
DE1795294B2 (de) * 1968-09-06 1979-04-26 Basf Ag, 6700 Ludwigshafen Verfahren zum Herstellen von Homo- oder Copolymerisaten des Äthylens
BE756426A (fr) * 1969-09-23 1971-03-22 Basf Ag Procede de preparation d'homo- ou de copolymeres de l'ethylene
DE3486145T2 (de) * 1983-07-11 1993-09-23 Commw Scient Ind Res Org Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere.
US4777230A (en) * 1985-05-30 1988-10-11 Pennwalt Corporation Solution polymerization of acrylic acid derived monomers using tertiary alkyl(ηC5)hydroperoxides
DE3912975A1 (de) * 1989-04-20 1990-11-08 Basf Ag Polyethylen sowie copolymerisate aus ueberwiegenden anteilen von ethylen
US5322912A (en) * 1992-11-16 1994-06-21 Xerox Corporation Polymerization processes and toner compositions therefrom
US6407191B1 (en) * 1998-01-12 2002-06-18 The Dow Chemical Company Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process
DE19829399A1 (de) * 1998-07-01 2000-02-03 Buna Sow Leuna Olefinverb Gmbh Verfahren zur Herstellung von Ethylenhomo- und Ethylencopolymerisaten niederer Dichte
DE10021886A1 (de) * 2000-05-05 2001-11-15 Basell Polyolefine Gmbh Verfahren zum Herstellen von Phillips-Katalysatoren für die Polymerisation von Olefinen mit verbesserten Produktivitäten im Paricle-Form-Verfahren
MX2007005190A (es) * 2004-11-02 2007-11-08 Dow Global Technologies Inc Proceso para la produccion de composiciones de polietileno de baja densidad y polimeros producidos a partir de las mismas.

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3775341A (en) * 1971-08-02 1973-11-27 Ppg Industries Inc Liquid dialkyl peroxydicarbonate composition
US3956396A (en) * 1974-04-12 1976-05-11 Pennwalt Corporation Safe diacyl peroxide solution compositions
CN1487958A (zh) * 2001-01-23 2004-04-07 �����ɷ� 通过高压法制备乙烯聚合物

Also Published As

Publication number Publication date
RU2009137375A (ru) 2011-04-20
US20100093961A1 (en) 2010-04-15
EP2121592A1 (en) 2009-11-25
TW200902561A (en) 2009-01-16
CA2680577A1 (en) 2008-09-18
JP2010520936A (ja) 2010-06-17
WO2008112373A1 (en) 2008-09-18
EP2121592B1 (en) 2012-05-23
KR20100015430A (ko) 2010-02-12
JP5415289B2 (ja) 2014-02-12
AR065665A1 (es) 2009-06-24
MX2009009638A (es) 2009-09-22
CN101679232A (zh) 2010-03-24
BRPI0808310A2 (pt) 2014-07-08

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