CN101098986A - 作为转化型涂层或作为漆中防腐蚀添加剂的季铵盐 - Google Patents
作为转化型涂层或作为漆中防腐蚀添加剂的季铵盐 Download PDFInfo
- Publication number
- CN101098986A CN101098986A CNA2005800465008A CN200580046500A CN101098986A CN 101098986 A CN101098986 A CN 101098986A CN A2005800465008 A CNA2005800465008 A CN A2005800465008A CN 200580046500 A CN200580046500 A CN 200580046500A CN 101098986 A CN101098986 A CN 101098986A
- Authority
- CN
- China
- Prior art keywords
- ion
- paint
- alkyl
- quaternary ammonium
- negatively charged
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 34
- 150000003242 quaternary ammonium salts Chemical class 0.000 title claims abstract description 27
- 238000007739 conversion coating Methods 0.000 title claims abstract description 18
- 239000011248 coating agent Substances 0.000 title claims description 28
- 239000003973 paint Substances 0.000 claims abstract description 127
- -1 halogen anions Chemical class 0.000 claims abstract description 39
- 238000000034 method Methods 0.000 claims abstract description 30
- 229910052751 metal Inorganic materials 0.000 claims abstract description 22
- 239000002184 metal Substances 0.000 claims abstract description 22
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 16
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 239000000654 additive Substances 0.000 claims abstract description 8
- 239000000758 substrate Substances 0.000 claims abstract description 6
- 229910000831 Steel Inorganic materials 0.000 claims description 50
- 239000010959 steel Substances 0.000 claims description 50
- 239000007921 spray Substances 0.000 claims description 42
- 229910052573 porcelain Inorganic materials 0.000 claims description 29
- 239000000839 emulsion Substances 0.000 claims description 28
- 150000002500 ions Chemical class 0.000 claims description 27
- 239000002253 acid Substances 0.000 claims description 16
- 125000003118 aryl group Chemical group 0.000 claims description 15
- 239000010452 phosphate Substances 0.000 claims description 15
- 229920006395 saturated elastomer Polymers 0.000 claims description 14
- 125000002015 acyclic group Chemical group 0.000 claims description 12
- YWWNNLPSZSEZNZ-UHFFFAOYSA-N n,n-dimethyldecan-1-amine Chemical compound CCCCCCCCCCN(C)C YWWNNLPSZSEZNZ-UHFFFAOYSA-N 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 9
- 150000001735 carboxylic acids Chemical class 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 7
- 125000000129 anionic group Chemical group 0.000 claims description 7
- 229940063013 borate ion Drugs 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 6
- 150000001450 anions Chemical class 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- GQZXNSPRSGFJLY-UHFFFAOYSA-N hydroxyphosphanone Chemical compound OP=O GQZXNSPRSGFJLY-UHFFFAOYSA-N 0.000 claims description 5
- 229940005631 hypophosphite ion Drugs 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 3
- 239000004816 latex Substances 0.000 claims description 3
- 229920000126 latex Polymers 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- 102000014171 Milk Proteins Human genes 0.000 claims description 2
- 108010011756 Milk Proteins Proteins 0.000 claims description 2
- 229920006387 Vinylite Polymers 0.000 claims description 2
- 125000005586 carbonic acid group Chemical group 0.000 claims description 2
- 239000005018 casein Substances 0.000 claims description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 2
- 235000021240 caseins Nutrition 0.000 claims description 2
- 235000021239 milk protein Nutrition 0.000 claims description 2
- 150000005837 radical ions Chemical class 0.000 claims 1
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 abstract description 9
- 238000005260 corrosion Methods 0.000 abstract description 9
- 230000007797 corrosion Effects 0.000 abstract description 9
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract description 8
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 239000001099 ammonium carbonate Substances 0.000 abstract description 4
- 235000012501 ammonium carbonate Nutrition 0.000 abstract description 3
- 235000012538 ammonium bicarbonate Nutrition 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 39
- 238000012360 testing method Methods 0.000 description 30
- 239000008367 deionised water Substances 0.000 description 27
- 229910021641 deionized water Inorganic materials 0.000 description 27
- 150000003839 salts Chemical class 0.000 description 20
- 239000000523 sample Substances 0.000 description 20
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 15
- 239000002131 composite material Substances 0.000 description 13
- 239000000126 substance Substances 0.000 description 11
- 239000008399 tap water Substances 0.000 description 10
- 235000020679 tap water Nutrition 0.000 description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 230000002787 reinforcement Effects 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 4
- 239000013068 control sample Substances 0.000 description 4
- 230000005764 inhibitory process Effects 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000012266 salt solution Substances 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 238000010186 staining Methods 0.000 description 4
- 230000009466 transformation Effects 0.000 description 4
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 4
- 229910000640 Fe alloy Inorganic materials 0.000 description 3
- UCTNAFQDPQLRRG-UHFFFAOYSA-H O[Cr](O)(=O)=O.O[Cr](O)(=O)=O.O[Cr](O)(=O)=O.P.P Chemical compound O[Cr](O)(=O)=O.O[Cr](O)(=O)=O.O[Cr](O)(=O)=O.P.P UCTNAFQDPQLRRG-UHFFFAOYSA-H 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 238000002161 passivation Methods 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical class CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- DGXRZJSPDXZJFG-UHFFFAOYSA-N docosanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCCCCCC(O)=O DGXRZJSPDXZJFG-UHFFFAOYSA-N 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 238000007790 scraping Methods 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- JYCQQPHGFMYQCF-UHFFFAOYSA-N 4-tert-Octylphenol monoethoxylate Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCO)C=C1 JYCQQPHGFMYQCF-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- HFNQLYDPNAZRCH-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O.OC(O)=O HFNQLYDPNAZRCH-UHFFFAOYSA-N 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 238000005524 ceramic coating Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000007744 chromate conversion coating Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000001177 diphosphate Substances 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- HCPOCMMGKBZWSJ-UHFFFAOYSA-N ethyl 3-hydrazinyl-3-oxopropanoate Chemical compound CCOC(=O)CC(=O)NN HCPOCMMGKBZWSJ-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000005294 ferromagnetic effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940033355 lauric acid Drugs 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229920002113 octoxynol Polymers 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- YARNEMCKJLFQHG-UHFFFAOYSA-N prop-1-ene;styrene Chemical compound CC=C.C=CC1=CC=CC=C1 YARNEMCKJLFQHG-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000012421 spiking Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/086—Organic or non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/50—Treatment of iron or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/14—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/14—Nitrogen-containing compounds
- C23F11/141—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/14—Nitrogen-containing compounds
- C23F11/141—Amines; Quaternary ammonium compounds
- C23F11/143—Salts of amines
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemical Treatment Of Metals (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
揭示了作为赋予油漆防腐蚀性质的转化型涂层或添加剂的含有非卤素阴离子(例如碳酸根离子、碳酸氢根离子、磷酸根离子、甘醇酸根离子和它们的混合物)的季铵盐。本发明涉及一种通过施涂包含一或多种季铵碳酸盐或碳酸氢盐的组合物来抑制金属表面腐蚀的方法。本发明还涉及用于金属基材的包含这些化合物的防腐蚀涂层，以及具有这些防腐蚀涂层的金属基材。
Description
发明领域
本发明涉及含有非卤素阴离子如碳酸根离子、碳酸氢根离子、磷酸根离子和甘醇酸根离子的季铵作为转化型涂层的活性成分和作为油漆和涂料的添加剂的用途。
发明背景
在金属表面会与水(无论是液态水或潮湿空气)接触的过程中，总是有腐蚀的危险。当金属本身有腐蚀的倾向且没有被涂布时，该问题尤其严重。
有腐蚀倾向的金属的例子发现于由铁合金制造的冲压金属汽车部件，研磨表面如机器加工的钢部件，和由铸铁制造的机器组件中。
转化型涂层被用来抑制腐蚀并保障油漆对金属表面(特别是对钢)的良好粘着。裸钢与有机涂料不能形成良好的粘合。为了改善金属/有机涂料的粘合，铬酸盐或磷酸盐转化型涂层与钢进行化学反应而形成具有金属-磷酸盐薄层的粗糙表面结构，该结构提供有机聚合物对金属表面的机械和化学联锁(粘着)。参见，例如，Watson，J.″A refresher：Understandingpretreatment″，Powder Coating 1996，7(3)和Ferguson，D.；Monzyk，B.，″Nonpolluting replacement for chromate conversion coating and zinc phosphatein powder coating applications″，Powder Coating 2001，12(7)。在此和下文中，应了解转化型涂层表示一种在金属基材表面上的保护性阻隔薄膜或层，其同时具有腐蚀抑制和油漆粘着的能力，且包括：(i)有机薄膜，(ii)由金属蚀刻和再沉积方法得到的无机氧化物，(iii)由真实沉积方法得到的无机氧化物，或(iv)任何来自(i)、(ii)和(iii)的无机和有机材料的混合物。最广泛使用的转化型涂层是铬酸盐处理、磷铬酸盐处理(phosphochromating)和磷酸锌处理。据信铬酸盐处理产生较好的腐蚀抑制作用，而磷铬酸盐处理产生较好的油漆粘着。在将转化型涂层施加到金属表面之前，必须清理金属表面以除去任何在金属表面上的油脂。然后可通过浸涂或喷涂来施加转化型涂层。铬酸盐和磷铬酸盐转化型涂层是最通常的化学转化型涂层，但是因为健康、安全和环境方面的考虑，需要其它类型的转化型涂层。
发明概述
研究发现，含有非卤素阴离子如碳酸氢根离子、碳酸根离子、磷酸根离子和甘醇酸根离子的季铵盐，更具体地，含有作为阴离子的碳酸氢根离子、碳酸根离子、磷酸根离子和甘醇酸根离子的二烷基二甲基铵盐、和它们的各种组合，具有作为金属表面(特别是钢表面)的转化型涂层的适用性。另外，已发现所述季铵盐类物能够产生所需的表面转变，例如所需的表面氧化物(即磁铁矿，Fe3O4)在钢基材上的生长。此氧化物的形成产生粘着至金属基材的明显的微晶区，油漆之类的涂层预期对此区表现出改善的粘着性。另外，所述季铵盐可直接加到油漆中，以提供油漆对金属表面的较好的粘着性，从而提高耐腐蚀性。
季铵碳酸盐和碳酸氢盐的腐蚀抑制性质已揭示于同在申请中的美国专利申请10/810279号(US 2005/0003978A1)中。此外，业已发现，在抑制剂薄膜下，受保护的钢表面生长出所需的表面氧化物(也就是磁铁矿，Fe3O4)。此氧化物的形成产生一些预期有机涂料如油漆会对其表现出改善的粘着性的区域。
发明详述
令人惊喜地发现，某些含有非卤素阴离子的季铵盐，例如碳酸二-正-癸基二甲基铵，当被涂覆至铁和铁合金如钢的表面时，具有在比先前已知的温和很多的温度条件下在铁和铁合金如钢的表面上产生已知的所需的转变的倾向。虽然钢表面在＞110℃时发生热诱发转变在本领域是已知的，但进行该转变需要高温迄今为止限制了其商业性开发。然而，上述季铵盐看来能够在低至室温的温度下产生相似的钢表面的转变。
另外，上述季铵盐(纯净的或以调配物形式)的独特性质允许在最后涂层涂覆之前进行一步式金属表面处理工艺。已经发现，金属暴露于它们的溶液将会在为最后涂层涂覆做准备的同时对金属表面完成清洁、腐蚀抑制和底漆涂布。
这明显优于现行方法，现行方法是以逐步方式完成下列独立功能，并且产生大量必须加以处置的工业污水：
a)用油钝化原料金属以防止快速生锈(flash rust)。
b)除去且废弃钝化油
c)在施加最后涂层之前，金属表面用转化型涂料溶液(酸性，含重金属的化学品)处理且固化。
也已经发现根据本发明处理的钢表面能抵抗快速生锈。当新形成的裸钢表面暴露于水中且发生反应形成红色氢氧化铁锈层时，发生快速生锈。
根据本发明处理的板卷型钢(coiled sheet steel)可抵抗在湿气冷凝在卷薄板(coils)边缘上时发生的边缘沾染。目前钢板在储存或运输之前先用轻油喷涂。该油必须在进行其它表面处理或涂布之前先除去。
根据本发明形成的氧化物薄膜具有作为钢的底下层油漆(under-paint)转化型涂层或底漆的可能性。裸钢不能与有机涂料形成良好的粘合。为了改善金属/有机涂料的粘合，铬酸盐或磷酸盐转化型涂层与钢进行化学反应，形成具有金属-磷酸盐板体的粗糙表面结构，该结构提供有机聚合物对金属表面的机械和化学联锁(粘着)性。
还发现本发明的转化型涂层和防腐蚀漆在刮擦时表现出一定的自行复原性，这意味着即使是刮痕的“裸”金属表面也显示一些钝化作用，这可能是由于季铵盐从周围涂料的迁移引起的。在某些情况中，还观察到永久的氧化物转变，结果导致刮擦区长期的钝化。这是一种类似于在铬涂布的金属表面上观察到的自行复原的效果。
特别地，本发明涉及一种将转化型涂层施加到金属基材表面的方法，该方法包括使基材与一种组合物接触的步骤，该组合物包含：
(a)至少一种含有非卤素阴离子的季铵盐，和
(b)任选地，溶剂。
较佳地，季铵盐的通式如下：
其中R1是任选地芳基取代的C1-20烷基，R2是任选地芳基取代的C1-20烷基，R3和R4彼此独立地是C1-4烷基，Xn-是一种选自下组的阴离子：氢氧根离子、碳酸根离子、碳酸氢根离子、磷酸根离子、亚磷酸根离子、次磷酸根离子、硝酸根离子、硫酸根离子、硼酸根离子、饱和及不饱和无环C1-20一元羧酸的阴离子、饱和及不饱和C2-20二元羧酸的阴离子和羟基取代的羧酸的阴离子，n表示所述阴离子的负电荷的适当数目。
在此和下文中，C1-20烷基是具有1到20个碳原子的直链或支链烷基，包括但不限于甲基、乙基、丙基、异丙基、丁基、异丁基、仲丁基、叔丁基、戊基、异戊基、己基、庚基、辛基、壬基、异壬基、癸基、十二烷基、十四烷基、十六烷基、十八烷基和二十烷基(icosyl)。芳基取代的C1-20烷基是任何具有芳基(特别是苯基)作为取代基的上述基。优选的芳基取代的C1-20烷基的例子是苄基、苯乙基和苯丙基。
应了解术语“磷酸根离子”包括磷酸的酸和中性盐，即，磷酸二氢根离子(H2PO4 2-)、磷酸氢根离子(HPO4 2-)和磷酸根离子(PO4 3-)，以及寡-和多磷酸的盐，例如二磷酸盐(焦磷酸盐)和三磷酸盐。
亚磷酸根离子是含有阴离子H2PO3 -和/或HPO3 2-的亚磷酸的盐。
硫酸根离子是硫酸氢根离子(HSO4 -)和硫酸根离子(SO4 2-)及二硫酸根离子(S2O7 2-)和相关阴离子。
硼酸根离子是任何衍生自硼酸(H3BO3)和各种多硼酸的阴离子。
饱和及不饱和无环C1-20一元羧酸具体是烷酸，例如甲酸、乙酸、丙酸、丁酸、戊酸、己酸(hecanoic acid)、辛酸、癸酸、十二酸、十四酸、十六酸、十八酸和二十酸；或烯酸，例如丙烯酸、甲基丙烯酸、油酸和亚麻酸。
饱和及不饱和无环C2-20二元羧酸具体是烷二酸，例如草酸、丙二酸、丁二酸、戊二酸和己二酸；或烯二酸，例如富马酸或马来酸。
羟基-取代的羧酸是任何除了含有羧酸基外还具有至少一个羟基的羧酸，例如甘醇酸、苹果酸、柠檬酸或水杨酸。
表现出上述效果的更优选的季铵盐是季铵碳酸盐、季铵碳酸氢盐、季铵磷酸盐和季铵甘醇酸盐。
更佳地，通式I的季铵中的R3和R4是甲基。
在一个优选的实施方式中，R1是甲基。
在另一个优选的实施方式中，R2是苄基或苯乙基。
在另一个优选的实施方式中，R1和R2是相同的C1-20烷基。
在一个优选的实施方式中，R1和R2是C10烷基。
在一个更优选的实施方式中，R1和R2是正-C10烷基。
在一个特别优选的实施方式中，季铵盐是碳酸二正癸基二甲基铵和/或碳酸氢二正癸基二甲基铵。
较佳地，金属基材是钢。
更佳地，钢是板卷型钢。
本发明的另一个目的是一种制件，其包括根据上述方法或其任何优选实施方式处理过的金属基材。
再次地，优选的金属基材是钢。
本发明的另一个目的是一种防腐蚀漆，其包含：
(a)至少一种含有非卤素阴离子的季铵盐，
(b)粘合剂，
(c)任选地，溶剂和
(d)任选地，颜料。
如在上述方法中，防腐蚀漆中的季铵盐优选具有以下通式：
1/n Xn- (I)
其中R1是任选地芳基取代的C1-20烷基，R2是任选地芳基取代的C1-20烷基，R3和R4彼此独立地是C1-4烷基，Xn-是选自下组的阴离子：氢氧根离子、碳酸根离子、碳酸氢根离子、磷酸根离子、硝酸根离子、硫酸根离子、硼酸根离子、饱和及不饱和无环C1-20一元羧酸的阴离子、饱和及不饱和C2-12二元羧酸的阴离子和羟基取代的羧酸的阴离子，n表示所述阴离子的负电荷的适当数目。
在上述方法中的季铵盐的更优选的实施方式类似地适用于防腐蚀漆。
较佳地，粘合剂选自下组：丙烯酸树脂、酪蛋白(乳蛋白质)、乙烯基树脂、乳胶漆树脂、乙酸酯树脂、环氧树脂和它们的混合物。
在一个优选的实施方式中，防腐蚀漆是乳胶漆。
在另一个优选的实施方式中，防腐蚀漆是瓷喷漆。
在一个更优选的实施方式中，防腐蚀漆是E-涂布漆。
在一个更优选的实施方式中，防腐蚀漆为丙烯酸漆。
本发明的另一个目的是制件，该制件包括用上述防腐蚀漆涂布的金属基材。关于防腐蚀漆、包含在该油漆中的铵盐及金属基材的性质的全部优选实施方式同样适用于所述制造件。
本发明的另一个目的是具有以下通式的季铵盐的应用：
1/n Xn- (I)
其中R1是任选地芳基取代的C1-20烷基，R2是任选地芳基取代的C1-20烷基，R3和R4彼此独立地是C1-4烷基，Xn-是选自下组的阴离子：氢氧根离子、碳酸根离子、碳酸氢根离子、磷酸根离子、亚磷酸根离子、次磷酸根离子、硝酸根离子、硫酸根离子、硼酸根离子、饱和及不饱和无环C1-20一元羧酸的阴离子、饱和及不饱和无环C2-20二元羧酸的阴离子和羟基取代的羧酸的阴离子，n表示作为油漆或涂料中的防腐蚀添加剂的所述阴离子的负电荷的适当数目。
上述方法中的季铵盐的更优选的实施方式类似地适合用作防腐蚀添加剂。
附图说明
图1是钢表面在含有0.1％碳酸二正癸基二甲基铵的3.5％NaCl水溶液中浸渍二个星期之后的SEM显微照片。注意表面上的六角板体的形成。
图2是钢表面在含有0.1％碳酸二正癸基二甲基铵的3.5％NaCl水溶液中浸渍二个月之后的SEM显微照片。该表面布满板体和球体颗粒。这些相之一为铁磁体(磁铁矿，Fe3O4)。
图3是钢表面在0.1％甘醇酸二正癸基二甲基铵的0.1％自来水溶液中在70℃浸渍48小时之后的SEM显微照片。
图4是钢表面在自来水中在70℃浸渍1小时之后(对照实验)的SEM显微照片。
图5描述几种E-涂布的钢样品在盐喷雾暴露之后的油漆剥离试验的结果。
图6描述通过加入季铵盐得到防腐蚀性的乳胶漆涂布的钢样品的盐喷雾试验的结果。
图7描述用含有各种量的季铵盐的光泽保护喷瓷涂布的钢样品的盐喷雾试验的结果。
以下实施例说明了本发明，但是不限制本发明。除非另有指示，所有份数和百分数以重量给出。
实施例1
为了制备钢板(S-46，购自Q-Panel Lab Products，Cleveland，俄亥俄州)，用CarboShield1000(碳酸氢/碳酸二正癸基二甲基铵)、“Phosphoquat”(磷酸二正癸基二甲基铵)和各种相关对照的各种水性处理进行转化型涂层研究(参考：NB5751-001至018)。
直径27.9厘米(11”)和高度27.9厘米(11”)的塑料槽用来处理这些钢板。用9,600克的试验溶液充满塑料槽。在离最高边缘6.35毫米(1/4”)处具有直径为6.35毫米(1/4”)的孔的10.16厘米×15.24厘米×1.59毫米(4”×6”×1/16”)钢(S-46)板通过将塑料吸管通过板中的孔来处理。使用相同的吸管歪斜(skew)最多三个板。使这些板站直，且只有板底碰触槽底。然后将槽在70℃的烤箱中放置一小时。在一小时之后，从槽中移出板，用纸巾弄干然后包装在塑料包装中，贴上标签。所制备的试验溶液可发现于下述列表中。所有的浓度以重量百分数给出。所述CarboShield和Phosphoquat的浓度是活性化合物的真实浓度：
试验溶液
去离子水
自来水(Allendale，NJ)
5％盐(NaCl)水
在去离子水中0.1％CarboShield1000*)
在自来水(Allendale，N.J.)中0.1％CarboShield1000
在5％盐(NaCl)水中0.1％CarboShieldl000
在去离子水中0.1％Phosphoquat**)(pH＝2.5)
在去离子水中0.1％Phosphoquat(pH＝4.0)
在去离子水中0.1％Phosphoquat(pH＝7.5)
在去离子水中0.1％Glycoquat***)(pH＝7.5)
*)CarboShield1000是浓度50％的碳酸(氢)二正癸基二甲基铵(90摩尔％碳酸氢盐，10摩尔％碳酸盐)的水溶液。
**)Phosphoquat是磷酸(氢)二正癸基二甲基铵溶液，通过将得到特定pH值所需的量的85％磷酸水溶液加到CarboShield1000中制得该溶液。
***)Glycoquat是甘醇酸二正癸基二甲基铵溶液，通过将得到特定pH所需的量的甘醇酸加到CarboShield1000中制得该溶液。
在这些钢板用试验溶液处理之后，使用三种不同的油漆方法将它们油漆。各种油漆方法油漆两块钢板。在油漆方法之一中，使用Rust-Oleum专业高效瓷(Hunter Green)喷漆将钢板喷漆。将四块钢板头尾相连平放且用约18克油漆喷漆而涂覆至钢板上表面的油漆喷漆且使其干燥过夜。次日以相似的方法处理板底。使用Rust-Oleum’s Painters Touch(Hunter Green)乳胶漆油漆第二组钢板。用泡沫滚筒将油漆涂覆至钢板。总计共两个油漆涂层涂覆至钢板的每侧。使用己知为E-Coating(电泳涂装)的商业油漆方法油漆第三组钢板。这些样品在Royal E-Coat(Costa Mesa，California)，使用专有方法油漆。使用其中以0.1％、0.5％或1.0％加入CarboShield1000的Rust-Oleum’s Painters Touch(Hunter Green)乳胶漆油漆第四组钢板(未处理)。同样使用其中以所示含量加入CarboShield1000、phosphoquat或glycoquat的Rust-Oleum’s光泽保护喷瓷(Hunter Green)漆油漆第五组钢板(未处理)。
所有油漆样品都送到保证试验服务(Assured Testing Services)(224River Rd.，Ridge-way，PA 15853)进行盐喷雾试验(ASTM B117)。一组钢板在钢板的中心刻划“X”。在5个不同位置测量刻划的X的油漆拉回的数量(毫米)。然后平均这些测量结果。平均值越低，处理性能越好。在试验过程期间，在不同时间间隔测量样品。第二组样品的边缘用蜡涂布以防止边缘效应。对未扰动的钢板表面周期性地评估总可见锈，并从0到100％分级。转化型涂层/油漆/盐喷雾试验结果：
经过喷漆(瓷)的钢板相对于对照样品在油漆粘着性方面显示出最大程度的改善。对于大部份所评估的试验样品，乳胶漆样品在试验样品和相应的对照样品之间没有显示出差异。E-Coat样品显示在144小时之后最少量的油漆拉回。试验样品和对照样品之间存在的差异的相关结果总结在下表1和2中。
表1
| 用水的类型 | 添加剂处理 | 油漆类型 | 等级*)(144小时之后)(油漆拉回的量) |
| 5％盐水 | CarboShield1000 | 瓷喷漆 | 7.36 |
| 5％盐水 | 无 | 瓷喷漆 | 12.36(对照) |
| 无 | 无 | 瓷喷漆 | 13.89(对照) |
| 去离子水 | Phosphoquat(pH＝7.5) | 瓷喷漆 | 5.71 |
| 去离子水 | CarboShield1000 | 瓷喷漆 | 7.63 |
| 去离子水 | 磷酸(pH＝4.0) | 瓷喷漆 | 8.86 |
| 去离子水 | Phosphoquat(pH＝2.5) | 瓷喷漆 | 9.87 |
| 去离子水 | Phosphoquat(pH＝4.0) | 瓷喷漆 | 9.98 |
| 无 | 无 | 瓷喷漆 | 13.89(对照) |
| 去离子水 | 无 | 瓷喷漆 | 15.20(对照) |
| 自来水 | CarboShield1000 | 瓷喷漆 | 10.04 |
| 自来水 | 无 | 瓷喷漆 | 11.86(对照) |
| 无 | 无 | 瓷喷漆 | 13.89(对照) |
| 自来水 | CarboShield1000 | 乳胶漆 | 7.65 |
| 自来水 | 无 | 乳胶漆 | 9.10(对照) |
| 自来水 | 无 | 乳胶漆 | 9.12(对照) |
| 去离子水 | Phosphoquat(pH＝2.5) | 乳胶漆 | 5.95 |
| 去离子水 | 无 | 乳胶漆 | 6.87(对照) |
*)平均油漆剥离(毫米)
此数据清楚地表明当用CarboShield1000和phosphoquat材料预处理测试板时，在商业喷瓷情况中，油漆剥离方面明显改善。
表2：E-涂布的样品的平均油漆剥离(peel-back)数据的总结。
| 盐喷雾小时数 | |||||
| 样品号 | 说明 | 48 | 144 | 384 | 552 |
| B10 | Ecoat对照，盐 | 0.97 | 3.31 | 6.22 | 7.32 |
| A10 | Ecoat，对照，未处理 | 1.15 | 2.42 | 4.61 | 7.24 |
| E32 | 磷酸，对照 | 0.79 | 2.49 | 5.57 | 6.22 |
| B16 | CS1000，Ecoat | 1.65 | 2.71 | 5.74 | 7.11 |
| F8 | Ecoat MP10 | 1.12 | 2.43 | 3.85 | 5.76 |
| D16 | Ecoat CS 1000 | 1.07 | 3.04 | 5.53 | 5.59 |
| E14 | PQ2.5 Ecoat | 1.10 | 2.36 | 4.40 | 5.46 |
| E16 | PQ4.0 Ecoat | 1.53 | 3.07 | 4.15 | 4.93 |
| E18 | PQ7.5，Ecoat | 1.12 | 2.00 | 2.76 | 3.09 |
PQ＝Phosphoquat；C＝CarboShield DI＝去离子水。
列在表2中的结果也被描述在图5中。
制备未刻划的油漆板的复制组而且进行盐喷雾暴露试验。下表3是试验样品和对照样品之间存在的差异的主要结果的总结。
表3：主要的未扰动的试验板表面盐喷雾试验的总结
| 用水 | 添加剂处理 | 油漆类型 | ％可见锈 | 时间(小时) |
| 去离子水 | Phosphoquat(pH＝2.5) | 乳胶漆 | 20％ | 288 |
| 去离子水 | Phosphoquat(pH＝4.0) | 乳胶漆 | 20％ | 288 |
| 去离子水 | Phosphoquat(pH＝7.5) | 乳胶漆 | 40％ | 288 |
| 去离子水 | 磷酸(pH＝4.0) | 乳胶漆 | 10％(对照) | 288 |
| 去离子水 | 无 | 乳胶漆 | 75％(对照) | 288 |
| 5％盐水 | CarboShield1000 | 瓷喷漆 | 20％ | 288 |
| 5％盐水 | 无 | 瓷喷漆 | 75％(对照) | 288 |
| 去离子水 | Phosphoquat(pH＝2.5) | 瓷喷漆 | 10 | 456 |
| 去离子水 | CS MP10 | 瓷喷漆 | 15 | 456 |
| 去离子水 | CarboShield1000 | 瓷喷漆 | 15 | 456 |
| 去离子水 | Phosphoquat(pH＝4.0) | 瓷喷漆 | 40 | 456 |
| 去离子水 | 磷酸(pH＝4.0) | 瓷喷漆 | 40％(对照) | 456 |
| 去离子水 | 无 | 瓷喷漆 | 40 | 456 |
| 去离子水 | Phosphoquat(pH＝7.5) | 瓷喷漆 | 50 | 456 |
| 自来水 | CarboShield1000 | 瓷喷漆 | 5 | 624 |
| 自来水 | 无 | 瓷喷漆 | 15 | 624 |
总的来说，此数据证明了CarboShield1000和phosphoquat类型的“转化型涂层”预处理在盐喷雾试验中明显减少商业乳胶漆和瓷喷漆处理的总锈的显著能力。
表4：加入刷式乳胶漆(brush latex)的CarboShield1000的剥离(peel-back)数据
| “强化掺料(Spiking)”处理 | 剥离等级(144小时) |
| 在乳胶漆中1.0％CarboShield | 3.79 |
| 在乳胶漆中0.1％CarboShield | 5.97 |
| 在乳胶漆中0.5％CarboShield | 6.98 |
| 在乳胶漆中0.0％CarboShield | 9.12 |
此数据显示当CarboShield1000直接结合到商业油漆调配物中时，油漆剥离方面的性质明显改善。
在另一试验中，对用掺入各种量的CarboShield1000(CS)强化的乳胶漆油漆过的未扰动的试验板表面在盐喷雾暴露24到456小时之后测定可见锈的量(％)。数据总结在下表5中且描述于图6中。
表5：用掺入CarboShield1000强化的乳胶漆油漆过的未扰动的试验板表面。
| 时间(小时) | 样品G10.1％CS强化，刷 | 样品G30.5％CS强化 | 样品G50.1％CS强化 | 样品A5刷，未处理 |
| 24 | 1 | 1 | 1 | 1 |
| 48 | 1 | 1 | 1 | 1 |
| 120 | 20 | |||
| 144 | 15 | 20 | 30 | |
| 192 | 25 | |||
| 216 | 25 | 45 | ||
| 288 | 35 | 3 | 80 | |
| 312 | 5 | 35 | ||
| 336 | 10 | |||
| 360 | 45 | 85 | ||
| 456 | 75 | 15 | 40 | 95 |
通过刷涂制备样品。
在另外的试验中，对用含有各种量的CarboShield1000(CS)、phosphoquat和glycoquat的光泽保护喷瓷油漆过的未扰动的试验板表面在盐喷雾暴露24到168小时之后测定可见锈的量(％)。数据总结在下表6中且描述于图7中。
表6：用掺入CarboShield1000(CS)、phosphoquat(PQ)和glycoquat(GQ)强化的光泽保护喷瓷(GPE)油漆的未扰动的试验板表面
| 时间(小时) | |||||
| 样品说明 | 24 | 48 | 72 | 96 | 168 |
| GPE喷瓷(对照) | 0.5 | 15 | 45 | 80 | 87.5 |
| 0.25％GQ(掺料强化) | 0 | 0 | 0 | 0 | 12.5 |
| 0.50％GQ(掺料强化) | 0 | 0 | 0 | 0 | 2.5 |
| 0.25％CS(掺料强化) | 0 | 0 | 0 | 0.5 | 12.5 |
| 0.50％CS(掺料强化) | 0 | 0 | 0 | 0 | 1.5 |
| 0.25％PQ4.0(掺料强化) | 0 | 0 | 0.5 | 0 | 3 |
| 0.50％PQ4.0(掺料强化) | 12.5 | 12.5 | 0 | 35 | 77.5 |
其中可适用的话，所有样品通过刷涂制备以便掺料强化。
表5&6中的数据显示当CarboShield1000或相关phosphoquat或glycoquat材料直接结合到商业油漆调配物中时，耐腐蚀性明显改善。
实施例2&比较例1
根据表7中所列成分的量和处理步骤的顺序调配两种乳胶漆。一种调配物(实施例2)包含CarboShield1000，而另一种(比较例1)包含阴离子表面活性剂(TritonX-100)和常规腐蚀抑制剂(Canguard327)的组合。
表7：调配成分的总结
| 材料/方法步骤 | 比较例1 | 实施例2 |
| 水 | 57.34升 | 57.34升 |
| 丙二醇 | 15.42千克 | 15.42千克 |
| Natrosol250 HBR | 816.5克 | 816.5克 |
| 混合30分钟 | ||
| Tamol850 | 4.536千克 | 4.536千克 |
| TritonX-100 | 1.043千克 | |
| CarboShield1000 | 1.043千克 | |
| DrewplusL-493 | 861.8克 | 861.8克 |
| Canguard327 | 1.021千克 | |
| AMP-95TM | 453.6克 | 453.6克 |
| 混合 | ||
| Ti-PureR-931 | 87.32千克 | 87.32千克 |
| ImsilA-15 | 87.32千克 | 87.32千克 |
| 以4,000RPM高速搅拌30分钟，然后减少速度到1,000RPM | ||
| UCAR123乳胶漆 | 154.0千克 | 154.0千克 |
| Texanol | 3.080千克 | 3.080千克 |
| DrewplusL-493 | 997.9克 | 997.9克 |
| AerosolRM-825 | 907.2克 | 907.2克 |
| 水 | 81.29升 | 81.29升 |
| 在测试材料之前使材料静置48小时以测试稳定性和分散性 |
Natrosol250 HBR是Hercules公司(美国Wilmington，Delaware)的水溶性羟乙基纤维素。
Tamol850是宾夕凡尼亚州费城罗门哈斯(Rohm and Haas)公司的聚丙烯酸钠。
TritonX-100是陶氏化学公司(Dow Chemical Company)的辛基苯酚乙氧基化物。
DrewplusL-493是新泽西州Boonton亚仕兰特用化学品公司(AshlandSpecialty Chemical Company)的消泡剂。
Canguard327是陶氏化学公司的子公司恩琪斯化学公司(ANGUSChemical Company)的基于唑烷的腐蚀抑制剂。
AMP-95TM是含有5％水的2-胺基-2-甲基-1-丙醇，其可得自恩琪斯化学公司。
Ti-PureR-931是杜邦钛科技(Wilmington，Delaware)的金红石二氧化钛颜料。
ImsilA-15是Unimin特用矿物公司(Tamms，Illinois)的微晶硅石。
UCAR123是UCAR乳胶系统(Cary，North Carolina)的高固体苯乙烯-丙烯酸粘合剂。
Texanol是伊士曼化学公司(Eastman Chemical Company)(Kingsport，Tennessee)的单异丁酸2，2，4-三甲基-1，3-戊二醇酯。
AcrosolRM-825是BASF AG(德国Ludwigshafen)的基于丙烯酸酯共聚物的流变改进剂。
测试表7的调配物的储存稳定性和粘度以及金属表面上的油漆薄膜的耐擦洗性和遮盖力。
实施例2的调配物几天内是稳定的，甚至优于比较例1，具有较少的分离。调配物也比比较调配物“更浓稠(creamier)”(更令人想要的)。此观察证实确定CarboShield1000可兼容于乳胶漆系统。
遮盖力是涂层隐藏污点的能力，在比较例中为96.8％，在根据本发明的实施例中为97.2％。这样表明CarboShield1000作用胜于表面活性剂TritonX-100。通过使用在标准Leneta(类型2C)卡上的伯尔得棒下降(birdbar draw down)(76.2微米＝3密耳)的对比率来测量遮盖力，且以黑和白的L-值(实验LAB彩色系统)的比值表示。
由实施例2的调配物制备的油漆薄膜的耐擦洗性为480循环到不合格，而由比较例1的调配物制备的油漆薄膜的耐擦洗性是仅370循环到不合格。明显改善了约30％。使用标准ASTM D2486方法学测量耐擦洗性。
光泽测量显示由两个调配物制备的涂层之间没有显著差异。
实施例2的调配物的史托马(Stormer)粘度明显高于比较例1的史托马粘度，即83KU对73KU。这样可以减少加入调配物的相关增稠剂的量。
Claims (23)
1.一种将转化型涂层涂覆到金属基材表面的方法，所述方法包括使基材与一种组合物接触的步骤，所述组合物包含：
(a)至少一种含有非卤素阴离子的季铵盐，和
(b)任选地，溶剂。
2.如权利要求1所述的方法，其特征在于，所述季铵盐具有以下通式：
其中R1是任选地芳基取代的C1-20烷基，R2是任选地芳基取代的C1-20烷基，R3和R4彼此独立地是C1-4烷基，Xn-是选自下组的阴离子：氢氧根离子、碳酸根离子、碳酸氢根离子、磷酸根离子、亚磷酸根离子、次磷酸根离子、硝酸根离子、硫酸根离子、硼酸根离子、饱和及不饱和无环C1-20一元羧酸的阴离子、饱和及不饱和无环C2-20二元羧酸的阴离子和羟基取代的羧酸的阴离子，n表示所述阴离子的负电荷的适当数目。
3.如权利要求2所述的方法，其特征在于，Xn-选自下组：碳酸根离子、碳酸氢根离子、磷酸根离子和甘醇酸根离子。
4.如权利要求2或3所述的方法，其特征在于，R3和R4是甲基。
5.如权利要求2至4中任一项所述的方法，其特征在于，R1是甲基。
6.如权利要求2至5中任一项所述的方法，其特征在于，R2是苄基或苯乙基。
7.如权利要求2至4中任一项所述的方法，其特征在于，R1和R2是相同的C1-20烷基
8.如权利要求7所述的方法，其特征在于，R1和R2是C10烷基
9.如权利要求8所述的方法，其特征在于，R1和R2是正-C10烷基。
10.如权利要求9所述的方法，其特征在于，所述季铵盐是碳酸二正癸基二甲基铵和/或碳酸氢二正癸基二甲基铵。
11.如权利要求1至10中任一项所述的方法，其特征在于，所述金属基材是钢。
12.如权利要求11所述的方法，其特征在于，所述钢是板卷型钢。
13.一种制件，其包括根据权利要求1至12中任一项所述的方法处理的金属基材。
14.如权利要求13所述的制件，其特征在于，所述金属基材是钢。
15.一种防腐蚀漆，其包含：
(a)至少一种含有非卤素阴离子的季铵盐，
(b)粘合剂，
(c)任选地，溶剂，和
(d)任选地，颜料。
16.如权利要求15所述的防腐蚀漆，其特征在于，所述季铵盐具有以下通式：
其中R1是任选地芳基取代的C1-20烷基，R2是任选地芳基取代的C1-20烷基，R3和R4彼此独立地是C1-4烷基，Xn-是选自下组的阴离子：氢氧根离子、碳酸根离子、碳酸氢根离子、磷酸根离子、亚磷酸根离子、次磷酸根离子、硝酸根离子、硫酸根离子、硼酸根离子、饱和及不饱和无环C1-20一元羧酸的阴离子、饱和及不饱和无环C2-20二元羧酸的阴离子和羟基取代的羧酸的阴离子，n表示所述阴离子的负电荷的适当数目。
17.如权利要求15或16所述的防腐蚀漆，其特征在于，所述粘合剂选自下组：丙烯酸树脂、酪蛋白(乳蛋白质)、乙烯基树脂、乳胶树脂、乙酸酯树脂、环氧树脂和它们的混合物。
18.如权利要求15或16所述的防腐蚀漆，其特征在于，其为乳胶漆。
19.如权利要求15或16所述的防腐蚀漆，其特征在于，其为瓷喷漆。
20.如权利要求15或16所述的防腐蚀漆，其特征在于，其为e-涂布漆。
21.如权利要求15或16所述的防腐蚀漆，其特征在于，其为丙烯酸漆。
22.一种制件，其包括用权利要求15至21中任一项所述的防腐蚀漆涂布的金属基材。
23.一种具有以下通式的季铵盐作为油漆或涂料中的防腐蚀添加剂的用途：
其中R1是任选地芳基取代的C1-20烷基，R2是任选地芳基取代的C1-20烷基，R3和R4彼此独立地是C1-4烷基，Xn-是选自下组的阴离子：氢氧根离子、碳酸根离子、碳酸氢根离子、磷酸根离子、亚磷酸根离子、次磷酸根离子、硝酸根离子、硫酸根离子、硼酸根离子、饱和及不饱和无环C1-20一元羧酸的阴离子、饱和及不饱和无环C2-20二元羧酸的阴离子和羟基取代的羧酸的阴离子，n表示所述阴离子的负电荷的适当数目。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US63479304P | 2004-12-09 | 2004-12-09 | |
| US60/634,793 | 2004-12-09 | ||
| PCT/EP2005/013191 WO2006061230A1 (en) | 2004-12-09 | 2005-12-09 | Quaternary ammonium salts as a conversion coating or as anticorrosive additive in paints |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110061366.6A Division CN102206437B (zh) | 2004-12-09 | 2005-12-09 | 作为转化型涂层或作为漆中防腐蚀添加剂的季铵盐 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101098986A true CN101098986A (zh) | 2008-01-02 |
| CN101098986B CN101098986B (zh) | 2012-05-30 |
Family
ID=35976446
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110061366.6A Expired - Fee Related CN102206437B (zh) | 2004-12-09 | 2005-12-09 | 作为转化型涂层或作为漆中防腐蚀添加剂的季铵盐 |
| CN2005800465008A Expired - Fee Related CN101098986B (zh) | 2004-12-09 | 2005-12-09 | 作为转化型涂层或作为漆中防腐蚀添加剂的季铵盐 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110061366.6A Expired - Fee Related CN102206437B (zh) | 2004-12-09 | 2005-12-09 | 作为转化型涂层或作为漆中防腐蚀添加剂的季铵盐 |
Country Status (19)
| Country | Link |
|---|---|
| US (3) | US20060151071A1 (zh) |
| EP (1) | EP1825023A1 (zh) |
| JP (2) | JP5477835B2 (zh) |
| KR (2) | KR101350720B1 (zh) |
| CN (2) | CN102206437B (zh) |
| AR (1) | AR051707A1 (zh) |
| AU (1) | AU2005313503B2 (zh) |
| BR (1) | BRPI0518858A2 (zh) |
| CA (1) | CA2589980C (zh) |
| EA (1) | EA014610B1 (zh) |
| HK (2) | HK1116839A1 (zh) |
| IN (1) | IN2014DN07328A (zh) |
| MX (1) | MX2007006915A (zh) |
| MY (1) | MY148568A (zh) |
| NO (1) | NO20073050L (zh) |
| NZ (1) | NZ555940A (zh) |
| TW (2) | TWI386519B (zh) |
| WO (1) | WO2006061230A1 (zh) |
| ZA (1) | ZA200705191B (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107683349A (zh) * | 2015-05-29 | 2018-02-09 | 汉高股份有限及两合公司 | 用于在转化处理之前进行调理的包含季胺的预漂洗 |
| US11230768B2 (en) | 2015-04-15 | 2022-01-25 | Henkel Ag & Co. Kgaa | Polymer-containing pre-rinse prior to a conversion treatment |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060261312A1 (en) | 2003-05-28 | 2006-11-23 | Lonza Inc. | Quaternary ammonium salts containing non-halogen anions as anticorrosive agents |
| MY148568A (en) | 2004-12-09 | 2013-04-30 | Lonza Ag | Quaternary ammonium salts as a conversion coating or coating enhancement |
| US7820068B2 (en) * | 2007-02-21 | 2010-10-26 | Houghton Technical Corp. | Chemical assisted lapping and polishing of metals |
| DE102008006391B4 (de) * | 2008-01-28 | 2016-11-17 | Airbus Operations Gmbh | Chromatfreie Zusammensetzung, deren Verwendung als Korrosionsschutz und damit hergestellte Korrosionsschutzbeschichtung für Kraftstofftanks |
| US8070043B1 (en) * | 2010-12-02 | 2011-12-06 | Rohm And Haas Electronic Materials Llc | Curable flux composition and method of soldering |
| US8070045B1 (en) * | 2010-12-02 | 2011-12-06 | Rohm And Haas Electronic Materials Llc | Curable amine flux composition and method of soldering |
| US8070047B1 (en) * | 2010-12-02 | 2011-12-06 | Rohm And Haas Electronic Materials Llc | Flux composition and method of soldering |
| US8070044B1 (en) * | 2010-12-02 | 2011-12-06 | Rohm And Haas Electronic Materials Llc | Polyamine flux composition and method of soldering |
| US8070046B1 (en) * | 2010-12-02 | 2011-12-06 | Rohm And Haas Electronic Materials Llc | Amine flux composition and method of soldering |
| US8430294B2 (en) | 2011-09-30 | 2013-04-30 | Rohm And Haas Electronic Materials Llc | Amine, carboxylic acid flux composition and method of soldering |
| US8430295B2 (en) | 2011-09-30 | 2013-04-30 | Rohm And Haas Electronic Materials Llc | Curable flux composition and method of soldering |
| US8430293B2 (en) | 2011-09-30 | 2013-04-30 | Rohm And Haas Electronic Materials Llc | Curable amine, carboxylic acid flux composition and method of soldering |
| US8434666B2 (en) | 2011-09-30 | 2013-05-07 | Rohm And Haas Electronic Materials Llc | Flux composition and method of soldering |
| US8434667B2 (en) | 2011-09-30 | 2013-05-07 | Rohm And Haas Electronic Materials Llc | Polyamine, carboxylic acid flux composition and method of soldering |
| US9580136B2 (en) | 2012-01-18 | 2017-02-28 | Shimano Inc. | Corrosion resistant bicycle disc brake rotor |
| GB2543488B (en) | 2015-10-14 | 2022-02-02 | Hexigone Inhibitors Ltd | Corrosion inhibitor |
| CA3004081A1 (en) | 2015-11-09 | 2017-05-18 | The Lubrizol Corporation | Using quaternary amine additives to improve water separation |
| CN107141545A (zh) * | 2017-06-22 | 2017-09-08 | 合肥易美特建材有限公司 | 一种以废旧轮胎胶粉为原料的橡胶地板及制备方法 |
Family Cites Families (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2759975A (en) * | 1952-05-28 | 1956-08-21 | Gen Aniline & Film Corp | Mixed alkyl-benzyl-alkylol quaternary ammonium salts |
| US3121091A (en) * | 1960-03-03 | 1964-02-11 | Nalco Chemical Co | Quaternary imidazolium and imidazolinium bisulfites |
| US3365313A (en) * | 1962-06-11 | 1968-01-23 | American Cyanamid Co | Anti-corrosion compositions |
| USRE30796E (en) * | 1962-07-23 | 1981-11-17 | The Dow Chemical Co. | Scale removal, ferrous metal passivation and compositions therefor |
| USRE30714E (en) * | 1965-10-18 | 1981-08-18 | The Dow Chemical Company | Removal of copper containing incrustations from ferrous surfaces |
| US3413160A (en) * | 1965-10-24 | 1968-11-26 | Dow Chemical Co | Passivation of ferrous metal surface |
| US4243417A (en) * | 1975-11-17 | 1981-01-06 | Rohm And Haas Company | Corrosion-inhibiting latex paints |
| US4226624A (en) * | 1978-08-28 | 1980-10-07 | The United States Of America As Represented By The Secretary Of The Navy | Solubilization of hexavalent chromium compounds in organic materials |
| CA1199786A (en) * | 1982-11-10 | 1986-01-28 | Kenneth F. Baxter | Anticorrosive paint |
| US4637899A (en) * | 1984-01-30 | 1987-01-20 | Dowell Schlumberger Incorporated | Corrosion inhibitors for cleaning solutions |
| DE3523088A1 (de) * | 1985-06-28 | 1987-01-08 | Hoechst Ag | Verfahren zur vermeidung der korrosion metallischer werkstoffe |
| IT1207517B (it) * | 1985-12-19 | 1989-05-25 | Enichem Sintesi | Inibitori di corrosione sottosforzo di acciai inossidabili. |
| US4693423A (en) * | 1986-02-25 | 1987-09-15 | The Wooster Brush Company | Power paint sprayer |
| EP0284000B1 (en) * | 1987-03-25 | 1992-09-02 | Hodogaya Chemical Co., Ltd. | Quaternary ammonium salt and electrophotographic toner |
| US5217946A (en) * | 1989-05-01 | 1993-06-08 | W. R. Grace & Co.-Conn. | Tin-containing ceramic composition |
| US5312491A (en) * | 1992-06-08 | 1994-05-17 | Binter Randolph K | Rust inhibiting compositions and methods for protecting metal surfaces with same |
| US5438034A (en) * | 1993-06-09 | 1995-08-01 | Lonza, Inc. | Quaternary ammonium carbonate compositions and preparation thereof |
| JP3209835B2 (ja) * | 1993-08-31 | 2001-09-17 | 日本ペイント株式会社 | 金属缶の化成処理方法 |
| JPH0762369A (ja) * | 1993-08-31 | 1995-03-07 | Nippon Paint Co Ltd | 金属缶の表面処理方法 |
| GB9321917D0 (en) * | 1993-10-23 | 1993-12-15 | Albright & Wilson | Corrosion inhibitors |
| US5409528A (en) * | 1993-12-28 | 1995-04-25 | General Chemical Corporation | Corrosion inhibitors for coatings |
| US5547990A (en) * | 1994-05-20 | 1996-08-20 | Lonza, Inc. | Disinfectants and sanitizers with reduced eye irritation potential |
| US5476615A (en) * | 1994-05-20 | 1995-12-19 | Lonza Inc. | Low foam sanitizers |
| JP2732239B2 (ja) * | 1994-10-21 | 1998-03-25 | 三洋化成工業株式会社 | ウレタン塗料用樹脂組成物 |
| WO1996017518A1 (en) * | 1994-12-09 | 1996-06-13 | Lonza Inc. | Disinfecting use of quaternary ammonium carbonates |
| FR2738837B1 (fr) * | 1995-09-14 | 1997-11-21 | Prod Chim Auxil Synthese | Composition de revetement pour la protection metallique contre la corrosion |
| JPH1055993A (ja) * | 1996-08-09 | 1998-02-24 | Hitachi Ltd | 半導体素子製造用洗浄液及びそれを用いた半導体素子の製造方法 |
| US6118000A (en) * | 1996-11-04 | 2000-09-12 | Hydrochem Industrial Services, Inc. | Methods for preparing quaternary ammonium salts |
| DE19649285A1 (de) * | 1996-11-28 | 1998-06-04 | Henkel Kgaa | Verfahren zum Schutz von Metalloberflächen gegenüber Korrosion in flüssigen oder gasförmigen Medien |
| KR100310169B1 (ko) * | 1997-09-10 | 2001-12-15 | 조민호 | 4급암모늄인산염화합물및그제조방법 |
| ATE289902T1 (de) * | 1999-05-24 | 2005-03-15 | Lonza Ag | Azol/amin oxid holzschutzmittel und fungizide |
| JP2001100436A (ja) * | 1999-09-28 | 2001-04-13 | Mitsubishi Gas Chem Co Inc | レジスト剥離液組成物 |
| ATE262505T1 (de) * | 2000-09-21 | 2004-04-15 | Ciba Sc Holding Ag | Neue diquaternäre ammoniumverbindungen |
| JP4172149B2 (ja) * | 2000-09-22 | 2008-10-29 | 富士ゼロックス株式会社 | 低電位電着用電着液及びこれを用いた電着方法 |
| US20030054193A1 (en) * | 2001-02-05 | 2003-03-20 | Mccollum Gregory J. | Photodegradation-resistant electrodepositable coating compositions and processes related thereto |
| TWI318100B (en) * | 2001-03-01 | 2009-12-11 | Lonza Ag | Preservative blends containing quaternary ammonium compounds |
| US20020197468A1 (en) * | 2001-05-04 | 2002-12-26 | Wayne Pigment Corporation | Corrosion inhibitor composition applicable for aluminum and steel protection and procedure |
| JP2002332447A (ja) * | 2001-05-09 | 2002-11-22 | Kansai Paint Co Ltd | 水性表面処理組成物および亜鉛系メッキ鋼材の表面処理方法 |
| US6727387B2 (en) * | 2001-05-16 | 2004-04-27 | Rohm And Haas Company | Quaternary ammonium salts having a tertiary alkyl group |
| JP2002348538A (ja) * | 2001-05-23 | 2002-12-04 | Dokai Chemical Industries Co Ltd | 鱗片状シリカ粒子を含有する塗料用硬化性組成物及び硬化塗膜 |
| JP2002363498A (ja) * | 2001-05-31 | 2002-12-18 | Sanyo Chem Ind Ltd | カチオン電着塗料用防腐剤 |
| UA76478C2 (uk) | 2001-07-09 | 2006-08-15 | Лонза Інк. | Способи одержання алкілкарбонатів четвертинного амонію in situ |
| JP2003113346A (ja) * | 2001-10-03 | 2003-04-18 | Nippan Kenkyujo Co Ltd | 防錆塗料、防錆膜を有する亜鉛メッキ鋼鈑、およびその製造方法 |
| JP3669973B2 (ja) * | 2002-06-10 | 2005-07-13 | Ｎｏｋ株式会社 | エンジン用シリンダヘッドガスケット素材 |
| US20050012077A1 (en) * | 2003-05-28 | 2005-01-20 | Lonza Inc. | Quaternary ammonium carbonates and bicarbonates as anticorrosive agents |
| US20060261312A1 (en) | 2003-05-28 | 2006-11-23 | Lonza Inc. | Quaternary ammonium salts containing non-halogen anions as anticorrosive agents |
| US20050003978A1 (en) * | 2003-05-28 | 2005-01-06 | Lonza Inc. | Quaternary ammonium carbonates and bicarbonates as anticorrosive agents |
| US20050123437A1 (en) * | 2003-12-03 | 2005-06-09 | Cassidy Juanita M. | Methods and compositions for inhibiting metal corrosion |
| MY148568A (en) * | 2004-12-09 | 2013-04-30 | Lonza Ag | Quaternary ammonium salts as a conversion coating or coating enhancement |
| US7842127B2 (en) * | 2006-12-19 | 2010-11-30 | Nalco Company | Corrosion inhibitor composition comprising a built-in intensifier |
| US20090004287A1 (en) * | 2007-01-31 | 2009-01-01 | Joseph Kimler | Disinfectant formulations containing quaternary ammonium compounds and hydrogen peroxide |
| US20090203645A1 (en) * | 2008-02-12 | 2009-08-13 | Larry Kent Hall | Broad Spectrum Disinfecting and Sterilizing Composition |
| US20090324820A1 (en) * | 2008-06-30 | 2009-12-31 | Chartier Douglas M | Systems, Methods, and Compositions for the Inhibition of Corrosion of Metallic Surfaces |
-
2005
- 2005-12-08 MY MYPI20055750A patent/MY148568A/en unknown
- 2005-12-09 BR BRPI0518858-0A patent/BRPI0518858A2/pt not_active Application Discontinuation
- 2005-12-09 KR KR1020077015653A patent/KR101350720B1/ko not_active IP Right Cessation
- 2005-12-09 TW TW094143497A patent/TWI386519B/zh not_active IP Right Cessation
- 2005-12-09 IN IN7328DEN2014 patent/IN2014DN07328A/en unknown
- 2005-12-09 NZ NZ555940A patent/NZ555940A/en not_active IP Right Cessation
- 2005-12-09 WO PCT/EP2005/013191 patent/WO2006061230A1/en active Application Filing
- 2005-12-09 CA CA2589980A patent/CA2589980C/en not_active Expired - Fee Related
- 2005-12-09 AR ARP050105172A patent/AR051707A1/es not_active Application Discontinuation
- 2005-12-09 TW TW101139664A patent/TWI454541B/zh not_active IP Right Cessation
- 2005-12-09 JP JP2007544824A patent/JP5477835B2/ja not_active Expired - Fee Related
- 2005-12-09 MX MX2007006915A patent/MX2007006915A/es active IP Right Grant
- 2005-12-09 AU AU2005313503A patent/AU2005313503B2/en not_active Ceased
- 2005-12-09 CN CN201110061366.6A patent/CN102206437B/zh not_active Expired - Fee Related
- 2005-12-09 CN CN2005800465008A patent/CN101098986B/zh not_active Expired - Fee Related
- 2005-12-09 EA EA200701162A patent/EA014610B1/ru not_active IP Right Cessation
- 2005-12-09 KR KR1020137003942A patent/KR20130027055A/ko not_active Application Discontinuation
- 2005-12-09 EP EP05822997A patent/EP1825023A1/en not_active Withdrawn
- 2005-12-09 US US11/299,323 patent/US20060151071A1/en not_active Abandoned
-
2007
- 2007-06-15 NO NO20073050A patent/NO20073050L/no not_active Application Discontinuation
- 2007-06-27 ZA ZA200705191A patent/ZA200705191B/en unknown
-
2008
- 2008-07-02 HK HK08107324.4A patent/HK1116839A1/xx not_active IP Right Cessation
-
2010
- 2010-11-23 US US12/952,690 patent/US8337640B2/en not_active Expired - Fee Related
-
2011
- 2011-11-02 JP JP2011241420A patent/JP5684092B2/ja not_active Expired - Fee Related
-
2012
- 2012-02-24 HK HK12101917.4A patent/HK1161285A1/zh not_active IP Right Cessation
- 2012-12-24 US US13/726,495 patent/US8580154B2/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11230768B2 (en) | 2015-04-15 | 2022-01-25 | Henkel Ag & Co. Kgaa | Polymer-containing pre-rinse prior to a conversion treatment |
| CN107683349A (zh) * | 2015-05-29 | 2018-02-09 | 汉高股份有限及两合公司 | 用于在转化处理之前进行调理的包含季胺的预漂洗 |
| CN107683349B (zh) * | 2015-05-29 | 2020-05-26 | 汉高股份有限及两合公司 | 用于在转化处理之前进行调理的包含季胺的预漂洗 |
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101098986B (zh) | 作为转化型涂层或作为漆中防腐蚀添加剂的季铵盐 | |
| JP2008523244A6 (ja) | 化成被覆または塗料中の防食添加剤としての第四級アンモニウム塩 | |
| CN101103139B (zh) | 稳定的非铬薄膜有机钝化剂 | |
| AU780777B2 (en) | Chromium-free anticorrosive and anticorrosive method | |
| CN101611170A (zh) | 稳定的薄膜有机钝化剂 | |
| AU2009309946B2 (en) | Paint adhesion by polyvinyl amines in acidic aqueous corrosion protection product containing polymers | |
| CN103038391A (zh) | 无机类无铬金属表面处理剂 | |
| CN103619757B (zh) | 基于锆的涂布组合物及涂布方法 | |
| CN103665981A (zh) | 一种丙烯酸乳液防锈涂料 | |
| CN104911615A (zh) | 镀锌板去除氧化斑清洗剂及其制备方法与用途 | |
| CN107892856A (zh) | 一种水性全能带锈防锈漆及其制备方法 | |
| CN115651436B (zh) | 一种维保用水性锈蚀转化防腐涂料及其制备方法 | |
| JPS62952B2 (zh) | ||
| JP2021134228A (ja) | 水性有機ジンクリッチ塗料組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 1116839 Country of ref document: HK |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: GR Ref document number: 1116839 Country of ref document: HK |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120530 Termination date: 20171209 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |