CN101607209B - 废气净化用催化剂的制备方法与废气净化方法 - Google Patents

废气净化用催化剂的制备方法与废气净化方法 Download PDF

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Publication number
CN101607209B
CN101607209B CN200910139514.4A CN200910139514A CN101607209B CN 101607209 B CN101607209 B CN 101607209B CN 200910139514 A CN200910139514 A CN 200910139514A CN 101607209 B CN101607209 B CN 101607209B
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CN
China
Prior art keywords
catalyst
zsm
zeolite
copper
type zeolite
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Expired - Fee Related
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CN200910139514.4A
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English (en)
Chinese (zh)
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CN101607209A (zh
Inventor
松元武史
小林孝夫
中根卓司
宇野高弘
堀内真
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Umicore Shokubai Japan Co Ltd
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ICT Co Ltd
International Catalyst Technology Inc
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/208—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/206—Rare earth metals
    • B01D2255/2065—Cerium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/7615—Zeolite Beta
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
CN200910139514.4A 2002-11-18 2003-11-18 废气净化用催化剂的制备方法与废气净化方法 Expired - Fee Related CN101607209B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2002333629 2002-11-18
JP2002-333629 2002-11-18
JP2002333629 2002-11-18

Related Parent Applications (1)

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CNA200380103507XA Division CN1711135A (zh) 2002-11-18 2003-11-18 废气净化用催化剂与废气净化方法

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CN101607209A CN101607209A (zh) 2009-12-23
CN101607209B true CN101607209B (zh) 2014-07-02

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CNA200380103507XA Pending CN1711135A (zh) 2002-11-18 2003-11-18 废气净化用催化剂与废气净化方法

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Country Status (8)

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US (1) US7393804B2 (ja)
EP (1) EP1579911A4 (ja)
JP (1) JP4425797B2 (ja)
KR (1) KR100719074B1 (ja)
CN (2) CN101607209B (ja)
CA (1) CA2506470C (ja)
WO (1) WO2004045766A1 (ja)
ZA (1) ZA200503957B (ja)

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US8381299B2 (en) 2006-02-28 2013-02-19 The Trustees Of Columbia University In The City Of New York Systems, methods, and media for outputting a dataset based upon anomaly detection
DE102006020158B4 (de) * 2006-05-02 2009-04-09 Argillon Gmbh Extrudierter Vollkatalysator sowie Verfahren zu seiner Herstellung
CN101134172B (zh) * 2006-08-31 2010-10-27 中国石油化工股份有限公司 一种烃类转化催化剂
EP3418807A1 (en) * 2006-08-31 2018-12-26 Nikon Corporation Exposure apparatus, exposure method, and device manufacturing method
EP2988320B1 (en) * 2006-08-31 2019-04-10 Nikon Corporation Exposure apparatus, exposure method, and device manufacturing method
CN101134913B (zh) * 2006-08-31 2011-05-18 中国石油化工股份有限公司 一种烃类催化转化方法
US8789172B2 (en) 2006-09-18 2014-07-22 The Trustees Of Columbia University In The City Of New York Methods, media, and systems for detecting attack on a digital processing device
JP5141063B2 (ja) * 2007-03-26 2013-02-13 トヨタ自動車株式会社 排ガス浄化装置
DE102007018612A1 (de) * 2007-04-19 2008-10-23 Süd-Chemie AG Katalysatorformkörper
US9079162B2 (en) 2008-04-28 2015-07-14 BASF SE Ludwigshafen Fe-BEA/Fe-MFI mixed zeolite catalyst and process for the treatment of NOX in gas streams
JP2009262098A (ja) * 2008-04-28 2009-11-12 Ne Chemcat Corp 選択還元触媒を用いた排気ガス浄化方法
US20110258994A1 (en) * 2008-12-12 2011-10-27 Korea Institute Of Energy Research Bifunctional Catalyst for Decomposition and Oxidation of Nitrogen Monoxide, Composite Catalyst Including the Same for Apparatus to Decrease Exhaust Gas, and Method for Preparation Thereof
CN101579639B (zh) * 2009-06-24 2011-10-05 江苏优士化学有限公司 一种用于合成脂肪腈的催化剂及其制备方法和应用
EP2527036A4 (en) 2010-01-20 2014-03-05 Jx Nippon Oil & Energy Corp CATALYST FOR USE IN THE PRODUCTION OF MONOCYCLIC AROMATIC HYDROCARBONS AND METHOD FOR THE PRODUCTION OF MONOCYCLIC AROMATIC HYDROCARBONS
JP2013523442A (ja) * 2010-04-08 2013-06-17 ビーエーエスエフ ソシエタス・ヨーロピア Ｆｅ−ＢＥＡ／Ｆｅ−ＭＦＩ混合ゼオライト触媒及びガス流中のＮＯＸ処理方法
WO2012131914A1 (ja) * 2011-03-29 2012-10-04 イビデン株式会社 ハニカム構造体及び排ガス浄化装置
CN102258941A (zh) * 2011-04-14 2011-11-30 李书伟 一种改性活化分子筛除味喷剂溶液及其制备方法
RU2543168C2 (ru) * 2011-09-07 2015-02-27 Закрытое Акционерное Общество "Саровские Лаборатории", Российская Федерация, Состав адсорбента для удаления токсичных веществ из выхлопных газов автомобиля и способ его изготовления
CN104066508B (zh) * 2011-10-05 2018-02-06 巴斯夫欧洲公司 Cu‑CHA/Fe‑BEA混合沸石催化剂和处理气流中的NOX的方法
US9999877B2 (en) 2011-10-05 2018-06-19 Basf Se Cu-CHA/Fe-BEA mixed zeolite catalyst and process for the treatment of NOx in gas streams
JP6239584B2 (ja) 2013-02-21 2017-11-29 Ｊｘｔｇエネルギー株式会社 単環芳香族炭化水素の製造方法
DE102015204012A1 (de) * 2015-03-05 2016-09-08 Clariant International Ltd. SCR-Katalysator mit verbesserter Haftung
CN105413738B (zh) * 2015-11-06 2019-01-15 中国第一汽车股份有限公司 高能球磨法scr分子筛催化剂及其制备方法
CN105233579A (zh) * 2015-11-13 2016-01-13 朱忠良 一种防治雾霾的过滤网
CN105595467A (zh) * 2015-11-13 2016-05-25 无锡桥阳机械制造有限公司 一种防治雾霾的口罩
CN105249563A (zh) * 2015-11-13 2016-01-20 无锡桥阳机械制造有限公司 一种防治雾霾的口罩
CN105361288A (zh) * 2015-11-13 2016-03-02 无锡桥阳机械制造有限公司 一种防治雾霾的口罩
CN105212359A (zh) * 2015-11-13 2016-01-06 无锡桥阳机械制造有限公司 一种防治雾霾的口罩
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JPH08173761A (ja) * 1994-12-26 1996-07-09 Tosoh Corp 窒素酸化物の除去方法
JPH11300211A (ja) * 1998-04-24 1999-11-02 Nissan Motor Co Ltd 排気ガス浄化用触媒及び排気ガス浄化方法
CN1320475A (zh) * 2000-04-22 2001-11-07 dmc2德古萨金属催化剂塞尔德克股份公司 还原氮氧化物的方法及催化剂

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JP2536104B2 (ja) 1988-11-19 1996-09-18 トヨタ自動車株式会社 排ガス浄化用触媒
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JPH078754A (ja) * 1993-06-11 1995-01-13 Tosoh Corp 排ガス浄化方法
JPH08173761A (ja) * 1994-12-26 1996-07-09 Tosoh Corp 窒素酸化物の除去方法
JPH11300211A (ja) * 1998-04-24 1999-11-02 Nissan Motor Co Ltd 排気ガス浄化用触媒及び排気ガス浄化方法
CN1320475A (zh) * 2000-04-22 2001-11-07 dmc2德古萨金属催化剂塞尔德克股份公司 还原氮氧化物的方法及催化剂

Also Published As

Publication number Publication date
JPWO2004045766A1 (ja) 2006-03-16
KR100719074B1 (ko) 2007-05-16
CA2506470C (en) 2010-10-26
CA2506470A1 (en) 2004-06-03
KR20050072141A (ko) 2005-07-08
US20060014630A1 (en) 2006-01-19
EP1579911A4 (en) 2010-06-02
US7393804B2 (en) 2008-07-01
WO2004045766A1 (ja) 2004-06-03
CN101607209A (zh) 2009-12-23
ZA200503957B (en) 2006-06-28
EP1579911A1 (en) 2005-09-28
JP4425797B2 (ja) 2010-03-03
CN1711135A (zh) 2005-12-21

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