TW200902561A - A free radical initiator system and a high pressure, freeradical polymerization process for producing a low density polyethylene polymer - Google Patents
A free radical initiator system and a high pressure, freeradical polymerization process for producing a low density polyethylene polymer Download PDFInfo
- Publication number
- TW200902561A TW200902561A TW097108111A TW97108111A TW200902561A TW 200902561 A TW200902561 A TW 200902561A TW 097108111 A TW097108111 A TW 097108111A TW 97108111 A TW97108111 A TW 97108111A TW 200902561 A TW200902561 A TW 200902561A
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- Taiwan
- Prior art keywords
- weight
- initiator system
- free radical
- radical initiator
- density polyethylene
- Prior art date
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- 239000003999 initiator Substances 0.000 title claims abstract description 111
- 150000003254 radicals Chemical class 0.000 title claims abstract description 81
- 229920000642 polymer Polymers 0.000 title claims abstract description 32
- 229920001684 low density polyethylene Polymers 0.000 title claims abstract description 26
- 239000004702 low-density polyethylene Substances 0.000 title claims abstract description 26
- 238000010526 radical polymerization reaction Methods 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 20
- 239000002904 solvent Substances 0.000 claims abstract description 56
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- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 36
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 35
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 35
- 239000006184 cosolvent Substances 0.000 claims abstract description 30
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000005977 Ethylene Substances 0.000 claims abstract description 25
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 55
- -1 propenol (1-pentanol) Chemical compound 0.000 claims description 41
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 29
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 16
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
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- 229920000573 polyethylene Polymers 0.000 claims description 6
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- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 4
- 238000002347 injection Methods 0.000 claims description 4
- 239000007924 injection Substances 0.000 claims description 4
- SYJRVVFAAIUVDH-UHFFFAOYSA-N ipa isopropanol Chemical compound CC(C)O.CC(C)O SYJRVVFAAIUVDH-UHFFFAOYSA-N 0.000 claims description 4
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- DOKHEARVIDLSFF-UHFFFAOYSA-N prop-1-en-1-ol Chemical compound CC=CO DOKHEARVIDLSFF-UHFFFAOYSA-N 0.000 claims 1
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- 239000012488 sample solution Substances 0.000 description 63
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- 238000006116 polymerization reaction Methods 0.000 description 37
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- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 23
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- 239000000523 sample Substances 0.000 description 7
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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- YKTNISGZEGZHIS-UHFFFAOYSA-N 2-$l^{1}-oxidanyloxy-2-methylpropane Chemical group CC(C)(C)O[O] YKTNISGZEGZHIS-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
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- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- FQFILJKFZCVHNH-UHFFFAOYSA-N tert-butyl n-[3-[(5-bromo-2-chloropyrimidin-4-yl)amino]propyl]carbamate Chemical compound CC(C)(C)OC(=O)NCCCNC1=NC(Cl)=NC=C1Br FQFILJKFZCVHNH-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US90599907P | 2007-03-09 | 2007-03-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200902561A true TW200902561A (en) | 2009-01-16 |
Family
ID=39430974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW097108111A TW200902561A (en) | 2007-03-09 | 2008-03-07 | A free radical initiator system and a high pressure, freeradical polymerization process for producing a low density polyethylene polymer |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20100093961A1 (https=) |
| EP (1) | EP2121592B1 (https=) |
| JP (1) | JP5415289B2 (https=) |
| KR (1) | KR20100015430A (https=) |
| CN (1) | CN101679232B (https=) |
| AR (1) | AR065665A1 (https=) |
| BR (1) | BRPI0808310A2 (https=) |
| CA (1) | CA2680577A1 (https=) |
| MX (1) | MX2009009638A (https=) |
| RU (1) | RU2009137375A (https=) |
| TW (1) | TW200902561A (https=) |
| WO (1) | WO2008112373A1 (https=) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102471388B (zh) * | 2009-07-14 | 2014-08-06 | 埃克森美孚化学专利公司 | 高压自由基聚合方法 |
| CN102985476B (zh) * | 2010-05-27 | 2015-08-19 | 陶氏环球技术有限责任公司 | 聚合物组合物、其制备方法、以及由该组合物制备的制品 |
| FR2971510B1 (fr) * | 2011-02-10 | 2013-03-22 | Arkema France | Polymerisation radicalaire de l'ethylene amorcee par des peroxydes organiques a haute productivite |
| KR102057264B1 (ko) | 2011-11-23 | 2019-12-19 | 다우 글로벌 테크놀로지스 엘엘씨 | 넓은 분자량 분포 및 낮은 추출가능물을 갖는 저밀도 에틸렌-계 중합체 |
| CN104053717B (zh) | 2011-11-23 | 2016-08-31 | 陶氏环球技术有限责任公司 | 具有较低分子量的提取物的低密度的基于乙烯的聚合物 |
| CA2907849C (en) * | 2013-04-25 | 2020-03-31 | Infiana Germany Gmbh & Co. Kg | Multilayer film resistant to linear tear propagation |
| KR101902971B1 (ko) * | 2014-08-05 | 2018-10-02 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 개질제를 이용하는 에틸렌 중합체의 제조 방법 |
| CN107873035B (zh) * | 2015-06-30 | 2021-04-09 | 陶氏环球技术有限责任公司 | 高压自由基聚合 |
| FR3041645B1 (fr) * | 2015-09-29 | 2017-09-08 | Arkema France | Polymerisation radicalaire de l'ethylene amorcee par un couple de peroxydes organiques a haute productivite |
| US10815321B2 (en) | 2016-04-22 | 2020-10-27 | Dow Global Technologies Llc | Methods for producing low volatile tubular low density ethylene-based polymers for clean extrusion coating processing |
| TWI648328B (zh) * | 2016-07-01 | 2019-01-21 | 旭化成股份有限公司 | Polyethylene resin composition |
| CA2960665A1 (en) * | 2017-03-14 | 2018-09-14 | Nova Chemicals Corporation | Method to control melt elasticity in ldpe |
| US11072669B2 (en) | 2017-06-28 | 2021-07-27 | Dow Global Technologies Llc | High pressure, free radical polymerizations to produce ethylene-based polymers |
| KR102410623B1 (ko) | 2017-10-19 | 2022-06-17 | 주식회사 엘지화학 | 폴리에틸렌 수지의 제조 방법 |
| US11684904B2 (en) | 2021-10-14 | 2023-06-27 | Chevron Phillips Chemical Company Lp | Initiator injection into high pressure LDPE reactors |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1795294B2 (de) * | 1968-09-06 | 1979-04-26 | Basf Ag, 6700 Ludwigshafen | Verfahren zum Herstellen von Homo- oder Copolymerisaten des Äthylens |
| BE756426A (fr) * | 1969-09-23 | 1971-03-22 | Basf Ag | Procede de preparation d'homo- ou de copolymeres de l'ethylene |
| US3775341A (en) * | 1971-08-02 | 1973-11-27 | Ppg Industries Inc | Liquid dialkyl peroxydicarbonate composition |
| US3956396A (en) * | 1974-04-12 | 1976-05-11 | Pennwalt Corporation | Safe diacyl peroxide solution compositions |
| DE3486145T2 (de) * | 1983-07-11 | 1993-09-23 | Commw Scient Ind Res Org | Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere. |
| US4777230A (en) * | 1985-05-30 | 1988-10-11 | Pennwalt Corporation | Solution polymerization of acrylic acid derived monomers using tertiary alkyl(ηC5)hydroperoxides |
| DE3912975A1 (de) * | 1989-04-20 | 1990-11-08 | Basf Ag | Polyethylen sowie copolymerisate aus ueberwiegenden anteilen von ethylen |
| US5322912A (en) * | 1992-11-16 | 1994-06-21 | Xerox Corporation | Polymerization processes and toner compositions therefrom |
| US6407191B1 (en) * | 1998-01-12 | 2002-06-18 | The Dow Chemical Company | Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process |
| DE19829399A1 (de) * | 1998-07-01 | 2000-02-03 | Buna Sow Leuna Olefinverb Gmbh | Verfahren zur Herstellung von Ethylenhomo- und Ethylencopolymerisaten niederer Dichte |
| DE10021886A1 (de) * | 2000-05-05 | 2001-11-15 | Basell Polyolefine Gmbh | Verfahren zum Herstellen von Phillips-Katalysatoren für die Polymerisation von Olefinen mit verbesserten Produktivitäten im Paricle-Form-Verfahren |
| DE10102937A1 (de) * | 2001-01-23 | 2002-07-25 | Basf Ag | Verfahren zur Herstellung von Ethylenpolymerisaten im Hochdruckverfahren |
| ATE534676T1 (de) * | 2004-11-02 | 2011-12-15 | Dow Global Technologies Llc | Verfahren zur herstellung von polyethylenzusammensetzungen mit niedriger dichte und damit hergestellte polymere |
-
2008
- 2008-02-12 CN CN200880015358.4A patent/CN101679232B/zh not_active Expired - Fee Related
- 2008-02-12 RU RU2009137375/04A patent/RU2009137375A/ru unknown
- 2008-02-12 EP EP08729613A patent/EP2121592B1/en not_active Not-in-force
- 2008-02-12 MX MX2009009638A patent/MX2009009638A/es not_active Application Discontinuation
- 2008-02-12 KR KR1020097021002A patent/KR20100015430A/ko not_active Withdrawn
- 2008-02-12 BR BRPI0808310-0A patent/BRPI0808310A2/pt not_active IP Right Cessation
- 2008-02-12 WO PCT/US2008/053677 patent/WO2008112373A1/en not_active Ceased
- 2008-02-12 CA CA002680577A patent/CA2680577A1/en not_active Abandoned
- 2008-02-12 JP JP2009552785A patent/JP5415289B2/ja not_active Expired - Fee Related
- 2008-02-12 US US12/529,787 patent/US20100093961A1/en not_active Abandoned
- 2008-03-07 AR ARP080100972A patent/AR065665A1/es unknown
- 2008-03-07 TW TW097108111A patent/TW200902561A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MX2009009638A (es) | 2009-09-22 |
| JP5415289B2 (ja) | 2014-02-12 |
| AR065665A1 (es) | 2009-06-24 |
| JP2010520936A (ja) | 2010-06-17 |
| EP2121592A1 (en) | 2009-11-25 |
| BRPI0808310A2 (pt) | 2014-07-08 |
| RU2009137375A (ru) | 2011-04-20 |
| CN101679232A (zh) | 2010-03-24 |
| WO2008112373A1 (en) | 2008-09-18 |
| KR20100015430A (ko) | 2010-02-12 |
| CN101679232B (zh) | 2014-02-12 |
| CA2680577A1 (en) | 2008-09-18 |
| EP2121592B1 (en) | 2012-05-23 |
| US20100093961A1 (en) | 2010-04-15 |
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